Tyre shine

Safety Data Sheet

According to SANS 10234:2008 and SANS 11014:2010
Date of issue:03/03/2020 Revision date: 03/03/2022 : Version: 1.0

SECTION 1: Identification
1.1. Product identifier
Product form : Mixture
Trade name : Tyre shine
Type of product : Vehicle interior plastic and rubber cleaner and shine
Product code : SH635
Product group : Trade product
1.2. Relevant identified uses of the substance or mixture and uses advised against
No additional information available
1.3. Supplier's details

Manufacturer
Shield Chemicals (Pty) Ltd
9 London Rd
Apex
P.O. Box 1939
1501 Benoni - South Africa
T (011) 421 7111
info@shieldchem.co.za
1.4. Emergency telephone number
Emergency number : (011) 421 7111

SECTION 2: Hazards identification

2.1. Classification of the substance or mixture
Classification according to the United Nations GHS
Flammable liquids, Category 3 H226
Acute toxicity (dermal), Category 5 H313
Skin corrosion/irritation, Category 2 H315
Germ cell mutagenicity, Category 1B H340
Carcinogenicity, Category 1B H350
Specific target organ toxicity — Repeated exposure, Category 1 H372
Hazardous to the aquatic environment — Acute Hazard, Category 2 H401
Hazardous to the aquatic environment — Chronic Hazard, Category 2 H411
Full text of H statements : see section 16
2.2. Label elements
Labelling according to the United Nations GHS
Hazard pictograms (GHS-ZA) :

GHS02 GHS08 GHS09

Signal word (GHS-ZA) : Danger
Hazard statements (GHS-ZA) : H226 - Flammable liquid and vapour.
H313 - May be harmful in contact with skin
H315 - Causes skin irritation.
H340 - May cause genetic defects.
H350 - May cause cancer.
H372 - Causes damage to organs through prolonged or repeated exposure.
H411 - Toxic to aquatic life with long lasting effects.
Precautionary statements (GHS-ZA) : P201 - Obtain special instructions before use.
P202 - Do not handle until all safety precautions have been read and understood.
P210 - Keep away from heat, hot surfaces, sparks, open flames and other ignition sources. No
smoking.
P233 - Keep container tightly closed.
P240 - Ground and bond container and receiving equipment.
P241 - Use explosion-proof equipment.
P242 - Use non-sparking tools.
P243 - Take action to prevent static discharges.
P260 - Do not breathe spray, vapours.
P264 - Wash hands, forearms and face thoroughly after handling.

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Safety Data Sheet
According to SANS 10234:2008 and SANS 11014:2010

P270 - Do not eat, drink or smoke when using this product.

P273 - Avoid release to the environment.
P280 - Wear eye protection, protective clothing, protective gloves.
P302+P352 - IF ON SKIN: Wash with plenty of water.
P303+P361+P353 - IF ON SKIN (or hair): Take off immediately all contaminated clothing.
Rinse skin with water/shower.
P308+P313 - IF exposed or concerned: Get medical advice.
P312 - Call a doctor if you feel unwell.
P314 - Get medical advice if you feel unwell.
P321 - Specific treatment (see supplemental first aid instruction on this label)
P332+P313 - If skin irritation occurs: Get medical advice.
P362+P364 - Take off contaminated clothing and wash it before reuse.
P370+P378 - In case of fire: Use carbon dioxide (CO2), extinguishing powder, foam to
extinguish.
P391 - Collect spillage.
P403+P235 - Store in a well-ventilated place. Keep cool.
P405 - Store locked up.
P501 - Dispose of contents and container to an approved waste disposal plant.
2.3. Other hazards
Adverse physicochemical, human health and : Flammable liquid and vapour,May cause cancer,May cause genetic defects,Causes damage to
environmental effects organs through prolonged or repeated exposure,Harmful in contact with skin,Causes skin
irritation,Toxic to aquatic life,Toxic to aquatic life with long lasting effects.

SECTION 3: Composition/information on ingredients

3.1. Substances
Not applicable
3.2. Mixtures
Name Product identifier % Classification according to
the United Nations GHS
Naphtha (petroleum), hydrodesulfurized heavy / Naphtha (CAS-No.) 64742-82-1 30.0 - 50.0 Flam. Liq. 2, H225
(petroleum), hydrodesulfurized heavy Acute Tox. Not classified (Oral)
Muta. 1B, H340
Carc. 1B, H350
STOT RE 1, H372
Asp. Tox. 1, H304
nonane (CAS-No.) 111-84-2 6.0 - 10.0 Flam. Liq. 3, H226
Acute Tox. Not classified (Oral)
Acute Tox. 5 (Dermal), H313
STOT RE 2, H373
Aquatic Acute 1, H400
Decane (CAS-No.) 124-18-5 6.0 - 10.0 Flam. Liq. 3, H226
Acute Tox. 5 (Dermal), H313
Kerosine (petroleum) (CAS-No.) 8008-20-6 10.0 - 20.0 Flam. Liq. 3, H226
Acute Tox. Not classified (Oral)
Acute Tox. 5 (Dermal), H313
STOT RE Not classified
Asp. Tox. 1, H304
Undecane (CAS-No.) 1120-21-4 2.0 - 7.0 Flam. Liq. 4, H227
Acute Tox. 5 (Dermal), H313
heptane (CAS-No.) 142-82-5 2.0 - 5.0 Flam. Liq. 2, H225
Acute Tox. Not classified (Oral)
Acute Tox. 5 (Dermal), H313
Skin Irrit. 2, H315
STOT SE 3, H336
Asp. Tox. 1, H304
Aquatic Acute 1, H400
Aquatic Chronic 1, H410
octane (CAS-No.) 111-65-9 2.0 - 5.0 Flam. Liq. 2, H225
Acute Tox. Not classified (Oral)
Acute Tox. 5 (Dermal), H313
Skin Irrit. 2, H315
STOT SE 3, H336
Asp. Tox. 1, H304
Aquatic Acute 1, H400
Aquatic Chronic 1, H410
methylcyclohexane (CAS-No.) 108-87-2 2.0 - 5.0 Flam. Liq. 2, H225
Skin Irrit. 2, H315
STOT SE 3, H336
Asp. Tox. 1, H304
Aquatic Chronic 2, H411

Full text of H-statements: see section 16

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Tyre shine
Safety Data Sheet
According to SANS 10234:2008 and SANS 11014:2010

SECTION 4: First aid measures

4.1. Description of first aid measures
First-aid measures general : IF exposed or concerned: Get medical advice/attention. Call a poison center or a doctor if you
feel unwell.
First-aid measures after inhalation : Remove person to fresh air and keep comfortable for breathing.
First-aid measures after skin contact : Rinse skin with water/shower. Take off immediately all contaminated clothing. If skin irritation
occurs: Get medical advice/attention.
First-aid measures after eye contact : Rinse eyes with water as a precaution.
First-aid measures after ingestion : Call a poison center or a doctor if you feel unwell.
4.2. Most important symptoms and effects, both acute and delayed
Symptoms/effects after skin contact : Irritation.
4.3. Indication of any immediate medical attention and special treatment needed
Treat symptomatically.

SECTION 5: Firefighting measures

5.1. Extinguishing media
Suitable extinguishing media : Water spray. Dry powder. Foam. Carbon dioxide.
5.2. Special hazards arising from the substance or mixture
Fire hazard : Flammable liquid and vapour.
5.3. Advice for firefighters
Protection during firefighting : Do not attempt to take action without suitable protective equipment. Self-contained breathing
apparatus. Complete protective clothing.

SECTION 6: Accidental release measures

6.1. Personal precautions, protective equipment and emergency procedures
No additional information available
6.1.1. For non-emergency personnel
Emergency procedures : No open flames, no sparks, and no smoking. Only qualified personnel equipped with suitable
protective equipment may intervene. Do not breathe vapours.
6.1.2. For emergency responders
Protective equipment : Do not attempt to take action without suitable protective equipment. For further information
refer to section 8: "Exposure controls/personal protection".
6.2. Environmental precautions
Avoid release to the environment. Notify authorities if product enters sewers or public waters.
6.3. Methods and material for containment and cleaning up
For containment : Collect spillage.
Methods for cleaning up : Take up liquid spill into absorbent material. Notify authorities if product enters sewers or public
waters.
Other information : Dispose of materials or solid residues at an authorized site.

SECTION 7: Handling and storage

7.1. Precautions for safe handling
Precautions for safe handling : Ensure good ventilation of the work station. Keep away from heat, hot surfaces, sparks, open
flames and other ignition sources. No smoking. Ground/bond container and receiving
equipment. Use only non-sparking tools. Take precautionary measures against static
discharge. Flammable vapours may accumulate in the container. Use explosion-proof
equipment. Wear personal protective equipment. Obtain special instructions before use. Do not
handle until all safety precautions have been read and understood. Take all necessary
technical measures to avoid or minimize the release of the product on the workplace. Limit
quantities of product at the minimum necessary for handling and limit the number of exposed
workers. Provide local exhaust or general room ventilation. Floors, walls and other surfaces in
the hazard area must be cleaned regularly. Do not breathe vapours. Do not get in eyes, on
skin, or on clothing.
Hygiene measures : Separate working clothes from town clothes. Launder separately. Wash contaminated clothing
before reuse. Do not eat, drink or smoke when using this product. Always wash hands after
handling the product.
7.2. Conditions for safe storage, including any incompatibilities
Technical measures : Ground/bond container and receiving equipment.
Storage conditions : Store in a well-ventilated place. Keep cool. Keep container tightly closed. Store locked up.

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Safety Data Sheet
According to SANS 10234:2008 and SANS 11014:2010

SECTION 8: Exposure controls/personal protection

8.1. Control parameters

methylcyclohexane (108-87-2)
South Africa - Occupational Exposure Limits (Recommended Limits)
Local name Methylcyclohexane
OEL TWA (mg/m³) 1600 mg/m³
OEL TWA (ppm) 400 ppm
OEL STEL (mg/m³) 2000 mg/m³
OEL STEL (ppm) 500 ppm
Regulatory reference Government Notice. R: 1179
South Africa - Occupational Exposure Limits (Airborne Pollutants)
Local name Methylcyclohexane
OEL TWA (mg/m³) 1600 mg/m³
OEL TWA (ppm) 400 ppm
OEL STEL (mg/m³) 2000 mg/m³
OEL STEL (ppm) 500 ppm
Regulatory reference Government Notice No. R 904

8.2. Appropriate engineering controls

Appropriate engineering controls : Ensure good ventilation of the work station.
Environmental exposure controls : Avoid release to the environment.
8.3. Individual protection measures, such as personal protective equipment (PPE)
Hand protection : Protective gloves
Eye protection : Safety glasses
Skin and body protection : Wear suitable protective clothing
Respiratory protection : [In case of inadequate ventilation] wear respiratory protection.

8.4. Exposure limit values for the other components

No additional information available

SECTION 9: Physical and chemical properties

9.1. Information on basic physical and chemical properties
Physical state : Liquid
Appearance : Liquid.
Colour : clear.
Odour : characteristic.
Odour threshold : No data available
pH : No data available
pH solution : No data available
Relative evaporation rate (butylacetate=1) : No data available
Relative evaporation rate (ether=1) : No data available
Melting point : Not applicable
Freezing point : No data available
Boiling point : No data available
Flash point : ≈ 49.1 °C
Auto-ignition temperature : No data available
Decomposition temperature : No data available
Flammability (solid, gas) : Not applicable
Vapour pressure : No data available
Vapour pressure at 50 °C : No data available
Relative vapour density at 20 °C : No data available
Relative density : No data available
Relative density of saturated gas/air mixture : No data available
Density : No data available
Relative gas density : No data available
Solubility : No data available

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Safety Data Sheet
According to SANS 10234:2008 and SANS 11014:2010

Log Pow : No data available

Log Kow : No data available
Viscosity, kinematic : No data available
Viscosity, dynamic : No data available
Explosive properties : No data available
Oxidising properties : No data available
Explosive limits : No data available
Lower explosive limit (LEL) : No data available
Upper explosive limit (UEL) : No data available

9.2. Other information

No additional information available

SECTION 10: Stability and reactivity

10.1. Reactivity
Flammable liquid and vapour.
10.2. Chemical stability
Stable under normal conditions.
10.3. Possibility of hazardous reactions
No dangerous reactions known under normal conditions of use.
10.4. Conditions to avoid
Avoid contact with hot surfaces. Heat. No flames, no sparks. Eliminate all sources of ignition.
10.5. Incompatible materials
No additional information available
10.6. Hazardous decomposition products
Under normal conditions of storage and use, hazardous decomposition products should not be produced.

SECTION 11: Toxicological information

11.1. Information on toxicological effects

Acute toxicity (oral) : Not classified

Acute toxicity (dermal) : May be harmful in contact with skin.
Acute toxicity (inhalation) : Not classified
ATE ZA (dermal) 3693.754 mg/kg bodyweight
nonane (111-84-2)
LD50 oral rat > 5000 mg/kg bodyweight Animal: rat, Guideline: OECD Guideline 401 (Acute Oral Toxicity),
Guideline: EPA OPPTS 870.1100 (Acute Oral Toxicity)
LD50 dermal rabbit > 2000 mg/kg bodyweight Animal: rabbit, Guideline: OECD Guideline 402 (Acute Dermal
Toxicity), Guideline: EPA OPPTS 870.1200 (Acute Dermal Toxicity)
LC50 inhalation rat (mg/l) 17 mg/l air Animal: rat, Animal sex: male, Guideline: OECD Guideline 403 (Acute Inhalation
Toxicity), 95% CL: 14 - 21
Undecane (1120-21-4)
LD50 dermal rat > 2000 mg/kg bodyweight Animal: rat, Guideline: OECD Guideline 402 (Acute Dermal Toxicity)
LD50 dermal rabbit >= 3160 mg/kg bodyweight Animal: rabbit, Guideline: OECD Guideline 402 (Acute Dermal
Toxicity)
Decane (124-18-5)
LD50 dermal rat > 2000 mg/kg bodyweight Animal: rat, Guideline: OECD Guideline 402 (Acute Dermal Toxicity)
LD50 dermal rabbit >= 3160 mg/kg bodyweight Animal: rabbit, Guideline: OECD Guideline 402 (Acute Dermal
Toxicity)
Naphtha (petroleum), hydrodesulfurized heavy / Naphtha (petroleum), hydrodesulfurized heavy (64742-82-1)
LD50 oral rat > 5000 mg/kg bodyweight Animal: rat, Guideline: OECD Guideline 401 (Acute Oral Toxicity)
Kerosine (petroleum) (8008-20-6)
LD50 oral rat > 5000 mg/kg bodyweight Animal: rat, Guideline: EPA OTS 798.1175 (Acute Oral Toxicity),
Guideline: OECD Guideline 420 (Acute Oral Toxicity - Fixed Dose Method)
LD50 dermal rabbit > 2000 mg/kg bodyweight Animal: rabbit, Guideline: EPA OTS 798.1100 (Acute Dermal
Toxicity), Guideline: OECD Guideline 402 (Acute Dermal Toxicity)
LC50 inhalation rat (mg/l) > 5.28 mg/l air Animal: rat, Guideline: OECD Guideline 403 (Acute Inhalation Toxicity), 95%
CL: 0,42 -
heptane (142-82-5)
LD50 oral rat > 5000 mg/kg bodyweight (Equivalent or similar to OECD 401, Rat, Male / female, Read-
across, Oral)
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Safety Data Sheet
According to SANS 10234:2008 and SANS 11014:2010

heptane (142-82-5)
LD50 dermal rabbit > 2000 mg/kg bodyweight (Equivalent or similar to OECD 402, 24 h, Rabbit, Male / female,
Read-across, Dermal)
LC50 inhalation rat (mg/l) > 29.29 mg/l air (Equivalent or similar to OECD 403, 4 h, Rat, Male / female, Experimental
value, Inhalation (vapours))
octane (111-65-9)
LD50 oral rat > 5000 mg/kg bodyweight Animal: rat, Guideline: OECD Guideline 401 (Acute Oral Toxicity),
Guideline: EPA OPPTS 870.1100 (Acute Oral Toxicity)
LD50 dermal rabbit > 2000 mg/kg bodyweight Animal: rabbit, Guideline: OECD Guideline 402 (Acute Dermal
Toxicity), Guideline: EPA OPPTS 870.1200 (Acute Dermal Toxicity)
LC50 inhalation rat (mg/l) > 24.88 mg/l air Animal: rat, Guideline: OECD Guideline 403 (Acute Inhalation Toxicity)

Skin corrosion/irritation : Causes skin irritation.

Serious eye damage/irritation : Not classified
Respiratory or skin sensitisation : Not classified
Germ cell mutagenicity : May cause genetic defects.
Carcinogenicity : May cause cancer.
Reproductive toxicity : Not classified
STOT-single exposure : Not classified
STOT-repeated exposure : Causes damage to organs through prolonged or repeated exposure.

nonane (111-84-2)
NOAEL (oral, rat, 90 days) 100 mg/kg bodyweight Animal: rat, Animal sex: female, Guideline: OECD Guideline 408
(Repeated Dose 90-Day Oral Toxicity in Rodents)
NOAEC (inhalation, rat, vapour, 90 days) 24.3 mg/l air Animal: rat, Guideline: OECD Guideline 413 (Subchronic Inhalation Toxicity: 90-
Day Study)
NOAEL (subchronic, oral, animal/male, 90 100 mg/kg bodyweight Animal: mouse, Animal sex: male, Guideline: OECD Guideline 408
days) (Repeated Dose 90-Day Oral Toxicity in Rodents)
Kerosine (petroleum) (8008-20-6)
NOAEL (oral, rat, 90 days) 750 mg/kg bodyweight Animal: rat, Animal sex: female
NOAEC (inhalation, rat, vapour, 90 days) >= 0.024 mg/l air Animal: rat, Guideline: OECD Guideline 412 (Subacute Inhalation Toxicity:
28-Day Study)
octane (111-65-9)
NOAEC (inhalation, rat, vapour, 90 days) 24.3 mg/l air Animal: rat, Guideline: OECD Guideline 413 (Subchronic Inhalation Toxicity: 90-
Day Study)
Aspiration hazard : Not classified

SECTION 12: Ecological information

12.1. Toxicity
Ecology - general : Toxic to aquatic life. Toxic to aquatic life with long lasting effects.
Hazardous to the aquatic environment, short- : Toxic to aquatic life.
term (acute)
Hazardous to the aquatic environment, long- : Toxic to aquatic life with long lasting effects.
term (chronic)

nonane (111-84-2)
EC50 Daphnia 1 0.2 mg/l Test organisms (species): Daphnia magna
LOEC (chronic) 0.32 mg/l Test organisms (species): Daphnia magna Duration: '21 d'
NOEC (chronic) 0.17 mg/l Test organisms (species): Daphnia magna Duration: '21 d'
heptane (142-82-5)
BCF other aquatic organisms 1 552 (BCFBAF v3.00, Calculated value)
Log Pow 4.66 (Experimental value)
Log Koc 2.38 (log Koc, SRC PCKOCWIN v2.0, Calculated value)
octane (111-65-9)
EC50 Daphnia 1 0.3 mg/l Test organisms (species): Daphnia magna
LOEC (chronic) 0.32 mg/l Test organisms (species): Daphnia magna Duration: '21 d'
NOEC (chronic) 0.17 mg/l Test organisms (species): Daphnia magna Duration: '21 d'
12.2. Persistence and degradability
Tyre shine
Persistence and degradability No additional information available

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Safety Data Sheet
According to SANS 10234:2008 and SANS 11014:2010

heptane (142-82-5)
Persistence and degradability Biodegradable in the soil. Readily biodegradable in water.
Biochemical oxygen demand (BOD) 1.92 g O₂/g substance
Chemical oxygen demand (COD) 0.06 g O₂/g substance
ThOD 3.52 g O₂/g substance
BOD (% of ThOD) > 0.5 (5 day(s), Literature study)
12.3. Bioaccumulative potential
Tyre shine
Bioaccumulative potential No additional information available

heptane (142-82-5)
BCF other aquatic organisms 1 See section 12.1 on ecotoxicology 55 2 (BC FBAF v3. 00, C alculat ed v alue )

Log Pow See section 12.1 on ecotoxicology 4. 66 (Ex peri men tal val ue)

Log Koc See section 12.1 on ecotoxicology 2. 38 (l og Koc , SRC PCKOCWIN v2. 0, Calc ulate d valu e)

Bioaccumulative potential Potential for bioaccumulation (4 ≥ Log Kow ≤ 5).

12.4. Mobility in soil
Tyre shine
Mobility in soil No additional information available

heptane (142-82-5)
Surface tension 19.66 mN/m (25 °C)
Log Pow See section 12.1 on ecotoxicology 4. 66 (Ex peri men tal val ue)

Log Koc See section 12.1 on ecotoxicology 2. 38 (l og Koc , SRC PCKOCWIN v2. 0, Calc ulate d valu e)

Ecology - soil Low potential for adsorption in soil.

12.5. Other adverse effects
Ozone : Not classified
Other adverse effects : No additional information available

SECTION 13: Disposal considerations

13.1. Disposal methods
Waste treatment methods : Dispose of contents/container in accordance with licensed collector’s sorting instructions.
Additional information : Flammable vapours may accumulate in the container.

SECTION 14: Transport information

In accordance with SANS / IMDG / IATA

SANS IMDG IATA

14.1. UN number
1223 1223 1223
14.2. Proper Shipping Name
KEROSENE KEROSENE Kerosene
14.3. Transport hazard class(es)
3 3 3

Not applicable
14.4. Packing group
III III III
14.5. Environmental hazards
Dangerous for the environment : Yes Dangerous for the environment : No Dangerous for the environment : No
:
No supplementary information available

14.6. Special precautions for user

- SANS
Limited quantities (SANS) : 5L
Limited quantities (SANS) : 5L
Packagings, large packagings and IBCs : P001, IBC03, LP01
Packing instructions (SANS)

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Safety Data Sheet
According to SANS 10234:2008 and SANS 11014:2010

Portable tank and bulk containers instructions : T2

(SANS)
Portable tank and bulk container special : TP2
provisions (SANS)

- IMDG
Special provisions (IMDG) : 363
Limited quantities (IMDG) : 5L
Excepted quantities (IMDG) : E1
Packing instructions (IMDG) : P001, LP01
IBC packing instructions (IMDG) : IBC03
Tank instructions (IMDG) : T2
Tank special provisions (IMDG) : TP2
EmS-No. (Fire) : F-E - FIRE SCHEDULE Echo - NON-WATER-REACTIVE FLAMMABLE LIQUIDS
EmS-No. (Spillage) : S-E - SPILLAGE SCHEDULE Echo - FLAMMABLE LIQUIDS, FLOATING ON WATER
Stowage category (IMDG) : A
Properties and observations (IMDG) : Immiscible with water.

- IATA
PCA Excepted quantities (IATA) : E1
PCA Limited quantities (IATA) : Y344
PCA limited quantity max net quantity (IATA) : 10L
PCA packing instructions (IATA) : 355
PCA max net quantity (IATA) : 60L
CAO packing instructions (IATA) : 366
CAO max net quantity (IATA) : 220L
Special provisions (IATA) : A324
ERG code (IATA) : 3L
14.7. Transport in bulk according to Annex II of MARPOL 73/78 and the IBC Code
Not applicable

SECTION 15: Regulatory information

15.1. Safety, health, and environmental national regulations specific for the product
No additional information available

SECTION 16: Other information

Date of issue : 03/03/2020
Revision date : 03/03/2022

Full text of H-statements:

H225 Highly flammable liquid and vapour.
H226 Flammable liquid and vapour.
H227 Combustible liquid
H304 May be fatal if swallowed and enters airways.
H312 Harmful in contact with skin.
H313 May be harmful in contact with skin
H315 Causes skin irritation.
H332 Harmful if inhaled.
H336 May cause drowsiness or dizziness.
H340 May cause genetic defects.
H350 May cause cancer.
H372 Causes damage to organs through prolonged or repeated exposure.
H373 May cause damage to organs through prolonged or repeated exposure.
H400 Very toxic to aquatic life.
H401 Toxic to aquatic life
H410 Very toxic to aquatic life with long lasting effects.
H411 Toxic to aquatic life with long lasting effects.

SDS South Africa

This information is based on our current knowledge and is intended to describe the product for the purposes of health, safety and environmental requirements only. It should not therefore be
construed as guaranteeing any specific property of the product.

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