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Revision 1 01 11 2024

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28 views1 page

Revision 1 01 11 2024

Uploaded by

sriyunesh26
Copyright
© © All Rights Reserved
We take content rights seriously. If you suspect this is your content, claim it here.
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XII – CBSE REVISION–1 MARKS: 45

CHEMISTRY 01 – 11 – 2024 TIME: 1½hr.


1. Define the following terms with a suitable reaction:
a) Schiff’s base b) Oxime. (2)
2. Explain the following:
a) 2,4-DNP test b) Dye test for phenol. (2)
3. Justify the following:
a) Anisole undergoes electrophilic substitution at ortho and para positions.
b) Alpha hydrogen in the carbonyl compounds is acidic in nature. (2)
4. Give reasons for the following: a) m-Cresol is more acidic than the corresponding isomers.
b) Sodium ethoxide is more basic than sodium hydroxide.(2)
5. Effect the following conversions: a) Sodium propanoate to butane
b) Sodium propanoate to ethane. (2)
6. Give reasons for the following observations:
a) Benzoic acid does not undergo Friedel-Crafts reaction.
b) Fluoroacetic acid is more acidic than chloroacetic acid.
c) Protonated alcohols act as electrophiles. (3)
7. Give tests for a) Ethene b) Carboxylic acids. (3)

8. Give suitable account for the following observations:


a) Dry.HCl is required during the addition of alcohol to carbonyl compounds.
b) Alkaline medium is needed for the addition of HCN to the carbonyl compounds.
c) In the case of optically active alkyl halides, racemization takes place during SN1 reaction.(3)
9. How does diborane react with
a) Nitromethane b) Ethyl chloride c) Methyl acetate? (3)
10. Ethanol reacts with Concentrated sulphuric acid at 413K and 443K. Identify the type of
reaction and products formed during the reaction. (3)
11. How does benzaldehyde react with a) Con.NaOH
b) Ethanal in the presence of dilute alkali c) Acetone in the presence of an alkali
d) Nitration mixture e) Alkaline CuSO4 (5)
12. How does tert-Butyl alcohol react with the following:
a) Aluminium b) Heated copper catalyst
c) Thionyl chloride d) Concentrated phosphoric acid e) Lucas reagent. (5)
13. Effect the following conversions: a) Bromoethane to butane
b) Bromoethane to 1,2-Dibromoethane c) Bromoethane to nitroethane
d) Bromoethane to chloroethane. e) Bromoethane to methanal. (5)
14. Explain the following:
a) Mixed ether cannot be prepared by intermolecular dehydration of alcohols.
b) Steam distillation is employed to separate ortho and para nitro phenols.
c) Aryl halides undergo nucleophilic substitution in the presence of electron withdrawing
groups.
d) To prepare alkyl iodide from alcohol, KI/Con.H2SO4 should not be used. (5)
ALL THE BEST

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