PODAR INTERNATIONAL SCHOOL , RAJKOT

Chapters : 7-9 Std 11 : Chemistry Date : 28/12/24

60 Work sheet 60 min
Section A
//X
• Write the answer of the following questions. [Each carries 1 Mark] [60]
1. The oxidation number of phosphorus in Ba(H2 PO 2)2 is.....
(A) +3 (B) +2 (C) +1 (D) –1
2. The oxidation state of chromium in Cr(CO)6 is.....
(A) 0 (B) +2 (C) –2 (D) +6
3. In the reaction,
2FeCl3 + H2 S ® 2FeCl2 + 2HCl + S
(A) FeCl3 acts as an oxidizing agent (B) Both H2 S and FeCl3 are oxidized
(C) FeCl3 is oxidized while H2S is reduced (D) H2 S acts as an oxidizing agent
4. Fluorine is the best oxidizing agent because it has.....
(A) highest electron affinity. (B) highest E° (reduction).
(C) highest E° (oxidation). (D) lower electron affinity.
5. What is the oxidation number of O in O2F2 ?
(A) –2 (B) –1 (C) 1 (D) +2
6. Which is the oxidation number of carbon underlined in CH3 COO · CH2 · CH3 ?
(A) +1 (B) +4 (C) –3 (D) +3
7. What is the oxidation number of underlined nitrogen in NH 4 NO 3 ?
(A) –3 (B) +3 (C) +5 (D) –1
8. Oxidation number of iodine in IO 3– , IO4–, KI and I2 respectively are ........
(A) –1, –1, 0, +1 (B) +3, +5, +7, 0
(C) +5, +7, –1, 0 (D) –1, –5, –1, 0(E)–2, –5, –1, 0
9. Which of the following is the most powerful oxidizing agent ?
(A) F2 (B) Cl2 (C) Br2 (D) l2
10. Which of the following acid processes oxidising reducing and complex forming properties ?
(A) HNO3 (B) H2SO4 (C) HCl (D) HNO2
11. The average oxidation number of iron in Fe3O4 (ferrousferic oxide) is.....
8 2
(A) +2 (B) +3 (C) (D)
3 3
12. Without losing its concentration, ZnCl 2 solution cannot be kept in contact with.....
(A) Au (B) Al (C) Pb (D) Ag
13. What is the oxidising agent in chlorine water ?
(A) HCl (B) HClO2 (C) HOCl (D) None of these
14. Which of the following reactions is an example of a redox reaction ?
(A) XeF4 + O2F2 -® XeF6 + O2 (B) XeF2 + PF5 -® [XeF]+ + PF6–
(C) XeF6 + H2O -® XeOF4 + 2HF (D) XeF6 + 2H2O -® XeO2F2 + 4HF
15. The oxidation number of K in K2O, K2O2 and KO2 respectively is...
(A) +0.5, +4, +1 (B) +2, +1, +0.5 (C) +1, +1, +1 (D) +0.5, +1, +2
16. What is the change in oxidation number of carbon in the following reaction ?
CH4(g) + 4Cl2(g) ® CCl4(l) + 4HCl(g)
(A) –4 to +4 (B) 0 to –4 (C) +4 to +4 (D) 0 to +4
 What is the change in oxidation number of carbon in the following reaction ?
CH4(g) + 4Cl2(g) ® CCl4(l) + 4HCl(g)
(A) –4 to +4 (B) 0 to –4 (C) +4 to +4 (D) 0 to +4
17. Identify the incorrect statement from the following :
(A) Ionisation enthalpy of alkali metals decreases from top to bottom in the group.
(B) Lithium is the strongest reducing agent among the alkali metals.
(C) Alkali metals react with water to form their hydroxides.
(D) The oxidation number of K in KO2 is 4.

18. The compound having both sp and sp2 hybridised carbon atoms is..... .
(A) propene (B) propyne (C) 3-ene 1-butyne (D) butadiene-1,3
19. The molecule in which the distance between the two adjacent carbon atom is largest in..... .
(A) ethane (B) ethene (C) ethyne (D) benzene
20. Among the given cations, the most stable carbonium ion is..... .
(A) sec · butyl (B) tert · butyl (C) n-butyl (D) isobutyl
21. The compound C4H10O can show..... .
(A) metamerism (B) position isomerism
(C) functional isomerism (D) all the three
22. The maximum number of isomers for an alkene with molecular formula C4H8 is ........ .
(A) two (B) three (C) four (D) six
23. The no. of possible isomers of C4H10O is. ...... .
(A) 7 (B) 6 (C) 4 (D) 3
24. The highest boiling point is expected for..... .
(A) iso - octane (B) n - octane
(C) 2, 2, 3, 3 - tetramethyl butane (D) n - butane
25. Only two isomeric monochloro derivatives are possible for..... .
(A) n-butane (B) 2, 4 - dimethyl pentane
(C) benzene (D) 2 - methyl propane
26. An isomer of ethanol is..... .
(A) methanol (B) diethyl ether (C) acetone (D) dimethyl ether
1 2 3
27. The bond between carbon atom (1) and carbon atom (2) in the compound N º C – CH = CH2 involves
the hybrids as..... .
(A) sp and sp2 (B) sp2 and sp2 (C) sp and sp (D) sp3 and sp
28. Which of the following has bond formed by overlap of sp3 – sp hybrid orbitals ?
(A) CH3 – C º C – H (B) CH3 – CH = CH – CH3
(C) CH2 = CH – CH = CH2 (D) HC º CH
29. Which is the correct decreasing order of stability ?
+
(i) CH3 – CH – CH3
+
(ii) CH3 – CH – O – CH3
+
(iii) CH3 – CH – CO – CH3
(A) (i) < (ii) < (iii) (B) (i) > (ii) > (iii) (C) (iii) > (ii) > (i) (D) (ii) > (iii) > (i)
30. Which of the following compound has incorrect IUPAC nomenclature ?
O
||
(A) CH3CH 2CH2 – C –OC2 H5 (B) CH3 C HCH 2CHO
|
Ethyl butanoate
CH 3
O 3-methyl butanal
||
(C) CH 3 C H – C – CH 2CH 3 (D) CH 3 – C H – C H CH 3
|
 (A) CH3CH 2CH2 – C –OC2 H5 (B) CH3 C HCH 2CHO
|
Ethyl butanoate
CH 3
O 3-methyl butanal
||
(C) CH 3 C H – C – CH 2CH 3 (D) CH 3 – C H – C H CH 3
| | |
CH3
2-methyl-3-pentanone CH3 OH
2-methyl-3-butanol
31. The IUPAC name of CH3COCH(CH3)2 is ...... .
(A) isopropylmethyl ketone (B) 2-methyl-3-butanone
(C) 4-methyl-isopropyl ketone (D) 3-methyl-2-butanone
32. Which is the most stable carbonium ion ?
(A) CH3 CH +2 (B) C+H3 (C) (CH3 )3 C+ (D) (CH3 )2 C+H
33. The increasing order of stability of the following free radicals is ...... .
& <(CH ) C& <(C H ) CH
(A) (CH3 )2 CH & < (C H ) C&
3 3 6 5 2 6 5 3
& & &
(B) (C H ) C < (C H ) CH <(CH ) C < (CH ) CH &
6 5 3 6 5 2 3 3 3 2
& <(C H ) C
(C) (C6H5 )2 CH & & &
6 5 3 <(CH3 )3 C < (CH3 )2 CH
& <(CH ) C
(D) (CH3 )2 CH & & &
3 3 < (C6 H5 )3 C < (C6 H5 )2 CH

34. The IUPAC name of the compound shown below is ........ .

Cl

Br
(A) 2-bromo-6-chlorocyclohex-1-ene (B) 6-bromo-2-chlorocyclohexene
(C) 3-bromo-1-chlorocyclohexene (D) 1-bromo-3-chlorocyclohexene
35. The correct decreasing order of priority for the functional groups of organic compounds in the IUPAC
system of nomenclature is ........ .
(A) – SO3H, – COOH, – CONH2, – CHO (B) – CHO, – COOH, – SO3H, – CONH2
(C) – CONH2, – CHO, – SO3H, – COOH (D) – COOH, – SO3H, – CONH2, – –CHO
36. Arrange the carbanions,
(CH)3 C , C Cl3, (CH3)2 C H, C6H5 C H2
in order of their decreasing stability
(A) C6H5 C H2 > C Cl3 > (CH3)3 C > (CH3)2 C H (B) (CH)2 C H > C Cl3 > C6H5 C H2 > (CH3)3 C
(C) C Cl3 > C6H5 C H2 > (CH3)2 C H > (CH3)3 C (D) (CH3)2 C H > (CH3)3 C > C6H5 C H2 > C Cl3
37. Which of the following is correct with respect to –I effect of the substituents ? (R = alkyl)
(A) – NR2 > – OR > – F (B) – NH2 < – OR < – F (C) – NH2 > – OR > – F (D) – NR2 < – OR < – F
38. The correct IUPAC name of the following compound is :
NO2

Cl
CH3
(A) 5-chloro-4-methyl-1-nitrobenzene (B) 2-methyl-5-nitro-1-chlorobenzene
(C) 3-chloro-4-methyl-1-nitrobenzene (D) 2-chloro-1-methyl-4-nitrobenzene
39. A tertiary butyl carbocation is more stable than a secondary butyl carbocation because of which of
the following ?
(A) –R effect of –CH3 groups (B) Hyperconjugation
(C) –I effect of –CH3 groups (D) +R effect of –CH3 groups
40. The IUPAC nameof the following compound is
CH3
O
C – OH
 The IUPAC nameof the following compound is
CH3
O
C – OH

Br
(A) 3-Bromo-5-methylcyclopentane (B) 3-Bromo-5-methylcyclopentanoic
(C) 5-Bromo-5-methylcyclopentanoic (D) 4-Bromo-2-methylcyclopentanecarboxylicacid
41. The correct structure of 2,6-Dimethyl-dec- 4-ene is

(A) (B) (C) (D)

42. NAME OF IUPAC : HO OH

OH
(A) Propane-1,2,3-triol (B) Pentane-1,3,5-triol (C) Butene-1,2,3-triol (D) Glycerol
43. In the preparation of Grignard reagent from haloalkane, the metal used is
(A) Mg (B) Zn (C) Li (D) K
44. Sodium acetate can be converted to ethane by
(A) Heating with LiAlH4 (B) Electrolysing its aqueous solution
(C) Heating with sodalime (D) Heating with calcium acetate
45. In Wurtz reaction, the reagent used is
(A) Na (B) Na/liquid NH3 (C) Na/dry ether (D) Na/dry alcohol
46. Which of the following has highest octane number
(A) n-hexane (B) n-heptane
(C) n-pentane (D) 2, 2, 4-trimethyl pentane
47. Which of the following is not formed by the reaction of Cl2 on CH4 in sunlight
(A) CHCl3 (B) CH3Cl (C) CH3 CH3 (D) CH3CH2 CH3
KMnO
48. CH2 = CH2 ¾¾¾¾¾ 4 ® X.
Product ‘X’ in above reaction is
KOH/H O 2
(A) Ethylene glycol (B) Glucose (C) Ethanol (D) All of these
49. The test for unsaturation is confirmed by the decolourisation of which of the following.
(A) Iodine water (B) CuSO4 solution (C) Bromine water (D) All of these
50. 1, 3-butadiene reacts with ethylene to form
(A) Benzene (B) Cyclohexane
(C) Cyclohexene (D) 2,3-dimethyl butane
51. When propyne reacts with aqueous H2SO4 in the presence of HgSO4, the major product is
(A) Propanal (B) Propyl hydrogen sulphate
(C) Acetone (D) Propanol
52. Which of the following is used to distinguish ehtylene and acetylene
(A) Alkaline KMnO 4 (B) Bromine water
(C) Ammonical cuprous chloride (D) Conc. H2SO 4

Anhydrous
53. C6H6 + CH3Cl ® C6H5CH3 + HCl is an example of
AlCl 3
(A) Friedel-Craft’s reaction (B) Kolbe’s synthesis
(C) Wurtz reaction (D) Grignard reaction
54. CH º CH + HBr ® X, product X is
(A) Ethylene bromide (B) Vinyl bromide
(C) Bromo ethane (D) Ethyledine bromide
 CH º CH + HBr ® X, product X is
(A) Ethylene bromide (B) Vinyl bromide
(C) Bromo ethane (D) Ethyledine bromide
55. The addition of HBr is easiest with
(A) Cl2C = CHCl (B) ClCH = CHCl (C) CH3 – CH = CH2 (D) (CH3 )2C = CH2
56. The most suitable reagent for the following conversion, is :
H3 C CH3
H3C – C º C – CH3 ®
H H
cis-2-butene
(A) Hg2+ / H+, H2O (B) Na / liquid NH3 (C) H2, Pd/C, quinoline (D) Zn / HCl
57. Which of the following alkane can not be made in good yield by Wurtz reaction ?
(A) n-Heptane (B) n-Butane
(C) n-Hexane (D) 2,3-Dimethylbutane
58. Dihedral angle of the least stable conformer of ethane is :
(A) 60° (B) 0° (C) 120° (D) 180°
59. The major product of the following chemical reaction is :
CH3 (C H CO)2O2
CH–CH=CH 2 + HBr 6 5 ?
CH3

CH3 CH3
(A) CH–CH–CH3 (B) CBr–CH 2–CH3
CH3 CH3
Br
CH3 CH3
(C) CH–CH2–CH 2–Br (D) CH–CH2– CH2–O–COC6H 5
CH3 CH3
60. Major product ‘B’ of the following reaction sequence is :
Br2 HI
CH3 – C = CH – CH3 A B
CH3OH (Major product)
CH3
HO Br I Br
| | | |
(A) CH3 – C – CH – CH3 (B) CH3 – C – CH – CH3
| |
CH3 CH3
Br OH Br I
| | | |
(C) CH3 – C – CH – CH3 (D) CH3 – C – CH – CH3
| |
CH3 CH3