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Alcohol 2081

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Alcohol 2081

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© © All Rights Reserved
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Alcohol

1. Starting from CH3MgI, how would you prepare


i. Ethanol
ii. Propan-2-ol
iii.2-methyl propan-2-ol
Give the chemical test to distinguish them
a. Why are lower member of alcohol highly soluble in water?
b. Convert Propan-1-ol to Propan-2-ol
2. a. Write the possible isomers of alcohol having molecular formula C4H10O
using Victor Meyer’s method
b. A monohydric alcohol reacts with PBr3 to give B. The compound B, if heated with
alc. KOH gives C.C on ozonolysis produces ethanal and methanal as major products.
The
compound A response to iodoform test. Identify A, B and C with reactions involved.
What happens when B is heated with sodium in presence of dry ether.
3. Consider a reaction +
PBr3 KCN H2O/H
A B C D
Compound A is primary alcohol which gives positive iodoform test. Identify organic
compound A,B,C,D and E.
i. What happens when ethyl alcohol is treated with acetic acid in presence of Conc.H2SO4
ii. What happens when ethanol is heated with conc.H2SO4
4. a. Consider the following reaction
PCl5 Mg/ether CO2 H2O/H+
A B C D E

Compound A is primary alcohol which on oxidation gives ethanol. Identify A, B, C, D and


E.
b. Convert Compound A into methanol and ethyne.
c. What are the oxidation products of primary, secondary and tertiary alcohol of mol.
formula C4H10O.
5. Give an example each of
a. Oxo process
b. Dehydration of alcohol
c. Fermentation of sugar
d. D. Hydroboration
e. Baeyer’s test
f. Iodoform test
6. Consider a reaction
PCl5 KCN H2O/H+
A B C D

Compound A is secondary alcohol having 3 C-atom and gives positive iodoform test.
Identify A, B, C and D with related reactions.
7. Consider a reaction
PBr3 KCN H2O/H+
A B C D
Compound A is primary alcohol which can give positive iodoform test. Identify A, B ,C and
D with related reaction.
8. Consider a reaction
PCl5 AgCN LiAlH4
A B C D
Compound A is secondary alcohol having 3 carbon atoms which can give positive iodoform
test. Identify A, B, C and D with related reactions.
9. i. Define fermentation. Write the reaction involved in fermentation of molasses from
alcohol.
ii. Prepare 1˚,2˚, and 3˚ alcohol from Grignard reagent.
10. An organic compound A reacts with SOCl2 to give B which on reduction in presence of
H2/Ni give Hydrocarbon containing three carbons. If A is primary alcohol which gives
iodoform test, identify A, B and C with reactions. What happens when B is reacted Na in dry
ether?
11. Convert
i. Ethanol to propanol
ii. Propan-2-ol to Propan-1ol and vice versa
iii.Ethane to ethanol
12. Consider a reaction
SOCl2 NH3 Br2/KOH NaNO2/HCl
A B C D E

The Compound E is primary alcohol which give positive iodoform test. Identify A, B, C, D
and E
13. The organic compound C3H8O gives isomeric alcohol A and B
i. Identify the isomer A and B and draw their structural formula
ii. Starting from isomer A, how would you obtain nitrolic acid
iii.Convert isomer A into B (NEB -2080)

14. Write a structural formula of 3° alcohol of C4H10O. How is this alcohol prepared by using
Grignard reagent.
15. Name any suitable secondary alcohol that gives iodoform test and write the test reaction.
16. What is the laboratory test of ethanol?
17. What happens when the product obtained by dehydrogenation of ethanol is allowed to react
with Tollen’s reagent?
18. Identify the organic compounds A, B, C, and D.
PCl3 Alc. KOH Ozonolysis
(CH3)2CHOH A B C+D
19. An organic compound M gives H2 gas with sodium metal. On treatment with alkaline iodine
gives yellow ppt and on oxidation with CeO2/H+ forms an aldehyde (C2H4O). Name the
compound M and write reactions involved. What happens when M is heated with P2O5?
20. An aliphatic compound A reacts with SOCL2 to give B. B on dehydrohalogenation yields C.
The compound C on ozonolysis gives mixture of ethanal and methanal. If A is an alcohol
which response iodoform test. Identify A, B, and C. What product would you expect when
compound B is heated with H2/Ni?
21. How is ethanol prepared from
i. Ethyne
ii. 1,1-dichloroethane.
Convert ethanol into propanone? What is the laboratory test of carbonyl compounds?
22. Write down the Isomeric alcohols of C 3H8O and IUPAC name. Explain Victor-Meyer’s
method to distinguish them.
23. Write down the isomers of monohydric alcohols from C 3H8O and give their IUPAC name.
What chemical test would you apply to distinguish them? Write the chemical reaction for it.
How would you convert the one isomer into another and vice-versa?
24. Consider the reaction
PBr3 KCN H2O/H+ CH3OH
A B C D E
Conc. H2SO4
Compound A is the primary alcohol which gives iodoform test. Identify compounds A, B, C,
D, and E with suitable reactions.
25. Write down the oxidation of primary, secondary, and tertiary alcohols? How would you
convert propan-1-ol into propan-2-ol?
26. Starting from methyl-magnesium bromide (CH3MgBr), how would you prepare
i. Ethanol
ii. Propan-2-ol
iii.2-methylpropan-2-ol
iv. Ethanoic acid
v. Methane
27. What is meant by Grignard’s reagent? How could you convert a primary alcohol to
Grignard’s reagent? By using a suitable Grignard’s reagent how would you synthesize.
i. 2-methylpropan-2-ol
ii. Ethanoic acid

Short Questions
1. Write a structural formula of 3° alcohol of C4H10O. How is this alcohol prepared by using
Grignard reagent.
2. Name any suitable secondary alcohol that gives iodoform test and write the test reaction.
3. What is the laboratory test of ethanol?
4. What happens when the product obtained by dehydrogenation of ethanol is allowed to react
with Tollen’s reagent?
5. Identify the organic compounds A, B, C, and D.
PCl3 Alc. KOH Ozonolysis
(CH3)2CHOH A B C+D

6. An organic compound M gives H2 gas with sodium metal. On treatment with alkaline iodine
gives yellow ppt and on oxidation with CeO 2/H+ forms an aldehyde (C2H4O). Name the
compound M and write reactions involved. What happens when M is heated with P2O5?
7. An aliphatic compound A reacts with SOCl2 to give B. B on dehydrohalogenation yields C.
The compound C on ozonolysis gives mixture of ethanal and methanal. If A is an alcohol
which response iodoform test. Identify A, B, and C. What product would you expect when
compound B is heated with H2/Ni?
8. How is ethanol prepared from
i. Ethyne
ii. 1,1-dichloroethane.

Convert ethanol into propanone? What is the laboratory test of carbonyl compounds?

9. Write down the Isomeric alcohols of C3H8O and IUPAC name. Explain Victor-Meyer’s
method to distinguish them.
10. Write down the isomers of monohydric alcohols from C 3H8O and give their IUPAC name.
What chemical test would you apply to distinguish them? Write the chemical reaction for it.
How would you convert the one isomer into another and vice-versa?
11. Consider the reaction
PBr3 KCN H2O/H+ CH3OH
A B C D E
Conc. H2SO4
Compound A is the primary alcohol which gives iodoform test. Identify compounds A, B, C,
D, and E with suitable reactions.
12. Write down the oxidation of primary, secondary, and tertiary alcohols? How would you
convert propan-1-ol into propan-2-ol?
13. Starting from methyl-magnesium bromide (CH3MgBr), how would you prepare
i. Ethanol
ii. Propan-2-ol
iii. 2-methylpropan-2-ol
iv. Ethanoic acid
v. Methane
14. What is meant by Grignard’s reagent? How could you convert a primary alcohol to
Grignard’s reagent? By using a suitable Grignard’s reagent how would you synthesize.
i. 2-methylpropan-2-ol
ii. Ethanoic acid
15. Write a structural formula of 3° alcohol of C4H10O. How is this alcohol prepared by using
Grignard reagent.
16. Name any suitable secondary alcohol that gives iodoform test and write the test reaction.
17. What is the laboratory test of ethanol?
18. What happens when the product obtained by dehydrogenation of ethanol is allowed to react
with Tollen’s reagent?
19. Identify the organic compounds A, B, C, and D.
PCl3 Alc. KOH Ozonolysis
(CH3)2CHOH A B C+D

20. An organic compound M gives H2 gas with sodium metal. On treatment with alkaline iodine
gives yellow ppt and on oxidation with CeO 2/H+ forms an aldehyde (C2H4O). Name the
compound M and write reactions involved. What happens when M is heated with P2O5?
21. An aliphatic compound A reacts with SOCL 2 to give B. B on dehydrohalogenation yields C.
The compound C on ozonolysis gives mixture of ethanal and methanal. If A is an alcohol
which response iodoform test. Identify A, B, and C. What product would you expect when
compound B is heated with H2/Ni?
22. How is ethanol prepared from
iii. Ethyne
iv. 1,1-dichloroethane.
Convert ethanol into propanone? What is the laboratory test of carbonyl compounds?
23. Write down the Isomeric alcohols of C3H8O and IUPAC name. Explain Victor-Meyer’s
method to distinguish them.
24. Write down the isomers of monohydric alcohols from C 3H8O and give their IUPAC name.
What chemical test would you apply to distinguish them? Write the chemical reaction for it.
How would you convert the one isomer into another and vice-versa?
25. Consider the reaction
PBr3 KCN H2O/H+ CH3OH
A B C D E
Conc. H2SO4
Compound A is the primary alcohol which gives iodoform test. Identify compounds A, B, C,
D, and E with suitable reactions.
26. Write down the oxidation of primary, secondary, and tertiary alcohols? How would you
convert propan-1-ol into propan-2-ol?
27. Starting from methyl-magnesium bromide (CH3MgBr), how would you prepare
i. Ethanol
ii. Propan-2-ol
iii. 2-methylpropan-2-ol
iv. Ethanoic acid
v. Methane

28. What is meant by Grignard’s reagent? How could you convert a primary alcohol to
Grignard’s reagent? By using a suitable Grignard’s reagent how would you synthesize.
iii. 2-methylpropan-2-ol Ethanoic acid

Long Questions
1. Explain distinction of 1°, 2°, and 3° alcohol by Victor-Meyer’s method.
2. Write down the structural formula of tertiary alcohol and its IUPAC name of C 4H10O. How
would you apply Victor Mayer’s method for the distinction of propan-1-ol from propan-2-
ol? Write an example of:
i. Oxo-process
ii. Baeyer’s test
3. What are the oxidation products of primary, secondary and tertiary alcohol? Write down
suitable methods for the conversion of
i. Ethanol to propanol
ii. Chloroform to dimethyl amine
4. Write short notes on:
i. Fermentation
ii. Victor-Meyer’s method for distinction between primary, secondary and tertiary alcohols.
iii.Use of Grignard’s reagent in the synthesis of 1°, 2° and 3° alcohols.
5. Explain why alcohol shows both acidic and basic nature? Convert methanol into ethanol and
vice versa. Sodium metal can be used for drying di-ethyl ether but not for ethanol. Why?
6. Convert:
i. Propan-2-ol into 1-bromo propane
ii. Propan-2-ol into pseudo-nitrol
iii. Ethanol into nitrolic acid
iv. Propan-2-ol into propan-1-ol
v. Propan-1-ol into propan-2-ol
vi. Ethanol into ethoxyethane
vi. Propan-2-ol into acetone
viii. Ethyl chloride into ethanoic acid
ix. Ethyl alcohol into propan-1-ol
x. Propan-1-ol into ethanol
xi. Methanol into methyl propanoate
xii. Butan-2-ol into but-2-ene

Phenols
Short Question
1. What is the laboratory test of phenol? What happens when phenol is heated with Zn-dust?
2. How is phenol obtained from:
i. Benzene diazonium chloride
ii. Chlorobenzene
3. Show your acquaintance with Riemer-Tiemann’s reaction.
4. What action takes place when phenol reacts with ethanoyl chloride?
5.. Convert:
i. phenol to m-nitrobenzoic acid.
ii. Benzene to m-bromophenol.
iii.Ethoxyethane to ethanoyl-chloride.
6. How would you synthesize Toluene from phenol?
7. How is phenol prepared from (a) Aniline and (b) benzene? How do you explain that the OH
group of phenol is ortho/para directing?
8. An aromatic compound A on reduction yields parent hydrocarbon B. B on nitration gives C.
C on reduction in acidic medium gives D. On coupling with diazonium salts, D gives
diazoamino benzene. Give names for A, B, C, and D. Write the chemical reactions involved.
9. Why is phenol more acidic than alcohol?
10. What happens when phenol is treated with:
i. Benzene diazonium chloride
ii. Methanal in acidic medium

Long Questions
1. Identify the major products A, B, C, D in the following reaction sequence:
Zn CH3Cl CeO2/H+
A B C D
Δ AlCl3, Δ Δ

Compound D gives methylbenzene when heated with alc. KOH and hydrazine.
2. Identify A, B, C, and D in the following reaction sequence:
Zn CH3Cl CeO2/H+
A B C D
Δ AlCl3, Δ Δ
Compound D when react with zinc amalgam in presence of acid to give toluene.
3. Convert phenol into

i. Aspirin ii. Salicylic acid iii. Toluene


iv. Chlorobenzene v. Aniline vi. Ester
vii. Azodye viii. Benzaldehyde ix. Anisol
x. Benzoquinone
4. How would you know if a given hydroxyl compound is alcohol or phenol? Write with two
reactions. Convert phenol into m-nitrobenzoic acid. How can you obtain phenolphthalein
from ethyne?
5. Identify A and B in the following chemical equation.

i. Sn/HCl NaNO2/HCl
A B C6H5OH
H 2O

Cl2/FeCl3 NaOH
ii. C6H6 A B
300atm, 3500C, H+

NaOH BDC
C6H5Cl A B
iii. 300atm, 3500C, H+

NaOH CO2, 1250C/H+


iv. C6H5OH A B

MCQ
1. The enzyme that converts glucose into ethanol is:
a. Diastase b. Invertase c. Maltase d. Zymase
2. Which of the following is used as antifreeze?
a. Methanol b. Ethanol c. Glycol d. Propan-2-ol
3. Formation of alcohol and carboxylic acid from ester is an example of
a. Esterification b. Transesterification c. Hydrolysis d. Oxidation
4. Which of the following compounds does not give iodoform test?
a. C2H5OH b. CH3CHO c. CH3COCH3 d. HCHO
5. Alcohols and phenols can be distinguished by
a. Iodoform test b. Acylation c. Libermann’s test d. Na
6. Ethyl acetate reacts with CH3MgBr to form:
a. 2° Alcohol b. 3 °Alcohol
c. 1° Alcohol and carboxylic acid c. Carboxylic acid
7. Alcohols containing three -OH groups linked to the same terminal carbon atom are
decomposed to
a. Ether b. Aldehyde c. Ketone d. Carboxylic acid
8. The molecular formula C4H10O represent four alcohols as structural isomers. How many
pairs of chain isomers are there?
a. 2 b. 3 c. 4 d. 5
9. Phenol on heating with Zn dust gives
a. Benzene b. Aniline c. Benzaldehyde d. Cyclohexane
10. Oil of wintergreen is
a. Phenyl-saliacylate b. Phenyl benzoate c. Benzoic acid d. Methyl salicylate
11. Reimer-Tiemann reaction yields
a. Salicylaldehyde b. Benzaldehyde c. Benzoic acid d. Aspirin

12. Phenol formaldehyde resin is


a. Bakelite b. Thermoplastic c. Melamine d. PMMA
13. Reimer-Tiemann reaction in phenol is
a. Electrophilic substitution b. Nucleophilic substitution
c. Free radical substitution d. Nucleophilic addition
14. Phenol and benzoic acid can be distinguished by
a. AgNO3 b. Baeyer’s reagent c. Tollen’s reagent d. NaHCO3
15. FeCl3 gives violet color with
a. Alcohols b. o-Nitrophenol c. Picric acid d. Anisole
16. Phenol and formaldehyde cannot be distinguished by?
a. DNP test b. Libermann’s test c. Tollen’s reagent d. Iodoform test
17. Phenol and ethanol cannot be distinguished by
a. DNP test b. Iodoform test c. FeCl3 test d. Libermann’s test
18. How many isomeric phenols are possible having molecular formula C7H8O?
a. 2 b. 3 c. 4 d. 7
19. Grignard’s reagent reacts with alcohols to for
a. Alkanes b. Alkenes c. Alkynes d. All
20. The amine is changed into corresponding alcohol by
a. Acidified KMnO4 b. HNO2 c. Br2/KOH d. HNO3

MCQ
1. The enzyme that convert glucose to ethanol is
a. diastase b. invertase c. maltase d. zymase
2. Which of the following compounds doesnot give iodoform test?
a. Ethanol b. Ethanal c. Propanone d. Formaldehyde
3. Which of the following alcohol gives elimination reaction rather than substitution reaction?
a. Methanol b. primary alcohol c. secondary alcohol d. tertiary alcohol
4. Alcohols and Phenols can be distinguished by
a. Iodoform test b. acylation c. liberman’s test d. sodium
5. Hydroboration oxidation of alkene give …..product
a. Markovnikov’s b. Anti-Markovnikov’s
c. Saytzeff’s d. Hoffmann’s
6. An organic compound X on treatment with acidified K2Cr2O7 gives compound Y which react
with I2 and Na2CO3 to form Triiodomethane. The Compound X is
a. Methanol b. 2-Propanone c. ethanol d. 2- propanol
7. N-Butyl alcohol and tertiary Butyl alcohol can be chemically distinguished by
a. PCl5 b. reduction c. oxidation d. Substitution
8. Organic compounds having -OH group attached to alkyl side chain of an aromatic ring are
a. Phenol b. aliphatic alcohol c. aromatic alcohol d. glycol
9. The molecular formula C4H10O represent four alcohol as structural isomers. How many
chain isomers are there?
a. 2 b. 3 c. 5 d. 4
10. Grignard reagent react with alcohols to form
a. Alkanes b. alkenes c. alkynes d. all
11. The amine is changed into corresponding alcohol by
a. Acidified KMnO4 b. HNO2 c. Br2/KOH d. HNO3
12. Formation of alcohol and carboxylic acid from ester is an example of
a. Esterification b. Transesterification c. Hydrolysis d. Oxidation
13. Which of the following compounds does not give iodoform test?
a. C2H5OH b. CH3CHO c. CH3COCH3 d. HCHO
14. Alcohols and phenols can be distinguished by
a. Iodoform test b. Acylation c. Libermann’s test d. Na

15. Ethyl acetate reacts with CH3MgBr to form:


a. 2° Alcohol b. 3 °Alcohol
c. 1° Alcohol and carboxylic acid d. Carboxylic acid
16. Alcohols containing three -OH groups linked to the same terminal carbon atom are
decomposed to
a. Ether b. Aldehyde c. Ketone d. Carboxylic acid
17. The molecular formula C4H10O represent four alcohols as structural isomers. How many
pairs of chain isomers are there?
a. 2 b. 3 c. 4 d. 5
18. Which of the following is used as antifreeze?
a. Methanol b. Ethanol c. Glycol d. Propan-2-ol
19. Primary alcohol which can give positive iodoform test is
a. ethanol b. methanol c. propanol d. butanol
20. The functional isomer of alcohol is
a. ether b. ester c. aldehyde d. ketone

Long Questions
1. Explain distinction of 1°, 2°, and 3° alcohol by Victor-Meyer’s method.
2. Write down the structural formula of tertiary alcohol and its IUPAC name of C 4H10O. How
would you apply Victor Mayer’s method for the distinction of propan-1-ol from propan-2-
ol? Write an example of:
i. Oxo-process
ii. Baeyer’s test
3. What are the oxidation products of primary, secondary and tertiary alcohol? Write down
suitable methods for the conversion of
i. Ethanol to propanol
ii. Chloroform to dimethyl amine
4. Write short notes on:
i. Fermentation
ii. Victor-Meyer’s method for distinction between primary, secondary and tertiary alcohols.
iii.Use of Grignard’s reagent in the synthesis of 1°, 2° and 3° alcohols.
5. Explain why alcohol shows both acidic and basic nature? Convert methanol into ethanol and
vice versa. Sodium metal can be used for drying di-ethyl ether but not for ethanol. Why?
6. Convert:
i. Propan-2-ol into 1-bromo propane ii. Propan-2-ol into pseudo-nitrol
iii. Ethanol into nitrolic acid iv. Propan-2-ol into propan-1-ol
v. Propan-1-ol into propan-2-ol vi. Ethanol into ethoxyethane
vii. Propan-2-ol into acetone viii. Ethyl chloride into ethanoic acid
ix. Ethyl alcohol into propan-1-ol x. Propan-1-ol into ethanol
xi. Methanol into methyl propanoate xii. Butan-2-ol into but-2-ene

Phenol
1. An organic hydrocarbon A on treatment with caustic soda at 350˚C under pressure and
acidification gives B. B on treatment with aq. Bromine give C. C on heating with zinc dust
gives 1,3,5- tribromobenzene. Identify A, B and C with related reactions.
2. An organic compound A on heating with zinc dust give parent hydrocarbon B. B can also be
obtained by polymerization of acetylene. Compound A gives violet colour on treatment with
FeCl3. Compound A on nitration gives C. Compound A decolourises aq Br 2 to give D.
Identify A, B, C and D.
3. a. Starting from phenol how would you obtain
i. Phenolphthalein ii. p-hydroxy azobenzene
iii.2,4,6-tribromophenol iv. Picric acid
b. Prepare following compound using phenol
a. salicylic acid b. salicyaldehyde
c. phenyacetate
4. Why is phenol more acidic than aliphatic alcohol?
5. Identify the major products A, b, C and D in the following reaction sequence
Zn CH3Cl/AlCl3 CeO2/H+
A B C D
Compound D gives methyl benzene which on heating with Hydrazine and alc.KOH.
6. Identify A, B, C D and E in the following reaction sequence.
Conc.H2SO4 Sn/HCl CHCl3/alc.KOH LiAlH4
A B C D E
Conc.HNO3
Compound A can be obtained by heating phenol in presence of zinc dust.
7. Compound A is popularly used as germicide and appears slightly pink on exposure to air and
can turn blue litmus to pink.
A. compound A on heating with zinc dust.
B. Compound A on treatment with PCl5 gives C
C. Compound A on treatment with benzene diazonium chloride give D
D. Compound A on treatment with CO2 and NaOH at 135˚Cunder pressure followed by
acidification give E which on further acylation produces an analgesic drug named
Aspirin,
Identify compound A, B, C, D and E
8. Compound A on treatment with caustic soda at 350˚Cunder pressure followed by
acidification give B. Compound B reacts with CO 2 in presence of alkali a 350˚C under
pressure followed by acidification give C. Compound C on acylation produces an analgesic
drug called apirin. Compound B on heating with zinc dust giving D of mol. formula C 6H6.
Identify A, B ,C and D with proper reaction described.
9. A. What happens when phenol is reacted with
i. CH3Cl/AlCl3 ii. aq.Br2
ii. B. An aromatic compound A when reacted with aq.KOH gives B which when reacted
with benzenediazonium chloride forms azo dye.identiy A and B with reactions.
10. a. Convert 1. Benzene to picric acid ii. Bezene to Toulene
b. i. Why phenol is ortho para directing towards electrophilic substitution?
ii. Why Nitrophenol is more acidic than phenol?

Alcohol
MCQ
1. The enzyme that convert glucose to ethanol is
a. diastase b. invertase c. maltase d. zymase
2. Which of the following compounds does not give iodoform test?
a. Ethanol b. Ethanal c. Propanone d. Formaldehyde
3. Which of the following alcohol gives elimination reaction rather than substitution reaction?
a. Methanol b. primary alcohol c. secondary alcohol d. tertiary alcohol
4. Alcohols and Phenols can be distinguished by
a. Iodoform test b. acylation c. liberman’s test d. sodium
5. Hydroboration oxidation of alkene give …..product
a. Markovnikov’s b. Anti-Markovnikov’s
c. Saytzeff’s d. Hoffmann’s
6. An organic compound X on treatment with acidified K2Cr2O7 gives compound Y which react
with I2 and Na2CO3 to form Triiodomethane. The Compound X is
a. Methanol b. 2-Propanone c. ethanol d. 2- propanol
7. n-Butyl alcohol and tertiary Butyl alcohol can be chemically distinguished by
a. PCl5 b. reduction c. oxidation d. Substitution
8. Organic compounds having -OH group attached to alkyl side chain of an aromatic ring are
a. Phenol b. aliphatic alcohol c. aromatic alcohol d. glycol
9. The molecular formula C4H10O represent four alcohol as structural isomers. How many chain
isomers are there?
a. 2 b. 3 c. 5 d. 4
10.Grignard reagent react with alcohols to form
a. Alkanes b. alkenes c. alkynes d. all

Phenol
MCQ
1. Picric acid is an example of
a. Azodye b. nitro dye c. Pthaleic dye d. anthracene dye
2. Riemer Tiemann reaction yields
a. salicyaldehyde b. benzaldehyde c. Benzoic acid d. aspirin
3. Carbolic acid is
a. dilute solution of Formaldehyde b. dilute solution of ethanol
c. dilute solution of phenol d. dilute solution of methanol
4. Phenol can be prepared by
a. Raschig process b. Down process c. Dow process d. Darzen’s process
5. Phenol is more acidic than
a. p-cresol b. p-Nitrophenol c. p-chloro phenol d. picric acid
6. Which of the following does have phenolic –OH?
a. oil of mirbane b. oil of wintergreen c. oil of bitter almond d. oil of vitriol
7. Phenol and ethanol can’t be distinguished by
a. DNP test b. iodoform test c. FeCl3 test d. Liberman’s test
8. Phenol and formaldeyde can’t be distinguished by
a. DNP test b. Libermann’s test c. Tollen’s reagent d. Iodoform test

9. FeCl3 gives violet color with


a. alcohol b. amine c. phenol d. aldehyde
10. which of the following is not phenol?
a. carbolic acid b. salicylic acid c. picric acid d. carbinol

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