Safety Data Sheet

according to Regulation (EC) No. 1907/2006 (REACH)

Aktiphos 6300
article number: 67259

Version number: Vers. 4.2 Revision: 2018-03-29

2017-05-16 (Vers. 3)

SECTION 1: Identification of the substance/mixture and of the company/undertaking

1.1 Product identifier

Trade name Aktiphos 6300
Registration number (REACH) not relevant (mixture)
Article number 67259
1.2 Relevant identified uses of the substance or mixture and uses advised against
Relevant identified uses Dispersing agent
Korrosionsinhibitor
1.3 Details of the supplier of the safety data sheet
Kurita Europe GmbH
Giulinistrasse 2
DE-67065 Ludwigshafen
Germany

Telephone: + 49 621 1218-3000

e-mail: MSDS@kurita.eu
Website: www.kurita.eu

1.4 Emergency telephone number

Emergency CONTACT (24-Hour-Number):
Europe: GBK GmbH +49 (0)6132-84463
International: GBK/Infotrac ID 108808: (001) 352 323 3500
Assistance in mother tongue.

SECTION 2: Hazards identification

2.1 Classification of the substance or mixture

Classification according to Regulation (EC) No 1272/2008 (CLP)
substance or mixture corrosive to metals 1 Met. Corr. 1 H290
skin corrosion/irritation 1A Skin Corr. 1A H314
serious eye damage/eye irritation 1 Eye Dam. 1 H318
hazardous to the aquatic environment - chronic hazard 2 Aquatic Chronic 2 H411
The most important adverse physicochemical, human health and environmental effects
Skin corrosion produces an irreversible damage to the skin; namely, visible necrosis through the epi-
dermis and into the dermis. Spillage and fire water can cause pollution of watercourses.

2.2 Label elements

Labelling according to Regulation (EC) No 1272/2008 (CLP)
Signal word danger
Pictograms
GHS05, GHS09

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 Safety Data Sheet
according to Regulation (EC) No. 1907/2006 (REACH)

Aktiphos 6300
article number: 67259

Version number: Vers. 4.2 Revision: 2018-03-29

2017-05-16 (Vers. 3)

Hazard statements
H290 May be corrosive to metals.
H314 Causes severe skin burns and eye damage.
H411 Toxic to aquatic life with long lasting effects.

Precautionary statements
P260 Do not breathe dust/fume/gas/mist/vapours/spray.
P273 Avoid release to the environment.
P280 Wear protective gloves/protective clothing/eye protection/face protection.
P303+P361+P353 IF ON SKIN (or hair): Take off immediately all contaminated clothing. Rinse skin
with water/shower.
P305+P351+P338 IF IN EYES: Rinse cautiously with water for several minutes. Remove contact
lenses, if present and easy to do. Continue rinsing.
P310 Immediately call a POISON CENTER/doctor.
Hazardous ingredients for labelling Zinc chloride, Etidronic acid, sulphuric acid ...%
2.3 Other hazards
Results of PBT and vPvB assessment
This mixture does not contain any substances that are assessed to be a PBT or a vPvB.

SECTION 3: Composition/information on ingredients

3.1 Substances
Not relevant (mixture)

3.2 Mixtures
Hazardous ingredients

Name of substance Identifier Wt% Classification acc. to M-Factors

GHS
Zinc chloride CAS No 7646-85-7 5 – < 10 Acute Tox. 4 / H302
EC No 231-592-0 Skin Corr. 1B / H314
Index No 030-003-00-2 STOT SE 3 / H335
REACH Reg. No 01-2119472431-44- Aquatic Acute 1 / H400
xxxx Aquatic Chronic 1 / H410
(2-methoxymethyleth- CAS No 34590-94-8 5 – < 10
oxy)propanol EC No 252-104-2
REACH Reg. No 01-2119450011-60-
xxxx
sulphuric acid ...% CAS No 7664-93-9 5 – < 10 Skin Corr. 1A / H314
EC No 231-639-5 Eye Dam. 1 / H318
Index No 016-020-00-8
REACH Reg. No 01-2119458838-20-
xxxx
2-phosphonobutane- CAS No 37971-36-1 1–<5 Met. Corr. 1 / H290
1,2,4-tricarboxylic acid EC No 253-733-5 Eye Irrit. 2 / H319
REACH Reg. No 01-2119436643-39-
xxxx
Etidronic acid CAS No 2809-21-4 1–<5 Met. Corr. 1 / H290
EC No 220-552-8 Acute Tox. 4 / H302
REACH Reg. No 01-2119510391-53- Eye Dam. 1 / H318
xxxx

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 Safety Data Sheet
according to Regulation (EC) No. 1907/2006 (REACH)

Aktiphos 6300
article number: 67259

Version number: Vers. 4.2 Revision: 2018-03-29

2017-05-16 (Vers. 3)

Name of substance Identifier Wt% Classification acc. to M-Factors

GHS
phosphonic acid CAS No 10294-56-1 <1 Met. Corr. 1 / H290
EC No 233-663-1 Acute Tox. 4 / H302
Index No 015-157-00-0 Skin Corr. 1A / H314
acetic acid ... % CAS No 64-19-7 <1 Flam. Liq. 3 / H226
EC No 200-580-7 Skin Corr. 1A / H314
Index No 607-002-00-6
REACH Reg. No 01-2119475328-30-
xxxx

For full text of abbreviations: see SECTION 16.

SECTION 4: First aid measures

4.1 Description of first aid measures

General notes
Do not leave affected person unattended. Remove victim out of the danger area. Keep affected per-
son warm, still and covered. Take off immediately all contaminated clothing. In case of unconscious-
ness place person in the recovery position. Never give anything by mouth.
Following inhalation
In case of respiratory tract irritation, consult a physician.
Following skin contact
After contact with skin, take off immediately all contaminated clothing, and wash immediately with
plenty of water. Immediately call a doctor.
Following eye contact
Irrigate copiously with clean, fresh water for at least 10 minutes, holding the eyelids apart. Remove
contact lenses, if present and easy to do. Continue rinsing. Call a physician immediately.
Following ingestion
Rinse mouth with water (only if the person is conscious). Rinse mouth. Do not induce vomiting. Imme-
diately call a doctor.

4.2 Most important symptoms and effects, both acute and delayed
Causes severe skin burns and eye damage. Splashes cause strong tearing, pain, may cause perman-
ent visual impairment. Prolonged contact may cause dryness, redness, burns, blistering and ulceration.
Can be partially absorbed by the skin. Ingestion causes pain, burns, abdominal pain, possible general
impact (shock).

4.3 Indication of any immediate medical attention and special treatment needed
No specific antidot is known. Treatment of the symptoms.

SECTION 5: Firefighting measures

5.1 Extinguishing media

Suitable extinguishing media
Non-combustible. Co-ordinate firefighting measures to the fire surroundings. Water spray, Alcohol res-
istant foam, Fire extinguishing powder, Carbon dioxide (CO2)
Unsuitable extinguishing media
Water jet

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 Safety Data Sheet
according to Regulation (EC) No. 1907/2006 (REACH)

Aktiphos 6300
article number: 67259

Version number: Vers. 4.2 Revision: 2018-03-29

2017-05-16 (Vers. 3)

5.2 Special hazards arising from the substance or mixture

Substance or mixture corrosive to metals.
Hazardous combustion products
Carbon monoxide (CO), Carbon dioxide (CO2)

5.3 Advice for firefighters

Keep containers cool with water spray. In case of fire and/or explosion do not breathe fumes. Co-or-
dinate firefighting measures to the fire surroundings. Do not allow firefighting water to enter drains or
water courses. Collect contaminated firefighting water separately. Fight fire with normal precautions
from a reasonable distance.
Special protective equipment for firefighters
Chemical protection suit, Use suitable breathing apparatus

SECTION 6: Accidental release measures

6.1 Personal precautions, protective equipment and emergency procedures

For non-emergency personnel
Remove persons to safety.
For emergency responders
Wear breathing apparatus if exposed to vapours/dust/spray/gases. Use personal protective equip-
ment as required.

6.2 Environmental precautions

Keep away from drains, surface and ground water. Retain contaminated washing water and dispose of
it. Chemicals generally shouldn't reach surface water.

6.3 Methods and material for containment and cleaning up

Advices on how to contain a spill
Covering of drains
Advices on how to clean up a spill
Wipe up with absorbent material (e.g. cloth, fleece). Collect spillage: Absorbent material (e.g. sand, di-
atomaceous earth, acid binder, universal binder, sawdust, etc.), Material for neutralising like diluted
soda or diluted caustic soda.
Appropriate containment techniques
Use of adsorbent materials.
Other information relating to spills and releases
Place in appropriate containers for disposal. Ventilate affected area.

6.4 Reference to other sections

See also to sections 8 and 13 of the safety data sheet. Section 7: Handling and storage.

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 Safety Data Sheet
according to Regulation (EC) No. 1907/2006 (REACH)

Aktiphos 6300
article number: 67259

Version number: Vers. 4.2 Revision: 2018-03-29

2017-05-16 (Vers. 3)

SECTION 7: Handling and storage

7.1 Precautions for safe handling

Recommendations
Measures to prevent fire as well as aerosol and dust generation
Use only in well-ventilated areas. Never add water to this product.
Handling of incompatible substances or mixtures
Do not mix with alkali.
Keep away from
Caustic solutions, Oxidisers, Reducing agents
Advice on general occupational hygiene
Wash hands after use. Do not eat, drink and smoke in work areas. Remove contaminated clothing and
protective equipment before entering eating areas. Never keep food or drink in the vicinity of chemic-
als. Never place chemicals in containers that are normally used for food or drink. Keep away from
food, drink and animal feedingstuffs.

7.2 Conditions for safe storage, including any incompatibilities

Managing of associated risks
Corrosive conditions
Store in corrosive resistant container with a resistant inner liner.
Specific designs for storage rooms or vessels
Keep container tightly closed.
Packaging compatibilities
Keep only in original container. Only packagings which are approved (e.g. acc. to ADR) may be used.

7.3 Specific end use(s)

Dispersing agent. Korrosionsinhibitor.

SECTION 8: Exposure controls/personal protection

8.1 Control parameters

Occupational exposure limit values (Workplace Exposure Limits)

Occupational exposure limit values (Workplace Exposure Limits)

Coun Name of agent CAS No Identi- TWA TWA STEL STEL Source
try fier [ppm] [mg/m³] [ppm] [mg/m³]
EU (2- 34590-94-8 IOELV 50 308 2009/161/EU
methoxymethylethoxy)pr
opanol (DPGME)
EU acetic acid 64-19-7 IOELV 10 25 2009/161/EU
EU sulfuric acid 7664-93-9 IOELV 0.05 2009/161/EU
GB (2- 34590-94-8 WEL 50 308 EH40/2005
methoxymethylethoxy)pr
opanol
GB zinc chloride 7646-85-7 WEL 1 2 EH40/2005

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 Safety Data Sheet
according to Regulation (EC) No. 1907/2006 (REACH)

Aktiphos 6300
article number: 67259

Version number: Vers. 4.2 Revision: 2018-03-29

2017-05-16 (Vers. 3)

Occupational exposure limit values (Workplace Exposure Limits)

Coun Name of agent CAS No Identi- TWA TWA STEL STEL Source
try fier [ppm] [mg/m³] [ppm] [mg/m³]
GB sulfuric acid 7664-93-9 WEL 0.05 EH40/2005
Notation
STEL short-term exposure limit: a limit value above which exposure should not occur and which is related to a 15-minute period
(unless otherwise specified)
TWA time-weighted average (long-term exposure limit): measured or calculated in relation to a reference period of 8 hours time-
weighted average (unless otherwise specified)

Relevant DNELs of components of the mixture

Name of sub- CAS No End- Threshold Protection goal, Used in Exposure time
stance point level route of expos-
ure
(2-methoxymethyl- 34590-94-8 DNEL 308 mg/m³ human, inhalatory worker (industry) chronic - system-
ethoxy)propanol ic effects
(2-methoxymethyl- 34590-94-8 DNEL 283 mg/kg human, dermal worker (industry) chronic - system-
ethoxy)propanol bw/day ic effects
(2-methoxymethyl- 34590-94-8 DNEL 37.2 mg/m³ human, inhalatory consumer chronic - system-
ethoxy)propanol (private house- ic effects
holds)
(2-methoxymethyl- 34590-94-8 DNEL 121 mg/kg human, dermal consumer chronic - system-
ethoxy)propanol bw/day (private house- ic effects
holds)
(2-methoxymethyl- 34590-94-8 DNEL 36 mg/kg human, oral consumer chronic - system-
ethoxy)propanol bw/day (private house- ic effects
holds)
sulphuric acid ...% 7664-93-9 DNEL 0.05 mg/m³ human, inhalatory worker (industry) chronic - local ef-
fects
sulphuric acid ...% 7664-93-9 DNEL 0.1 mg/m³ human, inhalatory worker (industry) acute - local ef-
fects
2-phosphonobutane- 37971-36-1 DNEL 15 mg/m³ human, inhalatory worker (industry) chronic - system-
1,2,4-tricarboxylic ic effects
acid
2-phosphonobutane- 37971-36-1 DNEL 158 mg/m³ human, inhalatory worker (industry) acute - systemic
1,2,4-tricarboxylic effects
acid
2-phosphonobutane- 37971-36-1 DNEL 4.2 mg/kg human, dermal worker (industry) chronic - system-
1,2,4-tricarboxylic bw/day ic effects
acid
2-phosphonobutane- 37971-36-1 DNEL 80 mg/kg human, dermal worker (industry) acute - systemic
1,2,4-tricarboxylic bw/day effects
acid
2-phosphonobutane- 37971-36-1 DNEL 3.7 mg/m³ human, inhalatory consumer chronic - system-
1,2,4-tricarboxylic (private house- ic effects
acid holds)
2-phosphonobutane- 37971-36-1 DNEL 79 mg/m³ human, inhalatory consumer acute - systemic
1,2,4-tricarboxylic (private house- effects
acid holds)
2-phosphonobutane- 37971-36-1 DNEL 2.1 mg/kg human, oral consumer chronic - system-
1,2,4-tricarboxylic bw/day (private house- ic effects
acid holds)

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 Safety Data Sheet
according to Regulation (EC) No. 1907/2006 (REACH)

Aktiphos 6300
article number: 67259

Version number: Vers. 4.2 Revision: 2018-03-29

2017-05-16 (Vers. 3)

Name of sub- CAS No End- Threshold Protection goal, Used in Exposure time
stance point level route of expos-
ure
2-phosphonobutane- 37971-36-1 DNEL 2.1 mg/kg human, dermal consumer chronic - system-
1,2,4-tricarboxylic bw/day (private house- ic effects
acid holds)
2-phosphonobutane- 37971-36-1 DNEL 40 mg/kg human, dermal consumer acute - systemic
1,2,4-tricarboxylic bw/day (private house- effects
acid holds)
2-phosphonobutane- 37971-36-1 DNEL 65 mg/kg human, oral consumer acute - systemic
1,2,4-tricarboxylic bw/day (private house- effects
acid holds)
Etidronic acid 2809-21-4 DNEL 6.5 mg/kg human, oral consumer chronic - system-
bw/day (private house- ic effects
holds)
Etidronic acid 2809-21-4 DNEL 6.5 mg/kg human, oral consumer acute - systemic
bw/day (private house- effects
holds)
acetic acid ... % 64-19-7 DNEL 25 mg/m³ human, inhalatory worker (industry) chronic - local ef-
fects
acetic acid ... % 64-19-7 DNEL 25 mg/m³ human, inhalatory worker (industry) acute - local ef-
fects
acetic acid ... % 64-19-7 DNEL 25 mg/m³ human, inhalatory consumer chronic - local ef-
(private house- fects
holds)
acetic acid ... % 64-19-7 DNEL 25 mg/m³ human, inhalatory consumer acute - local ef-
(private house- fects
holds)

Relevant PNECs of components of the mixture

Name of sub- CAS No End- Threshold Organism Environment- Exposure time

stance point level al compart-
ment
Zinc chloride 7646-85-7 PNEC 0.0061 unknown marine water short-term
(single instance)
Zinc chloride 7646-85-7 PNEC 117.8 unknown freshwater sedi- short-term
ment (single instance)
Zinc chloride 7646-85-7 PNEC 0.0206 unknown freshwater short-term
(single instance)
Zinc chloride 7646-85-7 PNEC 0.1 unknown sewage treat- short-term
ment plant (STP) (single instance)
Zinc chloride 7646-85-7 PNEC 35.6 unknown soil short-term
(single instance)
Zinc chloride 7646-85-7 PNEC 56.5 unknown marine sediment short-term
(single instance)
(2-methoxymethyl- 34590-94-8 PNEC 19 mg/l aquatic organisms freshwater short-term
ethoxy)propanol (single instance)
(2-methoxymethyl- 34590-94-8 PNEC 1.9 mg/l aquatic organisms marine water short-term
ethoxy)propanol (single instance)
(2-methoxymethyl- 34590-94-8 PNEC 4,168 mg/l aquatic organisms sewage treat- short-term
ethoxy)propanol ment plant (STP) (single instance)

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 Safety Data Sheet
according to Regulation (EC) No. 1907/2006 (REACH)

Aktiphos 6300
article number: 67259

Version number: Vers. 4.2 Revision: 2018-03-29

2017-05-16 (Vers. 3)

Name of sub- CAS No End- Threshold Organism Environment- Exposure time

stance point level al compart-
ment
(2-methoxymethyl- 34590-94-8 PNEC 70.2 mg/kg aquatic organisms freshwater sedi- short-term
ethoxy)propanol ment (single instance)
(2-methoxymethyl- 34590-94-8 PNEC 7.02 mg/kg aquatic organisms marine sediment short-term
ethoxy)propanol (single instance)
(2-methoxymethyl- 34590-94-8 PNEC 2.74 mg/kg terrestrial organ- soil short-term
ethoxy)propanol isms (single instance)
sulphuric acid ...% 7664-93-9 PNEC 0.00025 unknown marine water short-term
mg
/cm³ (single instance)
sulphuric acid ...% 7664-93-9 PNEC 0.002 unknown freshwater sedi- short-term
mg
/cm³ ment (single instance)
sulphuric acid ...% 7664-93-9 PNEC 0.0025 unknown freshwater short-term
mg
/cm³ (single instance)
sulphuric acid ...% 7664-93-9 PNEC 8.8 mg/cm³ unknown sewage treat- short-term
ment plant (STP) (single instance)
sulphuric acid ...% 7664-93-9 PNEC 0.0002 unknown marine sediment short-term
mg/ (single instance)
cm³

sulphuric acid ...% 7664-93-9 PNEC 0.003 mg/l aquatic organisms freshwater short-term
(single instance)
sulphuric acid ...% 7664-93-9 PNEC 0 mg/l aquatic organisms marine water short-term
(single instance)
sulphuric acid ...% 7664-93-9 PNEC 8.8 mg/l aquatic organisms sewage treat- short-term
ment plant (STP) (single instance)
sulphuric acid ...% 7664-93-9 PNEC 0.002 mg/kg aquatic organisms freshwater sedi- short-term
ment (single instance)
sulphuric acid ...% 7664-93-9 PNEC 0.002 mg/kg aquatic organisms marine sediment short-term
(single instance)
2-phosphonobutane- 37971-36-1 PNEC 3.33 mg/l aquatic organisms freshwater short-term
1,2,4-tricarboxylic (single instance)
acid
2-phosphonobutane- 37971-36-1 PNEC 0.33 mg/l aquatic organisms marine water short-term
1,2,4-tricarboxylic (single instance)
acid
2-phosphonobutane- 37971-36-1 PNEC 10.42 mg/l aquatic organisms water intermittent re-
1,2,4-tricarboxylic lease
acid
2-phosphonobutane- 37971-36-1 PNEC 50.4 mg/l aquatic organisms sewage treat- short-term
1,2,4-tricarboxylic ment plant (STP) (single instance)
acid
2-phosphonobutane- 37971-36-1 PNEC 1.47 mg/kg aquatic organisms freshwater sedi- short-term
1,2,4-tricarboxylic ment (single instance)
acid
2-phosphonobutane- 37971-36-1 PNEC 0.491 mg/kg terrestrial organ- soil short-term
1,2,4-tricarboxylic isms (single instance)
acid
Etidronic acid 2809-21-4 PNEC 0.136 mg/l aquatic organisms freshwater short-term
(single instance)
Etidronic acid 2809-21-4 PNEC 0.014 mg/l aquatic organisms marine water short-term
(single instance)
Etidronic acid 2809-21-4 PNEC 20 mg/l aquatic organisms sewage treat- short-term
ment plant (STP) (single instance)

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 Safety Data Sheet
according to Regulation (EC) No. 1907/2006 (REACH)

Aktiphos 6300
article number: 67259

Version number: Vers. 4.2 Revision: 2018-03-29

2017-05-16 (Vers. 3)

Name of sub- CAS No End- Threshold Organism Environment- Exposure time

stance point level al compart-
ment
Etidronic acid 2809-21-4 PNEC 59 mg/kg aquatic organisms freshwater sedi- short-term
ment (single instance)
Etidronic acid 2809-21-4 PNEC 5.9 mg/kg aquatic organisms marine sediment short-term
(single instance)
Etidronic acid 2809-21-4 PNEC 96 mg/kg terrestrial organ- soil short-term
isms (single instance)
acetic acid ... % 64-19-7 PNEC 3.058 mg/l aquatic organisms freshwater short-term
(single instance)
acetic acid ... % 64-19-7 PNEC 0.306 mg/l aquatic organisms marine water short-term
(single instance)
acetic acid ... % 64-19-7 PNEC 85 mg/l aquatic organisms sewage treat- short-term
ment plant (STP) (single instance)
acetic acid ... % 64-19-7 PNEC 11.36 mg/kg aquatic organisms freshwater sedi- short-term
ment (single instance)
acetic acid ... % 64-19-7 PNEC 1.136 mg/kg aquatic organisms marine sediment short-term
(single instance)
acetic acid ... % 64-19-7 PNEC 0.47 mg/kg terrestrial organ- soil short-term
isms (single instance)

8.2 Exposure controls

Appropriate engineering controls
Exhaust ventilation.
Individual protection measures (personal protective equipment)
Avoid contact with skin and eyes.
Eye/face protection
Wear eye/face protection.
Skin protection
Chemical resistant protective clothing.
Hand protection
Wear suitable gloves. Chemical protection gloves are suitable, which are tested according to EN 374.
Check leak-tightness/impermeability prior to use. For special purposes, it is recommended to check
the resistance to chemicals of the protective gloves mentioned above together with the supplier of
these gloves. In case of spray contact at least protection index 2 recommended, according to more
than 30 min. penetration time (EN 374).
Layer thickness of gloves at least: 0.4 mm
In case of prolonged and intensive contact protection index 6 recommended, according to more than
480 min. penetration time (EN 374).
Layer thickness of gloves at least: 0.7 mm.
Type of material
PVC: polyvinyl chloride, PE: polyethylene, CR: chloroprene (chlorobutadiene) rubber, NBR: acrylonitrile-
butadiene rubber, IIR: isobutene-isoprene (butyl) rubber, FKM: fluoro-elastomer
Other protection measures
Wash hands thoroughly after handling.

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 Safety Data Sheet
according to Regulation (EC) No. 1907/2006 (REACH)

Aktiphos 6300
article number: 67259

Version number: Vers. 4.2 Revision: 2018-03-29

2017-05-16 (Vers. 3)

Environmental exposure controls

Avoid release to the environment. Disposal considerations: see section 13.

SECTION 9: Physical and chemical properties

9.1 Information on basic physical and chemical properties

Appearance

Physical state liquid

Colour colourless - light yellow

Odour characteristic

Odour threshold no data available

Other safety parameters

pH (value) <0.5 (20 °C) (acid)

Melting point/freezing point not determined

Initial boiling point and boiling range not determined

Flash point not determined

Evaporation rate not determined

Flammability (solid, gas) not relevant (fluid)

Explosive limits not determined

Vapour pressure not determined

Density 1.22 – 1.26 g/cm³ at 20 °C

Vapour density this information is not available

Solubility(ies)

Water solubility miscible in any proportion

Partition coefficient

- n-octanol/water (log KOW) this information is not available

Auto-ignition temperature not determined

Decomposition temperature no data available

Viscosity not determined

Explosive properties none

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 Safety Data Sheet
according to Regulation (EC) No. 1907/2006 (REACH)

Aktiphos 6300
article number: 67259

Version number: Vers. 4.2 Revision: 2018-03-29

2017-05-16 (Vers. 3)

Oxidising properties none

9.2 Other information

Of no significance.

SECTION 10: Stability and reactivity

10.1 Reactivity
Substance or mixture corrosive to metals.

10.2 Chemical stability

Does not decompose when used for intended uses.

10.3 Possibility of hazardous reactions

Exothermic reaction with: Bases, Peroxides, Oxidiser.

10.4 Conditions to avoid

There are no specific conditions known which have to be avoided.

10.5 Incompatible materials

Bases, Oxidisers, Reducing agents, Peroxides
Release of flammable materials with:
Light metals (due to the release of hydrogen in an acid/alkaline medium)

10.6 Hazardous decomposition products

Reasonably anticipated hazardous decomposition products produced as a result of use, storage, spill
and heating are not known. Hazardous combustion products: see section 5.

SECTION 11: Toxicological information

11.1 Information on toxicological effects

Test data are not available for the complete mixture.
Classification procedure
The method for classification of the mixture is based on ingredients of the mixture (additivity formula).
Classification according to GHS (1272/2008/EC, CLP)
Acute toxicity
Shall not be classified as acutely toxic.

Acute toxicity estimate (ATE) of components of the mixture

Name of substance CAS No Exposure route ATE

Zinc chloride 7646-85-7 oral 1,260 mg/kg
Etidronic acid 2809-21-4 oral 1,878 mg/kg
phosphonic acid 10294-56-1 oral 1,900 mg/kg

Skin corrosion/irritation
Causes severe skin burns and eye damage.

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 Safety Data Sheet
according to Regulation (EC) No. 1907/2006 (REACH)

Aktiphos 6300
article number: 67259

Version number: Vers. 4.2 Revision: 2018-03-29

2017-05-16 (Vers. 3)

Serious eye damage/eye irritation

Causes serious eye damage.
Respiratory or skin sensitisation
Shall not be classified as a respiratory or skin sensitiser.
Germ cell mutagenicity
Shall not be classified as germ cell mutagenic.
Carcinogenicity
Shall not be classified as carcinogenic.
Reproductive toxicity
Shall not be classified as a reproductive toxicant.
Specific target organ toxicity - single exposure
Shall not be classified as a specific target organ toxicant (single exposure).
Specific target organ toxicity - repeated exposure
Shall not be classified as a specific target organ toxicant (repeated exposure).
Aspiration hazard
Shall not be classified as presenting an aspiration hazard.

SECTION 12: Ecological information

12.1 Toxicity
Toxic to aquatic life with long lasting effects.

Aquatic toxicity (acute) of components of the mixture

Name of sub- CAS No Endpoint Value Species Source Expos-

stance ure time
Zinc chloride 7646-85-7 EC50 0.86 mg/l daphnia magna 48 h
Zinc chloride 7646-85-7 IC50 0.28 mg/ algae 72 h
l

(2-methoxymethyl- 34590-94-8 EC50 969 mg/ Selenastrum capri- 48 h

l
ethoxy)propanol cornutum
(2-methoxymethyl- 34590-94-8 LC50 1,919 mg/l daphnia magna 48 h
ethoxy)propanol
sulphuric acid ...% 7664-93-9 EC50 >100 mg/l aquatic inverteb- European 48 h
rates Chemicals
Agency,
http://echa.eur
opa.eu/
sulphuric acid ...% 7664-93-9 ErC50 >100 mg/l algae European 72 h
Chemicals
Agency,
http://echa.eur
opa.eu/
sulphuric acid ...% 7664-93-9 LC50 22 mg/l bluegill (Lepomis 96 h
macrochirus)

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 Safety Data Sheet
according to Regulation (EC) No. 1907/2006 (REACH)

Aktiphos 6300
article number: 67259

Version number: Vers. 4.2 Revision: 2018-03-29

2017-05-16 (Vers. 3)

Aquatic toxicity (acute) of components of the mixture

Name of sub- CAS No Endpoint Value Species Source Expos-

stance ure time
2-phosphonobu- 37971-36-1 LC50 >1,042 mg/l fish European 96 h
tane-1,2,4-tri- Chemicals
carboxylic acid Agency,
http://echa.eur
opa.eu/
2-phosphonobu- 37971-36-1 ErC50 >1,081 mg/l algae European 72 h
tane-1,2,4-tri- Chemicals
carboxylic acid Agency,
http://echa.eur
opa.eu/
2-phosphonobu- 37971-36-1 EC50 >1,071 mg/l aquatic inverteb- European 48 h
tane-1,2,4-tri- rates Chemicals
carboxylic acid Agency,
http://echa.eur
opa.eu/
Etidronic acid 2809-21-4 LC50 279 mg/l fish European 48 h
Chemicals
Agency,
http://echa.eur
opa.eu/
Etidronic acid 2809-21-4 EC50 527 mg/l aquatic inverteb- European 48 h
rates Chemicals
Agency,
http://echa.eur
opa.eu/
acetic acid ... % 64-19-7 EC50 >300 mg/l daphnia magna 48 h
acetic acid ... % 64-19-7 EC50 >300 mg/ Skeletonema cost- 72 h
l
atum
acetic acid ... % 64-19-7 LC50 95 mg/l daphnia magna 24 h
mg/
acetic acid ... % 64-19-7 LC50 410 l orfe (Leuciscus 48 h
idus)
acetic acid ... % 64-19-7 LC50 >300 mg/l rainbow trout (On- 96 h
corhynchus mykiss)
acetic acid ... % 64-19-7 LC50 79 mg/l fathead minnow 96 h
(Pimephales pro-
melas)

Aquatic toxicity (chronic) of components of the mixture

Name of sub- CAS No Endpoint Value Species Source Expos-

stance ure time
2-phosphonobu- 37971-36-1 LC50 >1,042 mg/l fish European 14 d
tane-1,2,4-tri- Chemicals
carboxylic acid Agency,
http://echa.eur
opa.eu/
2-phosphonobu- 37971-36-1 EC50 >1,071 mg/l aquatic inverteb- European 21 d
tane-1,2,4-tri- rates Chemicals
carboxylic acid Agency,
http://echa.eur
opa.eu/

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 Safety Data Sheet
according to Regulation (EC) No. 1907/2006 (REACH)

Aktiphos 6300
article number: 67259

Version number: Vers. 4.2 Revision: 2018-03-29

2017-05-16 (Vers. 3)

Aquatic toxicity (chronic) of components of the mixture

Name of sub- CAS No Endpoint Value Species Source Expos-

stance ure time
Etidronic acid 2809-21-4 LC50 310 mg/l fish European 24 h
Chemicals
Agency,
http://echa.eur
opa.eu/
Etidronic acid 2809-21-4 EC50 871 mg/l aquatic inverteb- European 24 h
rates Chemicals
Agency,
http://echa.eur
opa.eu/

12.2 Persistence and degradability

Not readily biodegradable.

12.3 Bioaccumulative potential

Data are not available.

Bioaccumulative potential of components of the mixture

Name of substance CAS No BCF Log KOW BOD5/COD

(2-methoxymethylethoxy)propan- 34590-94-8 0.004 (25 °C)
ol
2-phosphonobutane-1,2,4-tri- 37971-36-1 -1.36 (25 °C)
carboxylic acid
Etidronic acid 2809-21-4 71 -3.5
acetic acid ... % 64-19-7 3.16 -0.17 (pH value: 7, 25 °C)

12.4 Mobility in soil

Data are not available.

12.5 Results of PBT and vPvB assessment

Not applicable.

12.6 Other adverse effects

Endocrine disrupting potential
None of the ingredients are listed.

Remarks
Do not empty into drains or surface water.

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 Safety Data Sheet
according to Regulation (EC) No. 1907/2006 (REACH)

Aktiphos 6300
article number: 67259

Version number: Vers. 4.2 Revision: 2018-03-29

2017-05-16 (Vers. 3)

SECTION 13: Disposal considerations

13.1 Waste treatment methods

This material and its container must be disposed of as hazardous waste. The allocation of waste iden-
tity numbers/waste descriptions must be carried out according to the EEC, specific to the industry and
process.
Waste treatment of containers/packagings
It is a dangerous waste; only packagings which are approved (e.g. acc. to ADR) may be used. Com-
pletely emptied packages can be recycled. Handle contaminated packages in the same way as the sub-
stance itself.

Remarks
Please consider the relevant national or regional provisions. Waste shall be separated into the categor-
ies that can be handled separately by the local or national waste management facilities. Do not empty
into drains or surface water. Avoid release to the environment.

SECTION 14: Transport information

14.1 UN number 3264

14.2 UN proper shipping name CORROSIVE LIQUID, ACIDIC, INORGANIC, N.O.S.
Technical name (hazardous ingredients) (Zinc chloride)
14.3 Transport hazard class(es)
Class 8
14.4 Packing group II
14.5 Environmental hazards hazardous to the aquatic environment
Environmentally hazardous substance (aquatic Zinc chloride
environment)
14.6 Special precautions for user
There is no additional information.

14.7 Transport in bulk according to Annex II of MARPOL and the IBC Code
The cargo is not intended to be carried in bulk.

Information for each of the UN Model Regulations

Transport of dangerous goods by road, rail and inland waterway (ADR/RID/ADN)
UN number 3264
Proper shipping name CORROSIVE LIQUID, ACIDIC, INORGANIC, N.O.S.,
(Zinc chloride)
Class 8
Classification code C1
Packing group II
Danger label(s) 8, fish and tree

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 Safety Data Sheet
according to Regulation (EC) No. 1907/2006 (REACH)

Aktiphos 6300
article number: 67259

Version number: Vers. 4.2 Revision: 2018-03-29

2017-05-16 (Vers. 3)

Environmental hazards yes

Special provisions (SP) 274
Excepted quantities (EQ) E2
Limited quantities (LQ) 1L
Transport category (TC) 2
Tunnel restriction code (TRC) E
Hazard identification No 80
Emergency Action Code 2X
International Maritime Dangerous Goods Code (IMDG)
UN number 3264
Proper shipping name CORROSIVE LIQUID, ACIDIC, INORGANIC, N.O.S.,
(Zinc chloride)
Class 8
Marine pollutant yes (hazardous to the aquatic environment)
Packing group II
Danger label(s) 8, fish and tree

Special provisions (SP) 274

Excepted quantities (EQ) E2
Limited quantities (LQ) 1L
EmS F-A, S-B
Stowage category B
Segregation group 1 - Acids
International Civil Aviation Organization (ICAO-IATA/DGR)
UN number 3264
Proper shipping name Corrosive liquid, acidic, inorganic, n.o.s., (Zinc
chloride)
Class 8
Environmental hazards yes (hazardous to the aquatic environment)
Packing group II
Danger label(s) 8

Special provisions (SP) A3

Excepted quantities (EQ) E2
Limited quantities (LQ) 0,5 L

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 Safety Data Sheet
according to Regulation (EC) No. 1907/2006 (REACH)

Aktiphos 6300
article number: 67259

Version number: Vers. 4.2 Revision: 2018-03-29

2017-05-16 (Vers. 3)

SECTION 15: Regulatory information

15.1 Safety, health and environmental regulations/legislation specific for the substance or mixture
Relevant provisions of the European Union (EU)
Restrictions according to REACH, Annex XVII
none of the ingredients are listed

Dangerous substances with restrictions (REACH, Annex XVII)

Name of substance Name acc. to inventory CAS No Restriction

Aktiphos 6300 this product meets the criteria for classifica- R3
tion in accordance with Regulation No
1272/2008/EC
Legend
R3 1. Shall not be used in:
- ornamental articles intended to produce light or colour effects by means of different phases, for example in ornamental
lamps and ashtrays,
- tricks and jokes,
- games for one or more participants, or any article intended to be used as such, even with ornamental aspects,
2. Articles not complying with paragraph 1 shall not be placed on the market.
3. Shall not be placed on the market if they contain a colouring agent, unless required for fiscal reasons, or perfume, or both, if
they:
- can be used as fuel in decorative oil lamps for supply to the general public, and,
- present an aspiration hazard and are labelled with R65 or H304,
4. Decorative oil lamps for supply to the general public shall not be placed on the market unless they conform to the European
Standard on Decorative oil lamps (EN 14059) adopted by the European Committee for Standardisation (CEN).
5. Without prejudice to the implementation of other Community provisions relating to the classification, packaging and la-
belling of dangerous substances and mixtures, suppliers shall ensure, before the placing on the market, that the following re-
quirements are met:
(a) lamp oils, labelled with R65 or H304, intended for supply to the general public are visibly, legibly and indelibly marked as fol-
lows: ‘Keep lamps filled with this liquid out of the reach of children’; and, by 1 December 2010, ‘Just a sip of lamp oil - or even
sucking the wick of lamps - may lead to life-threatening lung damage’;
(b) grill lighter fluids, labelled with R65 or H304, intended for supply to the general public are legibly and indelibly marked by 1
December 2010 as follows: ‘Just a sip of grill lighter may lead to life threatening lung damage’;
(c) lamp oils and grill lighters, labelled with R65 or H304, intended for supply to the general public are packaged in black
opaque containers not exceeding 1 litre by 1 December 2010.
6. No later than 1 June 2014, the Commission shall request the European Chemicals Agency to prepare a dossier, in accord-
ance with Article 69 of the present Regulation with a view to ban, if appropriate, grill lighter fluids and fuel for decorative lamps,
labelled R65 or H304, intended for supply to the general public.
7. Natural or legal persons placing on the market for the first time lamp oils and grill lighter fluids, labelled with R65 or H304,
shall by 1 December 2011, and annually thereafter, provide data on alternatives to lamp oils and grill lighter fluids labelled R65
or H304 to the competent authority in the Member State concerned. Member States shall make those data available to the
Commission.

List of substances subject to authorisation (REACH, Annex XIV) / SVHC - candidate list
none of the ingredients are listed
Seveso Directive

2012/18/EU (Seveso III)

No Dangerous substance/hazard categories Qualifying quantity (tonnes) for the ap- Notes
plication of lower and upper-tier require-
ments
E2 environmental hazards (hazardous to the aquatic envir- 200 500 57)
onment, cat. 2)
Notation
57) hazardous to the Aquatic Environment in category Chronic 2

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 Safety Data Sheet
according to Regulation (EC) No. 1907/2006 (REACH)

Aktiphos 6300
article number: 67259

Version number: Vers. 4.2 Revision: 2018-03-29

2017-05-16 (Vers. 3)

Directive on industrial emissions (VOCs, 2010/75/EU)

VOC content 10.74 %

Directive 2011/65/EU on the restriction of the use of certain hazardous substances in electrical
and electronic equipment (RoHS) - Annex II
none of the ingredients are listed
Regulation 166/2006/EC concerning the establishment of a European Pollutant Release and
Transfer Register (PRTR)
none of the ingredients are listed
Directive 2000/60/EC establishing a framework for Community action in the field of water policy
(WFD)
none of the ingredients are listed
Restrictions of occupation
Observe restrictions to employment for juvenils according to the 'juvenile work protection guideline'
(94/33/EC). Observe employment restrictions under the Maternity Protection Directive (92/85/EEC) for
expectant or nursing mothers.

15.2 Chemical Safety Assessment

Chemical Safety Assessment: No.

SECTION 16: Other information

Abbreviations and acronyms

Abbr. Descriptions of used abbreviations

2009/161/EU Comission Directive establishing a third list of indicative occupational exposure limit values in implementa-
tion of Council Directive 98/24/EC and amending Commission Directive 2000/39/EC
Acute Tox. Acute toxicity
ADN Accord européen relatif au transport international des marchandises dangereuses par voies de navigation
intérieures (European Agreement concerning the International Carriage of Dangerous Goods by Inland
Waterways)
ADR Accord européen relatif au transport international des marchandises dangereuses par route (European
Agreement concerning the International Carriage of Dangerous Goods by Road)
Aquatic Acute Hazardous to the aquatic environment - acute hazard
Aquatic Chronic Hazardous to the aquatic environment - chronic hazard
ATE Acute Toxicity Estimate
BCF Bioconcentration factor
BOD Biochemical Oxygen Demand
CAS Chemical Abstracts Service (service that maintains the most comprehensive list of chemical substances)
CLP Regulation (EC) No 1272/2008 on classification, labelling and packaging of substances and mixtures
COD Chemical oxygen demand
DGR Dangerous Goods Regulations (see IATA/DGR)
DNEL Derived No-Effect Level
EC No The EC Inventory (EINECS, ELINCS and the NLP-list) is the source for the seven-digit EC number, an identifi-
er of substances commercially available within the EU (European Union)
EH40/2005 EH40/2005 Workplace exposure limits (http://www.nationalarchives.gov.uk/doc/open-government-licence/)

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 Safety Data Sheet
according to Regulation (EC) No. 1907/2006 (REACH)

Aktiphos 6300
article number: 67259

Version number: Vers. 4.2 Revision: 2018-03-29

2017-05-16 (Vers. 3)

Abbr. Descriptions of used abbreviations

EINECS European Inventory of Existing Commercial Chemical Substances
ELINCS European List of Notified Chemical Substances
EmS Emergency Schedule
Eye Dam. Seriously damaging to the eye
Eye Irrit. Irritant to the eye
Flam. Liq. Flammable liquid
GHS "Globally Harmonized System of Classification and Labelling of Chemicals" developed by the United Na-
tions
IATA International Air Transport Association
IATA/DGR Dangerous Goods Regulations (DGR) for the air transport (IATA)
ICAO International Civil Aviation Organization
IMDG International Maritime Dangerous Goods Code
index No The Index number is the identification code given to the substance in Part 3 of Annex VI to Regulation (EC)
No 1272/2008
IOELV Indicative occupational exposure limit value
log KOW n-Octanol/water
MARPOL International Convention for the Prevention of Pollution from Ships (abbr. of "Marine Pollutant")
Met. Corr. Substance or mixture corrosive to metals
NLP No-Longer Polymer
PBT Persistent, Bioaccumulative and Toxic
PNEC Predicted No-Effect Concentration
ppm Parts per million
REACH Registration, Evaluation, Authorisation and Restriction of Chemicals
RID Règlement concernant le transport International ferroviaire des marchandises Dangereuses (Regulations
concerning the International carriage of Dangerous goods by Rail)
Skin Corr. Corrosive to skin
Skin Irrit. Irritant to skin
STEL Short-term exposure limit
STOT SE Specific target organ toxicity - single exposure
SVHC Substance of Very High Concern
TWA Time-weighted average
VOC Volatile Organic Compounds
vPvB Very Persistent and very Bioaccumulative
WEL Workplace exposure limit

Key literature references and sources for data

Regulation (EC) No 1272/2008 on classification, labelling and packaging of substances and mixtures.
Regulation (EC) No. 1907/2006 (REACH), amended by 2015/830/EU. ECHA: European Chemicals Agency,
http://echa.europa.eu/.
Transport of dangerous goods by road, rail and inland waterway (ADR/RID/ADN). International Mari-
time Dangerous Goods Code (IMDG). Dangerous Goods Regulations (DGR) for the air transport (IATA).

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 Safety Data Sheet
according to Regulation (EC) No. 1907/2006 (REACH)

Aktiphos 6300
article number: 67259

Version number: Vers. 4.2 Revision: 2018-03-29

2017-05-16 (Vers. 3)

Classification procedure
Physical and chemical properties: The classification is based on tested mixture.
Health hazards, Environmental hazards: The method for classification of the mixture is based on in-
gredients of the mixture (additivity formula).

List of relevant phrases (code and full text as stated in chapter 2 and 3)

Code Text
H226 Flammable liquid and vapour.
H290 May be corrosive to metals.
H302 Harmful if swallowed.
H314 Causes severe skin burns and eye damage.
H318 Causes serious eye damage.
H319 Causes serious eye irritation.
H335 May cause respiratory irritation.
H400 Very toxic to aquatic life.
H410 Very toxic to aquatic life with long lasting effects.
H411 Toxic to aquatic life with long lasting effects.

Disclaimer
This information is based upon the present state of our knowledge. This SDS has been compiled and is
solely intended for this product.

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