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Melamine Formaldehyde

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0% found this document useful (0 votes)
26 views8 pages

Melamine Formaldehyde

Uploaded by

Payam Parvasi
Copyright
© © All Rights Reserved
We take content rights seriously. If you suspect this is your content, claim it here.
Available Formats
Download as PDF, TXT or read online on Scribd
You are on page 1/ 8

SAFETY DATA SHEET

SDS No. 940C


Revision Date: October 26, 2023 Version: 4.0

GHS Compliant

Section 1 - Identification of the substance/mixture and of the company/undertaking


1.1 Product Identifier
Trade Name: duoMatrix® G C2, FORTON® MG MF-415, Melamine Formaldehyde Resin

1.2 Relevant identified uses of the substance or mixture and uses advised against
General Use: Casting Resin
Restrictions on Use: None known

1.3 Details of the supplier of the safety data sheet:


Company: Smooth-On, Inc.,
5600 Lower Macungie Rd., Macungie, PA 18062

Telephone: Phone (610) 252-5800 FAX (610) 252-6200

E-mail address: Visit our website at www.smooth-on.com or email


www.sds@smooth-on.com

1.4 Emergency Contact: Chem-Tel Domestic: 800-255-3924 International: 813-248-0585

Section 2 – Hazard(s) Identification


2.1 Classification of the substance or mixture:

GHS Classification in accordance with 29 CFR 1910.1200 (OSHA HCS)

H315 Skin irritation – Category 2


H317 Skin sensitization – Category 1
H350 Carcinogenicity – Category 1A

2.2 GHS Label elements, including precautionary statements

Pictogram(s):
Signal word: Warning

Health Hazards
H315 Causes skin irritation
H317 May cause an allergic skin reaction
H350 May cause cancer.
General Precautions
P101 If medical advice is needed, have product container or label at hand.
P102 Keep out of reach of children.
P103 Read label before use.
Prevention Precautions
P201 Obtain special instructions before use.
P202 Do not handle until all safety precautions have been read and understood.
P264 Wash skin thoroughly after handling.

Page 1 of 8
SDS No. 940C
P280 Wear protective gloves/protective clothing/eye protection/face protection.
Response Precautions
P308 + P313 IF exposed or concerned: Get medical advice/ attention.
P332 + P313 If skin irritation occurs: Get medical advice/attention.
Storage Precautions
P405 Store locked up.
Disposal Precautions
P501 Dispose of contents/container according to local, state and federal laws.

2.3 Hazards not otherwise classified (HNOC) or not covered by GHS – none known

Section 3 - Composition / Information on Ingredients


3.1 Substances/Mixtures
The following ingredients are hazardous according to Regulation 2012 OSHA Hazard
Communication Standard: 29 CFR 1910.1200:

Chemical name CAS-No. Concentration

Melamine formaldehyde resin 9003-08-1 >99%


Formaldehyde 50-00-0 <1.0%

Section 4 - First Aid Measures


4.1 Description of first aid measures

Inhalation
Remove source(s) of contamination and move victim to fresh air. If breathing has stopped, give
artificial respiration, then oxygen if needed. Contact physician immediately.

Eye Contact
Flush eyes with plenty of water occasionally lifting the upper and lower eyelids. Check and remove
any contact lenses if safe to do so. Continue to rinse for at least 15 minutes. If irritation develops,
seek medical attention.

Skin Contact
In case of skin contact, wash thoroughly with soap and water. Continue to rinse for at least 15
minutes. Chemical burns must be treated promptly by a physician.

Ingestion
Do not induce vomiting unless instructed by a physician. Never give anything by mouth to an
unconscious person. If material has been swallowed and the exposed person is conscious, give
small quantities of water to drink. Stop if the exposed person feels sick as vomiting may be
dangerous. if vomiting occurs, the head should be kept low so that vomit does not enter the lungs.

4.2 Most important symptoms and effects, both acute and delayed
In case of inhalation of decomposition products in a fire, symptoms may be delayed. The exposed
person may need to be kept under medical surveillance for 48 hours.

4.3 Indication of any immediate medical attention and specific treatment needed, if necessary.

Page 2 of 8
SDS No. 940C

Section 5 - Fire-Fighting Measures


5.1 Extinguishing Media
Water Fog, Dry Chemical, and Carbon Dioxide Foam

5.2 Special hazards arising from the substance or mixture


In a fire or if heated, a pressure increase will occur, and the container may burst.

5.3 Advice for firefighters


Use water spray to cool fire-exposed surfaces and to protect personnel. Shut off “fuel” to fire. If a
leak or spill has not ignited, use water spray to disperse the vapors. Either allow fire to burn under
controlled conditions or extinguish with foam or dry chemical. Try to cover liquid spills with foam.
Because fire may produce toxic thermal decomposition products, wear a self-contained breathing
apparatus (SCBA) with a full-face piece operated in pressure demand or positive-pressure mode.

Section 6 - Accidental Release Measures


6.1 Personal precautions, protective equipment and emergency procedures
Only properly protected personnel should remain in the spill area; dike and contain spill. Stop or
reduce discharge if it can be done safely.

6.2 Environmental precautions


Stop spill/release if it can be done safely. Prevent spilled material from entering sewers, storm
drains or unauthorized drainage systems and natural waterways by using sand, earth, or other
appropriate barriers. No special environmental precautions required.

6.3 Methods and material for containment and cleaning up


Put on appropriate protective gear including NIOSH/MSHA approved self-contained breathing
apparatus, rubber boots and heavy rubber gloves. Dike and contain spill; absorb or scrape up
excess into suitable container for disposal; wash area with dilute ammonia solution. Stop or
reduce discharge if it can be done safely. Follow applicable OSHA regulations (29 CFR
1910.120) for disposal.

6.4 Reference to other sections


See Section 3 for list of Hazardous Ingredients; Sections 8 for Exposure Controls; and Section 13
for Disposal.

Section 7 - Handling and Storage


7.1 Precautions for safe handling
Use good general housekeeping procedures. Wash hands after use. Do not get in eyes, on skin or
on clothing. Do not breathe vapors or mists. Use good personal hygiene practices.

7.2 Conditions for safe storage, including any incompatibilities


Keep container(s) tightly closed and properly labeled. Store in cool, dry, well ventilated place away
from heat, direct sunlight, strong oxidizers and any incompatibles. Store in approved containers
and protect against physical damage. Keep containers securely sealed when not in use. Indoor
storage should meet local standards and appropriate fire codes. Containers that have been
opened must be carefully resealed to prevent leakage. Empty containers retain residue and may
be dangerous. Avoid water contamination.

7.3 Specific end use(s)


These precautions are for room temperature handling. Other uses including elevated temperatures
or aerosol/spray applications may require added precautions.

Page 3 of 8
SDS No. 940C

Section 8 - Exposure Controls / Personal Protection


8.1 Control parameters
Component CAS ACGIH Exposure Limits Weight
Number TWA OSHA PEL Percent
(%)
Melamine Formaldehyde 9003-08-1 10mg/m3 total 15mg/m3 total >99
Resin dust dust
5mg/m3 respir 5mg/m3 respir.
dust dust
Formaldehyde 50-00-0 1 ppm 0.75 ppm <1.0

8.2 Exposure controls

Respiratory Protection
Respiratory protection is not normally required when using this product with adequate local
exhaust ventilation. Where risk assessment shows air-purifying respirators are appropriate, follow
OSHA respirator regulations 29 CFR 1910.134 and European Standards EN 141, 143 and 371;
wear an MSHA/NIOSH or European Standards EN 141, 143 and 371 approved respirators
equipped with appropriate filter cartridges as a backup to engineering controls.

Hand Protection
Wear any liquid-tight gloves such as butyl rubber, neoprene or PVC.

Eye Protection
Safety glasses with side shields per OSHA eye- and face-protection regulations 29 CFR 1910.133
and European Standard EN166. Contact lenses are not eye protective devices. Appropriate eye
protection must be worn instead of, or in conjunction with contact lenses.

Other Protective Clothing/Equipment


Additional protective clothing or equipment is not normally required. Provide eye bath and safety
shower.

Comments
Never eat, drink, or smoke in work areas. Practice good personal hygiene after using
this material, especially before eating, drinking, smoking, using the toilet, or applying cosmetics.
Wash thoroughly after handling.

Section 9 - Physical and Chemical Properties


9.1 Information on basic physical and chemical properties

Appearance: off white powder Vapor pressure: None (Polymeric Resin)


Odor: slight irritating Vapor density (Air=1): >1
pH: (50% in water) 8 - 10 Evaporation rate: 0.65
Flash Point: >200 °F Solubility in water: slightly soluble
Specific Gravity
Melting / freezing point: 221 – 239 °F (H2O=1, at 4 °C): No data
Low / high boiling point: No data Relative density: No data
Upper flammability limits: No data Decomposition temperature: No data
Lower flammability limits: f.p. at or above 200 °F Viscosity: powder

Page 4 of 8
SDS No. 940C

Section 10 - Stability and Reactivity


10.1 Reactivity
No hazardous reactions if stored and handled as prescribed/indicated., No corrosive effect on
metal. Not fire propagating.

10.2 Chemical stability


These products are stable at room temperature in closed containers under normal storage and
handling conditions.

10.3 Possibility of hazardous reactions


Hazardous polymerization cannot occur
.
10.4 Conditions to avoid
None known

10.5 Incompatible materials


Strong bases and acids

10.6 Hazardous decomposition products


Thermal oxidative decomposition can produce carbon oxides, gasses/vapors, and traces of
incompletely burned carbon compounds.

Section 11- Toxicological Information


11.1 Information on toxicological effects

Acute Toxicity
No data available

Skin Corrosion/Irritation
No data available

Serious Eye Damage/Irritation


No data available

Respiratory/Skin Sensitization
No data available

Germ Cell Mutagenicity


No data available

Carcinogenicity
No component of these products present at levels greater than or equal to 0.1% is identified as a
carcinogen or potential carcinogen by IARC, ACGIH or NTP.

Reproductive Toxicity
No data available

Specific Target Organ Toxicity – Single Exposure


No data available

Page 5 of 8
SDS No. 940C
Specific Target Organ Toxicity – Repeated Exposure
No data available

Aspiration Hazard
No data available

Potential Health Effects – Miscellaneous


No data available

Section 12 - Ecological Information


12.1 Toxicity
No data available

12.2 Persistence and Degradability


No data available

12.3 Bioaccumulative Potential


No data available

12.4 Mobility in Soil


No data available

12.5 Results of PBT and vPvB assessment


No data available

12.6 Other Adverse Effects


No data available

Section 13 - Disposal Considerations


13.1 Waste treatment methods
Under Resource Conservation and Recovery Act (RCRA) it is the responsibility of the user of the
product to determine at the time of disposal whether the product meets RCRA criteria for
hazardous waste as defined in 40 CFR Part 261. Waste management should be in full compliance
with federal, state and local laws. Regulations may vary in various locations. Waste
characterizations and compliance with applicable laws are the responsibility solely of the waste
generator.

Container disposal
Steel drums must be emptied and can be sent to a licensed drum reconditioner for reuse, a scrap
metal dealer or an approved landfill. Do not attempt to refill or clean containers since residue is
difficult to remove. Under no circumstances should empty drums be burned or cut open with gas or
electric torch as toxic decomposition products may be liberated. Do not reuse empty containers.

Section 14 - Transport Information


Not regulated by DOT / IMDG / IATA

Section 15 - Regulatory Information


15.1 Safety health and environmental regulations/legislation specific for the
substance or mixture:

Page 6 of 8
SDS No. 940C
REACH: Regulation (EC) No 1907/2006 of The European Parliament and of The Council of
December 2006 (including amendments and corrigenda as of June 2023)
This product complies with REACH or is not subject to regulation under REACH. The product does
not contain an ingredient listed on either the Candidate List or Authorization List for Substances of
Very High Concern (SVHC).

TSCA Inventory Status (40 CFR710)


All components of this formulation are listed in the TSCA Inventory. No component of this
formulation has been determined to be subject to manufacturing or use restrictions under the
Significant New Use Rules (SNURs).

EPA Regulations:
RCRA Hazardous Waste Number: Not listed (40 CFR 261.33)

CERCLA Hazardous Substance (40 CFR 302.4) listed specific per RCRA, Sec. 3001;
CWA,

Sec. 311 (b)(4); CWA, Sec. 307(a), CAA, Sec. 112


Chemical Name RQ % Reportable Component
Formaldehyde 100 lbs. <1.0

SARA Toxic Chemical (40 CFR 372.65):


Chemical Name CAS # % by Weight
Formaldehyde 50-00-0 <1.0

SARA EHS (Extremely Hazardous Substance) (40 CFR 355):


Chemical Name TPQ % Reportable Component
Formaldehyde 500 lbs. <1.0

This product contains the following chemicals that are subject to release reporting
requirements under section 313 of SARA Title III.
Chemical Name CAS # % by Weight
Formaldehyde 50-00-0 <1.0

California Proposition 65
This product does not intentionally contain any chemicals known to the state of California to cause
cancer, birth defects or other reproductive harm.

15.2 Chemical safety assessment


No chemical safety assessment has been carried out for this substance/mixture by the supplier.

16 - Other Information

1
HMIS
1 0
H 1
F 1 0
R 0
NFPA
Revision Date: October 26, 2023 Version: 4.0

Page 7 of 8
SDS No. 940C

Abbreviations and acronyms


ACGIH-American Conference of Governmental Industrial Hygienists; ANSI-American National Standards
Institute; Canadian TDG-Canadian Transportation of Dangerous Goods; CAS-Chemical Abstract Service;
Chemtrec-Chemical Transportation Emergency Center (US); CHIP-Chemical Hazard Information and
Packaging; DSL-Domestic Substances List; EC-Equivalent Concentration; EH40 (UK)-HSE Guidance
Note EH40 Occupational Exposure Limits; EPCRA-Emergency Planning and Community Right-To-Know
Act; ESL-Effects screening levels; GHS-Globally Harmonized System of Classification and Labelling of
Chemicals; HMIS-Hazardous Material Information Service; IATA-International Air Transport Association;
IMDG-International Maritime Dangerous Goods Code; LC-Lethal Concentration; LD-Lethal Dose; NFPA-
National Fire Protection Association; OEL-Occupational Exposure Limit; OSHA-Occupational Safety and
Health Administration, US Dept. of Labor; PEL-Permissible Exposure Limit; SARA (Title III)-Superfund
Amendments and Reauthorization Act; SARA 313-Superfund Amendments and Reauthorization Act,
Section 313; SCBA-Self-Contained Breathing Apparatus; STEL-Short Term Exposure Limit; TCEQ-Texas
Commission on Environmental Quality; TLV-Threshold Limit Value; TSCA-Toxic Substances Control Act
Public Law 94-469; TWA-Time Weighted Value; US DOT-US Department of Transportation; WHMIS-
Workplace Hazardous Materials Information System.

Disclaimer
The information contained in this Safety Data Sheet (SDS) is considered accurate as of the version
date. However, no warranty is expressed or implied regarding the accuracy of the data. Since the use of
this product is not within the control of Smooth-On Inc., it is the user's obligation to determine the suitability
of the product for its intended application and assumes all risk and liability for its safe use.

This SDS is prepared to comply with the Globally Harmonized System of Classification and Labelling of
Chemicals (GHS) as prescribed by the United States (US) Occupational Safety and Health Administration
(OSHA) Hazard Communication Standard (29 CFR 1910.1200), the Canadian Workplace Hazardous
Materials Information System (WHMIS), and European Union Regulation (EC) No 1907/2006 of the
European Parliament and of the Council of 18 December 2006 (REACH).

Classifications of the chemical in accordance with 29 CFR 1910.1200, signal word, hazard and
precautionary statement(s), symbol(s) and other information are based on listed concentration of each
hazardous ingredient. Unlisted ingredients are not "hazardous" per the OSHA Hazard Communication
Standard (29 CFR 1910.1200), WHMIS and EC No 1907/2006 and are considered trade secrets under
US Federal Law (29 CFR and 40 CFR), Canadian Law (Health Canada Legislation), and European Union
Directives.

Page 8 of 8

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