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Mpi 3540 MSDS

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0% found this document useful (0 votes)
31 views9 pages

Mpi 3540 MSDS

Uploaded by

Moukimou Bibene
Copyright
© © All Rights Reserved
We take content rights seriously. If you suspect this is your content, claim it here.
Available Formats
Download as PDF, TXT or read online on Scribd
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SAFETY DATA SHEET

Prepared according to UN GHS (the 9th revised edition)

RUCY MKL GROUP | Tel : + 33 6 59 41 97 90 / +33 2 32 71 21 64 | info@mkl-oil.fr | Siège : RUE DES PRES- RESIDENCE LA TOURELLE – 27950 SAINT MARCEL (France)
Bureau opéraXonnel : 35 Bis RUE DES DES PRES- BATIMENT C- ZONE INDUSTRIELLE LA GRANDE GARENNE Web : h^ps://mkl-group.fr/mkl-oil-and-gas/

Sec$on 1: Iden$fica$on of the chemical and supplier


Product Name : MPI-3540
Relevant Iden9fied uses : Lower the solidifica9on point of crude oil and improve the flow of crude oil.
Uses advised against : Industrial use only.
Name of the company : MKL OIL
Address of the company : 35 Bis Rue Des Prés- Bâ9ment C-Zone industrielle la Grande Garenne
Post code : 27950- SAINT MARCEL (France)
Telephone number : +33 2 32 71 21 64 / + 33 6 59 41 97 90
E-mail address : info@mkl-oil.fr
Emergency telephone number : +33 2 32 71 21 64 / + 33 6 59 41 97 90
Sec$on 2: Hazards iden$fica$on
Hazard classifica,on according to GHS :

Flammable Liquids : Category 3


Severe eye injury/irrita9on : Category 2A
Inhala9on hazards : Category 1
Skin Corrosion/Irrita9on : Category 2
Specific target organ system toxicity (repeated exposure : Category 2
Label elements:

Hazard pictograms :

Signal word : Danger

Hazard statements:
H226 : Flammable liquid and vapour
H304 : May be fatal if swallowed and enters airways
H332 : Inhala9on is harmful.
H315 : Causes skin irrita9on
H319 : Causing severe eye irrita9on
H373 : Repeated contact may damage the organs.

Precau0onary statements :
v Preven&on
P210: Keep away from heat, hot surfaces, sparks, open flames and other igni9on sources. No smoking
P233 : Keep container 9ghtly closed.
P240: Ground and bond container and receiving equipment.
P241: Use explosion-proof [electrical/ven9la9ng/ligh9ng] equipment.
P242: Use non-sparking tools.
P243: Take ac9on to prevent sta9c discharges.
P264: Wash thoroughly ajer handling
P280: Wear protec9ve gloves/protec9ve clothing/eye protec9on/face protec9on.

1
SAFETY DATA SHEET
Prepared according to UN GHS (the 9th revised edition)

RUCY MKL GROUP | Tel : + 33 6 59 41 97 90 / +33 2 32 71 21 64 | info@mkl-oil.fr | Siège : RUE DES PRES- RESIDENCE LA TOURELLE – 27950 SAINT MARCEL (France)
Bureau opéraXonnel : 35 Bis RUE DES DES PRES- BATIMENT C- ZONE INDUSTRIELLE LA GRANDE GARENNE Web : h^ps://mkl-group.fr/mkl-oil-and-gas/

v Response

P312: Call a POISON CENTER/doctor, if you feel unwell.


P331: Do NOT induce vomi9ng.
P301+P310: If SWALLOWED: Immediately call a POISON CENTER/doctor
P332+P313: If skin irrita9on occurs: Get medical advice/alen9on.
P362+P364: Take off contaminated clothing and wash it before reuse.
P303+P361+P353: If ON SKIN (or hair): Take off immediately all contaminated clothing. Rinse skin with
water/shower.

v Storage
P405: Store locked up.
P403+P235 : Store in a well-ven9lated place. Keep cool.

v Disposal
P501 : Dispose of contents/container in accordance with local/regional/na9onal/ interna9onal regula9ons.

Hazard descrip0on :

v Physical and chemical hazards:

No informa9on available

v Health hazards

Inhaled: Inhala9on of the product may produce adverse health effects or irrita9on of the respiratory tract
following discomfort.
Inges0on: Accidental inges9on of the product may be harmful to the health of the individual.
Skin Contact: The product can cause skin irrita9on following direct contact with the skin.
Eye: This product may cause temporary discomfort following direct contact with the eye.

v Environmental hazards

Please refer to 12th chapter of SDS.


Sec$on 3 : Composi$on/informa$on on ingredients

Component Cas No. EC No. Concentration (weight


percent, %)
alpha olefin maleic 68188-50-1 614-368-0 30-50
anhydride copolymer
esterified
Xylene 1330-20-7 215-535-7 50 -70

2
SAFETY DATA SHEET
Prepared according to UN GHS (the 9th revised edition)

RUCY MKL GROUP | Tel : + 33 6 59 41 97 90 / +33 2 32 71 21 64 | info@mkl-oil.fr | Siège : RUE DES PRES- RESIDENCE LA TOURELLE – 27950 SAINT MARCEL (France)
Bureau opéraXonnel : 35 Bis RUE DES DES PRES- BATIMENT C- ZONE INDUSTRIELLE LA GRANDE GARENNE Web : h^ps://mkl-group.fr/mkl-oil-and-gas/

Sec$on 4 : Ingredients First aid measures


Descrip$on of first aid measures:

General advice : Immediate medical alen9on is required. Show this safety data sheet (SDS) to the doctor in
alendance.
Eye contact : Rinse thoroughly with plenty of water for at least 15 minutes and consult a physician if feel
uncomfortable.
Skin Contact : Take off contaminated clothing and shoes immediately. Wash off with plenty of water for at least
15 minutes and consult a physician if feel uncomfortable.
Inges9on : Do not induce vomi9ng. Never give anything by mouth to an unconscious person. Call a physician or
Poison Control Center immediately.
Inhala9on : Move vic9m into fresh air. If breathing is difficult, give oxygen. Do not use mouth to mouth
resuscita9on if vic9m ingested or inhaled the substance. If not breathing, give ar9ficial respira9on and consult a
physician immediately.
Protec9ng of first-aiders : Ensure that medical personnel are aware of the substance involved. Take precau9ons
to protect themselves and prevent spread of contamina9on.

Most important symptoms and effects, both acute and delayed:

Substance accumula9on, in the human body, may occur and may cause some concern following repeated or long-
term occupa9onal exposure.

Indica$on of any immediate medical aHen$on and special treatment needed:

v Treat symptoma9cally.
v Symptoms may be delayed.
Sec$on 5 : Firefigh$ng measures
Ex$nguishing media :

Suitable ex9nguishing media : Use ex9nguishing media suitable for surrounding area.
Unsuitable ex9nguishing media : There is no restric9on on the type of ex9nguisher which may be used

Special hazards arising from the substance or mixture:

May expansion or decompose when heated or involved in fire.

Advice for firefighters :

v As in any fire, wear self-contained breathing apparatus(MSHA/NIOSH approved or equivalent) and


full protec9ve gear.
v Fight fire from a safe distance, with adequate cover.
v Prevent fire ex9nguishing water from contamina9ng surface water or the ground water system.
Sec$on 6 : Accidental release measures
Personal precau$ons, protec$ve equipment and emergency procedures :

v Ensure adequate ven9la9on. Remove all sources of igni9on. Take precau9onary measures against sta9c
discharges.
v Evacuate personnel to safe areas. Keep people away from and upwind of spill/leak.
v Use personal protec9ve equipment. Avoid breathing vapours, mist, gas or dust.
3
SAFETY DATA SHEET
Prepared according to UN GHS (the 9th revised edition)

RUCY MKL GROUP | Tel : + 33 6 59 41 97 90 / +33 2 32 71 21 64 | info@mkl-oil.fr | Siège : RUE DES PRES- RESIDENCE LA TOURELLE – 27950 SAINT MARCEL (France)
Bureau opéraXonnel : 35 Bis RUE DES DES PRES- BATIMENT C- ZONE INDUSTRIELLE LA GRANDE GARENNE Web : h^ps://mkl-group.fr/mkl-oil-and-gas/

Environmental precau$ons :
v Prevent further leakage or spillage if safe to do so.
v Discharge into the environment must be avoided.
Methods and material for containment and cleaning up:
v Absorb spilled material in dry sand or inert absorbent. In case of large amount of spillage, contain a
spill by bunding.
v Adhered or collected material should be promptly disposed of, in accordance with appropriate laws
and regula9ons.
v Remove all sources of igni9on. Use spark-proof tools and explosion-proof equipment.
Sec$on 7: Handling and storage
Precau$ons for safe handling:
v Handling is performed in a well-ven9lated place.
v Wear suitable protec9ve equipment.
v Avoid contact with skin and eyes.
v Keep away from heat/sparks/open flames/ hot surfaces.
Precau$ons for storage:
v Keep containers 9ghtly closed.
v Keep containers in a dry, cool and well-ven9lated place.
v Keep away from heat/sparks/open flames/hot surfaces.
v Store away from incompa9ble materials and foodstuff containers.
Sec$on 8: Exposure controls/personal protec$on
Control parameters:
v Occupa&onal Exposure limit values

Component Limit value - Eight hours Limit value - Short term


Country/Region
ppm mg/m³ ppm mg/m³

USA - OSHA 100 435 - -

South Korea 100 435 150 655

Xylene Ireland 50 221 100 442


1330-20-7 Germany (AGS) 100 440 200 880

Denmark 25 109 50 218

Australia 80 350 150 655

v Biological limit values


No informa9on available

v Monitoring methods
EN 14042 Workplace atmospheres. Guide for the applica9on and use of procedures for the assessment of
exposure to chemical and biological agents.
GBZ/T 160.1~GBZ/T 160.81-2004 Determina9on of toxic substances in workplace air(Series standard).

4
SAFETY DATA SHEET
Prepared according to UN GHS (the 9th revised edition)

RUCY MKL GROUP | Tel : + 33 6 59 41 97 90 / +33 2 32 71 21 64 | info@mkl-oil.fr | Siège : RUE DES PRES- RESIDENCE LA TOURELLE – 27950 SAINT MARCEL (France)
Bureau opéraXonnel : 35 Bis RUE DES DES PRES- BATIMENT C- ZONE INDUSTRIELLE LA GRANDE GARENNE Web : h^ps://mkl-group.fr/mkl-oil-and-gas/

Engineering controls:
v Ensure adequate ven9la9on, especially in confined areas.
v Ensure that eyewash sta9ons and safety showers are close to the worksta9on loca9on.
v Use explosion-proof electrical/ven9la9ng/ligh9ng/equipment.
v Set up emergency exit and necessary risk-elimina9on area.

Personal protec$on equipment:

v General requirement :

Eye protec9on : Tightly fiqng safety goggles (approved by EN 166(EU) or NIOSH (US).
Hand protec9on : Wear protec9ve gloves(such as butyl rubber), passing the tests according to EN 374(EU), US
F739 or AS/NZS 2161.1 standard.
Respiratory protec9on : If exposure limits are exceeded or if irrita9on or other symptoms are experienced, use a
full-face respirator with mul9-purpose combina9on (US) or type AXBEK (EN 14387) respirator cartridges.
Skin and body protec9on : Wear fire/flame resistant/retardant clothing and an9sta9c boots.
Sec0on 9: physical and chemical proper0es
Appearance : Yellow to brown liquid
Odor : Slight odor
Odor threshold : No informa9on available
Pour point(℃) : Not soluble in water, no pH value
Melting point/freezing point(℃) : ≤20
Initial boiling point and boiling range(℃) : >35
Flash point(Closed cup,℃) : >25
Evaporation rate : Not applicable
Flammability : Combustible
Upper/lower explosive limits[%(v/v)]: Upper limit:No information available;Lower limit:No
information available
Vapor pressure : Not applicable
Relative vapour density (Air=1) : Not applicable
Relative density(Water=1) : 0.85~0.90
Solubility(mg/L) : Soluble in common organic solvents
n-octanol/water partition coefficient : No information available
Auto-ignition temperature(℃) : No information available
Decomposition temperature(℃) : No information available
Kinematic viscosity : No information available
Particle characteristics : Not applicable
Sec$on 10: Stability and reac$vity
Reac9vity : Contact with incompa9ble substances can cause decomposi9on or other chemical reac9ons.
Chemical stability : Stable under proper opera9on and storage condi9ons.
Possibility of hazardous reac9ons : No informa9on available
Condi9ons to avoid : Incompa9ble materials, heat, flame and spark.
Incompa9ble materials : No informa9on available

5
SAFETY DATA SHEET
Prepared according to UN GHS (the 9th revised edition)

RUCY MKL GROUP | Tel : + 33 6 59 41 97 90 / +33 2 32 71 21 64 | info@mkl-oil.fr | Siège : RUE DES PRES- RESIDENCE LA TOURELLE – 27950 SAINT MARCEL (France)
Bureau opéraXonnel : 35 Bis RUE DES DES PRES- BATIMENT C- ZONE INDUSTRIELLE LA GRANDE GARENNE Web : h^ps://mkl-group.fr/mkl-oil-and-gas/

Hazardous decomposi9on products : Under normal condi9ons of storage and use, hazardous decomposi9on
products should not be produced.
Sec$on 11: Toxicological informa$on
v Acute toxicity:

Component Cas No. LD50(oral) LD50(dermal) LC50(inhalation,4h


)
Xylene 1330-20-7 4300mg/kg(Rat) > 1700mg/kg(Rabbit) 21.712mg/L(Rat)

v Carcinogenicity :

ID Cas No. Component IARC NTP


1 68188-50-1 alpha olefin maleic Not Listed Not Listed
anhydride
copolymer
esterified
2 1330-20-7 Xylene Category 3 Not Listed

v Others
Skin corrosion/irrita9on : Causes skin irrita9on(Category 2)
Serious eye damage/irrita9on : No informa9on available
Skin sensi9za9on : No informa9on available
Sec$on 12: Ecological informa$on
v Acute aqua0c toxicity :

Component Cas No. Fish Crustaceans Algae


Xylene 1330-20-7 LC50:15.7mg/L No informa9on No informa9on
(96h)(Fish) available available

v Chronic aqua$c toxicity:

No informa9on available

v Persistence and degradability:

Component Cas No. Persistence (water/soil) Persistence (air)


Xylene 1330-20-7 High(Half-life = 360 days) Low(Half-life = 1.83 days)

v Bioaccumula$ve poten$al :

Component Cas No. Bioaccumulative comments


potential
Xylene 1330-20-7 Medium BCF=740

v Mobility in soil :
No informa&on available

6
SAFETY DATA SHEET
Prepared according to UN GHS (the 9th revised edition)

RUCY MKL GROUP | Tel : + 33 6 59 41 97 90 / +33 2 32 71 21 64 | info@mkl-oil.fr | Siège : RUE DES PRES- RESIDENCE LA TOURELLE – 27950 SAINT MARCEL (France)
Bureau opéraXonnel : 35 Bis RUE DES DES PRES- BATIMENT C- ZONE INDUSTRIELLE LA GRANDE GARENNE Web : h^ps://mkl-group.fr/mkl-oil-and-gas/

v Results of PBT and vPvB assessment:

Component Cas No. Results of PBT and vPvB assessment


(according to (EC) No 1907/2006)
alpha olefin maleic anhydride copolymer 68188-50-1 not PBT/vPvB
esterified
Xylene 1330-20-7 not PBT/vPvB

Sec$on 13 : Disposal considera$ons


Waste chemicals : Before disposal should refer to the relevant na9onal and local laws and regula9on.
Contaminated packaging : Containers may s9ll present chemical hazard when empty. Keep away from hot and
igni9on source of fire.
Disposal recommenda9ons : Refer to sec9on 13.
Sec$on 14: Transport informa$on
v Label and Mark :
Transpor9ng Label :

Marine pollutant : None

v IMDG-CODE
UN number : 1993
UN proper shipping name : FLAMMABLE LIQUID, N.O.S.
Transport hazard class :3
Transport subsidiary hazard class : None
Packing group : Ⅱ
Special provisions : 274
Limited quan99es : 1L
Excepted quan99es : E2
Marine pollutant(Yes or no) : No
EmS No : F-E,S-E

v ICAO/IATA-DGR
UN number : 1993
UN proper shipping name : FLAMMABLE LIQUID, N.O.S
Transport hazard class : 3
Transport subsidiary hazard class : None
Packing group : Ⅱ
Excepted quan99es : E2
Passenger and Cargo Aircraj Limited Quan9ty Packing Instruc9ons : Y341
Passenger and Cargo Aircraj Limited Quan9ty Maxium net Quan9ty per Package : 1L

7
SAFETY DATA SHEET
Prepared according to UN GHS (the 9th revised edition)

RUCY MKL GROUP | Tel : + 33 6 59 41 97 90 / +33 2 32 71 21 64 | info@mkl-oil.fr | Siège : RUE DES PRES- RESIDENCE LA TOURELLE – 27950 SAINT MARCEL (France)
Bureau opéraXonnel : 35 Bis RUE DES DES PRES- BATIMENT C- ZONE INDUSTRIELLE LA GRANDE GARENNE Web : h^ps://mkl-group.fr/mkl-oil-and-gas/

Passenger and Cargo Aircraj Packing Instruc9ons : 353


Passenger and Cargo Aircraj Maxium net Quan9ty per Package : 5L
Cargo Aircraj Packing Instruc9ons : 364
Cargo Aircraj Maxium net Quan9ty per Package : 60 L
Special provisions : A3
ERG code : 3H

v UN-ADR
UN number : 1993
UN proper shipping name : FLAMMABLE LIQUID, N.O.S.
Transport hazard class : 3
Transport subsidiary hazard class : None
Packing group : Ⅱ
Special provisions : 274|601|640C or 274|601|640D
Limited quan99es : 1L
Excepted quan99es : E2
Packing instruc9ons : P001 or P001|IBC02|R001
Special packing provisions : -
Mixed packing provisions : MP19
Protable tanks and bulk containers instruc9ons : T7
containers special provisions : TP1|TP8|TP28
ADR tank code : L1.5BN or LGBF
ADR tank special provisions : -
Vehicle for tank carriage : FL
Transport category(Tunnel restric9on code) : 2 (D/E)
Special provisions for carriage(Packages : -
Special provisions for carriage(Bulk) : -
Special provisions for carriage(Loading,unloading and handling) : -
Special provisions for carriage(Opera9on) : S2|S20
Hazard iden.fica.on No : 33
Notes : -
Sec$on 15 : Regulatory informa$on
Interna0onal chemical inventory :

Component EINECS TSCA DSL IECSC NZIoC PICCS KECI AICS ENCS
alpha olefin maleic anhydride
× √ × × √ × √ √ ×
copolymer esterified
Xylene √ √ √ √ √ √ √ √ √

【EINECS】 European Inventory of Exis5ng Commercial Chemical Substances


【TSCA】 United States Toxic Substances Control Act Inventory
【DSL】 Canadian Domes5c Substances List
【IECSC】 China Inventory of Exis5ng Chemical Substances
【NZIoC】 New Zealand Inventory of Chemicals
【PICCS】 Philippines Inventory of Chemicals and Chemical Substances
【KECI】 Exis5ng and Evaluated Chemical Substances
【AICS】 Australia Inventory of Chemical Substances
【ENCS】 Exis5ng And New Chemical Substances

8
SAFETY DATA SHEET
Prepared according to UN GHS (the 9th revised edition)

RUCY MKL GROUP | Tel : + 33 6 59 41 97 90 / +33 2 32 71 21 64 | info@mkl-oil.fr | Siège : RUE DES PRES- RESIDENCE LA TOURELLE – 27950 SAINT MARCEL (France)
Bureau opéraXonnel : 35 Bis RUE DES DES PRES- BATIMENT C- ZONE INDUSTRIELLE LA GRANDE GARENNE Web : h^ps://mkl-group.fr/mkl-oil-and-gas/

Note
“√” Indicates that the substance included in the regula5ons
“×” That no data or included in the regula5ons

Sec$on 16: Other informa$on


Informa0on on revision

Crea9on Date 2023/08/20


Revision Date 2024/08/20
Reason for revision -

Reference :

[1]IPCS:The Interna5onal Chemical Safety Cards (ICSC) ,website: hQp://www.ilo.org/dyn/icsc/showcard.home.


[2]IARC,website: hQp://www.iarc.fr/.
[3]OECD: The Global Portal to Informa5on on Chemical Substances, website:
hQp://www.echemportal.org/echemportal/index?pageID=0&request_locale=en.
[4]CAMEO Chemicals, website: hQp://cameochemicals.noaa.gov/search/simple.
[5]NLM:ChemIDplus, website: hQp://chem.sis.nlm.nih.gov/chemidplus/chemidlite.jsp.
[6]EPA: Integrated Risk Informa5on System, website: hQp://cfpub.epa.gov/iris/.
[7]U.S. Department of Transporta5on:ERG, website: hQp://www.phmsa.dot.gov/hazmat/library/erg.
[8]Germany GESTIS-database on hazard substance, website: hQp://ges5s-en.itrust.de/

Abbrevia$ons and acronyms :


CAS –Chemical Abstracts Service CMR - Carcinogens, mutagens or substances toxic to reproduc5on
PC-STEL- Short term exposure limit PC-TWA - Time Weighted Average
DNEL - Derived No Effect Level IARC - Interna5onal Agency for Research on Cancer
RPE - Respiratory Protec5ve Equipment PNEC –Predicted No Effect Concentra5on
LC50 - Lethal Concentra5on 50% LD50 - Lethal Dose 50%
NOEC -No Observed Effect Concentra5on EC50 - Effec5ve Concentra5on 50%
PBT - Persistent, Bioaccumula5ve, Toxic POW - Par55on coefficient Octanol:Water
BCF - Bioconcentra5on factor (BCF) vPvB - very Persistent, very Bioaccumula5ve
IMDG-Interna5onal Mari5me Dangerous Goods ICAO/IATA-Interna5onal Civil Avia5on Organiza5on/Interna5onal Air
Transporta5on Associa5on
UN-The United Na5ons ACGIH-American Conference of Governmental Industrial Hygienists
NFPA-Na5onal Fire Protec5on Associa5on OECD-Organiza5on for Economic Co-opera5on and Development
Disclaimer :
This Safety Data Sheet (SDS) was prepared according to UN GHS (the 9th revised edi9on). The data included was
derived from interna9onal authorita9ve database and provided by the enterprise. Other informa9on was based
on the present state of our knowledge. We try to ensure the correctness of all informa9on. However, due to the
diversity of informa9on sources and the limita9ons of our knowledge, this document is only for user’s
reference. Users should make their independent judgment of suitability of this informa9on for their par9cular
purposes. We do not assume responsibility for loss, damage or expense arising out of or in any way connected
with the handling, storage, use or disposal of the product,the final power of interpreta9on belongs to
Dongying Konar New Materials Co., Ltd.

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