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Chemistry MCQ 12 - D F Block

class 12 d and f block chemistry

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28 views2 pages

Chemistry MCQ 12 - D F Block

class 12 d and f block chemistry

Uploaded by

mr782185
Copyright
© © All Rights Reserved
We take content rights seriously. If you suspect this is your content, claim it here.
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D and F-BLOCK ELEMENTS

1) The electron configuration of element with Z = 24 is


(a) 3d44s2 (b) 3d54s1 (c) 3d64s1 (d) none
2) The element showing oxidation state +7 is
(a) Cr (b) Mn (c) Co (d) V
3) The pair of elements which show + 1 oxidation state
(a) Cr & Zn (b) Fe & Zn (c) Cr & Cu (d) Cu & Zn
4) d-block elements form coloured ions because
(a) They absorb some energy for d- s transition
(b) They absorb some energy for p-d transition
(c) They absorb some energy for d-d transition
(d) They do not absorb any energy
5) Cuprous ion is colourless while cupric ion is coloured because

JI
(a) cuprous ion has incomplete d-orbital and cupric ion has a complete d-orbital
(b) both have half filled p and d-orbitals
(c) cuprous ion has a complete d-orbital and cupric ion has an incomplete d- orbital
(d) both have unpaired electrons in the d-orbitals
6) A transition metal ion has one electron in d-orbital. Its solution
(a) is colourless (b) has a characteristic colour
(c) appearance of colour is temporary (d) changes colour with time
LA
7) Which of the following ions are coloured?
(a)Cu+ (b) Zn2+ (c) Ti4+ (d)V3+
8) Which of the following d-block element would be paramagnetic?
(a) Aluminium (b) Magnesium (c) Copper (d) Sodium
9) Titanium shows magnetic moment of 1.73 BM in its compound. What is the oxidation
number of Ti in the compound?
(a) + 1 (b) + 4 (c) + 3 (d) + 2
10) Paramagnetism is a property of
(a) Completely filled electronic sub-shells
A
(b) unpaired electrons
(c) non-transition elements
(d) elements and not of compounds
11) A metal ion has a spin magnetic moment of 3.87 B.M. The number of unpaired electrons
present is
B

(a) 1 (b) 2 (c) 3 (d) 4


12) The expression used to calculate the magnetic moment is
(a)   n(n  2) (b)   ( n  2) (c)   n(n  1) (d)   n(n  2)
13) Which one of the following is diamagnetic?
(a) Cu2+ (b)Zn2+ (c) Ni2+ (d) Co2+
14) The highest magnetic moment is shown by the transition metal ion with the configuration
(a) 3d5 (b) 3d2 (c) 3d9 (d) Cu+
15) Which of the following ion has least magnetic moment?
(a)Cu2+ (b) Ni2+ (c) Co3+ (d) Fe2+

CLASSES BY ANKUR SIR @7983744732


16) Transition elements form a large number of complexes compound because they have
(a) small atomic size (b)small atomic size and high positive charge
(c) high positive charge (d) large atomic size and high negative charge
17) The ability of transition metals to form complexes is mainly due to
(a) they are metals (b) ns orbitals are vacant
(c) availability of d- orbitals (d) presence of active centres
18) Transition elements are generally used as catalysts because
(a) they form different intermediate compounds
(b) they are heavy metals
(c) they are paramagnetic
(d) they possess high melting points
19) Transition elements form alloys readily because they have
(a) similar properties
(b) same outer electronic configurations

JI
(c) similar crystal structure
(d) same incompletely filled d-orbitals
20) In dichromate dianion
(a) 4 Cr–O bonds are equivalent
(b) 6 Cr–O bonds are equivalent
(c) all Cr–O bonds are equivalent
(d) all Cr–O bonds are non-equivalent
LA
21) In chromite ore, the oxidation number of iron and chromium are respectively:
(a) +3, +2 (b) +3, +6 (c) +2, +6 (d) +2, +3
22) Identify the product and its colour when MnO2 is fused with solid KOH in the presence of
oxygen:
(a) KMnO4, purple (b) K2MnO4, dark green
(c) MnOcolour less, (d) MnO2, black
23) Lanthanoid contraction is caused due to
(a) the appreciable shielding on outer electrons by 4f-electrons from the nuclear charge
(b) the appreciable shielding on outer electrons by 5d-electrons from the nuclear charge
A
(c) the same effective nuclear charge from Ce to Lu
(d)the imperfect shielding on outer electrons by 4f-electrons from the nuclear charge
24) The lanthanoid contraction is responsible for the fact that
(a) Zr and Zn have the same oxidation state
(b) Zr and Hf have about the same radius
B

(c) Zr and Nb have similar oxidation state


(d) Zr and Y have the same radius
25) The actinoids exhibit more number of oxidation states in general than the lanthanoids.
This is because
(a) the 5f-orbitals are more buried than the 4f-orbitals
(b) there is a similarity between 4f and 5f-orbitals in their angular part of the wave function
(c) the actinoids are more reactive than the lanthanoids
(d)the 5f-orbitals extent farther from the nucleus than the 4f-orbitals
(1) (b) (2) (b) (3) (c) (4) (c) (5) (c) (6) (b) (7) (d) (8) (c) (9) (c) (10) (b)
(11) (c) (12) (a) (13) (b) (14) (a) (15) (a) (16) (b) (17) (c) (18) (a) (19) (c) (20) (b)
(21) (d) (22) (b) (23) (d) (24) (b) (25) (d)

CLASSES BY ANKUR SIR @7983744732

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