ALKANES * —_—_— kAIKantA Gt alo Knowy as Rasaggirs equal formula 9 AlkKamd 1 Crbnpe HUervadwuotior factory % “o’, Ferry Cowipound Lorloom m altaue g sp Lyboridircel & 7 bos tevalediat AKUAAY e: Flot G de. ofkomu. one pruent mm sil notuval Gen : Pr PH * Uathome is Hue ae pa pat 5 mot Ua e Jarrod Hn OG wogow “eoucpovuints Que propome Omd - butowe ...- 4 Utnome known os Mowat goa OH fieedomne » . #yeporotion Alkane s-, + tom Alkenu:- © @ Soboatier - Jovtluere Reaction - In Hus reachon ~Uydeogen’ BR Weatd - aid alk mM PRs a at goo 800e, 40 a" OKO, , R- a Raa Mt R-Cblg~ Chl R! oot-bontLachanism aIntially Aydroger ik Mbud wsdl Ue Ni surfoue crt attract — AYAAIGHK wool, ' due fo Vaud Waal forry, aks = Aowe Hue it form a tb valuut bonds usite frydroqer atom ue to uotucdy HH ond reget CULV COAL « £B How mintere alkene BR Added wurh 8 ottrocted by MM due to ty imitations — alu r-8 cloud cud voromu, m od ‘orota gy Ni «Gn dus prom byooqunr ul be addech to Alkewuw acevo, "Hae Couble ond OA CH bod pheougee ta maare, flrour CE bond $n tw veachim bydroqud at Qaldled frou AQUA) Aide % alkene Av it, B OW exoruple for Syn aclolthion . Acdaction, Rag® 4 ac uty oe aan Ni g ; a tea ace gee aso tour tue vole yeortion 2by ALTA LI-E lool energy. = ibe ee aN ‘ Pa os Pa a H Due sels ce Miu ‘ 7 | * ow , RS > ces ata " ty =C +4 a TC. ¢ | o \ be — pet Crecety Tr — Guiry | wooM , Sachin a. Hos -Gatl eae Dp é | Auten nop | oe ] | oe ph 4 ewan tomes 4 fame — Cut f C3 rp R ~ ee Racemric — Mitte F joature Tupe Type % aikue ,, Addon Covpour ch PPI 7 , yi@ex wd 6 dyn) Mao Frows Ace Syn Rawmico evs Rant Rocuute Trows ant Mu* courporrinch covtatmu wore tau ou doutle boyd at Orly Sut AyHvaleat g Wy danger wD aupplted dir Couble bop pile ay es Alplole until cru¢lurgo elds, eaten . : ; oe utd ott owl ‘ «Hg (t a NY (a #4 stuic Wabluante 2 wot sau mm bode. Aid 4 alkeue Hur 0A ydroqur will be added from UM “tinceueR Aicle- egy a UA -Relouteat He ® adceh pow ty droga) Aide et ue t u He TNR ‘J i He hu 31-6 Dusen Mee xgckeog euiastion_ wear oF wll oe Wouodted 4% Crodteranic Reachioyy: they Wort 7J eCoure yere® com be camitdl but af AGOUA fuup: toy using follousing Cot oLegr © Ramey wt [Al+4151 + a.cri] OPA Pt contd wsidy Corwen @ PtO. $y stoloiltty ] Alka & wore hydrogenation wsill be ln. Propet at mor Atoble Hix hylewe AD. Lat 4 hy co guration Prope %® UK. HRW - a-buteae i freaked esidte tH in pracuce Bi VKOF usill be stico cearishry — ] courpouucls — fosuseel 2 ar ye a Hy tla cae by ZN oes u Coptic oty, ., Sucrctione) GH R-Uy Chaat | | | | @ by dit additeon oF ts - ct raridle -— en. +pge hom = Alkynur © & Hydroquiation 9 alkynes mA preseut 5 Ni gins OlKoUAt* 4 R-L=ECR+t RHQ Sy pect Cey RI wy Orme wiolt ALKEME ALQLEVS OU Wy, 4 Uy to get OKO, WRAL FUL Une 9p Ue AeQerer — Quroles Op Hr fo get Adame - 3 alkyns acoctivity Bwore fuer alkeun Aeactivity towards WyduogenafiOn cacti aur fo UM Abate hinderounce . gtrom Alkyl Holt: © @ Wurtz Reackon » 4 HA Aracfion 2 wolu i ; : Alky halrde ue head wid = RU les @ Nain prs A day eur to, Get Alka ORR chon et ' arx + ano YS" RA + gioay was egoniic + px tana — Reo! + Vax Prt t R-X— RR tax —— RR-X ot RNA RRt AVa-KFr i = © i fey - Cg X tRNA oeige WR + ABX Or CHa RF Cll CHRAX—> Cy -Clae Clb Ub ~F Ritit . iro Ph ° +0 Lue Cig ct eh x t CS ce ae | Cth CH, + CepeChy ¥9n wound2 “aac du deste product je, otkome 8 foxvarcl due to wecleophilic aos htuhon acactien. Sade unde dear Atce product 8 fowl due fo eiurtyarion reo” FY de Mabiay Aide procluct imeveous Huon vate Aide HOH ey Furveans & tee» tyietol 4 duiacd » product Garr easy, & Side xroutiey PC murd2z yeac® @ QW OG for -auuproportonaction, nae’, ¥ Reaehivity paca pete Oe yietos ¥ eluaivect proauct im wurtz reactlen ae BRL RREXK PRK erplanoften— CH, Rage ‘ A 4 © tBC-G—X oye + thet ab, CHs dug 3 aes + Hac gs Cees,Cf3 7 Agc-G Xo tl CHR aba + ELS eae b HERE Chg be d a » Uy (- CHa-X ugc-ue + OHS tinh + Ure Cet D Hobty 21> 71> 0 CHyputonyiyata) pheocttity cade Ff OLky! hatides & as EL RULKR-Oy LRT WER ord duivedd Prom, Are tang aodity 9 faloque . ¥ Hed» ability 4 hatoge RB wove der Acactt ty unbl ke Wore: pytu loving coro than "XC hemes f 9 Stobiity B wore due "x core [art MY 305 B® > We > (rath) f MULONe cowt be a b oe wut eyeotHom * ene ‘ vt ML only aukene Hat ee prepared a a pute fom mH Wwurt, Reackion,ge s gs OA - | Rowen ' fy Hue % wo Aide ereachion « 4 Quarally fin Wisttod & wyut fo He prepoustiom 5 Aye act ical alas, » Gecaue a we wot fo prepare curyuuurrhr teal alkoue » WE care to take wuincture 4 alkyl hatiolu whiee Wack to He foxuaoctiore g WHOMY Cowpouricls. | Ot REK HANA a RAI MOY PR RX 4 AN ARR + ROK | next BIKA BUA 7 RR 4 2Waf alovy ute Harae ACachoM Aid, acachions | ako taku place- xalwoys wx atkout formc® prow wsurta aco” = Count = ewer Marge 4 coreow- +5 ts cee ute Rael Ou aovurt «as oH polaaity — wuadees silt olkyt Malice Ao dry will Ge Minciblen eH we use with chrer Ra wilt react with wwuture mukag 9 Ady! tolicle‘oder Yootial:— QR-X t Ra — ar t anar R-R — R-R ARK 420A — RR4 QNAY Cur . = acu Cy -X + ANA — Aerlg-4Q + ANAL Cety—ceta’ + Cute, 9 Chg CH CE CH, Side dea : t Cth- Clg 2 chy-tg t Gate Cry Cat CH=CH O gronwloud . Reactions #5} amos Alkyl hate B Werke? wxitl dwode Al a pruace duy aut otkaur & foam ah-x + mm She RR+ FonXe, pe Kuy frotuvr ore Adware OA Wurty Reowkror\ © Cowy- tHoure Syratunsis s- pris, watind B vatdl for te peepouns tn g. vensyuuaetioat MK quar. : QRext ali AKL + Quix’grPP + Cura Retuli + UX 3 perce RAAB tireh Rte Life, wa” g ium > RyGalid RK RREUKE RE meee efnd dur best PAH, to pv Deopent baie by cuing Covey- pps Pics House Ayettesid cy, %C—C-CHs, Pota-L i Cth - xe Cee Ges (CH, CULE 4 Hac- ie — tyc—b “cH, ag Paste-2 ‘ Cy, i Ga3 cy C-X 4, es (5 ‘ \ at is duy 72 Cy says uss iy | yx a mare thC-o —CH2 A puoi fa Porat? By tamer. but pad os douyi+ > Wave Aide ProclucH.edie HL bert pate for prepoucttion, 4 propane Ron dhs aeackon = alkylhaleder ust give good igietel Z| atkanes, Wwluerras ae o Alkyl Aalider give wazoily Okey | @Recuckion with fithium Aluwainivn Hydatde gr-x HAM, aR + UX + AlXs Guis Atduuction tok plaw Furqugh nuctophil —AubsKtubpy -Acaction- er Rex OH py - x AX Late , R-H eg Re Halle, RH + Aun Major)er 4 @ Rduction with — Sodlium Dowd Hycuicle 9 arx OBE GRU + Daxt Bx Wx acoction — fakes plac Hupgh riicleoplale Awos fituction. awuhauim | Hae Mable ye | pe XR Nab py | i Here Mable Ry FRedutiey Pour AGH, a UM Hoan Mut % Lat, 10s im Lally aw fur wrrtals | (wad eP conc BR woe WHE 4 iw ably dune BR Puy PAL tanta (We) Gf oft & non wetol (2) | (E-Bw,SnH CRituitiacy butyl Yin hydride) con fede all Fup ALKyl halictes to akanu. ees = © Recretioy gid “Zale ox Pefour HCOOH 4 py 1@ ton Grigqrouch Reapurt (RMg x) Griqroud Reayert covets whieh ; highly havin wnfte RMgx basic, 40 if amy “OMPound cuidic rydrogen % Meated Grigquondl Reogerrt, ux COA get H*Gnovgani) apy | R-0u Rut Mac ; ‘ fon * R- * g PR EOP RH + MQ? Tp Ou [i CoP oH ici y ay Roe Roy se Ney Rou ¢ RENHas ee * ),-na » p+ Rt fe Ps t Xx R-C-NH 1-4 2 RY 4 7 RI-C-NH-R" . . t————— R-H H,0 : = R-H*© wom Alcoholt - * Reduction usiti — Rec phn phovous + IT» Red P + Mr R-Uly R-CHOH H a-d-on Retrer, 2H i i a Fe R-C 0H Rar, Op hu Su #O trom | Coroorujl Compounols:- ® Clermenvon Reduction ferHays+ Hol. + Cemayasem, Ream zene Auatquae OM ; CR ust “convut A to CHa 9 p-t-H oR. R-CHg “et oO ~Uopl GR, R~cHy-R! » Pp a R-E~tuly-cllg- Foon 28, Rep eug-cey touO Woy Kishmer vcluction~ aN [ko TI, rover) pay, wang , Meceiny vols kin Reagent pe feu wKeR Rett R- fl_pt 8, pict’ Re f. (Hy Uy - Bou 22% Retth “teh - UB -t tp ey Herve ore aeidl Awarteve x compound Uke 0H & We, Me Kirbaur Arduction Preyuad 0 die quouyps Wil feGe be pec? ey HL im claw, Atagent O©Recurkion, uit Rech plrospliovou ¢ td t Rete the are R CH, 5 potiegt Reh, R-crg-R! ut > #@O Hom Carborylie Ads auc mH Auivativd @ Reduction, usidte — Rec plto rphorous yer aepeg on RSE Rely ™ yf HT @ Deearkorylation 4 Couboniyte Aciols:- gn 0g ney R-¢-OH (a (QD, R-H + Nagco, Mecham vAwe fu | eal? 0-H ° O..@ tl | ks fon J RO NP se 1 z R-4 # OL JL gt ~tn& i par” 0 ° it ! WS R- tuo t YAOH — Rtg ta R ¥9n. uu acachiom — Corbauriby, 8 formad as ictuuardiat (ve Uaauge 8 9% a-corbri). v I. + omy thong & ust daauriny gaoupe (Uke 490.) , CEO% “CEN B prot On o-(QLbon, AOE 4 ancarbox ylation, Macy eases. Aceprhony tok 4oker place by Cur luatiyy on ? dane.a © Uelg— bly ~ bu - coorl — Chl, CE ~ C120, +, 0g op a * Uly-C -COOLL ~—4 CHy- bly CRI + CO, ‘ CH - focuy fot A, os Becth 400, Maalaganioare et. y A gt! 4, uth ~C=ctt * yt Garey h-Cacth + Co,1 ! of ett e Qt 9 By ardiorot emisd Sy Hus compound dowlt unslgo ALLOK bony tate jus? © 4 wuateng, i fam wenclago by Naot! a an mufouion % formu od t B Sp? uyevidined: x.eat ts a 0) q 8 e ls oo + Wy © Kolbe's Eluctolysis i EWA AQUOS comloorny Ue aud is Ow fouurd - 9 0 i U tl Foods R-C-OoK — R-C—0° + it Kalk sats -% dechrotised , alkanes fod ° 1 As Roe RCO cs KLe-0 wy o=e=0T Oo ree eee Cattuocle - gins wee? 3 K K+ tO —+ KOH t FR Moke ear frews- A-c- O° + RS Ree -O-R “eRR (dis propordioyation) on uA prow OckOut. {& LO, Oe forus at Oodle woreda Kott & He ore at cotwuock- 4Burrmg dum proum PH ADEN Perey, #4, de found yacdtial B 3° free sadticas Har de Cia proportorah on productia ULL clesired? §— Kore. ah tue salt courtoaiw n-cordoms dun corbor prawat mr foomud oikowe BWR oui all Me produc > forurecl (ruclualing wuriwoy poctuct ) cuaiyy Hu Kolbe's elects 9 fortowsing COALA ~~» O ayy. Uy Hg COOK @winture 4 cH cook + CH ttle COOK o © Cy “la Alar Urls | yt! a Cry CH lca etHli- Chk / (lige ely GO -Ua Oth (Hy tet tbls cle ‘ 7-4 0 Ce lye ly Cel yr CEL g v 4 (uy- OH3 Tag eh v7 Cy -CHy © Gj Om CHa Chl, go orl pe Vg CHly= Ry Hy : \~_ }} — AOU Sonic (arpids oe our | dar Soute Coubides gives ureflraue upon Wycwolysis , Muse (arbicls Que kau A sartouatcles- Beye + HO —> Cy + be(ou), + AlyCa + Ha0 —> "Cle t At(Oti), #Physicol Proper tie ALKOUAG having corbors 1-4 Ore GouKs, S11 corborun que Uquids aut aca Wighry KAU = WALTHY Avltau- ay du mortar weeght Alkoure Mure 1H boi lay pow IVALx COAL. tHe & Quy < GH tustte MALY CaKe me by : Quncl Que to ducveore’ iM AWYOAM Gren. q G Ct-t-C-C > c-c-c-C ? c-F-c Cc (hailing portKwik, nacvease WH wolutar wrtiglet err bg pomt & alkOue iracxeaye: THe coubows = ty tH tig excoure odd ao’ 4 4 coroon, > MHOC “gon HABE] Onn 2 aio fo mek ly <% Cat < Coty <4 CuMto Cutting pore) x Alkquu ac Amoludle im way Ot caatuattions luo alKaues aud water wooltuuls ore wea Buck OlKourLs Ae Acrcdily woluble Mu wou polar Ao wuts like wourue , Cly » C2 do aQuuitis gy AKOUrs WALVEAIEA Wirt Aves wuroleclor wera tat KCromicatl Propuctics ~ kA we GM ALAA clue to fle ate 4 aWoug c-C, CH boucls aud, bince, O functional groups but ALY. Viqourour » couctttiows rR oblerved Haovt aLKoUnea Hocxe vnc ge AoW UH OVY « - -_o—~~ |. a MHarequaatior Fy alkour i treated wit kglogen im | prsuee Alig it o Ob Syve- bode L potty Ue fodured « Xr , RH og? RX + HX tReottivity ord | Wotequus ry dtuls Aas >). BR > Ota > Bro dTg. HAS “Fis wore veacbive cure this atpetoult to homndle Ph im tao om alternative, wrkiod ult. be. usta to preporw alkyl MAlrvidt futoricles. / Cla Cg CL + HQ,Fg —> 0Hs Lig + Alg,Cls CHg-CHa—OL + AQF — Cy cae 4 AglL e(htovinatio can be camtecl out m Har talo clepercting wpOr OWL halogur taken wr wil qu vaniouk proces CHa + Clg Es “Cec t GCL Cok) Ch, Fle AY, OLLy FHL (vow ee gee. | * Byowtnatio p~cactim uu Atuular ty Chorin adiow, #8odination . year” & vy Ablow as ty ccachinvity 4 Sodine % Us. FSodinaitm KA % om mM y Curr ple Atwrusabole — Aca” i Ura + Tg = Cy-T + HT flo Worn He yoetek 9f CLK YL Adlinle we Auoutd OAC on prurdbrg agemt Uke tour: HNO, BX bout: Ha sOp vstucele) WU oxidise HI to Tk hh touts Fo produc 3 deoeaued | wore xeacfout 8 macregqua Aultocously Mechawiawe CH, + Yo : ; xe BR Re (urnin, maittotion) K x + Hee dey + HE H Caan prope CH 4 XK Cu3x +X" 3 _ g okaeh Gq Xa % PYOmrt: Huse erecc® 40kHs W . Place | nit ie a CegX +t Hx |_e:. SUX } ese ty “CHRXQ eK! “ m® | 1 : Kew 9 EU 4 HX 4 a CHXe + xwcy Cox, + | x t+ CHXe, eX, + HX | thy t OK 4 hy FX \ « Fuurtyation — thy, + CH, CER CH, eee oltane AOE 6) x) om Bee olde B He node — cleHwiibyy atep Im diets Arcachon . fag ode vourpoucl coufoinms tat (3 Wyckroqus, darn Ra acachivity % fue youwords Ualoquatier iv gH > RH? Ce (bored wep Oh Hobluty a am vacttal k ’ a pred) Ftd products fotuaecl for a girs QUKOAAL : - - 3 SubcHtukol > * Aub stituted > Autatr one | try pective % Wabogen Wed SAUbytiy,, tKalogur 8 always wajor but fue wy oe deppuredl Huy Bue fo! deletes, oahu 4 Woalogems - ; Bx, > C2 FR (Selechytty oactey) Such e x 7 Ry = (0: C2* L Oo § 2 38: 1. $y dre courpouels tonto 46H, Yat RRA cs xx euch (1) tLe yxutltchevity (00 hx (seerhivity Us) + yxsecachnrity (2) Faxselectivity (x) we weary) soo secretly (+ Ys itLecdivvity (+ Dare teciny O Lae RK sucivity a) woow eexeecbity (0 4 yosetectivity a p pecelectivity WSeCalartake hin le yids % XBrowo buton oud pBvow0 - PM TUQUL poy Luovpta rome. 8 n-oUlme - Wwe LNW as Ww 4 AY BY Nx ye OX! xi. LAI00 = 1-97, : Gxt FAKED bor 4X92 plop. 92 Baty =4827. /Y a be ue 334 BY Un zt A) te MAGA | uw 6x! x00. Uo er ee 2 RUR A. fe BOT WI ” xt x38 Protentate gu +f yields produc sored pon, wow rromingtion J prope wanodubeviaation | Route.Olalaatak du uo. oy proctuth forueel upon wuowmoctulor ina Hen w-butone Cractuclivy Hx Uowuribw bx lxigo ‘ Dh oe O_o xe : , “Ny >t mab ae AO Bry. ny : ‘ DN the got Ae Toh we, 8 xi 4 evAD PAL 3 AA LY ol a. In t So pretusy Owlurlok Key uo-g Lureds ‘foruacel upon, und clbovimoion 9 ve puto 1O "AYN )& preachi “' Fr bowatelorinehbn 9 Awuedtiyl, perrtoure BA > Py Aa ha + Ady © rt 4 proctacts #NiWOtIOM -— Fusion atkaunr are Heated? twite Come. N03, wr ull get wuinture 4 TPO QUKOAAL | 4 CHy—CHly— Cg Si Olly - CH Hs + Chfy-Cligteirg i NOg hoguy Menor BU rR UD UH FSuulphowation - FF UUVOM atkaur 3% Neakd ust He Dleum CHeS201) (00 Conc FSD, urincteve 4 ra |' Cela Clg - LH oe bgt GES + Oly cH CH soy SOU Larvapt Hager SH DD SH x Doweni sation: piu, Otkaws are Crore usil auluyda Atumeviuu, ddtovice He wniotfure a chain — Bours unl be foaurd- Ne ee IN os DK, 4 Anomatisation patkoun, faving Ai ‘wore thom I conven = WL produc TAeAAe —cLerivadiny upon, deat = uw Fie urioctuxe MgQ + Ora0,, 0. Cubng POEM Guy —~— (0_ © |" OD OO #Courbusfien 2 ~ Wher, WkKows our leatkd usttle | oom 9 ORYGUA CO, G& HAO ORE JOA unt AUR autounut 9 UALNgy vtech & Kuounc of tat 4 Courtushbr | Coy Homer + nto, Ameo, + MAHno+ Ferqy | FH lat 9% Combustion vals cue ward to Uourpout SHAD Ly 8) ALkKoUne. Ay Wud e) “Courbustion Btu Huw Sto.bilty ot alkaue & dove ATEb(r. HOU AKL cowfoin ULore no. % | ! ¥ Corps] Wycrogews tur dat alour ORL oe wore stolole | ARyrolycis wv) (rock biny:- | 4 alkane B Neotel ct way igh Teupuoture, He vsll Spl into AMuapler WoleerlA udu ceucousy oA | Omen : ea |OH Chor AG Urry FC EH 4 CE Obl = CHa t Hy FM aunguut 4 a2, 4 brett priors 2 towidued ou otaut vo & i+ B wai fo cau Pus pay mp pune (Fior & He ofdue wo , ULove WILL be Fae QuOtsty 4 poroltun- @letome muwloerr ‘ ete Ourount Char} ECs & Kuourn ctone Mo. Hwee to lurk de purty 4 Rural . puove B He howe wo. dan Auove oil be purty 9 Seiad