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CETL1 - 02 Sapphire TFS PT-01 Class XII (20/10/2024)

Physics, Chemistry and Mathematics

Instructions
Instruction

Sections: 3 Time: 4 Hours

Section: Physics , Sub Section: Single Choice Questions

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1. A system contains charge +q, −2q, 4q, −6q . Find the total charge on the system.

(a) −3q (b) 3q

(c) −5q (d) 5q

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2. The number of electrons present in −1 C of charge is
(a) 6 × 1018 (b) 1.6 × 1019
(c) 6 × 1019 (d) 1.6 × 1018
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3. Two point charges are 3 m apart and their combined charge is 8 μC . The force of repulsion
between them is 0.012 N. Charges are
(a) 4 μC , 4 μC (b) 6 μC , 2 μC
(c) 5 μC , 3 μC (d) 7 μC , 1 μC
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4. The net electric force on a charge of +3 μC at the mid-point on the line joining two charges
of magnitude +2 μC and − 2 μC separated by the distance of 6 mm, is
(a) 6000 N (b) 500 N

(c) 60 N (d) 12000 N

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5. Consider the charges q, q and − q placed at the vertices of an equilateral triangle of each
side l. The sum of forces acting on q charge is
q2 q2
(a) (b)
4 2 πε0 l2 8 πε0 l2
​

​
​ ​

q2
(c) (d) zero
4 πε0 l2
​

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6. The dimensional formula of electric field intensity is

(a) [M1 L1 T3 A−1 ] (b) [ML−1 T−3 A1 ]

(c) [M1 L1 T−3 A−1 ] (d) [ M 1 L 2 T 1 A1 ]
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7. Two point charges +8q and −2q are located at x = 0 and x = L respectively. The point on x
axis at which net electric field is zero due to these charges is
(a) 8 L (b) 4 L

(c) 2L (d) L

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8. Which of the following figures represents the electric field lines due to a single positive
charge?

(a) (b)

(c) (d)

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9.
A surface element d s = 8i^ is placed in an electric field E = 4^i + 5^j + 6k^. What is the ​

total electric flux emanating from the surface?

(a) 32 Nm2 /C (b) 43 Nm2 /C
(c) 68 Nm2 /C (d) 72 Nm2 /C
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10.
An electric dipole of dipole moment p is placed in a uniform external electric field E . Then
​

the

(a) Torque experienced by the dipole is E× p ​

(b) Torque is zero if p is perpendicular to E

​

(c) Torque is maximum if p is perpendicular to E

​

(d) Torque is maximum if p is parallel to E

​

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11. A semicircular arc of radius a is charged uniformly and the charge per unit length is λ. The
electric field at its centre is
λ λ
(a) (b)
2πε0 a2 4πε0 a
​ ​

​ ​

λ2 λ
(c) (d)
2πε0 a 2πε0 a
​
​

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12. Shown below is a distribution of charges. The flux of electric field due to these charges
through the surface S is

(a) 3q/ε0 ​ (b) 2q/ε0 ​

(c) q/ε0 ​ (d) zero

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13. Find the electric potential at the centre of square as shown in figure

(a) 8 V (b) 10 V

(c) 12 V (d) zero

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14. In which of the following states is the potential energy of an electric dipole maximum?

(a) (b)

(c) (d)

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15. A capacitor plates are charged by a battery with 'V' volts. After charging battery is
disconnected and a dielectric slab with dielectric constant 'K' is inserted between its plates,
the potential across the plates of the capacitor will become
(a) Zero (b) V/2

(c) V/K (d) KV

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16. A parallel plate capacitor has a capacitor C . The separation between the plates is doubled
and a dielectric medium is inserted between the plates. If the capacity is 3C , then the
dielectric constant of the medium will be
(a) 1.5 (b) 3

(c) 6 (d) 12

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17. Two metal plate form a parallel plate capacitor. The distance between the plates is d. A metal
sheet of thickness d/2 and the same area is introduced between the plates. What is the ratio
of the capacitances in the two cases?
(a) 4 : 1 (b) 2 : 1

(c) 3 : 1 (d) 5: 1

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18. Three capacitors 3 μF , 6 μF , and 6μF are connected in series to a source of 120 V. The
potential difference, in volts, across the 3 μF capacitor will be
(a) 24 (b) 30

(c) 40 (d) 60

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19. Calculate equivalent capacitance between the points P and Q in the adjoining figure.

(a) C1 + 2C2 + C3
​ ​ ​
(b) 2C1 + C2 + 2C 3
​ ​ ​

(c) C1 + C2 + C3
​ ​ ​ (d) C1 + C2 + 2C 3
​ ​ ​

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20. Figure shows four plates each of area A and separated from one another by a distance d what
is the capacitance between P and Q?

ε0 A 2ε0 A
(a) (b)
​ ​

​ ​

d d
3ε0 A 4ε0 A
(c) (d)
​ ​

​ ​

d d
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21. In the arrangement of capacitors shown in figure, each capacitor is of 9 μF , then the
capacitance between the points A and B is

(a) 9 μF (b) 18 μF

(c) 4.5 μF (d) 15 μF

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22. A parallel plate capacitor with air as a dielectric has capacitance C. A slab of dielectric
constant 2 K, having same thickness as the separation between the plates is introduced so as
to fill one-fourth of the capacitor as shown in figure. The new capacitance will be

C C
(a) (2K + 3) (b) (2K + 2)
4 4
​ ​

C KC
(c) ( K + 1) (d)
4 4
​ ​

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23. The capacitance between the point P and Q in the following circuit, is

(a) 3.5 μF (b) 3 μF

(c) 2 μF (d) 1 μF
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24. Five capacitors each of capacitance 20 μF are joined as shown in the figure. The equivalent
capacitance between A and C is

(a) 10 μF (b) 20 μF
(c) 30 μF (d) 40 μF
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25. Two copper wires of length l and 2l have radii r and 2r respectively. What is the ratio of
their specific resistances?
(a) 1 : 2 (b) 2 : 1

(c) 1 : 1 (d) 1 : 3

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26. One kg of copper is drawn into a wire of 1 mm diameter and a wire of 2 mm diameter. The
resistance of the two wires will be in the ratio
(a) 2 : 1 (b) 1 : 2

(c) 16 : 1 (d) 4 : 1

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27. The charge passing through a conductor is function of time and it is given by q =
2
(2t − 4t + 3) mC. The current through the conductor at t = 4 s, is
(a) 7 mA (b) 19 mA

(c) 15 mA (d) 12 mA

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28. Two wires that are made up of different materials whose specific resistances are in the ratio 2
: 3 , length 3 : 4 and area 4 : 5. The ratio of their resistances is
(a) 6 : 5 (b) 6 : 8

(c) 5 : 8 (d) 1 : 2

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29. In wire of cross-section radius r, free electrons travel with drift velocity v when a current I
flows through the wire. What is the current in another wire of half the radius of the same
material when the drift velocity is 2v?

(a) 2I (b) I
(c) I/2 (d) I/4
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30. A cell having an emf ε and internal resistance r is connected across a variable external
resistance R. As the resistance R is increased, the plot of potential difference V across R is
given by.

(a) (b)

(c) (d)

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31. What is the value of the current I in the following part of an electric network?

(a) 1.3 A (b) 2.7 A

(c) 3.3 A (d) 4.7 A

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32. Potential difference between A and B in the given circuit is

(a) 4 V (b) 5.6 V

(c) 2.8 V (d) 6 V

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33. Determine the current thorough 4Ω resistance.

(a) 0.5 A (b) 1 A

(c) 1.414 A (d) 1.6 A

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34. In the given circuit, the current in the arm BD is

(a) I/2 (b) zero

(c) 2I (d) I/3

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35. Five resistances are joined as shown in the figure.

The equivalent resistance between the points X and Y is

(a) 10 Ω (b) 15 Ω
(c) 20 Ω (d) 30 Ω

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36. In a particle wheatstone bridge circuit as shown, when one more resistance of 100 Ω is
connected in parallel with unknown resistance ′ X ′ , then ratio l1 /l2 become '2'. AB is a ​ ​

uniform wire. The value of 'X' must be

(a) 50 Ω (b) 100 Ω

(c) 200 Ω (d) 400 Ω
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37. 100 W bulb B two 60 W bulbs B
1 2 ​ ​ and B3 are connected to a 250 V source as shown. If W1
​ ​

, W2 and W3 are powers of the bulbs, then

​ ​

(a) W1 > W2 = W3 ​ ​ ​ (b) W1 > W2 > W3

​ ​ ​

(c) W1 < W2 = W3
​ ​ ​ (d) W1 < W2 < W3
​ ​ ​

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38. In the following network potential at O

(a) 4 V (b) 3 V

(c) 6 V (d) 4.8 V

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39. The I -V graphs for two different electric appliances P and Q are shown in the diagram. if RP ​

and RQ be the resistances of the devices, then

​

(a) RP = RQ ​ ​ (b) RP > RQ ​ ​

RQ
(c) RP < RQ (d) RP =
​

2
​ ​
​ ​

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40. A straight wire of length 1 m, and carrying a current of 1.8 A, is placed in a uniform magnetic
field of induction 2 T. If the magnetic field is perpendicular to the length of the wire, then the
force acting on the wire is
(a) 1.8 N (b) 3.6 N

(c) 0.9 N (d) 2.5 N

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41. Ionized hydrogen atoms and α-particles with same momenta enters perpendicular to a
constant magnetic field B., The ratio of their radii of their paths rH ​
: rα will be
​

(a) 1 : 4 (b) 2 : 1

(c) 1 : 2 (d) 4 : 1

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42. Two particles of equal charges after being accelerated through the same potential difference
enter in a uniform transverse magnetic field and describe circular paths of radii R1 and R2 . ​ ​

Then the ratio of their respective masses (M1 /M2 ) is ​ ​

(a) R1 /R2 ​ ​ (b) (R1 /R2 )2 ​ ​

(c) (R2 /R1 ) ​ ​ (d) (R2 /R1 )2 ​ ​

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43. Two particles X and Y having equal charges, after being accelerated through the same
potential difference, enter a region of uniform magnetic field and describes circular path of
radius of ratio 3 : 2. The n, ratio of mass of X to that of Y is
3 4
(a) (b)
2 9
​ ​

9 2
(c) ( ) (d)
4 3
​
​

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44. Two strength of the magnetic field at a point distant r near a long straight current carrying
r
wire is B. The field at a distance will be
2
​

B
(a) (b) 2 B
2
​

B
(c) (d) 4B
4
​

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45. Two parallel long wires A and B carry currents i1 and i2 ( < i1 ). When i1 and i2 are in the
​ ​ ​ ​ ​

same direction, the magnetic field at a point mid way between the wires is 10 μT . If i2 is
​

reverse the field becomes 30 μT . The ratio i1 / i2 is​ ​

(a) 1 (b) 2

(c) 3 (d) 4

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46. PQ and RS are long parallel conductors separated by certain distance. M is the midpoint
between them (see the figure). The net magnetic field at M is B. Now, the current 2 A is
switched off. The field at M now becomes

(a) 2 B (b) B
B
(c) (d) 3 B
2
​

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47. A straight conductor carrying a current I splits into two identical semicircular arcs as shown
in figure below. What is the magnitude of the magnetic field at the centre C of the
resulting circular arcs of radius R?

μ0 I
(a) 0 (b)
​

4R
​

μ0 I μ0 I
(c) (d)
​ ​

2R
​ ​

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48. A long wire carrying a steady current is bent into a circular loop of one turn. The magnetic
field at the centre of the loop is B . It is then bent into a circular coil of n terms. The magnetic
field at the centre of this coil of n turns will be
(a) nB (b) n2 B
(c) 2nB (d) 2n2 B
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49. The wire in the figure carries a current i and consists of a circular arc of radius R and central
π
angle rad, and two straight sections whose extensions intersect the centre C of the arc.
2
​

The magnetic field B that the current produces at C is

μ0 i
(a) B = into the plane of the figure
​

8R
​ ​ ​

μ0 i
(b) B = out of the plane of the figure
​

8R
​ ​ ​

μ0 i
(c) B = into the plane of the figure
​

8πR
​ ​ ​

μ0 i
(d) B = out of the plane of the figure
8πR
​ ​ ​

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50. A conducting wire carrying current is arranged as shown. The magnetic field at O

μ0 i 1 1 μ0 i 1 1
[ − ] [ + ]
​ ​

(a) (b)
12 R1 12 R1
​ ​ ​ ​ ​

R2 ​ ​ R2 ​ ​

μ0 i 1 1 μ0 i 1 1
[ − ] [ + ]
​ ​

(c) (d)
24 R1 24 R1
​ ​ ​ ​ ​ ​

R2 ​ ​ R2 ​ ​

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51. The force per unit length between two straight conductors separated by a distance of 0.02 m
is 2 × 10−3 . The current in one conductor is 10 A and that in the other conductor is
(a) 20 A (b) 5 A

(c) 2 A (d) 10 A

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52. A wire of length L is bent in the form of a circular coil of some turns. A current I flows through
the coil. The coil is placed in a uniform magnetic field B. The maximum torque on the coil can
be

(a)
IBL2 (b)
IBL2
2π 4π
​ ​

(c)
IBL2 (d)
2IBL2
​ ​

π π
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53. Three metal rods of same material and identical in all respects are joined as shown in the
figure. The temperatures at the ends are maintained as indicated.
Assuming no loss of heat from the curved surfaces of the rods, the temperature at the
junction X would be

(a) 45∘ C (b) 60∘ C

(c) 30∘ C (d) 20∘ C
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54. The coefficient of thermal conductivity of copper is nine times that of steel. In the composite
cylindrical bar as shown in the figure given below, what will be the temperature at the
junction of copper and steel?

(a) 75∘ C (b) 67∘ C

(c) 33∘ C (d) 25∘ C
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55. A rectangular body has maximum wavelength λ at 2000 K. its corresponding wavelength at
m ​

3000 K will be
3 2
(a) λm (b) λm
2 3
​ ​ ​ ​

16 81
(c) λm (d) λm
81 16
​ ​ ​ ​

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56. The density of a newly discovered planet is twice that of earth. The acceleration due to
gravity at the surface of the planet is equal to that at the surface of the earth. If the radius of
the earth Re , the radius of the planet would be ​

(a) 2Re ​ (b) 4Re ​

1 1
(c) Re (d) Re
4 2
​ ​ ​ ​

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57. Figure shows elliptical orbit of the planet P about the sun S. The shaded area SCD is twice the
shaded area SAB. If t1 is the time for the planet to move from C to D and t2 is the time to
​ ​

move from A to B, then

(a) t1 = t2 ​ ​ (b) t1 = 2t2

​ ​

(c) t1 = 4t2
​ ​ (d) t1 > t2
​ ​

Correct Marks : 1 Wrong Marks : 0

58. If v is the escape velocity and v is orbital velocity of a satellite for orbit close to the Earth's
e ​

0 ​

surface. The these are related by

(a) v0 = ​ 2 ve ​ ​ (b) v0 = ve ​ ​

v0
ve = ve = 2 v0
​

(c) (d)
2
​ ​
​ ​ ​

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59. A cyclist is travelling with velocity v on a banked curved road of radius R. The angle θ through
which the cyclist leans inwards is given by
Rg
(a) tan θ = (b) tan θ = v 2 Rg
v2
​

v2 g v2
(c) tan θ = (d) tan θ =
Rg
​

R
​

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60. A particle of mass m is observed from an inertial frame of reference and is found to move in a
circle of radius r with a uniform speed v . The centrifugal force on it is
mv2
(a) towards the centre ​

r
mv2
(b) away from the centre ​

r
(c)
mv2
along the tangent through the particle
​

r
(d) Zero
Section: Chemistry , Sub Section: Single Choice Questions

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1. The heteroatoms present in CH3 ​
− CH2 − O − CH2 − CH2 Cl are
​ ​ ​

(i) Oxygen
(ii) Carbon
(iii) Hydrogen
(iv) Chlorine
(a) (i) and (ii) (b) (ii) and (iii)

(c) (iii) and (iv) (d) (i) and (iv)

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2. The major product formed in dehydrohalogenation reaction of 2-Bromo pentane is Pent-2-ene.
This product formation is based on?
(a) Hund's rule (b) Hofmann rule

(c) Huckel's rule (d) Saytzeff's rule

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3. The correct sequence of bond enthalpy of ‘C-X’ bond is:

(a) CH3 − F > CH3 − Cl > CH3 − Br > CH3 − I

​ ​ ​ ​

(b) CH3 − F < CH3 − Cl > CH3 − Br > CH3 − I

​ ​ ​ ​

(c) CH3 − Cl > CH3 − F > CH3 − Br > CH3 − I

​ ​ ​

(d) CH3 − F < CH3 − Cl < CH3 − Br < CH3 − I

​ ​ ​ ​

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4. An assertion and a reason are given below. Choose the correct answer from the following
options.
Assertion(A): Vinyl halides do not undergo nucleophilic substitution easily.
Reason(R): Even through the intermediate carbocation is stabilized by loosely held π -
electrons, the cleavage is difficult because of strong bonding.
(a) Both A and R are correct statements and (R) is the correct statement of (A).

(b) Both (A) and (R) are wrong statements

(c) Both A and R are correct statements but (R) is not the correct explanation of (A).

(d) (A) is a correct statement but (R) is a wrong statement.

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5. Which of the following SN 2 reactions is the slowest?

(a) CH3 CH2 CH2 B r + HO− → CH3 CH2 CH3 OH + Br−

​ ​ ​ ​ ​ ​

(b) CH3 CH2 CH2 Cl + HO− → CH3 CH2 CH2 OH + Cl−

​ ​ ​ ​ ​ ​

(c) CH3 CH2 CH2 I + HO− → CH3 CH2 CH2 OH + I −

​ ​ ​ ​ ​ ​

CH3 CHCH3 + HO− → CH3 CHCH3 + F −

​ ​ ​ ​ ​ ​

∣ ∣
(d)
​ ​

F OH

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6. Compare rate of SN 1 ​

(a) II > III > I (b) II > I > III

(c) I > II > III (d) III > II > I

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7. Tertiary alkyl halides are practically inert to SN 2 mechanism because of ​

(a) Insolubility (b) Instability

(c) Inductive effect (d) Steric hindrance

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8. In SN 1 reaction, the racemization takes place. It is due to
​

(a) (a) Inversion of configuration (b) (b) Retention of configuration

(c) (c) Conversion of configuration (d) Both Inversion and Retention

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9. When ethyl chloride is heated with AgCN, the main product is

(a) Ethyl cyanide (b) ethyl isocyanide

(c) Ethyl amine (d) ethyl nitrate

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10. In the reaction
R − OH + PCl5 → R − Cl+ Other products are
​

(a) HCl and POCl3 ​

(b) H2 O + PCl3 ​

(c) HCl + PO2 Cl ​ (d) H3 PO4 + HCl

​ ​

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11. Consider the following halides

Which is/are correct statement (s)?

1. Reactivity for SN 1 reactions is I > II > III
​

2. Reactivity for SN 2 reactions is I > II > III

​

3. Reactivity for SN 1 reactions is I < II < III

​

4. Reactivity for SN 2 reactions is I < II < III

​

(a) 1, 2 (b) 2, 3

(c) 1, 4 (d) 3, 4

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12. Grignard reagent is not prepared in aqueous medium but prepared in ether medium. because

(a) It is insoluble in water (b) the reagent is highly reactive in ether

the reagent becomes inactive in

(c) the reagent reacts with water (d)
water

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13. Under the influence of air and light, chloroform decomposes into:

OH
(a) CCl4 ​ (b) ∣
(CH3 )2 C − CCl3
​ ​ ​

(c) COCl2 ​ (d) CCl3 C HO ​

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14. Match the columns

Column - I Column - II

Cl2 /UV light

(A) C2 H6 C2 H5 Cl (p) Finkelstein reaction
​

​ ​ ​ ​ ​

NaNO2 +HCl/Cu2 Cl2

(B) C6 H5 NH2 C6 H5 Cl (q) Free radical substitution
​ ​ ​

273−278K
​ ​ ​ ​ ​

(C) CH3 Cl + NaI → CH3 I + NaCl

​ ​
(r) Swarts reaction

(D) CH3 − Br + AgF → CH3 F + AgBr

​ ​
(s) Sandmeyer's reaction
(a) A − (q), B − (s), C − (p); D − (r)
(b) A − (q), B − (r), C − (p); D − (s)
(c) A − (r), B − (p), C − (s); D − (q)
(d) A − (s), B − (r), C − (p); D − (q)
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15. Elimination of bromine from 2-bromobutane results in the formation of

(a) Predominantly 2-butyne

(b) Predominantly 1-butene

(c) Predominantly 2-butene

(d) Equimolar mixture of 1 and 2-butene

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16. In which of the following compounds −I effect of methyl group is operating?

(a) CH3 − Cl ​
(b) CH3 − CH3
​ ​

(c) CH3 MgBr ​

(d) CH3 − NO2
​ ​

Correct Marks : 1 Wrong Marks : 0

17. Which amongst the following is the most stable carbocation?
+ +
(a) CH3 C H2 ​ ​
(b) C H3 ​

CH3 ​

⨁
∣ CH3 − CH
CH3 − C +
​

(c) (d)
​

∣
∣ CH3 ​

CH3 ​

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18. Which of the following species is paramagnetic in nature

(a) Free radical (b) Carbonium ion

(c) Carbanion (d) All the above

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19. The correct order of increasing acid strength of the compounds is

(a) d<a<b<c (b) d<a<c<b

(c) a<d<c<b (d) b<d<a<c
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20. Which of the following is the most stable compound?
+
(a) P h3 C + ​ (b) P h2 C H​

+ +
(c) P h3 C C H 2
​ ​
(d) PhC H2 ​

Correct Marks : 1 Wrong Marks : 0

21. Which of the following is antiaromatic ?

(a) (b)

(c) (d)

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22. Which of the following carboanion is not resonance stabilized ?

(a) (b)

(c) (d)

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23. Among the following

The set which represents the aromatic species is

(a) I, II and III (b) III, IV and V

(c) II and III (d) I, II and IV

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24. The correct order of increasing acidic strength is:

(a) Phenol < Ethanol < Chloroacetic acid < Acetic acid

(b) Ethanol < Phenol < Chloroacetic acid < Acetic acid

(c) Ethanol < Phenol < Acetic acid < Chloroacetic acid

(d) Chloroacetic acid < Acetic acid < Phenol < Ethanol

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25. The IUPAC name for

(a) 1− chloro −2− nitro −4− methylbenzene

(b) 1− chloro −4− methyl −2− nitrobenzene
(c) 2− chloro −1− nitro −5− methylbenzene
(d) m− nitro −p− chlorotoluene
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26. Which one among the following has maximum basic strength.

(a) (b)

(c) (d)

Correct Marks : 1 Wrong Marks : 0

27. The function of AlCl3 in Friedel-Craft's reaction is
​

(a) To absorb HCl (b) To absorb water

(c) To produce nucleophile (d) To produce electrophile

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28. HNCO (isocyanic acid) has following resonating structures:
The order of stability is:

(a) I > III > II (b) I > II > III

(c) II > III > I (d) II > I > III

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29. Rank the following in decreasing order of heat of hydrogenation

(a) i > ii > iii (b) ii > iii > i

(c) i > iii > ii (d) ii > i > iii
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30. Alkyl halides are generally insoluble in water, this is due to

(a) Presence of alkyl group

(b) Polar nature of water

(c) Inability to form hydrogen bond with water

(d) Polar nature of alkyl halides

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31. During osmosis, flow of water through a semi-permeable membrane is:

(a) From a solution having higher concentration only

(b) From both sides of a semi-permeable membrane with equal flow rates.

(c) From both sides of a semi-permeable membrane with unequal flow rates.

(d) From a solution having lower concentration only.

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32. The value of Henry's constant KH is _________. ​

(a) Greater for gases with higher solubility

(b) Greater for gases with lower solubility

(c) Constant for all gases

(d) Not related to the solubility of gases

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33. What is the molarity of a solution containing 10 g of NaOH in 500 mL of solution?
(a) 0.25 mol L−1 (b) 0.75 mol L−1
(c) 0.5 mol L−1 (d) 1.25 mol L−1
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34. The relative lowering in vapour pressure is proportional to the ratio of number of

(a) Solute molecules to solvent molecules

(b) Solvent molecules to solute molecules

(c) Solute molecules to the total number of molecules in solution

(d) Solvent molecules to the total number of molecules in solution.

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35. Express the terms representing the following formulae.

No. of moles of solute

(i) = (w)
Volume of solution in litres
​

No. of moles of solute

(ii) = (X)
Mass of solvent in kg
​

No. of moles of component

(iii) = (Y )
Moles in he solution
​

Mass of component
(iv) = (Z)
Mass of solution
​

(a) W - Molality, X - Molarity, Y - Mass fraction, Z - Mole fraction

(b) W - Molarity, X - Molality, Y - Mass fraction, Z - Mole fraction

(c) W - Molarity, X - Molality, Y - Mole fraction, Z - Mass fraction

(d) W - Molality, X - Molarity, Y - Mole fraction, Z - Mass fraction

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36. The mixture that shows positive deviation from Raoult's law is-

Benzene + Toluene
(a) (b) Acetone + Chloroform

Chloroethane + Bromoethane
(c) (d) Ethanol + Acetone

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37. Which of the following is a colligative property ?

(a) Surface tension (b) Osmotic pressure

(c) Optical rotation (d) Viscosity

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38. A solution is made by dissolving 49 g of H2 SO4 in 250 mL of water. The molarity of the
​ ​

solution prepared is
(a) 2M (b) 1M
(c) 4M (d) 5M
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39. Saturated solution of KNO3 with agar-agar powder is used to make `salt bridge' because:
​

+ −
(a) Size of K is greater than that of NO3 ​

− +
(b) Velocity of NO3 is greater than that of K
​

+ −
(c) Velocity of K and NO3 are nearly the same
​

+ −
(d) Both velocity and sizes of K and NO3 ions are same
​

Correct Marks : 1 Wrong Marks : 0

40. For the reaction Ax By y+ x−
​ ​ ⇌ xA + yB , Ksp can be represented as
​

x y y x
(a) [Ay+ ] [Bx− ] (b) [ A] [ B ]
x y x+y x−y
(c) [ A] [ B ] (d) [ A] [B ]
Correct Marks : 1 Wrong Marks : 0
41. Given below are the half-cell reactions:

Mn2+ + 2e− → Mn; E∘ = −1.18 V

2 (Mn3+ + e− → Mn2+ ) ; E∘ = +1.51 V

∘ 2+
The E for 3Mn → Mn + 2Mn3+ will be:
(a) −0.33V : reaction will not occur (b) −0.33V : reaction will occur
(c) −2.69V : reaction will not occur (d) −2.69V : reaction will occur
Correct Marks : 1 Wrong Marks : 0
2−
42. Find out the oxidation number of carbon in the compound: CO3 . ​

(a) +1 (b) −5
(c) +6 (d) +4
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43. Which is a redox reaction?

(a) 4N a + O2 → 2N a2 O ​ ​ (b) 3O2 → 2O3​ ​

AgNO3 + N aCl → AgCl +

(c) (d) KI → K + + I −
​

NaNO3 ​

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44. Peroxide among the following compound is:

(a) KO2 ​
(b) BaO2 ​

(c) MnO2 ​
(d) NO2 ​

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45. Which one of the following statements is true for electrochemical cell?

(a) H2 is cathode and Cu is anode

​ (b) H2 is anode and Cu is cathode
(c) Reduction occurs at H2 electrode ​ (d) Oxidation occurs at Cu electrode

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46. A cell reaction would be spontaneous if the cell potential and Δr G are respectively: ​

(a) Positive and negative (b) Negative, negative

(c) Zero, zero (d) Positive, zero

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47. Statement I : The water pouch of instant cold pack for treating athletic injuries breaks
when squeezed and NH4 NO3 dissolves lowering the temperature. ​ ​

Statement II : Addition of non-volatile solute into solvent result into depression of

freezing point of the solvent.
(a) Both statement I and statement II are incorrect

(b) Statement I is correct but statement II is incorrect

(c) Statement I is incorrect but statement II is correct

(d) Both statement I and statement II are correct

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48. Limiting molar conductivity of NH4OH (i.e., Λ0m(NH OH) is equal to - ​

4 ​

0 0 0
(a) Λm(NaOH) + Λm(NaCl) − Λm(NaOH)
​ ​ ​

0 0 0
(b) Λm(NaOH) + Λm(NaCl) − Λm(NH Cl) ​ ​ ​

4 ​

0 0 0
(c) Λm(NH OH) + Λm(NH Cl) − Λm(HCl) ​ ​ ​

4 4 ​ ​

0 0 0
(d) Λm(NH Cl) + Λm(NaOH) − Λm(NaCl) ​ ​ ​

4 ​

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49. Which metal is used in galvanization to protect iron from rusting?

(a) Zinc (b) Copper

(c) Silver (d) Gold

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50. The electrical properties and their respective SI units are given below. Identify the wrongly
matched pair.

Electrical property SI unit

(a) Specific conductance S m−1
(b) Conductance S
(c) Equivalent conductance S m2 gequiv −1
(d) Cell constant m
(a) (a) (b) (b)

(c) (c) (d) (d)

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51. Which one is not called a anode reaction from the following?
1
(a) Cl− → Cl2 + e− (b) Cu → Cu++ + 2e−
2
​ ​

(c) Hg + → Hg ++ + e− (d) Zn2+ + 2e− → Zn

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52. At infinite dilution, equivalent conductances of ions are 127 & 76 ohm−1 cm−1 eq−1 Ba+2 & Cl−
respectively. Equivalent conductance (ohm−1 cm−1 eq−1 ) of BaCl2 at infinite dilution is:
(a) 139.5 (b) 101.5

(c) 203 (d) 279

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53. In which of the following cases, empirical formula is the same as molecular formula?

(a) sucrose (C12 H22 O11 ) ​ ​ ​ (b) C6 H6 ​ ​

(c) C2 H5 CO3 H
​ ​ ​ (d) glucose C6 H12 O6 ​ ​ ​

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54. Which of the following is not an example of redox reaction?

(a) CuO + H2 → Cu + H2 O ​ ​
(b) Fe2 O3 + 3CO → 2Fe + 3CO2
​ ​ ​

BaCl2 + H2 SO4 → BaSO4 +

(c) 2K + F2 → 2KF (d)
​ ​ ​ ​

2HCl
​

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55. What are the conditions for an ideal solution which obeys Raoult's law the entire range of
concentration.
(a) Δmix H = 0, Δmix V = 0, PTotal = ρ∘A xA + ρ∘B xB
​ ​ ​ ​ ​ ​

(b) Δmix H = +ve, Δmix V = 0, PTotal = ρ∘A xA + ρ∘B xB

​ ​ ​ ​ ​ ​ ​

(c) Δmix H = 0, Δmix V = +ve, PTotal = ρ∘A xA + ρ∘B xB

​ ​ ​ ​ ​ ​ ​

(d) Δmix H = 0, Δmix V = 0, PTotal = ρ∘B xB

​ ​ ​ ​ ​

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56. Which of the following is a mixture with positive deviation from Ideal nature

(a) Chloroform + Acetone (b) Toulene + Benzene

(c) Water + Nitric acid (d) Water + Ethyl alcohol

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57. 1 amu is equal to
1 1
(a) of C − 12 (b) of O − 16
12 14
​ ​

(c) 1 g of H2 ​ (d) 1.6 × 10−23 kg

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58. Mass of 0.1 mole of methane is

(a) 1.6 g (b) 0.1 g

(c) 1g (d) 16 g
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59. What is the mole fraction of a solute if the solution contains 2 moles of solute and 8 moles of
solvent?
(a) 0.2 (b) 0.25

(c) 0.8 (d) 0.1

Correct Marks : 1 Wrong Marks : 0

60. If the mole fraction of solute in a solution is 0.2, what is the mole fraction of the solvent?

(a) 0.8 (b) 0.5

(c) 1 (d) 0.2

Section: Mathematics , Sub Section: Single Choice Questions

Correct Marks : 1 Wrong Marks : 0

1. The domain of y 1
= is
∣x∣−x
​

(a) [0 , ∞ ) (b) (−∞, 0)

(c) (−∞ , 0] (d) [1 , ∞ )
Correct Marks : 1 Wrong Marks : 0
2. 3π
If sin−1 x + sin−1 y + sin−1 z = , then what is the value of x + y + z ?
2
​

(a) −3 (b) 3
1 1
(c) − (d)
3 3
​ ​

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−1 −1 −1
3. If sin x + sin y + sin z= − 3π
2 then x
​
50
+y 50
+ z 50
− 3
x49 +y 49 + z 49 is
​

(a) 4 (b) 6

(c) 0 (d) 3

Correct Marks : 1 Wrong Marks : 0

4. If x + 1 −1
x
​ = 2,the principal value of sin x is
π π
(a) 4 ​
(b) 2 ​

3π
(c) π (d) 2
​

Correct Marks : 1 Wrong Marks : 0

−1
5. sin (x−3)
The domain of the function f (x) = 9−x2
​

(a) [1, 2) (b) [2, 3)

(c) [1, 2] (d) [2, 3]
Correct Marks : 1 Wrong Marks : 0
6. Domain of f (x) −1 2
= sin (x − 3) is
(a) [− 52 , −1) ∪ (1, 52 ) ​ ​ (b) [− 52 , −1] ∪ [1, 52 ]
​ ​

(c) (− 52 , −1) ∪ (1, 52 ) ​ ​

(d) None of these
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7. If ∣x∣ −1 −1 2x
≤ 1, then 2 tan x + sin ( 1+x 2 ) is equal to
​

(a) 4 tan−1 x (b) 0

(c) π/2 (d) π
Correct Marks : 1 Wrong Marks : 0
8. 3 24
2 sin−1 + cos−1 =
5 25
​ ​

π 2π
(a) (b)
2 3
​
​

5π
(c) (d) None of these
3
​

Correct Marks : 1 Wrong Marks : 0

9. The value of sin −1
(sin 10) is
(a) 10 (b) 10 − 3π
3π − 10 7π
(c) (d) 10 − 2 ​

Correct Marks : 1 Wrong Marks : 0

10. cot [cos−1 7
25 ]
​ =
25 25
(a) 24
​ (b) 7
​

(c) 24 (d) 7
25 ​

24 ​

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2
11. If f x + 2x+5
:R → R be given by f (x) = x2 + x+1 , then f is
​

(a) One-one and onto (b) Many-one and onto

(c) One-one and into (d) Many-one and into

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12. Given function is:

f : R → {0, 1}, such that:

1 if x is rational
f ( x) = {
0 if x is irrational
​

Which one of the following is correct?

(a) The function is one-one into

(b) The function is many-one into

(c) The function is one-one onto

(d) The function is many-one onto

Correct Marks : 1 Wrong Marks : 0

13. The function f (x) = 3 sin 2x − cos 2x + 4 is one-one in the interval
​

(a) [− π2 , π2 ] ​ ​ (b) [− π4 , π4 ]
​ ​

(c) [− π6 , π3 ]
​ ​ (d) [−π, π ]
Correct Marks : 1 Wrong Marks : 0
14. If f be the greatest integer function and g be the modulus function, then (gof) (− 53 ) − ​

(fog) (− 53 ) ​ =
(a) 1 (b) −1
(c) 2 (d) 4
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15. Which of the following functions, f : R → R is one one?
(a) f(x) = ∣x∣ , ∀x ∈ R (b) f (x) = x2 , ∀x ∈ R
(c) f(x) = −x, ∀x ∈ R (d) None of these
Correct Marks : 1 Wrong Marks : 0
16. The function f (x) = sec [log (x + 1 + x2 )] is
​

(a) An odd function

(b) An even function

(c) Neither an odd nor an even function

(d) A constant Function

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17. Match with range of following functions:
Function Range
−1
i) Sin x p) (− π2 , π2 ) ​ ​

−1
ii) Cos x q) [− π2 , π2 ] ​ ​

−1
iii) tan x r) [0, π ]
(a) (i) − p, (ii) − r, (iii) − q (b) (i) − q, (ii) − p, (iii) − r
(c) (i) − r, (ii) q, (iii) − p (d) (i) − q, (ii) − r, (iii) − p
Correct Marks : 1 Wrong Marks : 0
x
18. Let f :R → R be defined by f (x) = 3x2 − 5 and g : R → R by g (x) = x2 +1 then gof is
​

(a) 3x2 (b) 3x2 −5

x4 +2x2 −4 ​

9x4 −30x2 +26 ​

(c) 3x2 (d) 3x2 −5

9x4 +30x2 −2 9x4 −6x2 +26
​ ​

Correct Marks : 1 Wrong Marks : 0

3 6 3 2
19. If g (x + 1) = x + x + 2 then the value of g (x − 1) is
(a) x4 − 3x2 + 2 (b) x4 + x2 + 4
(c) x4 − 3x2 + 4 (d) x4 + x2 + 2
Correct Marks : 1 Wrong Marks : 0
3
20. The function f : (−∞, 1] → (0, e5 ] defined as f (x) = ex −3x+2
is
(a) Many one and onto (b) Many one and into

(c) One-one and onto (d) One-one and into

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21. ⎧ x2 + 1, x ≥ 1
If f (x) = ⎨
⎩
​ , then the value of limx→1 f(x) is ​ ​

3x − 1, x < 1
(a) 2 (b) −2
(c) 1 (d) −1
Correct Marks : 1 Wrong Marks : 0
x+1
22.
The value of limx→∞ ( 3x−4 ) 3
is
​

3x+2
​ ​

(a) e−2/3 (b) e−1/3

(c) e−2 (d) e−1
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23. 1 (1−cos 2x)
The value of limx→0 2
is
​ ​

x
​ ​

(a) 1 (b) −1
(c) 0 (d) Does not exist

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2 n
24. The value of lim x+x +…+x −n
x→1 x−1 is ​ ​

n+1
(a) n (b)
2
​

n(n+1) n(n−1)
(c) (d)
2 ​

2 ​

Correct Marks : 1 Wrong Marks : 0

4 3 3
25. Find the value of k, if lim x −1 x −k
x→1 x−1 ​ ​ = limx→k ​

x2 −k2
​

8
(a)
3
​
(b) 8
(c) 3 (d) Limit doesn’t exists
Correct Marks : 1 Wrong Marks : 0
1
26. e x ​

1/x2
​
;x > 0
Let f ( x) = ​
( 1 + x) ​

k ;x = 0

If f (x) is continuous at x = 0 then k equals

(a) e (b) e ​

(c) e2 (d) e3
Correct Marks : 1 Wrong Marks : 0
3
27. The value of lim 1−cos x
x→0 x sin x cos x ​ ​

(a) 2/5 (b) 3/5

(c) 3/2 (d) 3/4
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28. 4x2
(e −1)
What is the value of limx→0 ​

x sin x
​
?
(a) 1 (b) 6
(c) 4 (d) 8
Correct Marks : 1 Wrong Marks : 0
29. x.2x −x
limx→0 1−cos x
​ ​ =
(a) 0 (b) log 4
(c) log 2 (d) None of these
Correct Marks : 1 Wrong Marks : 0
30. limθ→0 sin 3θ−sin
sin θ
​
θ
​ =
(a) 1 (b) 2
(c) 1/3 (d) 3/2

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31. limx→0 tan x−x
x2 tan x equals ​ ​

(a) 1 (b) 1/2

(c) 1/3 (d) None of these.
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sin x
32. e − 1
lim ​ = ​

x→0 x
(a) 1 (b) e
(c) 1/e (d) none of these

Correct Marks : 1 Wrong Marks : 0

n+1 n 2n
33. 5 +3 −2
limn→∞ ​

5n +2n +32n+3 is equal to

​

(a) 5 (b) 3

(c) 1 (d) zero

Correct Marks : 1 Wrong Marks : 0

34. sin [ 14 cos−1 (− 12 )] =
​ ​

1
(a) 2
​ (b) 1
1 3
(c) 2
(d) ​

2
​

Correct Marks : 1 Wrong Marks : 0

35.
If 0 <x< 2 then cot
π
​
−1
{ 1+sinx+ 1+sinx
​

} ​

​ =
1+sinx− 1−sinx ​ ​

(a) x
2
​
(b) π
4
​ − x
4
(c) π
4
​ + x
4
​
(d) −x
Correct Marks : 1 Wrong Marks : 0
36. sin−1 [x 1 − x − ​
x 1 − x2 ] is equal to
​ ​

(a) sin−1 x + sin−1 x ​ (b) sin−1 x − sin−1 x ​

(c) sin−1 x − sin−1 x

​ (d) none of these

Correct Marks : 1 Wrong Marks : 0

37. The solution of the inequality 2
(tan−1 x) − 3 tan−1 x + 2 ≥ 0 is
(a) (−∞, tan 1] ∪ [tan 2, ∞) (b) (−∞, tan 1]
(c) (−∞, − tan 1] ∪ [tan 2, ∞) (d) [tan 2, ∞)
Correct Marks : 1 Wrong Marks : 0
38. Which one of the following is a bijective function on the set of real numbers

(a) 2x − 5 (b) ∣x ∣
(c) x2 (d) x2 + 1

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Correct Marks : 1 Wrong Marks : 0
39. Let f : x
R → R be a function defined as f(x) = e for each x ∈ R, R is being the set of real
numbers. Which one of the following is correct?
(a) f is one-one but not onto (b) f is onto but not one-one
(c) f is both one-one and onto (d) f is neither one-one nor onto
Correct Marks : 1 Wrong Marks : 0
sin 3x
40. x=0,
If f(x) ={ e2x −1 is continuous at x = 0, then the value of k is
​

k − 2, x = 0
​

3 9
(a) 2
​ (b) 5
​

1 7
(c) 2 ​
(d) 2 ​

Correct Marks : 1 Wrong Marks : 0

1 − tan x π π π
= , x ∈ (0, ). If f (x) is continuous in (0, ), then
41.
Let f ( x) = , x
4x − π 4 2 2
​ ​ ​ ​

π
f ( )=
4
​

1
(a) 1 (b)
2
​

1
(c) − (d) −1
2
​

Correct Marks : 1 Wrong Marks : 0

42. ⎧
⎪ x + λ, −1 < x < 3⎫
⎪
If f (x) =⎨ 4, x = 3 ⎬is continuous at x = 3 then λ =
⎩
⎪3x − 5, ⎭
x>3 ⎪
​ ​ ​ ​

(a) 1 (b) −1
(c) 0 (d) none

Correct Marks : 1 Wrong Marks : 0

43. Let f (x) 2
= [x ] sin πx, x > 0. Then
(a) f is discontinuous everywhere.
(b) f is continuous everywhere.
(c) f is continuous at only those points which are perfect squares.
(d) None of the above

Correct Marks : 1 Wrong Marks : 0

44. x2 sin ( x1 ) , x 
=0
Let f(x) ={ Then at x = 0
​

0, x=0
​

(a) f is continuous but not differentiable

(b) f is continuous but f ′ is not continuous
(c) f ′ is continuous but not differentiable
(d) f and f ′ both are continuous
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Correct Marks : 1 Wrong Marks : 0
45. x + a, if x ≤ 1
If the function f : R → R is given by f (x) = { is continuous at x =1 ,
3 − x2 , if x > 1
​

then a =
(a) 4 (b) 3
(c) 2 (d) 1
Correct Marks : 1 Wrong Marks : 0
46. If f (x) = sgn (x2 − ax + 1) has maximum number of points of discontinuity, then
(a) a ∈ (1, ∞) (b) a ∈ (−1, 1)
(c) a ∈ (−∞, −2) ∪ (2, ∞) (d) a ∈ (−2, 2)
Correct Marks : 1 Wrong Marks : 0
47. The points at which the function f(x) x+1
= x2 +x−12 is discontinuous, are
​

(a) −3, 4 (b) 3, −4

(c) −1, −3, 4 (d) −1, 3, 4
Correct Marks : 1 Wrong Marks : 0
48. ⎧ 2
−x , when x ≤ 0
If f(x) = ⎨ 2
5x − 4, when 0 < x ≤ 1
, then
⎩
4x − 3x, when 1 < x < 2
​ ​

3x + 4, when x ≥ 2
(a) f(x) is continuous at x = 0 (b) f(x) is continuous at x = 2
(c) f(x) is discontinuous at x = 1 (d) None of these

Correct Marks : 1 Wrong Marks : 0

49. The number of points of discontinuity of the greatest integer function f (x) = [x ] , x ∈
(− 72 , 100) is equal to
​

(a) 104 (b) 102

(c) 101 (d) 103
Correct Marks : 1 Wrong Marks : 0
2
50. 3x − 4 x + 1 for x < 1
Let g (x) =[ ]
​

ax + b for x ≥ 1
​

If g (x) is continuous and differentiable at x =1 then

(a) a=b=4 (b) a = b = −4
(c) a = 4 and b= -4 (d) a = - 4 and b = 4

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Correct Marks : 1 Wrong Marks : 0
2
51. 2x + 3 ; x>3
If f (x) ={ 2 is differentiable everywhere, then a
b2
is equal
ax + bx + 1 ; x≤3
​ ​

to
7
(a) 5 (b)
3
​

16
(c) 1 (d)
9
​

Correct Marks : 1 Wrong Marks : 0

52. ⎧ px + q : x≤2
If f (x) = ⎨x − 5x + 6
⎩
2 :
​ 2 < x < 3 is differentiable everywhere, then ∣p∣ +
​

2
ax + bx + 1 : x≥3
1 1
∣q∣ + 4 a + 5 b is equal to
​ ​ ​ ​ ​ ​

(a) 12 (b) 15
(c) 14 (d) 18
Correct Marks : 1 Wrong Marks : 0
53. x2 sin ( x1 ) , x 
=0
The set of all points of differentiability of the function f ( x) = { is
​

0, x=0
​

(a) (−∞, 0) (b) (−∞, ∞) ∼ {0}

(c) [0 , ∞ ) (d) (−∞, ∞)
Correct Marks : 1 Wrong Marks : 0
54. Consider the function f(x) defined by f(x) = ∣x − 2∣ + ∣x∣ + ∣x + 2∣ . Then,
(a) f is derivable at x = 0, 2 (b) f is derivable at x = −2, 0
(c) f is derivable at x = −2, 2 (d) f is not derivable at x = −2, 0, 2
Correct Marks : 1 Wrong Marks : 0
55. If f (x) −1
= ∣1 − x∣, then the points where sin (f ∣x∣) is non-differentiable are
(a) {0, 1} (b) {0, −1}
(c) {0, 1, −1} (d) None of these
Correct Marks : 1 Wrong Marks : 0
2
56. If x = 3 tan t and y = 3 sec t, then the value of d y
at t = π4 , is;
dx2
​ ​

3 1
(a) 2 2
​

​
(b) 3 2 ​

1 1
(c) 6
(d)
6 2
​
​

Correct Marks : 1 Wrong Marks : 0

57. f (x) = ∣∣x∣ − 1∣ is not differentiable at
(a) 0 (b) ±1, 0
(c) 1 (d) ±1

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Correct Marks : 1 Wrong Marks : 0
2
58. ax + bx + 5 x < 3
Let the function f be define by f (x) = { is differentiable ∀ x ϵ R,
bx2 + 2ax x≥3
​

then
25 20 20 25
(a) a= 9 ,b = 9
​ ​ (b) a= 9 ,b = 9
​ ​

4 5 5 4
(c) a= 9, b = 9
​ ​ (d) a= 9, b = 9
​ ​

Correct Marks : 1 Wrong Marks : 0

59. x + 1, when x < 2
If f (x) ={ ′
then f (2) equals
2x − 1, when x ≥ 2
​

(a) 0 (b) 1
(c) 2 (d) Does not exist
Correct Marks : 1 Wrong Marks : 0
60. λ 2x + 3, 0≤x≤3
If f (x) ={ is differentiable at x = 3, then the value of λ +
​

μx + 12, 3<x≤9
​

μ is equal to
(a) 6 (b) 8
(c) 10 (d) 9

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Answer with Explanation

Section: Physics , Sub Section: Single Choice Questions

Q.No. Answer Answer Explanation

1. a -

2. a -

3. b -

4. d -

5. c -

6. c -

7. c -

8. a -

9. a -

10. c -

11. d -

12. b -

13. d -

14. a -

15. c -

16. c -

17. b -

18. d -

19. c -

20. b -

21. d -

22. a -

23. d -

24. b -

25. c -

26. c -

27. d -

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Q.No. Answer Answer Explanation

28. c -

29. c -

30. b -

31. c -

32. b -

33. b -

34. b -

35. b -

36. b -

37. d -

38. d -

39. b -

40. b -

41. b -

42. b -

43. c -

44. b -

45. b -

46. b -

47. a -

48. b -

49. a -

50. c -

51. a -

52. b -

53. b -

54. a -

55. b -

56. d -

57. b -

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Q.No. Answer Answer Explanation

58. d -

59. d -

60. d -

Section: Chemistry , Sub Section: Single Choice Questions

Q.No. Answer Answer Explanation

1. d -

2. d -

3. a -

4. d -

5. d -

6. b -

7. d

SN 1 reaction involves carbocation which are planar (sp2 hybridised)

8. d
​ ​

and thus can be attacked on either face of the carbon.

9. b -

10. a -

11. b -

12. c -

13. c -

Alkyl iodides are often prepared by the reaction of

alkyl chlorides/bromides with NaI in dry acetone. This reaction is known
as Finkelstein reaction. R − X + Nal ⟶ R − I + NaX X =
Cl,Br NaCl thus formed is precipitated in dry acetone. It facilitates the
14. a forword reaction according to le chatelier's principle. The synthesis of
alkyl fluorides is best accomplished by heating an alkyl chloride/
bromide in the presence of a metallic fluoride such as
AgF, Hg2 F2 , CoF2 or SbF3 . The reaction is termed as Swarts
​ ​ ​ ​

reaction. H3 C − Br + AgF ⟶ H3 C − F + AgBr

​ ​

15. c -

16. c -

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Q.No. Answer Answer Explanation

17. c (CH3 )3 C + being 3∘ is the most stable carbocation.

​ ​

18. a -

19. a -

The positive charge on the carbon of triphenylmethyl carbocation is

distributed uniformly over a number of structure. More is the resonance
20. a
structure, greater is the stability

21. a -

22. d -

I, II and IV are aromatic species as they follow Huckel’s rule of

23. d
aromaticity.

The correct order of increasing acidic strength is Ethanol<Phenol<

Acetic acid<Chloroacetic acid.

• Phenol is more acidic than ethanol because in phenol, the

phenoxide ion obtained on deprotonation is stabilized by
resonance which is not possible in case of ethanol.
24. c
• Also carboxylic acids are more acidic than alcohols and phenols
as the carboxylate ion is stabilized by resonance. Chloroacetic
acid is more acidic than acetic acid due to inductive effect of
chlorine atom which stabilizes the carboxylate anion.

Hence, the correct option is (C).

25. b -

26. d -

27. d -

28. a -

29. d -

30. c -

31. c -

32. b -

33. c -

34. c -

35. c -

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Q.No. Answer Answer Explanation

36. d -

37. b -

38. a -

39. c velocities of ions are nearly the same.

Ax By ⇌ xAy+ + yBx−
​ ​

40. a
x y
Ksp = [Ay ] = [Bx− ]
​

41. c -

42. d -

43. a -

44. b -

45. b

For spontaneous Δ, G = −nFE < 0

46. a
∴E>0
47. d -

48. d -

49. a -

50. d -

51. d -

52. c -

53. a -

54. d -

55. a -

56. d -

57. a -

58. a -

59. a -

60. a -

Section: Mathematics , Sub Section: Single Choice Questions

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Q.No. Answer Answer Explanation

The given function is defined for those values of N for which this
1. b inequality is satisfied only if X = 0. Hence the domain of the given
function is (−∞, 0)

2. b -

3. a -

4. b -

5. b -

6. d -

7. a 2 tan−1 x + sin−1 2x
1+x2 ​ = 2 tan−1 x + 2 tan−1 x = 4 tan−1 x
8. a -

sin−1 (sin 10) = 3π − 10

9. c
∵ (sin−1 (sin θ) = 3π − θ if 5π
2 ​ <0< 7π
2 )
​

10. d -

11. d -

12. d Let f(x) be any function

f(x) is onto if range of f(x) = Co-domain

The function f is said to be many-one functions if there exist two or more

than two different elements in X having the same image in Y.

Given function is:

f : R → {0, 1}, such that:

1 if x is rational
f ( x) = {
0 if x is irrational
​

Co-domain = {0, 1}

Since, on taking a straight line parallel to the 𝑥-axis, the group of given
function intersect it at many points

⇒ f(x) is many-one

Range of function is {0, 1}

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Q.No. Answer Answer Explanation

As range of f(x) = Co-domain

⇒ f(x) is onto.

Therefore, f(x) is many-one onto

Hence, the correct option is (D).

13. c -

Given

14. a (gof) ( −5
3
) − (fog) ( −5
​

3
) ​

= g {f ( −5 −5 5
3 )} − f {g ( 3 )} = g (−2) − f ( 3 ) = 2 − 1 = 1.
​ ​ ​

15. c Let us check for each option: (A) Given:

f(x) = ∣x∣ , ∀x ∈ R

As we know that,

f(x) = ∣x∣

−x, x < 0
⇒ f ( x) = {
x, x ≥ 0
​

So, f(−1) = −(−1) = 1 and f(1) = 1

⇒ f(−1) = f(1), but −1 =

1

∴ The property, f (x1 ) ​ = f (x2 ) ⇒ x1 = x2 , does not hold true

​ ​ ​

∀x1 , x2 ∈ R.
​ ​

Therefore, the function f (x) = ∣x∣ , ∀x ∈ R is not an injective function.

(B) Given:

f(x) = x2 , ∀x ∈ R

Let x1 ​ = 1 and x2 = −1 ​

⇒ f (x1 ) = x21 = 1 and f (x2 ) = x22 = 1

​ ​ ​ ​

⇒ f (x1 ) = f (x2 ) but −1 =

​
1 ​

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Q.No. Answer Answer Explanation

∴ The property, f(x)1 ​ = fx2 ⇒ x1 = x2 , does not hold true ∀x1 , x2 ∈

​ ​ ​ ​ ​

R.

Therefore, the function f(x) = x2 , ∀x ∈ R is not an injective function.

(C) Given

f(x) = −x∀x ∈ R

Let x1 and x2 be any two real numbers.

​ ​

f (x1 ) = −1 and f (x2 ) = −x2

​ ​ ​

If f (x1 ) = f (x2 )​ ​

- x1 ​ = −x2 ​

∴ The property f (x1 ) = f (x2 ) ​ ​

x1 = x2 holds true ∀x1 , x2 ∈ R

​ ​ ​ ​

Therefore, the function f(x) = −x, ∀x ∈ R is an injective function.

Hence, the correct option is (C).

16. b -

17. d -

18. b -

19. c -

20. b -

21. a -

22. a -

23. d

24. c -

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Q.No. Answer Answer Explanation

25. a -

26. b -

27. c -

Given that:

2
(e4x −1)
x→0 x sin x ​

Let

2
(e4x −1) 4x
L = limx→0 ​

x sin x ​ × 4x ​

2
(e4x −1)
L = limx→0 ​

x sin x ​ × ( sinx x ) × 4
​

We know that:

ex −1
28. c
limx→0 ​

x
​ =1

sin x
limx→0 ​

x ​ =1
2
(e4x −1)
∴ limx→0 ​

4x2 ​ =1

and limx→0 ( sinx x ) = 1 ​ ​

and,

Now,

L=1×1×4=4

Hence, the correct option is (C).

29. b -

30. b -

31. c -

32. a -

33. d -

34. a -

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Q.No. Answer Answer Explanation

35. a -

Domain x ∈ [0, 1]

π
put sin
−1
x=θ θ ∈ [0, ] ⇒ x = sin θ
2
​

π
sin−1 x = ϕ ⇒ ϕ ∈ [0, ]⇒ x = sin ϕ
2
​ ​ ​

36. b

sin−1 [sin θ 1 − sin2 ϕ − sin ϕ

​ 1 − sin2 θ]
​ sin−1 [sin θ cos ϕ −
cos θ sin ϕ]

sin−1 [sin(θ − ϕ)] = θ − ϕ = sin−1 x − sin−1 x ​

37. b -

∣x∣ is not one-one; x2 is not one-one;

x2 + 1 is not one-one. But 2x − 5 is one-one because f (x) = f (y) ⇒

2x − 5 = 2y − 5 ⇒
38. a

x=y

Now f (x) = 2x − 5 is onto, ∴ f (x) = 2x − 5 is bijective.

39. a Given that:

f : R → R, given by f(x) = ex

one − one:

Let x1 and x2 be any two elements in the domain (R), such that
​ ​

f ( x1 ) = f ( x2 )
​ ​

f ( x1 ) ​

⇒ f ( x 1 ) = ex 1 ​
​

Now f (x1 ) ​ = f ( x2 ) ​

⇒ ex 1 = ex 2 ​ ​

⇒ x1 = x2 ​ ​

∴ f is one-one function
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Q.No. Answer Answer Explanation

Onto:

We know that:

Range of ex is (0, ∞) = R+

⇒ Co-domain = R

Both are not same.

∴ f is not onto function.

+
If the co-domain is replaced by R then the co-domain and
range become the same and in that case, f is onto and therefore, it is
a bijection. Hence, the correct option is (A).

Hence, the correct option is (A).

40. d Since f(x) is given to be continuous at x =0

limx→0 f (x) = f(0)

​

Also limx→a+ ​ f (x) = limx→a− f (x) because f(x) is same for x > 0
​

and x <0

∴ limx→0 f (x) = f(0)​

We know that

ex −1
limx→0 ​

x ​ =1

Therefore

sin 3x
⇒ limx→0 ​

e2x −1 ​ =k−2

Multiplying and dividing by 3x in numerator and by 2x in

denominator, we get:

sin 3x ×3x
⇒ limx→0 3x
=k−2
​

e2x −1
2x ×2x
​ ​

3
⇒ 2 ​ =k−2

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Q.No. Answer Answer Explanation

7
⇒k= 2
​

Hence, the correct option is (D).

41. c -

42. a -

43. d -

44. b -

45. d -

For maximum point of discontinuity x2 − ax + 1 = 0 must have two

distinct roots.

46. c
⇒Δ>0 ⇒ a2 − 4 > 0

⇒ a ∈ (−∞, −2) ∪ (2, ∞)

47. b -

48. b -

49. d -

50. c -

51. c -

52. b -

(d)
2 1
We have f (0 + 0) = limh→0 (0 + h) sin 0+h =​ ​

2 1
limh→0 h sin h = 0
​ ​

Similarly f (0 − 0) = 0
Since f (0 + 0) = f (0 − 0) = f (0), the function is continuous at x =
53. d 0
′ 2
If f (0) = limh→0 (0+h) sin {h1/(0+h)}−0
​ ​

limh→0 h sin (1/h) = 0

​

′
Similarly L, f (0) = 0
Hence f is differentiable at x = 0, and hence for all x
∴ (−∞, ∞)

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Q.No. Answer Answer Explanation

54. d

55. c -

56. d -

57. b There are two modulii in the problem

y = ∣∣x∣ − 1∣ hence we have to consider the cases

When x ≥ 0, x < 0 ∣x∣ ≥ 1 or ∣x∣ ≤ 1

Now x ≥ 1 = x2 − 1 ≥ 0 = ( x + 1) ( x − 1) ≥ 0

x ≥ 1 or x ≤ −1

∣x ∣ ≤ 1 = x 2 − 1 ≤ 0 = ( x + 1 ) ( x − 1 ) ≤ 0

−1 ≤ x ≤ 1

y = ∣x∣ − 1, x ≥ 1 or x ≤ −1

= − (∣x∣ − 1) = 1 − ∣x∣ , −1 ≤ x ≤ 1

now, consdier ∣x∣ = x, x ≥ 0 ∣x ∣ , x < 0

Now we redefine the given function

y = −x − 1 x ≤ −1

y=x+1 −1≤x<0

y = −x + 1 0≤x<1

y=x−1 x≥1

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24/12/2024, 11:14 Deeple Learning Tool

Q.No. Answer Answer Explanation

From the graph it is clear that f(x) is not differentiable at x = −1 , 0, 1

58. a -

59. d As Lf (2) = Rf (2).


60. b -

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