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Cutting Oil Sheet

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Cutting Oil Sheet

Uploaded by

tushambansal2
Copyright
© © All Rights Reserved
We take content rights seriously. If you suspect this is your content, claim it here.
Available Formats
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MATERIAL SAFETY DATA SHEET

1. Identification
Product identifier

Cutting Oil

2. Hazard(s) identification

Physical hazards Flammable aerosols Category 1


Gases under pressure Liquefied
gas
Reproductive toxicity
Category 2
(oral)
Health hazards Category 3
Hazardous to the aquatic environment,
Environmental hazards acute hazard

Label elements

Signal word Danger


Hazard statement Extremely flammable aerosol. Contains gas under pressure; may explode if heated.
Suspected of damaging fertility or the unborn child by ingestion. Harmful to aquatic
life.
Precautionary statement
Prevention Obtain special instructions before use. Do not handle until all safety precautions have
been read and understood. Keep away from heat, hot surfaces, sparks, open flames
and other ignition sources. No smoking. Do not spray on an open flame or other
ignition source. Do not pierce or burn, even after use. Wear protective
gloves/protective clothing/eye protection/face protection. Avoid release to the
environment.
Response IF exposed or concerned: Get medical advice/attention.
Storage Store locked up. Store in a well-ventilated place. Protect from sunlight. Do not
expose to temperatures exceeding 50°C/122°F.
Disposal Dispose of contents/container in accordance with local/regional/national/international
regulations.
Other hazards None known.
4. First-aid measures
Inhalation
Move to fresh air. Call a physician if symptoms develop or persist.
Skin contact
Wash off with soap and water. Get medical attention if irritation develops
Eye contact
and persists. Rinse with water. Get medical attention if irritation develops
Ingestion
and persists.
If swallowed, observe for signs of stomach discomfort or nausea. If symptoms persist,
Most important seek medical help. Do not induce vomiting. If there is any suspicion of aspiration into
lungs, obtain immediate medical attention.
symptoms/effects, acute and
delayed Direct contact with eyes may cause temporary irritation.
Indication of immediate
medical attention and special
treatment needed Provide general supportive measures and treat symptomatically. Keep victim under
observation. Symptoms may be delayed.
General information

IF exposed or concerned: Get medical advice/attention. Ensure that medical personnel


are aware of the material(s) involved, and take precautions to protect themselves.
Show this safety data sheet to the doctor in attendance.

5. Fire-fighting measures
Suitable extinguishing media
Water fog. Foam. Dry chemical powder. Carbon dioxide
Unsuitable extinguishing
(CO2). None known.
media
Specific hazards arising from
Contents under pressure. Pressurized container may rupture when exposed to heat or
the chemical
flame. When exposed to extreme heat or hot surfaces, vapors may decompose to
harmful or fatal corrosive gases such as hydrogen fluoride.
Special protective equipment
Firefighters must use standard protective equipment including flame retardant coat,
and precautions for firefighters
helmet with face shield, gloves, rubber boots, and in enclosed spaces, SCBA.
Fire fighting
In case of fire: Stop leak if safe to do so. Move containers from fire area if you can do so
equipment/instructions
without risk. Containers should be cooled with water to prevent vapor pressure build
Specific methods up.
Use standard firefighting procedures and consider the hazards of other involved
materials. Cool containers exposed to flames with water until well after the fire is out. In
General fire hazards the event of fire and/or explosion do not breathe fumes.
Extremely flammable aerosol. Contents under pressure. Pressurized container may
rupture when exposed to heat or flame.

6. Accidental release measures


Personal precautions,
Keep unnecessary personnel away. Keep people away from and upwind of spill/leak.
protective equipment and Keep out of low areas. Many gases are heavier than air and will spread along ground
emergency procedures and collect in low or confined areas (sewers, basements, tanks). Wear appropriate
protective equipment and clothing during clean-up. Emergency personnel need self-
contained breathing equipment. Do not touch damaged containers or spilled material
unless wearing appropriate protective clothing. Ventilate closed spaces before
entering them. Local authorities should be advised if significant spillages cannot be
contained. For personal protection, see section 8 of the SDS.
Methods and materials for Stop leak if you can do so without risk. Eliminate all ignition sources (no smoking, flares,
containment and cleaning up sparks, or flames in immediate area). Keep combustibles (wood, paper, oil, etc.) away
from spilled material. This product is miscible in water. Prevent product from entering
drains. Absorb in vermiculite, dry sand or earth and place into containers.

Small Spills: Wipe up with absorbent material (e.g. cloth, fleece). Clean surface
thoroughly to remove residual contamination. For waste disposal, see section 13
Environmental precautions of the SDS.
Avoid release to the environment. Inform appropriate managerial or supervisory
personnel of all environmental releases. Prevent further leakage or spillage if safe to
do so. Avoid discharge into drains, water courses or onto the ground.

7. Handling and storage


Precautions for safe handling
Obtain special instructions before use. Do not handle until all safety precautions have
been read and understood. Pressurized container: Do not pierce or burn, even after
use. Do not use if spray button is missing or defective. Do not spray on a naked flame or
any other incandescent material. Do not smoke while using or until sprayed surface is
thoroughly dry. Do not cut, weld, solder, drill, grind, or expose containers to heat,
flame, sparks, or other sources of ignition. Do not re-use empty containers. Pregnant
or breastfeeding women must not handle this product. Should be handled in closed
systems, if possible. Use only in well-ventilated areas. Wear appropriate personal
protective equipment. Avoid release to the environment. Observe good industrial
Conditions for safe storage, hygiene practices.
including any incompatibilities
Level 3 Aerosol.

Pressurized container. Protect from sunlight and do not expose to temperatures


exceeding 50°C/122 °F. Do not puncture, incinerate or crush. Do not handle or store
near an open flame, heat or other sources of ignition. This material can accumulate
static charge which may cause spark and become an ignition source. Store in a well-
ventilated place. Store away from incompatible materials (see Section 10 of the SDS).

8. Exposure controls/personal protection


Occupational exposure limits
US. ACGIH Threshold Limit Values
Components Type Value Form
distillates TWA 5 mg/m3 Inhalable fraction.
(petroleum),
hydrotreated
heavy naphthenic
(CAS 64742-52-5)
distillates (petroleum), TWA 5 mg/m3 Inhalable fraction.
solvent-dewaxed heavy
paraffinic (CAS 64742-
65-0)
distillates (petroleum), TWA 5 mg/m3 Inhalable fraction.
solvent-dewaxed light
paraffinic (CAS 64742-
56-9)
lubricating oils, TWA 5 mg/m3 Inhalable fraction.
petroleum,
hydrotreated spent
(CAS 64742-58-1)
Canada. Alberta OELs (Occupational Health & Safety Code, Schedule 1, Table 2)
Components Type Value Form

distillates STEL 10 mg/m3 Mist.


(petroleum),
hydrotreated
heavy naphthenic
(CAS 64742-52-5)
TWA 5 mg/m3 Mist.
distillates (petroleum), STEL 10 mg/m3 Mist.
solvent-dewaxed heavy
paraffinic (CAS 64742-
65-0)
TWA 5 mg/m3 Mist.
distillates (petroleum), STEL 10 mg/m3 Mist.
solvent-dewaxed light
paraffinic (CAS 64742-
56-9)
TWA 5 mg/m3 Mist.
Canada. British Columbia OELs. (Occupational Exposure Limits for Chemical Substances, Occupational Health and
Safety Regulation 296/97, as amended)
Components Type Value Form
distillates (petroleum),
solvent-dewaxed heavy TWA 1 mg/m3 Mist.
paraffinic (CAS 64742-
65-0)
Canada. Manitoba OELs (Reg. 217/2006, The Workplace Safety And Health Act)
Components Type Value Form
distillates TWA 5 mg/m3 Inhalable fraction.
(petroleum),
hydrotreated
heavy naphthenic
(CAS 64742-52-5)
distillates (petroleum), TWA 5 mg/m3 Inhalable fraction.
solvent-dewaxed heavy
paraffinic (CAS 64742-
65-0)
distillates (petroleum), TWA 5 mg/m3 Inhalable fraction.
solvent-dewaxed light
paraffinic (CAS 64742-
56-9)
lubricating oils, TWA 5 mg/m3 Inhalable fraction.
petroleum,
hydrotreated spent
(CAS 64742-58-1)
Canada. Ontario OELs. (Control of Exposure to Biological or Chemical Agents)
Components Type Value Form

lubricating oils,
petroleum, TWA 5 mg/m3 Inhalable fraction.
hydrotreated spent
(CAS 64742-58-1)
Canada. Quebec OELs. (Ministry of Labor - Regulation Respecting the Quality of the Work Environment)
Components Type Value Form
distillates STEL 10 mg/m3 Mist.
(petroleum),
hydrotreated
heavy naphthenic
(CAS 64742-52-5)
TWA 5 mg/m3 Mist.
distillates (petroleum), STEL 10 mg/m3 Mist.
solvent-dewaxed heavy
paraffinic (CAS 64742-
65-0)
TWA 5 mg/m3 Mist.
distillates (petroleum), STEL 10 mg/m3 Mist.
solvent-dewaxed light
paraffinic (CAS 64742-
56-9)
TWA 5 mg/m3 Mist.
Biological limit values No biological exposure limits noted for the ingredient(s).
Appropriate engineering Good general ventilation (typically 10 air changes per hour) should be used. Ventilation
controls rates should be matched to conditions. If applicable, use process enclosures, local
exhaust ventilation, or other engineering controls to maintain airborne levels below
recommended exposure limits. If exposure limits have not been established, maintain
airborne levels to an acceptable level.
Individual protection measures, such as personal protective equipment
Eye/face protection Respiratory protection

Skin protection
Hand protection
Other Thermal hazards
General hygiene Wear safety glasses with side shields (or goggles).
considerations

Wear protective gloves such as: Nitrile.


Neoprene. Wear suitable protective clothing.
If engineering controls are not feasible or if exposure exceeds the applicable exposure
limits, use a NIOSH-approved cartridge respirator with an organic vapor cartridge. Use a
self-contained breathing apparatus in confined spaces and for emergencies. Air
monitoring is needed to determine actual employee exposure levels.
Wear appropriate thermal protective clothing, when necessary.
Observe any medical surveillance requirements. When using do not smoke. Always
observe good personal hygiene measures, such as washing after handling the material
and before eating, drinking, and/or smoking. Routinely wash work clothing and
protective equipment to remove contaminants.
9. Physical and chemical properties
Appearance
Physical state Liquid.
Form Aerosol
Color .
Odor Brown.
Mild petroleum.
Odor threshold Not available.
pH Not available.
Melting point/freezing point -40 °F (-40 °C) estimated
Initial boiling point and boiling 500 °F (260 °C) estimated
range
Flash point > 300 °F (> 148.9 °C) Cleveland Open Cup
Evaporation rate Slow.
Flammability (solid, gas) Not available.
Upper/lower flammability or explosive limits
Flammability limit - lower Not
(%) available.
Flammability limit - upper
(%) Not
available.
Vapor pressure 3261 hPa estimated
Vapor density > 5 (air = 1)
Relative density 0.85
Solubility(ies)
Solubility (water) Negligible.
Partition coefficient Not available.
(n-octanol/water)
Auto-ignition temperature 600 °F (315.6 °C) estimated
Decomposition temperature Not available.
Viscosity Not available.
Other information
Percent volatile 95.3 % estimated

10. Stability and reactivity


Reactivity
The product is stable and non-reactive under normal conditions of use, storage and
Chemical stability
transport. Material is stable under normal conditions.
Possibility of hazardous
No dangerous reaction known under conditions of normal use.
reactions
Conditions to avoid
Heat, flames and sparks. Contact with incompatible materials. When exposed to
extreme heat or hot surfaces, vapors may decompose to harmful or fatal corrosive
gases such as hydrogen fluoride.
Incompatible materials
Strong oxidizing agents.
Hazardous decomposition
Carbon oxides. Sulfur oxides. Hydrogen fluoride. Aldehydes.
products

11. Toxicological information


Information on likely routes of exposure
Inhalation Prolonged inhalation may be harmful.
Skin contact Prolonged skin contact may cause temporary irritation.
Eye contact Direct contact with eyes may cause temporary irritation.
Ingestion Suspected of damaging fertility or the unborn child by ingestion.
Symptoms related to the physical, chemical and toxicological characteristics
Direct contact with eyes
may cause temporary
irritation.
Information on toxicological effects
Acute toxicity
Components Species Test Results
distillates (petroleum), hydrotreated heavy naphthenic (CAS
64742-52-5)
Acute
Dermal
LD50 Rabbit > 2000 mg/kg
Inhalation
LC50 Rat > 20 mg/l, 4
hours
Oral
LD50 Rat > 5000 mg/kg

* Estimates for product may be based on additional component data not shown.

Skin corrosion/irritation Prolonged skin contact may cause temporary


Serious eye damage/eye irritation. Direct contact with eyes may cause
irritation
temporary irritation.
Respiratory sensitization Not a respiratory sensitizer.
Skin sensitization This product is not expected to cause skin sensitization.
Germ cell mutagenicity No data available to indicate product or any components present at greater than 0.1%
are mutagenic or genotoxic.
Carcinogenicity This product is not considered to be a carcinogen by IARC, ACGIH, NTP, or OSHA.
ACGIH Carcinogens
distillates (petroleum), hydrotreated heavy A4 Not classifiable as a human
naphthenic (CAS 64742-52-5)
distillates (petroleum), solvent-dewaxed heavy carcinogen. A4 Not classifiable as a
paraffinic (CAS 64742-65-0)
distillates (petroleum), solvent-dewaxed light human carcinogen. A4 Not classifiable
paraffinic (CAS 64742-56-9)
lubricating oils, petroleum, hydrotreated as a human carcinogen. A4 Not
spent (CAS 64742-58-1)
Canada - Manitoba OELs: carcinogenicity classifiable as a human carcinogen.
distillates (petroleum), hydrotreated heavy
naphthenic (CAS 64742-52-5)
distillates (petroleum), solvent-dewaxed heavy Not classifiable as a human
paraffinic (CAS 64742-65-0)
distillates (petroleum), solvent-dewaxed light carcinogen. Not classifiable as a
paraffinic (CAS 64742-56-9)
lubricating oils, petroleum, hydrotreated
human carcinogen. Not classifiable
spent (CAS 64742-58-1)
IARC Monographs. Overall Evaluation of Carcinogenicity as a human carcinogen. Not
distillates (petroleum), hydrotreated heavy
paraffinic (CAS 64742-54-7) classifiable as a human carcinogen.
distillates (petroleum), solvent-dewaxed heavy
paraffinic (CAS 64742-65-0)
3 Not classifiable as to carcinogenicity to

humans. 3 Not classifiable as to

carcinogenicity to humans.

Reproductive toxicity Possible reproductive hazard. Suspected of damaging fertility or the


Specific target organ toxicity - unborn child. Not classified.
single exposure
Specific target organ toxicity - Not classified.
repeated exposure
Aspiration hazard Not expected to be an aspiration hazard.

12. Ecological information


Ecotoxicity Harmful to aquatic life.
Components Species Test Results
alkylated phenol (CAS 121158-
58-5)
Aquatic
Acute
Crustace EC5 Water flea (Daphnia magna) 0.037 mg/l, 48 hours
a Fish 0 Fathead minnow (Pimephales 40 mg/l, 96 hours
promelas)
LC50
distillates (petroleum), hydrotreated heavy naphthenic (CAS 64742-52-5)
Aquatic
Acute
Fish LC50 Pimephales > 30000 mg/l, 96 hours
promelas

* Estimates for product may be based on additional component data not shown.
Persistence and degradability No data is available on the degradability of this product.
Bioaccumulative potential
Bioconcentration factor (BCF)
alkylated phenol 794.33
Mobility in soil No data available.
Other adverse effects No other adverse environmental effects (e.g. ozone depletion, photochemical
ozone creation potential, endocrine disruption, global warming potential) are
expected from this component.
13. Disposal considerations

Disposal of waste from


residues / unused products
Collect and reclaim or dispose in sealed containers at licensed waste disposal site. Do
not allow this material to drain into sewers/water supplies. Do not contaminate ponds,
Local disposal regulations waterways or ditches with chemical or used container. Dispose of contents/container
Hazardous waste code in accordance with local/regional/national/international regulations.
Contaminated packaging Dispose in accordance with all applicable
regulations. Not regulated.
Since emptied containers may retain product residue, follow label warnings even after
container is emptied. Empty containers should be taken to an approved waste handling
site for recycling or disposal.

14. Transport information


TDG
UN number UN1950
UN proper shipping name AEROSOLS, flammable, Limited Quantity
Transport hazard class(es)
Class
2.1
Subsidiary risk
-
Packing group
Not
Environmental hazards applicable.
No.
Special precautions for user Read safety instructions, SDS and emergency procedures before handling.
Special provisions 80, 107
IATA
UN number UN1950
UN proper shipping name Aerosols, flammable, Limited Quantity
Transport hazard class(es)
Class 2.1
Subsidiary risk -
Packing group Not
Environmental hazards applicable.
ERG Code No.
10L
Special precautions for user Read safety instructions, SDS and emergency procedures before handling.
Other information
Passenger and cargo Allowed with
aircraft restrictions.
Cargo aircraft only
IMDG Allowed with
restrictions.
UN number UN1950
UN proper shipping name AEROSOLS, LIMITED QUANTITY
Transport hazard class(es)
Class 2
Subsidiary risk -
Packing group Not applicable.
Environmental hazards
Marine pollutant
No.
EmS
F-D, S-U
Special precautions for user Read safety instructions, SDS and emergency procedures before handling.
Transport in bulk according to Not established.
Annex II of MARPOL 73/78 and
the IBC Code

15. Regulatory information


Canadian regulations
Controlled Drugs and Substances Act
Not regulated.
Export Control List (CEPA 1999, Schedule 3)
Not listed.
Greenhouse Gases
Not listed.
Precursor Control Regulations
Not regulated.
International regulations
Stockholm Convention
Not applicable.
Rotterdam Convention
Not applicable.
Kyoto protocol
Not applicable.
Montreal Protocol
Not applicable.
Basel Convention
Not applicable.
International Inventories
Country(s) or region Inventory name On inventory (yes/no)*
Australia Australian Inventory of Chemical Substances (AICS) Yes
Canada Domestic Substances List (DSL) Yes
Canada Non-Domestic Substances List (NDSL) No
China Inventory of Existing Chemical Substances in China (IECSC) Yes
Europe European Inventory of Existing Commercial No
Chemical Substances (EINECS)
Europe European List of Notified Chemical Substances (ELINCS) N
Japan Inventory of Existing and New Chemical Substances (ENCS) o
Korea Existing Chemicals List (ECL) No
New Zealand New Zealand Inventory Yes
Philippines Philippine Inventory of Chemicals and Chemical Yes
Substances (PICCS)
Yes
United States & Puerto Rico Toxic Substances Control Act (TSCA) Inventory
*A "Yes" indicates that all components of this product comply with the inventory requirements administered by the Yes
governing country(s)
A "No" indicates that one or more components of the product are not listed or exempt from listing on the inventory administered by
the governing country(s).

16. Other information


Issue date 07-26-2016
Version # 01
Further information CRC # 574/1002598
Disclaimer The information contained in this document applies to this specific material as
supplied. It may not be valid for this material if it is used in combination with any other
materials. This information is accurate to the best of CRC Canada Co.'s knowledge or
obtained from sources believed by CRC to be accurate. Before using any product, read
all warnings and directions on the label. For further clarification of any information
contained on this (M)SDS consult your supervisor, a health & safety professional, or
CRC Canada Co.

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