Full Paper J Haz
Full Paper J Haz
A R T I C L E I N F O A B S T R A C T
Keywords: As the population and urbanization continue to grow, we expect an increase in industrial demand, which will
Bibliometric analysis lead to higher water consumption and, consequently, the generation of substantial amounts of industrial
Industrial wastewater treatment wastewater (IWW). This presents significant environmental challenges that necessitate effective treatment so
Research trends
lutions. This study addresses the gap in the existing literature by conducting a bibliometric analysis of 1,714
VOSviewer
research papers on IWW treatment published in the Scopus database from 2015 to 2024. The findings indicate
that over 59.7 % of these publications emerged within the past five years, with a peak of 244 papers published in
2022, reflecting an increased recognition of the necessity for effective IWW treatment approaches. The Journal of
Water Process Engineering is identified as the leading journal in this domain. The analysis reveals that the
majority of research is concentrated in the fields of chemistry and chemical engineering, with India and China
contributing the highest outputs, at 11.79 % and 10.44 %, respectively. The University of Chinese Academy of
Sciences is highlighted as a significant contributor, with seven publications and 74 citations, underscoring its
prominence in IWW research. The studies indicate a focused interest in addressing various pollutants from in
dustrial wastewater, including chemical oxygen demand (COD), dyes, and heavy metals. Furthermore, this body
of research highlights a significant shift from traditional treatment methods toward integrated strategies that
combine multiple techniques to enhance efficacy and sustainability in IWW treatment. Electrocoagulation,
adsorption, and activated carbon are identified as the predominant treatment methods being explored for specific
types of IWW, particularly textile and tannery wastewater. This research significantly contributes to the un
derstanding of contemporary trends and advancements in IWW treatment, emphasizing the critical role of
innovative methodologies in effectively addressing pollutant removal and promoting environmental
sustainability.
1. Introduction to clean water and sanitation—has grown more important given esti
mates that more than a billion people may experience water shortages
Water resources and quality are under a lot of strain due to the by 2025 (Amdeha, 2023). According to the World Health Organization
world’s ongoing population expansion and urbanization (Christian (WHO), around 1.6 million deaths in 2018 were attributed to water
et al., 2023; Hamaideh et al., 2024). This issue is not limited to devel pollution, highlighting the critical need for clean water management
oping countries; even developed nations experience persistent water (Amdeha, 2023; Naidu et al., 2021; Sanganyado, 2022). Industries such
shortages exacerbated by pollution from industrial activities (Christian as petroleum refining (Jiad and Abbar, 2024), textile manufacturing
et al., 2023; Hamaideh et al., 2024; Amr et al., 2024). Furthermore, the (Christian et al., 2023), dairy industry (Faraj et al., 2024), pharmaceu
United Nations Sustainable Development Goal 6 (SDG 6) ensuring access ticals (Al-Qodah et al., 2024; Al-Zghoul et al., 2023), paint industry
* Corresponding author.
E-mail address: my.azaiza@gmail.com (M.Y.D. Alazaiza).
https://doi.org/10.1016/j.hazadv.2024.100567
Received 3 November 2024; Received in revised form 1 December 2024; Accepted 14 December 2024
Available online 16 December 2024
2772-4166/© 2024 The Authors. Published by Elsevier B.V. This is an open access article under the CC BY license (http://creativecommons.org/licenses/by/4.0/).
M.Y.D. Alazaiza et al. Journal of Hazardous Materials Advances 17 (2025) 100567
(Nair et al., 2021), leather industry (Khilji et al., 2022), and pulp and advancements within specialized fields (Mao et al., 2021; Durán-Sán
paper industry (Patel et al., 2021) are among the largest consumers of chez et al., 2020). Co-citation analysis, which examines citation re
water, resulting in substantial amounts of wastewater that contain a lationships among documents, further enriches this approach by
variety of pollutants. For instance, the textile industry alone is known to enabling researchers to identify and analyze quantitative relationships
generate approximately 20 % of global wastewater (Amdeha, 2023). The within their areas of interest (De Battisti and Salini, 2013). Such ana
industrial capacity for manufacturing increased from 1.2 billion tons in lyses yield valuable bibliometric data that provide an overview of
2000 to 2.3 billion tons in 2017, largely due to the fourth industrial research efforts, helping to uncover new research fronts (Zheng et al.,
revolution (Amdeha, 2023; Naidu et al., 2021; Sanganyado, 2022). This 2017). Ultimately, bibliometrics can be divided into two primary cate
growth has correspondingly led to a rise in industrial effluents, further gories: one focusing on research activity levels, which highlights sig
contaminating water sources with toxic heavy metals, phenolic com nificant subjects, nations, and journals, and the other that uses social
pounds, and other persistent pollutants (Badawi et al., 2023; Kamali network analysis and relationship indicators to explore interconnections
et al., 2019). among keywords, countries, and institutions (De Battisti and Salini,
Industrial effluents exhibit a wide range of characteristics that 2013; Ramos-Rodríguez and Ruíz-Navarro, 2004). These categories
depend on the products manufactured and the chemicals used in the collectively elucidate central and peripheral themes in a field and
production process (Dvořák et al., 2016; Amr et al., 2023). These ef illustrate how they evolve over time (De Battisti and Salini, 2013). As a
fluents often contain high concentrations of organic and inorganic pol result, bibliometric analysis aids researchers in better comprehending
lutants, dissolved and suspended solids, poisonous compounds, the state of knowledge, identifying important publications, and evalu
non-biodegradable materials, and different colors, all of which are ating trends in a given scientific subject, all of which point to areas that
harmful to human health and the environment (Bilińska et al., 2020; require more investigation. These analyses provide details on the main
Ayangunna et al., 2016). With industrial activities consuming enormous ideas and dynamic procedures of a certain field of research (Vasseghian
amounts of fresh water and discharging large volumes of untreated et al., 2023; Jamrah et al., 2024).
effluent, effective wastewater management strategies are essential to Despite valuable bibliometric studies conducted on IWW treatment,
mitigate these impacts and promote sustainable development (Ashrafi limitations exist. Some researchers have restricted their focus to specific
et al., 2015; Badawi et al., 2021; An et al., 2023). The intensity of regions or topics, such as EC (Huang et al., 2024), adsorption (da Silva
pollution is especially alarming in developing nations, where the pro Santos et al., 2021), C/F (Noor and Ngadi, 2024), membrane bioreactor
duction of raw materials generates higher pollution levels compared to (Segredo-Morales et al., 2023), textile wastewater (Halepoto et al.,
finished products (Amr et al., 2023; An et al., 2023; Tong and Elimelech, 2022), tannery wastewater (Li et al., 2022; Zhao et al., 2022), dairy
2016; Nazari et al., 2023). These nations often lack the necessary wastewater (Faraj et al., 2024; Praful and Pattnaik, 2023), and phar
treatment technologies, leading to severe environmental degradation maceutical wastewater treatment (Al-Qodah et al., 2024; Wang et al.,
and public health crises (An et al., 2023; Tong and Elimelech, 2016; 2023). Our research aims to perform a temporal bibliometric analysis of
Nazari et al., 2023). However, the treatment of industrial wastewater the publications on IWW within this framework, specifically covering
(IWW) is complex due to the diverse compounds present at varying the period from 2015-2024. This study is novel in its comprehensive
concentrations (Badawi et al., 2023; Badawi et al., 2021), and each type approach, quantitatively examining characteristics such as the most
of wastewater can differ significantly, even within the same industry active authors and countries, the top journals by publication output, the
(Badawi et al., 2021). Currently, researchers are exploring various number of publications, affiliations, subject areas, co-authorship net
treatment technologies, such as adsorption (Liu et al., 2021), electro works among countries, and the identification of emerging thematic
coagulation (EC) (Al-Zghoul et al., 2023; Amr et al., 2023), membrane areas and research gaps in the field. The papers analyzed were exclu
filtration (Liu et al., 2021), advanced oxidation processes (AOPs) (Islam sively sourced from the Scopus database, ensuring a robust and sys
et al., 2023), coagulation/flocculation (C/F) (Amr et al., 2024), and tematic evaluation of IWW treatment literature. By focusing on recent
membrane bioreactors (Dvořák et al., 2016), focusing on optimizing publications, this study aims to supplement and expand upon the find
performance (Liu et al., 2021), understanding treatment dynamics (Liu ings described in earlier research, providing a clearer picture of the
et al., 2021), and targeting specific pollutants (Islam et al., 2023). Be current trends and advancements in IWW treatment.
sides, after appropriate treatment, wastewater is regarded as a signifi
cant resource for reuse and recycling, providing economic advantages 2. Materials and methods
(Amdeha, 2023; Naidu et al., 2021).
The field of IWW treatment faces significant challenges due to a lack 2.1. Data source and search strategy
of quantitative methods that systematically summarize existing litera
ture. This gap complicates the identification of research hotspots and The Preferred Reporting Items for Systematic Reviews and Meta-
future trends from a macro perspective. Therefore, emerging new trends Analyses (PRISMA) method was used in this study to review the litera
and directions that may eventually aid in the creation of useful and the ture (Durán-Sánchez et al., 2020). Regarding the sort of meta-analysis,
development of economical and practical applications in the future we did not incorporate meta-analysis procedures into the analysis, but
(Baarimah et al., 2024; Shokri and Fard, 2023). Bibliometrics emerges as rather adhered to PRISMA recommendations. One of the useful methods
a vital tool evaluations of scientific activity that are both quantitative for building a sizable and reproducible database in systematic literature
and qualitative (Zheng et al., 2015; Wallin, 2005; Purba et al., 2024). reviews is bibliometric analysis (Durán-Sánchez et al., 2020). When
Bibliometrics employs mathematical and statistical techniques to doing bibliometric analysis, it is important to clearly define the study’s
examine the exterior characteristics of literature, including books, pa goals and provide thorough explanations of how the relevant materials
pers, and patents, as well as their references, which include citations and were found. One may argue that bibliometric analysis’s widespread
co-citations (Purba et al., 2024; Mao et al., 2021; Fard et al., 2023). This acceptability and success can be attributed to its capacity to provide a
analysis reveals quantitative patterns within specific subject areas, comprehensive overview of the research industry, outputs, organiza
allowing for the evaluation of research productivity across individuals, tions, and trends (Biberci, 2023; Donthu et al., 2021; Firdaus et al.,
institutions, and countries (Mao et al., 2021; Fard et al., 2023). The 2019). In order to comprehend the relationship between journal cita
knowledge gathered from bibliometric analysis helps researchers tions and provide a perspective on the current or emerging field of
discover new study directions in addition to improving our compre research, they may be utilized extensively for the evaluation and anal
hension of the state of the field (Mao et al., 2021; De Battisti and Salini, ysis of vast amounts of scholarly data (Firdaus et al., 2019). According to
2013). academics, bibliometric analysis and its consequences might support
Moreover, bibliometric analysis is essential for forecasting future future study and development (Zheng et al., 2017). Bibliometric
2
M.Y.D. Alazaiza et al. Journal of Hazardous Materials Advances 17 (2025) 100567
approaches are used in many different fields because of these features converted into Comma-Separated Values (CSV) files. To guarantee the
(Hallinger and Suriyankietkaew, 2018; Müßigmann et al., 2020). This authenticity and dependability of the data, a number of filtering tech
study used bibliometric analysis to monitor the trends and advance niques were used during the source selection process. Procedures
ments of IWW treatment research. The Scopus database for the years including eliminating redundancies and implementing inclusion and
2015–2024 was used to analyze publications. Because the Scopus exclusion criteria according to language, document type, and source
database covers many academic disciplines and has a wealth of pub were put into place throughout these stages. Following the segmentation
lished articles in the literature sector, it was chosen (Vasseghian et al., and search of the information, the source name, authors, and affiliations
2023; Donthu et al., 2021). A literature search was conducted using the were carefully examined annually. The quality of the discovered papers
following query string and the provided keywords: “(TITLE-ABS-KEY was also taken into account in the document title, abstracts, and key
((“Treatment*”) AND (“Industrial” OR “Industry”) AND (“Wastewaters” words sections. Regretfully, the data filterization procedure required
OR “Effluent*” OR “Sewage”) AND PUBYEAR > 2014 AND PUBYEAR < that any inaccurate or incomplete entries be appropriately removed in
2025 AND (LIMIT-TO (DOCTYPE, “ar”)) AND (LIMIT-TO (SRCTYPE, order to bring the data.
“j”)) AND (LIMIT-TO (LANGUAGE, “English”))). Fig. 1 below provides
an illustration of the search approach. 2.3. Data analysis
According to the keywords, our initial search produced 2672 publi
cations in the form of books, book chapters, conference papers, review The practice of creating, drawing, and presenting bibliometric maps
articles, and articles, as shown in Fig. 1. We then went ahead and nar for readability is common in bibliometric research. This method appears
rowed down this corpus to just include journal articles written in En to make working with literature and identifying the connections be
glish. Following this screening procedure, 1714 publications were tween certain sources easier (Durán-Sánchez et al., 2020). We down
chosen. loaded the data for VOSviewer software processing as we needed to see
the results and familiarize ourselves with the bibliometric results’ out
2.2. Data extraction and filtering lines. The open-source, user-friendly VOSviewer software is used for
networking and bibliometric data visualization (Durán-Sánchez et al.,
Data was extracted, organized in the Scopus database, and then 2020). There are certain aspects in which it is different from other
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M.Y.D. Alazaiza et al. Journal of Hazardous Materials Advances 17 (2025) 100567
software programs, such as CiteSpace, SciMAT, Gephi, and Bib Excel contributions before the year concludes. This data not only highlights a
(Vasseghian et al., 2023; Zahoor et al., 2022). VOSviewer software was generally positive trend in research activity but also emphasizes the
used for data processing and analysis since it has text-mining skills and growing importance and focus on IWW treatment methodologies. By
can handle networks of very large sizes (Hallinger and Suriyankietkaew, situating these findings within the context of identified research gaps,
2018). VOSviewer software was used to create bibliometric maps, which we can better understand how they contribute to advancing knowledge
show the relationships between the chosen articles and aid in the dis in this field. It is essential to distinguish these contributions from
covery of relationships, trends, and patterns in the literature (Kasavan existing literature, as they reflect emerging themes and innovative ap
et al., 2021). One of the program’s advantages is its ability to dynami proaches that warrant further exploration.
cally alter the labels being used, which fits the algorithm’s goal of dis The distribution of publications on IWW treatment reveals signifi
playing co-occurrences (Kasavan et al., 2021). cant patterns in research production across various scientific fields,
The investigation focused on four main areas: the article database, highlighting areas of both strength and opportunity. Notably, “chemical
the author keywords used in the papers and journals where the articles engineering” emerges as the dominant field, accounting for 66.69 % of
were published, and the countries of origin. For bibliometric studies, the published studies. This prominence underscores the critical role that
these elements are crucial because they provide a thorough picture of chemical engineers play in developing and optimizing treatment pro
the state of the research (Van Eck and Waltman, 2013; Usmani et al., cesses, designing efficient systems, and ensuring compliance with
2021; Rai et al., 2020). Publications, average normalized citations, and environmental regulations.
total link strength (TLS) were all considered while determining the In addition, the field of “chemistry” contributes 22.29 % of the
analysis’s parameters. These metrics are helpful in assessing the effect research, emphasizing the vital importance of understanding chemical
and visibility of the item (Rai et al., 2020). reactions and properties in IWW treatment. Insights into the chemical
Only journal articles were among the 1714 papers that were found composition of wastewater and the interactions during treatment pro
throughout the search. 356 distinct publication sources or venues pro cesses are essential for formulating effective purification strategies,
vided these materials. The literature on the topic was authored by 4481 thereby addressing gaps in current methodologies. Furthermore, the
writers from 2635 different institutions throughout the globe. Signifi “energy” domain, representing 11.03 % of the publications, highlights
cant contributions to the literature were made by authors from 99 the intersection between IWW treatment and energy resource manage
different nations. A total of 12679 citations demonstrated the cumula ment. This area focuses on the energy consumption associated with
tive impact of these 1714 publications, highlighting their significance in various treatment methods and the potential for energy recovery from
the academic community. The study of author-supplied keywords effluent, emphasizing the necessity for sustainable practices in IWW
revealed a complex tapestry of 3122 distinct phrases, providing more management. Overall, these findings illustrate the interdisciplinary na
insight into the research emphasis of the literature. The main biblio ture of IWW treatment research and its connection to broader environ
metric conclusions drawn from the review of the literature on IWW mental challenges.
treatment are briefly summarized in Table 1.
3.2. Preeminent journals for research on the IWW treatment
3. Results and discussion
The analysis of the top sources publishing research on IWW treat
3.1. Trend of annual publications ment highlights significant insights into the field’s landscape. The top 15
sources that have published a lot of material about the IWW treatment
Fig. 2a shows how the number of published papers on IWW and the are included in Table 2, together with information about their publi
six major Scopus subject categories has changed over time. A total of cation counts, total citations, TLS, h-index, and SCImago Journal Rank
1,714 research papers in this area published between 2015 and July (SJR). The majority of the papers on IWW treatment are found in a few
2024 were found through a search of the Scopus database. Of them, high-profile scholarly journals. According to the statistics, there is a
“articles,” which include 1714 articles and 64.1 % of all publications, is noticeable concentration of research output in high-impact journals,
the most prevalent form. “Book chapters” (9.8 %), “review articles” indicating that these sources are essential for expanding our under
(7.9 %), “conference articles” (10 %), and others (like “book” and “not standing of this area.
journal”) comprise the others. The other categories were not further Notably, the “Journal of Water Process Engineering” leads with 49
taken into consideration because "articles" made up the majority of publications and 800 citations, demonstrating a strong influence within
publications. the field, with an average of 16.33 citations per paper. In contrast, the
The annual publication trends, illustrated in Fig. 2b, reflect the dy “Desalination of Water Treatment” journal has 45 publications but only
namic nature of research activity in IWW treatment methodologies over 125 citations, resulting in an average of approximately 2.75 citations per
the past decade. Starting with 112 published papers in 2015, there was a article, indicating a more specialized impact despite its significant
steady increase to 138 in 2016. Subsequent years exhibited fluctuations, output. The “Journal of Environmental Chemical Engineering” stands
with 119 publications in 2017, 154 in 2018, and a notable rise to 167 in out with 37 publications and an impressive 1,551 citations, yielding an
2019. The upward trend continued, peaking at 208 publications in 2021 average of 41.89 citations per publication, which reflects its widespread
and reaching 244 articles in 2022. However, a slight decline was recognition and influence in the research community. Other notable
observed in 2023, with 231 papers published. As of 2024, 153 articles journals, such as “Chemosphere” and “Environmental Science and
have already been published, indicating the potential for further Pollution Research,” have published 32 and 28 articles, respectively,
with citation counts of 1,263 and 401. This suggests that these journals
Table 1 not only contribute a substantial volume of research but also provide
Key bibliometric findings summarized. valuable knowledge that resonates within the scientific community.
Furthermore, journals like “Science of the Total Environment” and
Description Findings
“Separation and Purification Technology” have made their mark with 21
Countries 99
and 20 publications and citation averages of 17.57 and 20.9, respec
Authors` Affiliations 2635
Publication Venues 356 tively. The “Journal of Environmental Management” and “Journal of
Author Keywords 3122 Cleaner Production” also contribute significantly, with 19 publications
Authors 4481 and 234 citations, and 18 publications and 474 citations, respectively.
Total Citations 12679 Lastly, “Water Science and Technology” has 17 publications with 148
Publications 1714
citations, indicating a steady, albeit less influential, contribution to the
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M.Y.D. Alazaiza et al. Journal of Hazardous Materials Advances 17 (2025) 100567
Fig. 2. (a) The percentage of document type reports for research on IWW treatment; (b) The annual of IWW treatment research-related publication every year, as
determined by the Scopus database until September 2024 (n = 1714).
field. Overall, this analysis underscores the diverse contributions and 3.3. Country IWW treatment collaboration network
varying impacts of these journals in advancing research on IWW treat
ment methodologies. The current bibliometric study provides a comprehensive overview
Journals with 12 papers published in this field of study between of the leading nations contributing to research on IWW treatment. As
2015 and 2024 were identified as the primary sources. Fifteen of the detailed in Table 3, key data such as publication counts and associated
sources that were found satisfied these requirements, as shown in Fig. 3. citation metrics highlight the significant roles of various countries.
These 15 periodicals serve as the primary information sources for IWW China and India emerge as frontrunners in this field, with 202 and 179
treatment research and are essential to the development of the subject. published papers, respectively, and citation totals of 3,598 and 3,248.
Overall, this analysis illustrates a robust network of high-impact This substantial output positions both countries as major players in IWW
journals dedicated to IWW treatment, emphasizing the importance of treatment research, reflecting their robust research infrastructure and
these platforms in disseminating pivotal research findings. The varying active scholarly engagement.
citation counts reflect both the influence and the specific focus areas of Following closely are Iran and Turkey, which contributed 65 and 62
each journal, suggesting that researchers should consider these factors publications, respectively, garnering total citations of 637 and 568.
when selecting publication venues for their work. These figures indicate a growing interest and investment in wastewater
treatment research within these nations. Brazil, Egypt, and Saudi Arabia
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M.Y.D. Alazaiza et al. Journal of Hazardous Materials Advances 17 (2025) 100567
Table 2 including Spain, Pakistan, South Korea, and the United States,
The top 15 sources by citation count for IWW treatment study. contribute 33, 30, 29, and 29 publications, respectively, with citation
Source TLS Documents Citations H- SJR counts of 459, 407, 785, and 512. This indicates a competitive landscape
index where multiple nations are making valuable research contributions,
Journal of Water Process 630 49 800 89 1.278 albeit with varying levels of impact.
Engineering Finally, the United Kingdom, Morocco, and Mexico, with 26, 25, and
Desalination and Water 574 45 125 83 0.256 23 publications, have accumulated 896, 289, and 260 citations,
Treatment respectively. The disparities in citation counts among these nations
Journal of Environmental 550 37 1551 127 1.355
Chemical Engineering
suggest differing levels of academic influence and recognition within the
Chemosphere 541 32 1263 311 1.806 global research community. Overall, this analysis highlights the dy
Environmental Science and 411 28 401 179 1.006 namic and diverse contributions of nations to the field of IWW treatment
Pollution Research research.
Science of the Total 278 21 396 353 1.998
Because of this approach’s great treatment efficiency, IWW treat
Environment
Separation and Purification 294 20 418 202 1.533 ment has become a global research priority (Costa et al., 2021). A bib
Technology liometric examination of the published literature is necessary to have a
Journal of Environmental 317 19 234 243 1.771 thorough grasp of the state of research in this area at the moment.
Management One common paradigm in this field is research cooperation, which is
Journal of Cleaner 213 18 474 309 2.058
Production
described as the cooperative generation of scientific knowledge (Han
Water Science and 157 17 148 157 0.554
Technology
International Journal of 29 16 95 101 0.598 Table 3
Environmental Science Leading 15 countries in terms of IWW treatment publications between 2015 and
and Technology 2024.
Chemical Engineering 187 15 359 309 2.852
Nation TLS Publications Citations
Journal
Water (Switzerland) 106 13 86 102 0.724 India 47 202 3598
Environmental Research 171 12 134 179 1.679 China 55 179 3248
Sustainability (Switzerland) 126 12 147 169 0.672 Iran 14 65 637
Turkey 8 62 568
Brazil 6 57 1298
also demonstrate notable contributions, with 57, 52, and 45 publica Egypt 26 52 693
Saudi Arabia 53 45 643
tions, respectively. Brazil’s citation count of 1,298 highlights its strong
Malaysia 20 36 303
impact relative to its publication output, while Egypt and Saudi Arabia Spain 10 33 459
have accumulated 693 and 643 citations, respectively. This trend un Pakistan 27 30 407
derscores the diverse research capabilities across different regions and South Korea 29 29 785
suggests that these countries are increasingly addressing the challenges United States 23 29 512
United Kingdom 23 26 896
associated with IWW management.
Morocco 0 25 289
Additionally, Malaysia’s 36 publications, along with 303 citations, Mexico 5 23 260
reflect the relevance of its research output in this area. Other countries,
Fig. 3. Co-occurrence map of journals with over 12 articles treating IWW published between 2015 and 2024.
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M.Y.D. Alazaiza et al. Journal of Hazardous Materials Advances 17 (2025) 100567
et al., 2014). Collaborations can take place between nations, in Other institutions, such as the “Environmental Science and Tech
stitutions, and individual writers, among other levels (Han et al., 2014). nology Research Center” and the “Department of Environmental Science
Using VOSviewer software, a network diagram was created to analyze at the University of Gujrat,” each with four publications, show varying
the network of global partnerships. The participating nations are citation counts of 25 and 15, respectively. This indicates differing levels
depicted as labeled nodes in this image, and the lines connecting the of impact, with the former suggesting relevance in specific areas of IWW
nodes indicate the relative contributions of each country to the total treatment. The “Academy of Scientific and Innovative Research” has
project. The thickness of the lines indicates the intensity of the collab also published four articles, achieving 68 citations, which underscores
orative relationships, and the size of the nodes indicates the number of the significance of its research output. Conversely, the “Center of
citations that the articles from each country have received (Van Eck and Excellence in Environmental Studies at King Abdulaziz University” and
Waltman, 2010). the “Department of Environmental Engineering at Karabuk University,”
As shown in Fig. 4, the network analysis showed that 15 nations have both with four publications, report lower citation counts of 12. This may
shown a strong interest in studying IWW treatment. The nations with the suggest that their research is still developing in terms of visibility and
most significant roles—shown by the thicker connecting linkages and influence.
higher node sizes—are probably leading the way in this area of study. Overall, the analysis reveals a diverse landscape of research in IWW
The worldwide scope of study endeavors and the key figures propelling treatment, with varying levels of publication output and citation impact.
the development of IWW treatment procedures might be represented by The “University of Chinese Academy of Sciences” leads in both quantity
this data. and quality, while “Tianjin University” stands out for its high citation
All things considered, this analysis shows how research efforts in rates, providing valuable insights for future study collaborations and
IWW treatment are distributed globally and emphasizes the disparities funding decisions in the area.
in the level of influence that various nations have had in this new field of These institutions align with the countries that demonstrate signifi
study. The data indicates that while India and China lead the field, other cant contributions, reflecting the strong connection between
nations are making significant contributions, reflecting a collaborative geographical origin and affiliations in this research field. This pattern
international effort to address the pressing challenges of wastewater can be attributed to the countries’ support for scientific research and
management. This growing body of knowledge presents opportunities innovation in IWW treatment, as well as the presence of collaborative
for future research collaborations and policy development aimed at networks among institutions within each country.
enhancing IWW treatment technologies worldwide.
To identify the leading institutions engaged in research on IWW
3.4. Network of co-citation authors in IWW treatment research
treatment, a comprehensive map was developed based on 1,714 publi
cations available in the Scopus database, as illustrated in Fig. 5.
One well-known bibliometric method that makes it possible to map
Instead than naming particular universities or research organiza
the body of existing literature in a systematic manner is co-citation
tions, the initial data mostly gave affiliations in terms of departments or
author network analysis (Hallinger and Suriyankietkaew, 2018). The
colleges. In order to appropriately represent the universities or research
underlying conceptual frameworks and thematic links within a study
institutes involved, this data had to be rearranged, as shown in Table 4.
subject are revealed by this technique, which makes it easier to identify
Among the top affiliations, the “University of Chinese Academy of
studies that are commonly referenced together. We used the VOSviewer
Sciences,” stands out with seven publications and 74 citations, indi
software to do a thorough co-citation network analysis for this investi
cating a strong research presence in the field. Following closely is the
gation. We were able to get important information on the groupings and
“Department of Chemical Engineering at Adama,” which has produced
connections between the articles in the area of interest thanks to our
five publications with 49 citations, reflecting significant contributions to
analytical method. The findings of this in-depth analysis are shown in
the area. The “Department of Applied Chemistry at Razi University in
Table 5, which provide a comprehensive picture of the article’s current
Kermanshah,” has four publications and 22 citations, suggesting that
status in this field. As indicated by their numerous publication outputs,
while its output is moderate, it has added valuable insights to the
the writers found using this co-citation network analysis have proven to
discipline. Notably, the “School of Environmental Science and Engi
be exceptionally committed and knowledgeable in furthering the aca
neering at Tianjin University,” also with four publications, boasts an
demic work in this field. This material is intended to draw attention to
impressive 273 citations, highlighting the high regard and influence of
the significant personalities and foundational works that have influ
its research.
enced the theoretical underpinnings and scholarly conversation
Fig. 4. A network visualization showing the main countries participating in the study on IWW treatment.
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M.Y.D. Alazaiza et al. Journal of Hazardous Materials Advances 17 (2025) 100567
Fig. 5. A network visualization showing the main universities involved in the study examining the treatment of IWW.
Table 4 Table 5
Top 9 universities according to authors’ affiliation. Co-occurrence map of researcher cooperation from 2015 to 2024.
Affiliation Country TLS Documents Citations Author Publications Author Citation
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M.Y.D. Alazaiza et al. Journal of Hazardous Materials Advances 17 (2025) 100567
E. (126 citations), Nidheesh, P. V. (114 citations), and Aadil, M. (97 95.3 % and 97.8 % at nitrate concentrations of 200 mg/L and 2000
citations) round out the top cited authors. These findings suggest that mg/L, respectively. According to research, Ni(OH)2 nanoparticles are
while the field of IWW treatment embraces a collaborative, multi-author formed on the electrode surface during self-activation and are essential
approach, certain researchers have emerged as particularly influential, for the nitrate reduction reaction (NO3RR) because they minimize
significantly impacting both publication outputs and citation counts. hydrogen evolution events and promote an atomic hydrogen-mediated
route. With its high yields and Faradaic efficiency, the self-activated
3.5. The most cited publications in IWW treatment Ni(OH)2@Ni cathode may be readily scaled up to process large
amounts of IWW and effectively convert nitrate into ammonia. This
The scientific mapping of citation analysis is a crucial method for research presents an innovative and efficient method for treating
identifying the intellectual relationships between publications, partic nitrate-laden IWW, producing ammonia as a valuable byproduct, thus
ularly when one study is referenced in another (Donthu et al., 2021). advancing wastewater management and resource recovery (Zheng et al.,
This approach facilitates the analysis of citation trends and patterns and 2021).
aids in identifying the most significant research publications within a The research with 128 citations is the second most cited on the list.
certain academic area (Bang et al., 2023). In order to do this, the study The article published in Chemosphere in 2020 with the title “Treatment
used citation analysis to look at the published publications. Table 6 of dairy industry wastewater by combined aerated electrocoagulation
displays the top 15 publications with the highest number of citations and phytoremediation process” was written by Akansha et al. (2020).
based on the Scopus database. Adherence to the Scopus database is the This study examined the efficacy of treating wastewater from the dairy
sole criterion utilized to rate these articles. This citation analysis offers sector using aerated EC in conjunction with phytoremediation. The
insightful information about the most significant and important works in impacts of several factors, such as electrode type, pH, and voltage, were
the field of IWW treatment research. studied using iron and aluminum electrodes. The results indicated that
The following information summarizes the top seven papers with EC was most effective at neutral pH, with efficiency increasing as
more than 83 citations that were found using a search of the Scopus voltage was raised. With an initial pH of 7 and a voltage of 5 V, the Al–Fe
database: “Electrocatalytic Nitrate Reduction to Ammonia Using a Self- electrode combination produced a maximum chemical oxygen demand
Activated Ni Cathode: From Basics to Scale-Up for Industrial Wastewater (COD) removal efficiency of 86.4 % after 120 min. When comparing
Treatment.” The most cited publication, with 131 citations. In 2021, EC-treated wastewater to raw wastewater, a significant increase in
Zheng et al. published this work in the journal Environmental Science & Canna indica was seen. A 97 % clearance rate of COD was achieved
Technology (Zheng et al., 2021). This study demonstrates the effec when EC and phytoremediation were combined. Tests for bacterial
tiveness of an in situ activated pristine nickel (Ni) electrode for nitrate toxicity also showed that wastewater, whether treated or not, encour
reduction to ammonia in both laboratory and pilot-scale settings. The aged the development of bacteria. These results highlight how well the
self-activated Ni cathode exhibited remarkable activity, selectivity, and combined treatment approach manages effluent from the dairy industry.
stability, achieving ammonium nitrogen (NH+ The third most referenced paper, authored by Iloms, E., is titled
4 –N) conversion yields of
Table 6
The top 15 most-cited articles.
First Author Year Title Source Citations Refs.
Zheng, W. 2021 Self-Activated Ni Cathode for Electrocatalytic Nitrate Reduction to Ammonia: Environmental Science and 131 (Zheng et al., 2021)
From Fundamentals to Scale-Up for Treatment of Industrial Wastewater Technology
Akansha, J. 2020 Treatment of dairy industry wastewater by combined aerated Chemosphere 128 (Akansha et al.,
electrocoagulation and phytoremediation process 2020)
Iloms, E. 2020 Investigating industrial effluent impact on municipal wastewater treatment International journal of 126 (Iloms et al., 2020)
plant in vaal, South Africa environmental research and
public health
Nidheesh, P. 2020 Treatment of mixed industrial wastewater by electrocoagulation and indirect Chemosphere 114 (Nidheesh et al.,
V. electrochemical oxidation 2020)
Aadil, M. 2021 Fabrication of MnO2 nanowires and their nanohybrid with flat conductive FlatChem 97 (Aadil et al., 2021)
matrix for the treatment of industrial effluents
Cai, Q.Q. 2020 Potential of combined advanced oxidation – Biological process for cost- Chemical Engineering Journal 88 (Cai et al., 2020)
effective organic matters removal in reverse osmosis concentrate produced
from industrial wastewater reclamation: Screening of AOP pre-treatment
technologies.
Azari, A. 2023 Magnetic multi-walled carbon nanotubes-loaded alginate for treatment of International Journal of 83 (Azari et al., 2023)
industrial dye manufacturing effluent: adsorption modelling and process Environmental Analytical
optimisation by central composite face-central design. Chemistry
Vélez-Pérez, 2020 Industrial acid mine drainage and municipal wastewater co-treatment by dual- International Journal of Hydrogen 78 (Vélez-Pérez et al.,
L.S. chamber microbial fuel cells. Energy 2020)
Yang, Y. 2020 Activated sludge microbial community and treatment performance of International Journal of 72 (Yang et al., 2020)
wastewater treatment plants in industrial and municipal zones. Environmental Research and
Public Health
EL-Mekkawi, 2020 Solar photocatalytic treatment of industrial wastewater utilizing recycled Journal of cleaner production 71 (EL-Mekkawi et al.,
D. M. polymeric disposals as TiO2 supports. 2020)
Kumari, U. 2020 Facile method to synthesize efficient adsorbent from alumina by nitric acid Journal of hazardous materials 68 (Kumari et al., 2020)
activation: Batch scale defluoridation, kinetics, isotherm studies and
implementation on industrial wastewater treatment.
Manni, A. 2020 New low-cost ceramic microfiltration membrane made from natural magnesite Journal of Environmental 68 (Manni et al., 2020)
for industrial wastewater treatment. Chemical Engineering
He, R. 2023 Tunable Bi-bridge S-scheme Bi2S3/BiOBr heterojunction with oxygen vacancy Separation and Purification 67 (He et al., 2023)
and SPR effect for efficient photocatalytic reduction of Cr(VI) and industrial. Technology
Gholipour, A. 2020 A novel pilot and full-scale constructed wetland study for glass industry Chemosphere 66 (Gholipour et al.,
wastewater treatment. 2020)
Venugopal, V. 2021 Seafood industry effluents: Environmental hazards, treatment and resource Journal of Environmental 64 (Venugopal and
recovery. Chemical Engineering, Sasidharan, 2021)
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M.Y.D. Alazaiza et al. Journal of Hazardous Materials Advances 17 (2025) 100567
“Investigating Industrial Effluent Impact on Municipal Wastewater and FTIR analyses, highlighting the potential of this nanohybrid for
Treatment Plant in Vaal, South Africa,” published in the “International environmental remediation (Aadil et al., 2021).
Journal of Environmental Research and Public Health,” with 126 cita In the Chemical Engineering Journal, the study “Potential of com
tions (Iloms et al., 2020). This study evaluated the effects of industrial bined advanced oxidation–Biological process for cost-effective organic
wastewater containing hazardous heavy metals on the water quality of matter removal in reverse osmosis concentrate produced from industrial
the Vaal River, focusing on the Leeuwkuil wastewater treatment plant wastewater reclamation: Screening of AOP pre-treatment technologies,”
(WWTP) from January to September 2017. The researchers monitored written by Cai et al. (2020), has received 88 citations. The viability of
river samples, WWTP inflow and effluent, as well as physicochemical using AOPs in conjunction with biological treatment to eliminate
parameters and heavy metal concentrations from five industrial sources. organic pollutants from genuine reverse osmosis concentrate (ROC) is
The results revealed significant differences in pH, total dissolved solids assessed in this study. UV/H2O2, UV/Persulfate (PS), Fenton, and Flu
(TDS), dissolved oxygen (DO), COD, biological oxygen demand (BOD), idized Bed Reactor (FBR)-Fenton processes were the four AOPs evalu
and electrical conductivity (EC), with industrial samples exhibiting ated. The most economical pre-treatment choice was the FBR-Fenton
higher values. Elevated amounts of aluminum, copper, lead, and zinc method, which had a chemical cost of S$0.519/m3. The FBR-Fenton
were found in industrial effluents using inductively coupled plasma procedure achieved a COD removal efficiency between 30.9 % and
optical emission spectrometry (ICP-OES), with seasonal variations seen 59.8 % by considerably increasing the BOD5/COD ratios in ROC by 4.2
for zinc and aluminum. Although the WWTP adhered to most South to 10 times under ideal circumstances (10 mM H2O2, 1.25 mM Fe2+, pH
African Green Drop Standards, the concentrations of copper, zinc, and 3, and a hydraulic retention duration of 1 h). The FBR-Fenton technique
lead in the treated effluent exceeded permissible limits, posing risks to was combined with a biological activated carbon (BAC) column that had
river health and biodiversity. The study concluded that the WWTP’s a 120-minute empty bed contact period to improve treatment. This in
capacity was inadequate for effectively reducing heavy metal concen tegrated system continuously eliminated organics from ROC during a
trations due to the high levels of non-biodegradable content in the 120-day period, yielding in an effluent COD level of 26 mg/L and an
influent. Recommendations included improving the pre-treatment of average COD removal efficiency of 69 %. According to analysis, the
industrial effluents, continuous water quality monitoring, and main FBR-Fenton procedure successfully eliminated 83 % of the humic com
taining WWTP infrastructure to mitigate pollution in the Vaal River. pounds that were the predominant organic species in ROC while
Further research on heavy metals in sediments was also suggested to simultaneously enhancing biodegradability. Finding the best AOP for
assess ecological risks (Iloms et al., 2020). ROC pre-treatment, combining certain AOPs with BAC for continuous
In 2020, Nidheesh et al. published a noteworthy study in “Chemo flow therapy, and examining how AOPs affect BAC performance were
sphere” titled “Treatment of Mixed Industrial Wastewater by Electro the objectives of the study. Planctomycetes was the predominant
coagulation and Indirect Electrochemical Oxidation,” which has been phylum under high salinity circumstances, according to microbiological
cited 114 times (Nidheesh et al., 2020). This research addresses the characterization of the BAC media. The FBR-Fenton procedure encour
challenges associated with treating mixed IWW, emphasizing the aged its growth, which improved the removal efficiency of COD.
effectiveness of electrochemical techniques, specifically EC and indirect Lastly, Azari et al. published a study in the “International Journal of
electrochemical oxidation. The authors investigated the removal effi Environmental Analytical Chemistry” that focuses on the use of mag
ciencies for color and COD under various conditions. Their findings netic multi-walled carbon nanotubes loaded with alginate for treating
revealed that both treatment methods performed optimally at neutral industrial dye manufacturing effluent (Azari et al., 2023). This research,
pH levels. Notably, the study compared two connection configurations: which has received 83 citations. In this work, magnetic multi-walled
monopolar (MP) and bipolar (BP). The results indicated that the MP carbon nanotubes loaded with alginate (CNT-Alg-Fe3O4) are used to
configuration outperformed the BP setup, achieving a COD removal of evaluate the removal of dyes from raw textile effluent. The goal is to use
55 % and a color removal of 56 % at a voltage of 1.5 V over one hour, response surface methodology-based central composite face-centered
while the BP configuration yielded lower efficiencies of 43 % COD and design (RSM-CCF) to optimize important parameters including pH,
48 % color removal. Furthermore, when employing indirect electro adsorbent dose, and contact duration. Energy-dispersive X-ray spec
chemical oxidation with graphite electrodes at a pH of 7.7 and a voltage troscopy (EDS), scanning electron microscopy (SEM), vibrating-sample
of 4 V, the researchers found that the addition of sodium chloride magnetometer (VSM), FTIR spectroscopy, and X-ray diffraction (XRD)
significantly enhanced the removal efficiencies, achieving 55 % COD were among the methods used to characterize the adsorbents. A high
and an impressive 99.8 % color removal. The study concluded that the match between the model and the experimental data was shown by the
indirect electrochemical oxidation process, combined with EC using results, which showed a low p-value (7.9714e-13), a relative standard
aluminum electrodes, presents promising and cost-effective options for deviation (RSD) of 1.121, and a coefficient of determination larger than
treating mixed IWW (Nidheesh et al., 2020). 0.953. The removal effectiveness achieved 98.43 % with an adsorption
Another important study, conducted by Aadil et al. and published in capacity of 138.97 ADMI/g under ideal circumstances, which included a
“FlatChem,” focuses on the fabrication of manganese dioxide (MnO2) pH of 3, an adsorbent dosage of 10 g/L, and a contact period of around
nanowires and their hybridization with MXene to treat IWW (Aadil 85.55 min. The adsorption process is monolayer and chemical in char
et al., 2021). This research has garnered 97 citations and emphasizes the acter, as shown by data fitting with the Langmuir isotherm (R2 = 1, X2 =
development of a stable MXene nanohybrid to overcome performance 0.012) and pseudo-second-order kinetics (R2 = 0.993, X2 = 0.015). The
limitations associated with MXene’s tendency to restack and oxidize. dye removal process was spontaneous and endothermic, according to
The study employed various characterization techniques to confirm the thermodynamic characteristics (ΔH◦ > 0, ΔS◦ > 0, and ΔG◦ < 0). Ten
structural integrity and properties of the nanohybrid. The photocatalytic successive studies using the same adsorbent revealed a decline in
and antibacterial activities of the nanohybrid were assessed using removal effectiveness of around 11.94 %. This study demonstrates how
Staphylococcus aureus bacteria and crystal violet dye under solar light well CNT-Alg-Fe3O4 treats wastewater from textiles, which is a signifi
conditions. Remarkably, the H2O2-supported MXene/MnO2 nanohybrid cant component of IWW, particularly in the dyeing and finishing
exhibited superior photocatalytic activity, achieving approximately processes.
91.5 % dye degradation after 50 min with a rate constant of 0.045 As shown in Table 5, these highly referenced published papers
min− 1, demonstrating its effectiveness compared to pure MnO2 and the emphasize the use of various treatment techniques for various forms of
MXene/MnO2 hybrid. According to the results, the MXene/MnO2 IWW, such as dairy wastewater (Akansha et al., 2020), municipal
nanohybrid is a powerful photocatalyst that may break down dangerous wastewater (Vélez-Pérez et al., 2020; Yang et al., 2020), food sector
organic dyes and stop microorganisms from growing in industrial waste. effluents (Shrivastava et al., 2022), and textile wastewater (Azari et al.,
Successful synthesis and integration were verified through SEM, PXRD, 2023; Aghilesh et al., 2021). This body of research highlights a
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communities—create a robust framework for enhancing the sustain membrane surface, reducing its efficiency and lifespan. Addressing
ability and efficiency of IWW treatment, addressing both environmental fouling is crucial for maintaining optimal performance in dye removal
and operational challenges. processes. Together, these keywords illustrate the advancements and
The third cluster focuses on innovative techniques for treating textile challenges in employing membrane technologies for effective IWW
wastewater, which is often characterized by high levels of pollutants and treatment, particularly in the textile industry.
toxicity. EC is a process that utilizes electrical currents to destabilize and The fifth cluster highlights sustainable strategies for managing
remove suspended particles and contaminants from wastewater, offer textile effluent, focusing on both treatment and resource recovery.
ing a highly effective treatment option. The optimization of this process Ozonation is a powerful oxidation process used to degrade organic
is crucial to enhance its efficiency and reduce operational costs. In pollutants and dyes in wastewater, enhancing the overall treatment ef
conjunction with EC, activated carbon can be employed to adsorb ficiency. Coupled with this, the Photo-Fenton process utilizes light to
remaining contaminants, further improving water quality. Coagulation activate Fenton’s reagent, generating hydroxyl radicals that effectively
is a fundamental method where chemicals are added to promote the break down complex contaminants. Conducting a cost analysis is
aggregation of particles, which can then be removed from the water. The essential for evaluating the economic feasibility of these advanced
Electro-Fenton method combines EC with Fenton’s reagent, utilizing treatment technologies, ensuring that the benefits outweigh the ex
iron and hydrogen peroxide to generate hydroxyl radicals that effec penses. Additionally, life cycle assessment provides a comprehensive
tively degrade organic pollutants. The focus on biodegradability and evaluation of the environmental effects associated with the entire
toxicity is essential in wastewater treatment, as these factors determine method, from treatment to disposal. The concept of ZLD aims to elimi
the safety and environmental impact of the treated effluent. Fenton’s nate wastewater discharge by recovering and reusing all water and re
process, similar to Electro-Fenton, also employs the generation of hy sources, thus minimizing environmental impact. Together, these
droxyl radicals to enhance the degradation of recalcitrant compounds. keywords represent a holistic approach to textile effluent management,
Together, these keywords represent a comprehensive approach to emphasizing the importance of sustainability and resource efficiency in
improving the treatment of textile wastewater, addressing both effi IWW treatment.
ciency and environmental concerns. The sixth cluster focuses on advanced methods for treating industrial
The fourth cluster emphasizes the role of membrane methods in the effluent, emphasizing the importance of combining various treatment
treatment of IWW, particularly for dye removal. Ceramic membranes are technologies. Adsorption is a widely used method for eliminating pol
increasingly used due to their durability and resistance to fouling, lutants from wastewater, where pollutants adhere to the surface of ad
making them suitable for harsh wastewater conditions. Ultrafiltration sorbents, effectively reducing their concentration. Photocatalysis is
(UF), nanofiltration (NF), and microfiltration (MF) are key processes another innovative approach that utilizes light-activated catalysts to
that utilize membranes with varying pore sizes to separate contaminants degrade organic pollutants, offering a sustainable method for treating
from water. MF targets larger particles and suspended solids, while UF is effluents. This process can be particularly effective for breaking down
effective for smaller organic molecules and colloids. NF can remove even complex compounds that are resistant to conventional treatments. In the
smaller dissolved substances, including certain dyes and salts, providing context of effluent treatment, monitoring COD is crucial, as it indicates
a comprehensive approach to treating complex wastewater streams. A the amount of organic matter present and helps assess treatment effi
significant challenge in using these membrane technologies is mem ciency. Additionally, anaerobic digestion is an effective biological
brane fouling, which occurs when contaminants accumulate on the treatment method that breaks down organic materials in the absence of
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M.Y.D. Alazaiza et al. Journal of Hazardous Materials Advances 17 (2025) 100567
oxygen, producing biogas that can be harnessed for energy. Together, comprehensive understanding of the ecological footprint associated
these keywords illustrate a multifaceted approach to industrial effluent with these methods.
treatment, integrating adsorption, photocatalysis, and anaerobic diges • Most of the technologies explored in the reviewed literature are at
tion to enhance pollutant removal and promote sustainability. the experimental or laboratory scale, with very limited real-world
The seventh cluster explores the interplay between kinetics and applications. Scaling these technologies up to an industrial level
AOPs in the treatment of IWW. IWW treatment often involves complex still faces many technical, financial, and logistical obstacles.
chemical reactions aimed at removing contaminants effectively. Un
derstanding the kinetics of these reactions is essential for optimizing 4.2. Recommendations for future work
treatment conditions and improving efficiency. AOPs utilize powerful
oxidants to degrade organic pollutants that are typically resistant to To effectively address these challenges in IWW treatment and
conventional treatments. One such oxidant is persulfate, which, when advance the field, the following recommendations are proposed:
activated, generates sulfate radicals capable of breaking down a wide
range of pollutants. The oxidation reactions facilitated by AOPs are • Focus should be directed toward creating scalable, eco-friendly
crucial in achieving significant reductions in pollutant concentrations, technologies for IWW treatment. Emphasis on innovative methods
leading to cleaner effluents. Together, these keywords highlight the such as EC, adsorption, and activated carbon can enhance environ
importance of studying reaction kinetics and employing AOPs to mental sustainability compared to traditional techniques. Research
enhance the effectiveness of IWW treatment. should aim to improve the efficiency, cost-effectiveness, and scal
Finally, the eighth cluster focuses on innovative approaches for ability of these technologies.
addressing the challenges of IWW treatment, particularly in the context • Investigating sustainable practices that not only treat wastewater but
of COD removal. COD is a critical parameter that indicates the level of also recover valuable resources, such as nutrients and energy, will be
organic pollutants present in wastewater, making its reduction essential crucial. Research could explore circular economy approaches that
for environmental compliance and sustainability. Microbial fuel cells view wastewater as a resource rather than a waste product.
(MFCs) represent a promising method for treating IWW while simulta • The exploration of novel materials, such as nanomaterials and bio-
neously generating electricity. In these systems, microorganisms break based adsorbents, can improve pollutant removal efficiency. Future
down organic matter, facilitating COD removal. As they metabolize the studies should assess their effectiveness and scalability in real-world
pollutants, they release electrons, which can be captured as electrical applications.
energy. By integrating MFCs into IWW treatment processes, facilities can • Continued exploration of emerging technologies, such as membrane
enhance COD removal efficiency while benefiting from renewable en bioreactors and electrochemical methods, can provide new avenues
ergy generation. This cluster highlights the potential of combining for enhancing IWW treatment processes.
biological treatment methods with energy recovery strategies to create • Investigating the implications of policies and regulations on the
more sustainable solutions for managing IWW. adoption of advanced treatment technologies can help in under
The eight clusters collectively illustrate a comprehensive framework standing barriers and facilitators for implementation in various
for IWW treatment, integrating traditional and advanced methodolo industries.
gies. They emphasize the importance of effective pollutant removal • Integrating wastewater valorization into circular economy frame
through biological, chemical, and physical processes, while also high works at national and global levels is crucial. Clear guidelines for the
lighting innovative techniques such as EC, AOPs, and membrane tech collection, processing, and redistribution of wastewater across
nologies. Additionally, the research underscores the significance of various industries should be established. Wastewater should be
optimizing treatment conditions using statistical and computational viewed not as a burden but as a valuable resource that can contribute
methods like RSM and ANNs. Sustainable strategies, including ozona to economic growth through the production of biofuels, bioplastics,
tion and Zero Liquid Discharge, further enhance resource recovery and animal feed, and other valuable products.
environmental compliance. By incorporating microbial fuel cells, these • Strengthening collaboration between academic institutions and in
clusters showcase a multifaceted approach that combines pollutant dustry partners is vital for translating laboratory research into large-
degradation with renewable energy generation, ultimately promoting scale applications. Such partnerships can drive innovation, particu
efficiency and sustainability in wastewater management. larly in refining treatment methodologies and enhancing the func
tional properties of treated wastewater.
4. Challenges and recommendations for future works • Comprehensive public awareness campaigns should be implemented
to educate all stakeholders in the agricultural value chain—from
4.1. Challenges farmers to consumers—about the importance of wastewater valori
zation. Training programs focused on sustainable practices, waste
The current study identified several limitations regarding the treat management, and the benefits of a circular economy should be
ment of IWW: developed to encourage active involvement in valorization
initiatives.
• The research relied exclusively on publications indexed in the Scopus
database. This focus may exclude relevant studies from other data By implementing these recommendations, the field of IWW treat
bases or those published in non-English languages and regional ment can make significant strides toward more effective, sustainable,
journals. Consequently, the dataset might not accurately represent and economically viable solutions.
the global research landscape.
• The variety of methodologies used in different studies poses a sig 5. Conclusion
nificant challenges. This diversity prevents direct comparisons and
general conclusions about the effectiveness of various IWW treat A bibliometric analysis of IWW treatment research was carried out in
ment methods, complicating the identification of best practices for this study. After filtering, 1714 articles from the Scopus database were
IWW. subjected to bibliometric analysis using the VOSviewer software. Sig
• While many studies highlight the effectiveness of IWW treatment nificant new developments in this area were made public. According to
methods, few provide a thorough assessment of their environmental the bibliometric study, more than 59.7 % of the research on IWW
impacts. Limited data on life cycle assessment (LCA) restrict a treatment has been published in the previous five years, with a peak of
244 articles in 2022. This indicates that the need to treat IWW is
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M.Y.D. Alazaiza et al. Journal of Hazardous Materials Advances 17 (2025) 100567
becoming more widely recognized. This trend highlights a strong Alazaiza, M.Y.D., Albahnasawi, A., Ali, G.A., Bashir, M.J., Nassani, D.E., Al Maskari, T.,
Abu Amr, S., Abujazar, M.S.S., 2022. Application of natural coagulants for
concern for treating IWW and underscores the research community’s
pharmaceutical removal from water and wastewater: a review. Water 14 (2), 140.
awareness of the rising levels of IWW resulting from urbanization and Alazaiza, M.Y., Albahnasawi, A., Eyvaz, M., Nassani, D.E., Amr, S.S.A., Abujazar, M.S.S.,
pollution. To overcome these obstacles, there is an evident need for the Al-Maskari, O., 2023. Electrochemical-based advanced oxidation for hospital
creation of novel treatment technologies. wastewater treatment. Desalin. Water Treat. 300, 44–56.
Alazaiza, M.Y., Alzghoul, T.M., Amr, S.A., Bangalore Ramu, M., Nassani, D.E., 2024.
The Journal of Water Process Engineering, Desalination and Water Bibliometric insights into car wash wastewater treatment research: trends and
Treatment, and Journal of Environmental Chemical Engineering are the perspectives. In: Water, 16, p. 2034.
three highest ranked scholarly journals that address the treatment of Al-Qodah, Z., Al-Zghoul, T.M., Jamrah, A., 2024. The performance of pharmaceutical
wastewater treatment system of electrocoagulation assisted adsorption using
IWW, according to the results of the current study. The majority of perforated electrodes to reduce passivation. Environ. Sci. Pollut. Res. 31 (13),
research is carried out in relatively common fields with concentrations 20434–20448.
in energy, chemistry, and chemical engineering (66.69 %, 22.29 %, and Al-Zghoul, T.M., Al-Qodah, Z., Al-Jamrah, A., 2023. Performance, modeling, and cost
analysis of chemical coagulation-assisted solar powered electrocoagulation
11.03 %, respectively). With contributions of 11.79 %, 10.44 %, and treatment system for pharmaceutical wastewater. In: Water, 15, p. 980.
3.4 %, respectively, India, China, and Iran made the biggest contribu Amdeha, E., 2023. Biochar-based nanocomposites for industrial wastewater treatment
tions to the field of IWW therapy. The University of Chinese Academy of via adsorption and photocatalytic degradation and the parameters affecting these
processes. Biomass Convers. Biorefin. 1–26.
Sciences made noteworthy contributions in this area with 7 publications Amr, S.S.A., Abujazar, M.S.S., Alazaiza, M.Y., Albahnasawi, A., Omer, F., 2024. Heavy
and 74 citations. Additionally, Tianjin University’s School of Environ metals removal from industrial wastewater using date seeds powder and aluminum
mental Science and Engineering has four publications and an astounding chloride-based hybrid natural/chemical coagulation. Desalin. Water Treat. 318,
100392.
273 citations, demonstrating the importance and impact of its research.
Amr, S.S.A., Abujazar, M.S.S., Karaağaç, S.U., Mahfud, R., Alazaiza, M.Y., Hamad, R.J.,
Co-occurrence and clustering were used to assess the author’s IWW 2023. Application of plant-based natural coagulant for sustainable treatment of steel
treatment terms. The most commonly used terms are “heavy metals,” and iron industrial wastewater, Karabuk, Turkey. Desalin. Water Treat. 287, 39–45.
“electrocoagulation,” “adsorption,” “treatment,” “wastewater,” “indus An, Y.C., Gao, X.X., Jiang, W.L., Han, J.L., Ye, Y., Chen, T.M., Ren, N.Q., Zhang, J.H.,
Liang, B., Li, Z.L., Wang, A.J., Ren, N.Q., 2023. A critical review on graphene oxide
trial wastewater,” “wastewater treatment,” and “response surface membrane for industrial wastewater treatment. Environ. Res. 223, 115409.
methodology.” The primary focus of this field’s research is adequately Ashrafi, O., Yerushalmi, L., Haghighat, F., 2015. Wastewater treatment in the pulp-and-
defined by the keywords that were selected. The most prevalent con paper industry: a review of treatment processes and the associated greenhouse gas
emission. J. Environ. Manag. 158, 146–157.
taminants found in IWW, such as dye, COD, and heavy metals, must be Ayangunna, R.R., Giwa, S.O., Giwa, A., 2016. Coagulation-flocculation treatment of
eliminated. Researchers are also concentrating on ways to remediate industrial wastewater using tamarind seed powder. Int. J. ChemTech Res. 9 (05),
certain kinds of IWW, such wastewater from tanneries and textiles. The 771–780.
Azari, A., Nabizadeh, R., Mahvi, A.H., Nasseri, S., 2023. Magnetic multi-walled carbon
most popular treatment techniques for IWW, according to bibliometric nanotubes-loaded alginate for treatment of industrial dye manufacturing effluent:
study, are ozonation, activated carbon, EC, adsorption, and ceramic adsorption modelling and process optimisation by central composite face-central
membranes. design. Int. J. Environ. Anal. Chem. 103 (7), 1509–1529.
Baarimah, A.O., Bazel, M.A., Alaloul, W.S., Alazaiza, M.Y.D., Al-Zghoul, T.M.,
Almuhaya, B., Khan, A., Mushtaha, A.W., 2024. Artificial intelligence in wastewater
CRediT authorship contribution statement treatment: research trends and future perspectives through bibliometric analysis.
Case Stud. Chem. Environ. Eng. 100926.
Badawi, A.K., Abd Elkodous, M., Ali, G.A., 2021. Recent advances in dye and metal ion
Motasem Y.D. Alazaiza: Formal analysis, Conceptualization.
removal using efficient adsorbents and novel nano-based materials: an overview.
Tharaa M. Alzghoul: Writing – original draft. Madhusudhan Banga RSC Adv. 11 (58), 36528–36553.
lore Ramu: Writing – review & editing. Salem S. Abu Amr: Writing – Badawi, A.K., Salama, R.S., Mostafa, M.M.M., 2023. Natural-based coagulants/
review & editing, Validation. Mohammed F.M. Abushammala: flocculants as sustainable market-valued products for industrial wastewater
treatment: a review of recent developments. RSC Adv. 13 (28), 19335–19355.
Writing – review & editing. Dia Eddin Nassani: Writing – review & Bang, N.P., Ray, S., Kumar, S., 2023. Women in family business research–what we know
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Declaration of competing interest Bilińska, L., Blus, K., Foszpańczyk, M., Gmurek, M., Ledakowicz, S., 2020. Catalytic
ozonation of textile wastewater as a polishing step after industrial scale
The authors declare that they have no known competing financial electrocoagulation. J. Environ. Manag. 265, 110502.
Cai, Q.Q., Wu, M.Y., Li, R., Deng, S.H., Lee, B.C.Y., Ong, S.L., Hu, J.Y., 2020. Potential of
interests or personal relationships that could have appeared to influence combined advanced oxidation–Biological process for cost-effective organic matters
the work reported in this paper. removal in reverse osmosis concentrate produced from industrial wastewater
reclamation: screening of AOP pre-treatment technologies. Chem. Eng. J. 389,
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