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Analysis and Analyzer in FnB Industry

Slide 1 01/16/2018 Nissyia Mazhaly, ST.,MT

Analysis and Analyzer in FnB Industry

Curiculum Vitae

Nissyia Mazhaly, ST., MT

( Industry Manager F&B ǀ Analysis Product )
PT. Endress + Hauser Indonesia
Multika Building, suite 300, 3rd floor
Jl. Mampang Parapatan Raya Kav 71-73
Jakarta – Selatan
HP : 0811-1986620

2010 – Present : PT. Grama Bazita – PT. Endress +Hauser Indonesia

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Analysis and Analyzer in FnB Industry

Content

• Analysis
• pH
• Conductivity
• Chlorine
• Dissolve Oxygen
• Turbidity
• Analyzer
• CA80AM
• CA80PH
• CA80NO
• CA80FE
• CA80CR
• CA80COD
• CA80TP

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Analysis and Analyzer in FnB Industry

Analytical Portfolio

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Analysis and Analyzer in FnB Industry

Analyzer Portfolio ( System )

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 Analysis and Analyzer in FnB Industry
Liquiline CM44 platform
Memosens sensors with
Digital fixed-cable sensors inductive plug-in head
with Memosens protocol • pH
• Nitrate, SAC • ORP
• Turbidity • Conductivity conductive
• ISE • DO amperometric+optical
• DO opt. • Chlorine
• Conductivity inductive

Product properties
Product • Backlit display • Profibus DP with Profile 3.02
• 1..4 relays Modbus TCP,
• Memosens technology
• 1..8 x 0/4..20mA Modbus RS485 (RTU),
• Hot Plug & Play for all sensors
analog output, HART EtherNet/IP
• Modular extendable
• Digital in/outputs* • Ethernet configuration
• Identical HMI for 1..8 channels • 4..20mA analog input* via web browser
• Identical hardware for 1..8 channels • Heartbeat Technology*
• Seamless integration by standardized • Easy diagnostics
communication technologies (NE107 categories, plain text messages, graphical
trend monitoring)

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Analysis and Analyzer in FnB Industry

Analytical – p H
pH is a potentiometric measurement method.
The measuring effect is based on a pH sensitive glass
membrane whose surface reacts to the acid content
with a specific voltage.
This voltage is then measured relative to a reference
element.
pH is calculated according the Nernst law equation.

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Analysis and Analyzer in FnB Industry

p H Sensors

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Analysis and Analyzer in FnB Industry

p H Sensors

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Analysis and Analyzer in FnB Industry

Analytical – p H

• Application example: Raw sugar juice

Challenge:
The raw sugar juice (90°C / pH11)
is sticky and viscous: Very fast soiling of the pH
electrode.

Solution:
Installation of an automatic cleaning system with
Chemoclean Plus and hygienic retractable
assembly CPA875.
Cleaning interval: every 30 min

•CPS471D pH of sulfated juice with CM442

•CPS441D pH in lime solution

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Analysis and Analyzer in FnB Industry

Analytical – p H

• Application: Mayonnaise and Ketchup

Reason to measure pH
pH is important for the taste, the life
period and the consistency of
mayonnaise/ ketchup

Challenges of the application

Mayonnaise with very high content of fat
and very high viscosity, ketchup with high
content of sugar

Equipment:
Liquiline CM44x with Ceramax CPS341D

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Analysis and Analyzer in FnB Industry

Analytical – p H

Application: • Sensor is coated within short time with lime and

For all hygienic applications with frequent soiling of the raw sugar juice
sensor to maintain best measuring performance. • Continuous measurement 24 hours / 7 days a
week
• Cleaning using condensate, water and acid
• Cleaning start is triggered by PLC via DI (2x
Benefit: “Chemoclean plus”)
Safe money due to regular & automatic instead of time • Hot flushing/sealing water (condensate) at
consuming manual cleaning cleaning process

+ +
Liquiline CM44x including Chemoclean valve block CYR10 hygienic retractable
Plus with Cleanfit Control CYC25 and cleansing agent assembly CPA875

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Analysis and Analyzer in FnB Industry

Analytical – p H

• Application : Low conductivity

• pH measurement in ultrapure water, which is used for PC board cleaning
• Conductivity can be low to 0.2 μS/cm

• CPS41D-BB + CPY7 with assembly CPA240

• Cautions of application
• Plastic assembly(CPA250) can not be used, we must use stainless steel
assembly (order code: 71042404)
• Flow rate should be controlled under 50-100ml/min
• Make sure sensor be immersed in buffer solution with long time for better
adaption when calibration

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Analysis and Analyzer in FnB Industry

Analysis - Conductivity

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Analysis and Analyzer in FnB Industry

Analysis - Conductivity

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Analysis and Analyzer in FnB Industry

Analysis - Conductivity
Electrolytic conductivity
Capability of a liquid to conduct current. This depends on the
quantity of ions in the liquid.

Core application:
• CIP control
• Phase separation
• Bottle cleaning
• Product monitoring

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Analysis and Analyzer in FnB Industry

Analysis - Conductivity
Application : CIP
Concentration managing

•Caustic detergent concentration

•Acid detergent concentration

Concentration curves:

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Analysis and Analyzer in FnB Industry

Conductivity Segmentation Food & Beverages -Applications

Applications Suitable sensors

Process monitoring CLS54D CLD134 CLD18 CLS82D

Compact Small pipes DN50
instrumentation fit for purpose

Phase separation CLS54D CLD134 CLD18

(Process/Utilities) Compact
instrumentation
Small pipes DN50
fit for purpose

CIP (Utilities) CLS54D CLD134 CLD18

Compact fit for purpose
instrumentation

Final rinse CLS54D CLD134 CLS82D

(Process/Utilities) Trent indication
below 100 µS/cm
Compact
instrumentation
trent indication

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Analysis and Analyzer in FnB Industry

Conductivity Success in the Food & Beverage Industry

• Smartec CLD18
• Caustic soda monitoring
• Bottle washer, robust application, harsh environmental,
• small pipes and strong vibrations
Compact instrument easy and safe

• Smartec CLD 134

• Brewery CIP kitchen, concentration adding and CIP return
• hygienic sensor, compact instrument,

• Indumax CLS54D
• Hygienic sensor , comply with (EC) 1935/2004 and (EU) 10/2011
• Digital sensor, high accuracy, reliable values due to active connection monitoring
• Liquiline multi channel and multi parameter instrument CM44x oder CM444R

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Analysis and Analyzer in FnB Industry

Conductivity in CIP Process

Customer requirement
• Minimizing cleaning agents
• Optimization of cleaning during CIP at the batch
tanks
• Hygienic environment (diary)

Our solution
• Liquiline CM442 + Profibus DP
+ 2x CLS54D (Peek, FDA/EHEDG/3A)

*pictures puplished in: P&A Edition 2: F&B 2013, p. 46

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Analysis and Analyzer in FnB Industry

Measuring feature for CIP

CIP application e.g. in food

• Concentration adding
• Phase separation CLS54D Concentration adding

• Product monitoring CLS54D

• Interface detection CIP return

• 4 complete parameter sets

• operation mode, concentration table, temp. compensation, output range,
limit switches (=also alarms, warnings), etc.
• Via digital inputs (same as with Smartec CLD134)
• Via digital fieldbus

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Analysis and Analyzer in FnB Industry

Conductivity in Boiler Feed Water

One for all:

2x conductivity : CLS15D, CM444

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Analysis and Analyzer in FnB Industry

Analysis - Chlorine
Fundamentals Cl2/ClO2: How does it work ?

The disinfectant agent used must effectively kill off all of

the pathogens in the water. It is added to the water in
appropriate quantities; the minimum and maximum
concentrations must be observed and monitored.
Adherence to the applicable official regulations is
mandatory.

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Analysis and Analyzer in FnB Industry

Chlorine Cell

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Analysis and Analyzer in FnB Industry

Analysis - Chlorine

• Application
• Media : Demine water

• Solution :
• CCS142D
• CPS42D
• CCA250
• CPY7

Demine Water Non Demine Water

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Analysis and Analyzer in FnB Industry

Analysis - Turbidity

Turbidity occurs when light is scattered at

heterogeneous surfaces of particles.

The reflection is not only a function of the

amount (concentration) of suspended solids
but additionally of the size and shape of the
particles.

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Analysis and Analyzer in FnB Industry

Analysis - Turbidity

Industry Landscape

Utilities OUSTF10, OUSAF11/12/13/21/22

CUS51D, CUS52D
process process

Application
Water, Waste water Processes
Industry

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Analysis and Analyzer in FnB Industry

Analysis - Turbidity

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Analysis and Analyzer in FnB Industry

OUSAF11 ( Milk Loss Monitoring )

• Applications in the food and beverage

industry
• Milk detection in CIP solutions
• Phase separation, e.g. milk/water
• Product loss detection in outlet

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 Analysis and Analyzer in FnB Industry
Application: Identification of beer

Reason to measure
Identification of beer type by color measurement
before filling of road tanker to ensure that the
right pipe line is used for filling.
Equipment:
Optical sensor OUSAF22 with CM44P

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Analysis and Analyzer in FnB Industry

Analysis – Dissolve Oxygen

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Analysis and Analyzer in FnB Industry

Analysis – Dissolve Oxygen

• Application : Boiler Feeding Water

• Fast, detailed measurement allows in-time control of steam de-aeration

• Fast, detailed measurement allows control of steam production according to plant needs
Boiler feeding water

0,006
Concentration oxygen [mg/l]

0,005

0,004

0,003

0,002

0,001

0
10:33 10:48 11:02 11:16 11:31 11:45
Time

Zoomed view over 1h

shows fast response

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 Analysis and Analyzer in FnB Industry

Analysis – Dissolve Oxygen

• Application : Fermentation in pharmaceutical production
(frequent SIP)

• Starting point: DO concentration is high

• Bacteria start working DO is consumed

• To have constant DO available for the bacteria, more and

more stirring is needed
6 140
300  COS22D
Flow [Nm3/h]

[%SAT]
rpm
DO

0 0 0

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Analysis and Analyzer in FnB Industry

Heartbeat Technology in the Memosens and Liquiline platform

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Analysis and Analyzer in FnB Industry

Heartbeat Monitoring in the Memosens and Liquiline platform

Heartbeat monitoring functions

• Key Performance Indicators (KPIs)
via fieldbus to the PLC / SCADA system
• Total operation time, Availability, Time in failure, Number of failures, MTBF, MTTR
• Control of the effects of maintenance and process optimizations
• Provision of additional measuring loop values and process variables
via fieldbus to the PLC/SCADA system
• Standardized values: Sensor status, Sensor health (0 … 100%), Maintenance timer
• Additional sensor information depending on sensor type
• Trend identification (in combination with the customer’s application experience)
• …

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Analysis and Analyzer in FnB Industry

Heartbeat Verification in the Memosens and Liquiline platform

Heartbeat verification functions

• Online verification of the measuring loop during its operation
• Avoids down-time of the measurement
• Automatically generated reports for documentation
with structured and comprehensive information
• Minimize the documentation effort to fulfill regulatory requirements
• Clear and unambiguous verification results
• Help the staff to understand the results clearly and avoid misinterpretations

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Analysis and Analyzer in FnB Industry

Heartbeat Diagnostics

• Overview screen shows the • Detailed screen per channel • Standardized classification of
status of each connected • Information about current all status messages (NE107)
sensor at a glance sensor health and remaining • Clear remedy
• Heartbeat permanently time to next maintenance recommendations allow to
calculates the sensor health quickly take the right action
during its operation

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Analysis and Analyzer in FnB Industry

Heartbeat Verification

• One-click generation of verification reports

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 Analysis and Analyzer in FnB Industry

Diagnostics with Namur NE107

All diagnostic codes are classified according Namur NE107

• Safer plant operation with plain status signals for clear directives
• Cost savings by well defined procedures for operation and maintenance

“NE107 is essential to
distinguish between
messages for
maintenance and
operational staff.”
Fieldbus

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Analysis and Analyzer in FnB Industry

Liquiline Compact

Liquiline Compact CM72

• 4..20mA; Non-Ex / Ex; fixed parameter
Liquiline Compact CM82
• 4..20mA/HART; Non-Ex / Ex; Multi Parameter; Smartphone App with Bluetooth

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Analysis and Analyzer in FnB Industry

Organics in Water & Wastewater (Pollution)

COD TOC

LOAD

BOD
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Analysis and Analyzer in FnB Industry

Organics in Water & Wastewater (Pollution)

• BOD5: Biochemical Oxygen Demand
• Detects the consumption of oxygen by bacteria. Measurement time: 5 days.
• COD: Chemical Oxygen Demand
• Consumption of an oxidizing agent, which is expressed as an amount of Oxygen.
Measurement time: two hours.
• TOC: Total Organic Carbon
• The amount of organic carbon in the waste. Detection is accomplished by oxidation of
the carbon in water. Measurement time: Minutes, dependent on TOC level.

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Analysis and Analyzer in FnB Industry

Analyzer - COD ( Chemical Oxygen Demand )

Chemically induced degradation of organic compounds

• Permanganate method
• MnO4- + CH4  H2O + CO2 + Mn2+
• Dichromate method
• Cr2O72- + CH4  H2O + CO2 + Cr3+
• Other methods
• Organic matter can be oxidized by different substances (e.g., ozone or hydrogen peroxide). These
oxidants are often used in on-line analyzers.

The results from these COD-methods strongly depend on the process and the conditions (method specific)

E+H USA does not offer a COD analyzer

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 Analysis and Analyzer in FnB Industry

Analyzer - TOC (Total Organic Carbon)

Total Carbon (TC)

Total Inorganic Carbon (TIC) Total Organic Carbon (TOC)

Particulate Dissolved Inorganic Purgeable Organic Non-Purgeable

Inorganic Carbon Carbon (DIC) Carbon (POC) Organic Carbon
(graphite, carbide) (carbonic acid, dissolved (ethanol, benzene, acetone) (NPOC)
carbonates)

Dissolved Organic Particulate Organic

Carbon (DOC) Carbon
(algae, biology)

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Analysis and Analyzer in FnB Industry

Main analyzer parameters for the wastewater market

CA80COD CA80TP CA80AM CA80PH CA80CR

CA72TOC

Operating Expenditures reduction and improved plant reliability

• Easy to install, commission
• Cost-efficient through low reagent consumption and tool-free maintenance
• Remote access for improved plant safety and reliability

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Analysis and Analyzer in FnB Industry

SAC : Spectral Absorption Coefficient

The absorption of UV light by the sample at the wavelength 254 nm.
Measurement time: seconds.

2mm open path cell 8mm open path cell 40mm open path cell
(CAS51D-**C3**) (CAS51D-**C2**) (CAS51D-**C1**)
Application Organic load inlet WWTP, WWTP outlet, surface Clear water, water works
industrial applications water, water works inlet outlet, WWTP outlet

Measurement range SAC 1.5 – 700 1/m SAC 0.5 – 250 l/m SAC 0.1 – 50 1/m
eq. COD 2.5 – 1000 mg/l eq. COD 0.75 – 370 mg/l eq. COD 0.15 – 75 mg/l
eq. TOC 0.9 – 410 mg/l eq. TOC 0.3 – 150 mg/l eq. TOC 0.06 – 30 mg/l

Max. error 2% of measuring range (Basis: KHP, potassium hydrogen phthalate)

Repeatability 0.5% of measuring range (homogeneous media)

Drift Drift less 0.2% of measuring range related to KHP per week

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Analysis and Analyzer in FnB Industry

Optical - SAC UV 254

Spectral Absorption Coefficient (SAC)

• Advantage
• Simple method using an in-situ sensor
• No chemicals, increased temp/pressure
• Disadvantage
• Not all organic materials absorb at 254 nm
• Sample matrix must be stable
• Lab study to correlate SAC to TOC (or BOD or COD)
• RESULTS – just a trending tool

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Analysis and Analyzer in FnB Industry

Thank you for your attention…

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