Safety Data Sheet

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Japan Chemical Industries JQI-MSDS-5024-2
Preparation / Revision Date : 29 January 2010
Product: TOYOTA Diesel Injector Cleaner P/N:08813-00860
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1. IDENTIFICATION

Trade name TOYOTA Diesel Injector Cleaner

Manufacturer
Company Name Japan Chemical Industries co.,Ltd
Address 813, Kikkawa, Shimizu-ku, Shizuoka, 424-8558 Japan
Telephone Number ＋81(54)345-3476
Facsimile Number ＋81(54)347-6865
Person In Charge H.Tami(Prepared by Y.Umehara)

Emergency Telephone Number: ＋81(54)345-3476

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2. HAZARDS IDENTIFICATION
GHS classification
PHYSICAL HAZARDS
Explosives Not applicable
Flammable gases Not applicable
Flammable aerosols Not applicable
Oxidizing gases Not applicable
Gases under pressure Not applicable
Flammable liquids Category 4
Flammable solids Not applicable
Self-reactive substances and mixtures Classification not possible
Pyrophoric liquids Not classified
Pyrophoric solids Not applicable
Self-heating substances and mixtures Classification not possible
Substance and mixtures which, in contact Classification not possible
with water, emits flammable liquids
Oxidizing liquids Classification not possible
Oxidizing solids Not applicable
Organic peroxides Not applicable
Corrosive to metals Classification not possible

HEALTH HAZARDS
Acute toxicity (Oral) Not classified
Acute toxicity (Dermal) Not classified
Acute toxicity (Inhalation: gas) Not applicable
Acute toxicity (Inhalation: Vapor) Classification not possible
Acute toxicity (Inhalation: Dust) Not applicable
Acute toxicity (Inhalation: Mist) Classification not possible
Skin corrosion/irritation Category 2
Serious eye damage/eye irritation Category 2A
Respiratory Classification not possible
Skin sensitization Category 1
Germ cell mutagenicity Classification not possible
Carcinogenicity Category 2
Reproductive toxicity Classification not possible
Safety Data Sheet
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Japan Chemical Industries JQI-MSDS-5024-2
Preparation / Revision Date : 29 January 2010
Product: TOYOTA Diesel Injector Cleaner P/N:08813-00860
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Specific target organ toxicity‐Single exposure Category 1,2,3
Specific target organ toxicity‐Repeated exposure Category 1,2
Aspiration hazard Category 1

ENVIRONMENTAL HAZARDS
Hazardous to the aquatic environment－Acute hazard Category 2
Hazardous to the aquatic environment－Chronic hazard Category 2

Pictogram

Signal word Danger

Hazard statement
Combustible liquid
Causes mild skin irritation
Causes serious eye irritation
May cause an allergic skin reaction
Suspected of causing cancer
Causes damage to organs
May cause damage to organs
May cause respiratory irritation; or May cause drowsiness and dizziness
Causes damage to organs through prolonged or repeated exposure
May be fatal if swallowed and enters airways
Toxic to aquatic life
Toxic to aquatic life with long lasting effects

Precautionary statement
[A safety measure]
Wear protective gloves and eye/face protection.
Keep away from flames and hot surfaces.
Avoid breathing mist/vapours.
Contaminated work clothing should not be allowed out of the workplace.
Obtain special instructions before use.
Do not handle until all safety precautions have been read and understood.
Use personal protective equipment as required.
Do not eat, drink or smoke when using this product.
Wash hands thoroughly after handling.
Do not breathe mist/vapours.
Use only outdoors or in well-ventilated area.
Avoid release to the environment.

[First-aid measures]
In the case of fire, use carbon dioxide / powder extinguishant / sprinkling /
alcohol-resistant-related fire foam for fire extinguishing. The stick flooding adds to danger.
If skin irritation occurs, get medical advice/attention.
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Japan Chemical Industries JQI-MSDS-5024-2
Preparation / Revision Date : 29 January 2010
Product: TOYOTA Diesel Injector Cleaner P/N:08813-00860
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IF IN EYES: Rinse cautiously with water more than 15 minutes. Remove contact lenses, if
present and easy to do. Continue rinsing.
If eye irritation persists, get medical advice/attention.
Wash hands after handling.
IF ON SKIN: Wash with plenty of soap and water.
If skin irritation or rash occurs, seek medical advice/attention.
Wash contaminated clothing before reuse.
IF exposed or concerned: Get medical attention/advice.
IF exposed: Call a POISON CENTER or doctor/physician.
Call a POISON CENTER or doctor/physician if exposed or you feel unwell.
IF INHALED: Remove to fresh air and keep at rest in a position comfortable for breathing.
Get medical attention/advice if you feel unwell.
IF SWALLOWED: Immediately call a POISON CENTER or doctor/physician.
Do NOT induce vomiting.
Collect spillage.

[Handling and storage]

Store locked up.
Store container tightly closed in cool/well-ventilated place.
Keep out of reach of children.

[Disposal considerations]
In the case of the disposal, please confirm local disposal regulation concerned by all means.
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3. COMPOSITION / INFORMATION ON INGREDIENTS

Chemical nature Diesel fuel additive in solvent naphtha

Hazardous ingredients
Component Wt% CAS No. EINECS No. Hazard R-phrase
Symbol
Solvent naphtha 70～80 64742-94-5 265-198-5 Xn,N R51/53,R65,R66,R67
2-Ethylhexyl nitrate 10～20 27247-96-7 248-363-6 Xn,N R20/21,R44
1,2,4-Trimethylbenzene 7.3～8.8 95-63-6 202-436-9 Xn,N R10,R20,R36/37/38,
R51/53
Naphthalene 0.5～11.3 91-20-3 202-049-5 Xn,N R22,R40,R50/53
Kerosene 3～6 8008-20-6 232-366-4 Xn R65
1,2,3-Trimethylbenzene 3.9～5.1 526-73-8 208-394-8
1,3,5-Trimethylbenzene 0.7～1.1 108-67-8 203-604-4 Xn,N R10,R37,R51/53

The wording of the hazard symbols and R-phrases is specified in chapter 16 if dangerous
ingredients are mentioned.
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4. FIRST AID MEASURES
General advice : Immediately remove contaminated clothing.

Inhalation : Remove to fresh air. If rapid recovery does not occur, transport to
nearest medical facility for additional treatment.

Skin contact : Wash thoroughly with soap and water. Get medical attention if
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Japan Chemical Industries JQI-MSDS-5024-2
Preparation / Revision Date : 29 January 2010
Product: TOYOTA Diesel Injector Cleaner P/N:08813-00860
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irritation develops.

Contact with eyes : Wash affected eyes for at least 15 minutes under running water with
eyelids held open. If irritation persists, get medical attention.

On ingestion : DO NOT INDUCE VOMITING. If conscious, give 1 glasses of water.

Get immediate medical attention.

Advice to Physician
: Causes central nervous system depression. Dermatitis may result
From prolonged or repeated exposure. Potential for chemical
pneumonitis. Consider: gastric lavage with protected airway,
administration of activated charcoal.
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5. FIRE-FIGHTING MEASURES
Flash point: : 63 degrees Celsius（Closed Cup）

Suitable extinguishing media : CO2, dry chemical, or foam. Water can be used to cool
and protect exposed material.

Unsuitable extinguishing media : Water jet for safety reasons

Firefighting Procedures : Wear full protective fire-fighting gear including self-containing

breathing apparatus operated in the positive pressure
mode with full-face coat, pants, gloves and boots.
Water may cause splattering.

Unusual Fire & Explosion Hazards : Toxic fumes, gases or vapors may evolve on burning.
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6. ACCIDENTAL RELEASE MEASURES
Protective measures : Avoid contact with spilled or released material, Immediately
remove all contaminated clothing.
For guidance on selection of personal protective equipment see
Chapter 8 of this Material Safety Data Sheet.
For guidance on disposal of spilled material see Chapter 13 of this
Material Safety Data Sheet.
Shut off leaks, if possible without personal risks.
Remove all possible sources of ignition in the surrounding area.
Use appropriate containment (of product and fire fighting water) to
avoid environmental contamination.
Prevent from spreading or entering drains, ditches or rivers by
using sand, earth, or other appropriate barriers. Attempt to
disperse the vapor or to direct its flow to a safe location for
example by using fog sprays.

Environmental Precautions : If emergency personnel are unavailable, contain spilled material.

and Clean-up Methods For small spills, add absorbent (soil may be used in the absence
of other suitable materials) and use a non-sparking or
explosion-proof means to transfer material to a sealable,
appropriate container for disposal.
For large spills, dike spilled material or otherwise contain material
to ensure runoff does not reach a waterway.
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Japan Chemical Industries JQI-MSDS-5024-2
Preparation / Revision Date : 29 January 2010
Product: TOYOTA Diesel Injector Cleaner P/N:08813-00860
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Place spilled material in an appropriate container for disposal.
Minimize contact of spilled material with soils to prevent runoff to
surface waterways.

Additional Advice
: See Chapter 13 for information on disposal. Notify authorities if
any exposure to the general public or the environment occurs or is
likely to occur.
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7. HANDLING AND STORAGE
Handling : Do not ingest.
Avoid breathing vapor or mist.
Avoid contact with skin, eyes, and clothing.
Keep containers closed when not in use.
Only use in well ventilated areas.
Do not smoke.
Remove ignition sources.
Keep away from heat, sparks and flame.
Wash thoroughly after handling.

Storage
: Store in a segregated and approved area.
Store in a cool place.
Protect from direct sunlight.
Keep container in a well-ventilated area.
Keep container tightly closed and sealed until ready for use.
Avoid all possible sources of ignition (spark or flame).
Keep away from flammables, oxidizing agents, and corrosives.
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8. EXPOSURE CONTROLS/PERSONAL PROTECTION
Additional Information : Wash hands before eating, drinking, smoking and using the
toilet.

Exposure Controls : The level of protection and types of controls necessary will
vary depending upon potential exposure conditions. Select
controls based on a risk assessment of local circumstances.
Appropriate measures include adequate explosion-proof
ventilation to control airborne concentrations below the
exposure guidelines/limits. Eye washes and showers for
emergency use.

Personal Protective Equipment : Personal protective equipment (PPE) should meet

recommended national standards. Check with PPE suppliers.

Respiratory Protection : Respiratory protection in case of vapor/aerosol release.

Hand Protection : Where hand contact with the product may occur the use of
gloves approved to relevant standards (e.g. Europe: EN374,
US: F739) made from the following materials may provide
suitable chemical protection: Suitability and durability of a
glove is dependent on usage, e.g. frequency and duration of
contact chemical resistance of glove material, glove
thickness, dexterity. Always seek advice from glove suppliers.
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Japan Chemical Industries JQI-MSDS-5024-2
Preparation / Revision Date : 29 January 2010
Product: TOYOTA Diesel Injector Cleaner P/N:08813-00860
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Contaminated gloves should be replaced. Longer term
protection: Nitrile rubber gloves Incidental. contact/Splash
protection: PVC or neoprene rubber gloves.

Eye Protection : Safety glasses with side-shields (frame goggles) (EN 166)

Body protection
: Body protection must be chosen depending on activity and
possible exposure, e.g. apron, protecting boots,
chemical-protection suit (according to DIN-EN 465).
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9. PHYSICAL AND CHEMICAL PROPERTIES
Form liquid
Color Dark brown
Odor Aromatic
pH Not determined.
Boiling point 168℃
Melting point Not determined.
Flash point 63 degrees Celsius（Closed Cup）
Autoignition temperature ＞400℃（at Solvent naphtha）
Explosive limit in air between 0.6 and 7 vol% (at Solvent naphtha)
Vapor pressure Not determined.
Density 0.899 g/cm3 (15 degrees Celsius)
Solubility in water insoluble
Viscosity 5.2 mm2/s (25 degrees Celsius)
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10. STABILITY AND REACTIVITY
Stability : Material is normally stable at moderately elevated temperatures
and pressures.

Decomposition Temperature : Not determined.

Incompatibility : Strong acids. Strong oxidizing agents.

Polymerization : Will not occur.

Thermal Decomposition
: Smoke, carbon monoxide, carbon dioxide, aldehydes and other
products of incomplete combustion. Ammonia may be formed on
burning in limited air supply. Propylamine, polyalkylglycols, and
aliphatic alcohols may also be released.
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11. TOXICOLOGICAL INFORMATION
Basis for Assessment : Information given is based on product data and on data on the
components and the toxicology of similar products.

Routes of Entry : Skin, Eyes, Inhalation, and, Ingestion.

Target Organs : Contains material which may cause damage to the following organs:
blood, kidneys, lungs, liver, spleen, gastrointestinal tract,
cardiovascular system, upper respiratory tract, skin, eyes, central
nervous system (CNS)，nose/sinuses.
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Japan Chemical Industries JQI-MSDS-5024-2
Preparation / Revision Date : 29 January 2010
Product: TOYOTA Diesel Injector Cleaner P/N:08813-00860
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Acute Exposure
Oral Toxicity : The LD50 in rats is >2000 mg/kg. Based on data from components
or similar materials. Aspiration into the lungs when swallowed or
vomited may cause chemical pneumonitis which can be fatal.

Dermal Toxicity : The LD50 in rabbits is > 2000 mg/Kg. Based on data from
components or similar materials. Overexposure to organic nitrates by
skin contact may cause headach, nausea and decreased blood
pressure.

Inhalation Toxicity : Harmful by inhalation. Irritating to respiratory system. Overexposure

to organic nitrates by inhalation of vapor or skin contact may cause
headache, dizziness, nausea, and decreased blood pressure.

Skin Irritation : May cause skin irritation (but insufficient to classify). Based on data
from components or similar materials. Prolonged or repeated skin
contact as from clothing wet with material may cause dermatitis.
Symptoms may include redness, edema, drying, and cracking of the
skin.

Eye Irritation : May cause irritating to eyes (but insufficient to classify).Based on

data from components or similar materials.

Respiratory Irritation : Inhalation of vapours or mists may cause irritation to the respiratory
system based on data from similar materials.

Chronic Exposure
Repeated Dose Toxicity : Central nervous system: repeated exposure affects the nervous
system.

Mutagenicity : Not expected to be mutagenic.

Carcinogenicity : Limited evidence of carcinogenic effect. (Naphthalene)

Reproductive and : Causes foetotoxicity in animals at doses which are maternally toxic.
Developmental Toxicity Not expected to impair fertility.
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12. ECOLOGICAL INFORMATION
Environmental Toxicity
Fish : Expected to be toxic: 1 < LC/EC/IC50 <= 10 mg/I
Aquatic Invertebrates : Expected to be toxic: 1 < LC/EC/IC50 <= 10 mg/I
Algae : Expected to be toxic: 1 < LC/EC/IC50 <= 10 mg/I
Microorganisms : Expected to be toxic: 1 < LC/EC/IC50 <= 10 mg/I

Environmental Hazards : Toxic to aquatic organisms. May cause long-term adverse effects in
the aquatic environment. Based on calculation.

Environmental Fate
: This product contains components which may be persistent in the
environment.
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Safety Data Sheet
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Japan Chemical Industries JQI-MSDS-5024-2
Preparation / Revision Date : 29 January 2010
Product: TOYOTA Diesel Injector Cleaner P/N:08813-00860
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13. DISPOSAL CONSIDERATIONS
Disposal should be in accordance with applicable regional, national, and local laws and
regulations. Local regulations may be more stringent than regional or national requirements and
must be complied with.
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14. TRANSPORT INFORMATION
Land and inland navigation transport （ADR/RID）
Transport document name ENVIRONMENTALLY HAZARDOUS SUBSTANCE,LIQUID,N.O.S.
UN No. 3082
Class 9
Packing Group Ⅲ

Marine transport （IMDG）

Proper shipping name ENVIRONMENTALLY HAZARDOUS SUBSTANCE,LIQUID,N.O.S.
UN No. 3082
Class 9
Packing Group Ⅲ
Marine Pollutant applicable

Air transport （ICAO/IATA）

Proper shipping name ENVIRONMENTALLY HAZARDOUS SUBSTANCE,LIQUID,N.O.S.
UN No. 3082
Class 9
Packing Group Ⅲ
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15. REGULATORY INFORMATION
Regulations of the European union (Labeling) / National legislation / Regulations
Directive 1999/45/EEC (Preparation Directive'):

Hazard symbol(s)
Xn Harmful
N Dangerous for the environment

R-phrase(s)
R40 Limited evidence of carcinogenic effect.
R51/53 Toxic to aquatic organisms, may cause long-term adverse effects in the aquatic
environment.
R65 Harmful: may cause lung damage If swallowed.
R66 Repeated exposure may cause skin dryness or cracking.
R67 Vapors may cause drowsiness and dizziness.

S-phrase(s)
S23 Do not breathe vapor.
S24 Avoid contact with the skin.
S24/25 Avoid contact with skin and eyes.
S36/37/39 Wear suitable protective clothing, gloves and eye/face protection.
S61 Avoid release to the environment. Refer to special instructions/safety data sheets.
S62 If swallowed, do not induce vomiting: seek medical advice immediately and show
this container or label.
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Japan Chemical Industries JQI-MSDS-5024-2
Preparation / Revision Date : 29 January 2010
Product: TOYOTA Diesel Injector Cleaner P/N:08813-00860
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Global Chemical Inventories
EU All components on EINECS.
USA All components on TSCA Inventory or exempt.
Canada All components on DSL.
Japan All components METI.
Australia All components on NICNAS.
Korea All components on ECL.
Philippines All components on PICCS.
China All components IECSC.
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16. OTHER INFORMATION
Full text of hazard symbols and R-phrases if mentioned as hazardous components
in chapter 2:

R-phrase(s)
R10 Flammable.
R20 Harmful by inhalation.
R20/21 Harmful by inhalation and in contact with skin.
R22 Harmful if swallowed.
R36/37/38 Irritating to eyes, respiratory system and skin.
R37 lrritating to respiratory system.
R44 Risk of explosion if heated under confinement.
R50/53 Very toxic to aquatic organisms, may cause long-term adverse effects in the
aquatic environment.

The information contained herein is based on the present state of our knowledge and does not
therefore guarantee certain properties. Recipients of our product must take responsibility for
observing existing laws and regulations.