EXPERIMENT- 1

|Atm To analyue he given inohqanie salt fod

Qucic and bauic nadicali

Relininary Imvestigatien
Physicar state Solid
olour white (Cut, fet, ce
Ni, Mnco abient)
Cdou Anmenium smell (may be NH)
Salubility Solubie in wates
Flame TUt No Charactehe flame (Pb Cu2+ ca' Sat
Bat, znt abient)

)TAetification ¢ Acdic Radical

a) relimina Ty tit i
Observation nferenee
Erpesment
. Salt Soluhon +elous less, colouyley gaj coth Ghoup Aanion
dil H,s04 briak efesvesc ence lhich (co may be
Husn lime wates milky
enfsnative tet:
Lßacl, Test: Salt ohite ppt of Bal0s
Soluthont Bacle
2.MgsO Tet: white ppt Mycls Co Conßrmd
Sat Sol tM9s04
 Chenical Reaetions i
Adie Radial
rulininasy Tuti

1.(NHa), Co, + H,s0, (NHa), so,t Co 1 t4,o

2. Ca(OH), +Co, ’ CaCO, t H,o

Confirmative Tes -

. Bacl, Test:
(NHa), co, t BaCl, ’ BacO, t t2 NH, c!

SO4
(NH+2 Mgco, t (NH+),
 Date Page Me.

(B) Identifation ef basis Radical

a Pheliniaary Tat
, No. Experiment Dhuervation Ingerence
Place a sed litmus n Red ltonus Zexo soup pruent
tht mecth of teat tuteusns blue (NHÊ may be

b) Con6mative test

Expeximent bsevatim lofeene

NHT confsm ed
L. Neley's Aeagea- tst:| Keddizh bron
Salt t solut on + NaoH ppt. formed
+ Neslexs Reagent
NaOH test : Smelled NH NH; Conftmed
Salt ol cti on + NaOH+ Dense white
Heat fumes of NH;
6ring a glas sod
dipþed ín conc.
HC
Chenical Reaction
2 Basic Radical
(a) fselininy Teut i
Na, Co,t 2H,o +2NH,
I. (NH4), Co, + 2NaD4
N H,t Red itnus - - - ’ Litnu t u e blus

(b) Confsrmative Test i

I. Nesler's Test :
’ 2 KI+
(Neslrs Reagent)
’ NH, Hg I + HI
2NH, HgIt Ho’NH,

. NalH Test
(NH), Co,t 2 NabH Na,Co,t2 H,0+2NHa
NH, 1 HC| NH4 CI ( Dense ohite fumes)

Keaut : The given inovganic salt contains foll ocoing

udie Radi cal: Co
Bosic Radial: NH
 EXPE KI MENT- 2
Aim To analyse tae given dadt of aidic
Cud b&eic hadical

(A)Identifeatin f Aeidic kadical

SNo.Expeinent Obervahion loferce

Salt Solution + No qas ç evolved
dil H,sD4 Sol utH on JcH, CDO, NO, SO
abyert)
Sal +Conc H,so4 t Colousley qa wit
Heat. Bring lpungent Amu which Groufo s auin
(cì mag be)
9tas od dipþed in 9ives olene white
NH40H fumes NH4CI

b- Conirmatve Test i
Dbsewatin Infenence
S. Noxpeument CCenßrOned
|Ag NO, Test : Salt Solutio Cwcy white ppt
ppt in NH 0H b e ppt.Soluble in Ny bH
DiMolve the

Chrorny! chloride Teat i

evolvel
a) Salt +Solid kC, 0,(!2) i
TConc. H, SO 4 t Heat
 Dated ........J..
Serial No.
Radi cal
Chenwcal Reaeian for Aidic
frelimnay Teet
2NHcl + H,sO4 Heat, (NH), So4 t 2HCI
NH0H + HC’NH4Cl+ H, 0
(white dene fu me)
Confir mative Test
AgNo, test
NH¡cl t 2Ag NOs ’24gci NH¡ NO3
white ppt)
Agtl + NH4oH LAgNHa),JcI +2H
(ia mmine silvey (I) chloride)
Chao myl chlonide Teut:
K, Cr,0,t H,so4’kso4 t 2Cr,D, tH,0
2NM4 tH,s0, (NH), So4+ 2 HCI
Cr Oz+ 2 4cIC*, 0,cl,? + H,0

CrOcl t4
(Veapou)
NaOHNacrOgt 2 Nacl + H,0
Sociumchromate (yellow Solutiom)
Na, (r 04 t Pb (CH, Co0), Pbcro, +CHa CO0 Na
(Lead Chsomate)
 .*...***

) Pass these vapour

Solution be comnes
througs NaoH yello)
) Add Qcetc
ad and yellow ppt of lead
Jead acetate to
Chxomate i
yellow soluti on forme
(B) Tden ifcaim Baic Ractical
a. Peiminay Tet
No, Expiment O6esvation Nerenee
Salt Solution t
NaOH+Smelof Anomona Zero hou (N
Heat may be
Plave a sed litmus onRed i tmus tura
the mouth o tet tube blue

b. (oniimative Tut:
No. Erperiment Obervai on |erence
Nestex Tet Salt sluti on + Reddish bxoon ppt NH
NaoH t Nesler! reagent ii fosmed |Confimed

NaDH Test : Salt Solution+ Smell ed NHa NH

Na oH + Heat Cmfsmed
6Ting agass rod dippeo |Loite clernse fumes
in di HCI NHI au form ed
Chemical Reeeton forr Bie Raolical
Test
Batinainay
NH,C1+ NaoH
NH, tRed litmu - -’ Litmw turs blu

Confmatve Test :
Nessles's Test: k, Hgl 2kI 4 Hgz
Hg I2+NH+ NH, HgI+ HI
2NH, HgI tH,0 NHtNH4I
H9

I (Iocine mällion
NabH Test: bauj
NHaclt Na0H
NH,t HC ’ NHC
(Dense whitb fumu)
Keswti- The gven in organie _alt Coutaud
Aiaic Radi cal c1
Baic Radical NH
 Page ho.

eXPERIMENT-3
Aim i To analyze the given inDganic solt far
acidic Qnd baic xadical.
(ATdeaHfcatisn o Aidic Radical
SNo.Expeim eat Dbewatian Inferene
salt solution + dil No gas i Group A (Co,c,co0
H5sOa Solution evotued NO so s aby ent
. SalttConc^ HSOa t Broon Colour Grop B (N O3 ma
Heat ed gas (No,) be present)
evolved

|b. Confirmative Tet

6. No Experim ent Obervatton Iene
. Dipheny amine teut: Decp blue calouxad NOG Confirmu
Salt + Conc^H, SO4 t solutim
diphenyl amins
NO, configmed
|Ring Teat:
Salt +f ehly prepa ved fosmed at the
Pe So a t (oncn juncion f two
H, So4 along thu side
the t e t ube
 Raoical
Checal Reaction fot Aci°c PbSO4 t 2 HN Og
Test i Pb (NO3, tH, S0,4
Pseliminay ’ CulNOs), t+ 2 NOz t H0
Confrm ative Tert i ’ Pb S0+ 2HNO
Ring Test : Pb ( NOs) t H, So4
i)
6 FeSO4 t 8H SO t 2H NO, 2 NO

feSo4. NO
Fe SO4 +NO (Nitsoso feros slphate)

i) DIth engl amne Tes t (CG Hs), +Ho

Hs ), N- N
2(Ce Hs),NH+C0]-’(Cs
(Dibheny amine hydrazine)

of Base Radical
6) Identißcation
freliminy Teeti PbCly
+ 2 H cl
Pb(NO) ( whit)

Test i
Conjtematie PbI2 t 2kCa
>lbCro 2kcl
Test: Pb Clz t 2kI
í) KI Pbca, tkcr O4
KaCr O4 Test : (yeltow Pet)
ii)
 Date
Page o.

Ldeaifcation o Baic Radical

4lxelimigay
SNoXp imen Tet
DbsewaHon yerenee
Satt Solution +NaoH |No Smeu ef
ammoaia|7e90 950utp(NH
abeent
Salt solution + dl HCI
wkitt ppt fbee q20up
Eter the above ppt and
boll it with wates and
divide into pats

b Conirmative Tet
S,No. Erperim ent Obeervat on Ingewe
L. KITest paut t KI 6I (Yelos ppt)l Pb

k, Cr Og Test 2nd
formd

salt contauy
Reault : The qiuen harga
Aidic kadical NO

Baie Radical
 Date
Page Mo.
EXPERIMENT- 4
Aim To analze tu
aicic aud balic qiven inorgai salr fca
hadical
(ATdentißcation Aidic Radical
$,No.
Saer
Expeument Obeesv atien
nyerenes
Soluion t diI H,S04 NO gas ! GDup A(co, sso
Solution evolved
No,CHc00* absent)
Salt t Con C"H, sO 4t HeatNo ga 4 Group B cuions(Cait
evolvd
absent)

b- Confirmative Test
ENpeutment |ferene
1. Bacl, tes t : Sa coluti nt hite ppt fosmeeso, Conftmd
Ball, Soluti on pPt remains
Add d' I,. MeA os dil HN03 insoluble

| Lead Acetate Tet i

t Coluton+ lead acetate sol.
sol PPt betomeg
Add ammonium aetate
&oluble
CeHac0 oNH) to above pet
Chenical Reaction
Acid'c Radical
BacA, Test

Cu So4 t BaC!, Ba SO, t Cu Cu

(wnite pPpt)
2. (CH, Co0), Pb Tet :
CuSO, + (CHa Co0), Pb PbSO4 t2(CH, C00),Cu
( wkite ppt)
Pbs o, + 2CH, coo NH(CH,COO) PE t (NH)s,
 Identifcation o Batc Radical
a- Prelinninay Tet :
S No. Expesimen Dbeevetton loferenee
Salt solutim+ Na0H + heat| No Amele |zero qTOup
ammoia (NH absent

Satt solution + dil. HCU No wute ppt s0up1,(PB absent

Above soluti on + HS ga Black ppt is Gro uf Ii ,(Cuy

formeol PBmay be preses
4. Disolve above pet | Solutio tusns
HNOg bluzh neen
5 Divide the above Solwtion
n 2 pant

b- Confsmatie Test
EYperi ment 6Aeration Ifeene
. NH¡0H Test: ! Deep byue Cut
NH0H Colou Cenfrme

Po taium ferrocyide hoc olte bso on Cy27

teut: l nd partt t K+ PPt copper feo
Cee (cN] |Cyanicde s fom ed
Chen'cal Renetion
Basi Radical
CuS t 2H7
B la ck Ppt

3Cus + gHNOs cu(DH), +2NO 4 H, 0+ 3S

1. NH04 test

Cu (N09), + 4NH, oH [Cu (N Ha)J(No),tH0

beepblue ppt

2. K4 [Pe len) tes t

2Cu(ND,), + kelte (CN),J’ cu [e (CN)]+
4 kN 03

Slyatne
PratikKumarClasses
 EXPERTMENT- 9
Aim loideuify th funetimal giaup n 1h given
Dganit compound
Appaatu Ruquind i Teat tue, teur tue Ltand,
t t tube haldes, dinppes, itmuslblu), daHco,,

State i Solid
Celus ahite
Vintgan Lile
|Clamma kiiyi BusH itt non J0ty flame [Alihhati
Prallminay tet i
Expenimnt bervation Infexenes
Ltms test : LitmwAolution tuns-CoOH or- OH
ganic compoerd +2fom blw to red b present
|ops d tm olution
ganie Curnpound t olousleu, ororleu (00H gieu
NaHco, soluti on qad coith bxisk be o
eyesc ence OH
Pes ent)
 Chemical ReactHon :
Na HCO, Test:
RCOOH + Na HcO,
Eastea Test ?
Conc
RCOOH+ R-H
H_sOy
(Fruity smu ete)
FeCls Test RCOoH +NH4OH ’RC 00Na
RCOONa t H0 ’ Ammoniac Salt ( Solublu)
RCOONHa t fe Cl3 ’ (RCOo), fe
+3NHyCl
(RCO0) Fe + H, fe
(oH)(RcoO),+ RCOOM
Baic fesric acetate.
Esat. .....
Date ........e.
Page e.

Canimatony teit i
fste Epeniment
test:
DbLCwaion

|Ogani COmpound t Fruy smell

C HsOH+ Conc H soy C-0H
tHeat Cnirmed
fe Cls Tet:
Compownd t dil1qanicRed colous
Pe Clg Solution appeas C- 0H
Confis mad

Kesult The funciaal qiaup pei ent sn the

given ongaaic canpond i canboxyac uid

C-OH
 **..****

ExPERIMENT- 40
Aimi To idenify the funetional gicup in the
gen agai cempawd
Appatus Requiudi Tt tube,test tube Atand,
ttt tube holdeA, dhapbeh itmusl blu) Dutin,
Al HL NaDH Na metal di H, SOy CH, c00H

Phyucal faahetckia
State
Colous
Liquuid
Colowale
Ddou Spi uit Lke
atea tolwbilihy: Solwbt in water
Mamnabillty Busn itth non sDoty flam (Alifhatd
1.Prel'minasy tet :
$. No. Expeint Obsewatin Iyexene
O24anit Compound +blue No chang (Phene) jve
Stmus oluti on abient

aqanic conpound +dil HH.Nc ppt on cily-N,9sp. Abseat

NabH

3.
0gaie comp. +Na metal H, qas evolved OH (alcohe)
Chemical Reaetion, ?
I. Na Metal Tet i
2R0H 2 Na

9. cERRIC AMMONIUM NITRAT TEsT :

2ROH+(NH), Ce (NO,) ’ (ROH), Ce (Nos )+t

(Red col ouwn)

3 Cster Test :
Cone, R'COOR + HO
H,Soy
Aleohol acid
eiter
 Date Paoe o. .........

Cnkrnatory Tet :
SNo Experiment Obevation ferene
Cesie ammonium nitrate Red Colour

Oxgade compowd tcCoie Cofirmed

ammoium n°trate
Estes Test: Fuity ameef
O9anic Compound t este
CHcooHt Conc. Mso4
(1-2dsops) + Heat

Reatult - The funcimal gioup pruet in

Dhganic Campaund æ aleohol %o4p
(- OH)
 solution NaHCo,
qietpfhenolic Compoundt O34anic
ere Vesc efeY No Test: HcO; Na
mayblIRe-(OH) Red dolutim
phena -COOH
Q5 tuxn itw Alue bluel wnot Compo
Is<eana Erpextmet
OBeeswatim fliminany
Teut
Alammability
ii) A00hy non- uth Busn
indoleble WateA Solubilihyi Watta
Smell Phenolic Odous
white
Solid
laekotie Physical teSta
labt anhycsuide,
cm Pathaic Solutim, Pell,
aHCOslitmulbluj deahþer
tubehald, tur
dtand, tube teLt tube, Requiudi-
Tet asatus App
Cempound osganic given
the funetianhal
n
qsoup the identify To Aim
XPERIMENT-
11
 Chenicat Reaction i
Ceaisnative Teet :
fe Cls Teu t
3c,Hs OH +fe Cls ’fe (0c,Hs), +3HC4
teerrie perode

OH
Conc
O+ 2

DNa ONa
(Violet)
OH (Red GloLA

PratikKumarClasses
Siguatwre
 Date
Page e.

EXPERIMENT- 12
im: To idantify ths functianal giaup in puent
in ths qiven aågani Compoend
Appaxatw Requikedi lert tubi, tee tuhe ltand,
test tube haldes dsopbeh, litqu Aolution, 2
4 DNe, dil. H NaDH, ALagent, fehling
Solution Schiff eagent
I'hyaital s.ahexb'en
Colous:
iguid
Cololss
Ddous Pungent
Wates solwkiity:oluble u ates
flammabil ty i Busn with no1- Jopts flame (Al iphatc)
A) Plininaky Teet !
enpuiosat bs esvatHn Iyeune
Caganie ompound +blu change -CooH a phe nolic
WtnwAblution houp ahsent
CAgan't Campound+ Nalt 1 Ne ppt or
dil HL
3
4 DNP Shake and allou it fpt
to stand.
 (-CHo) gsous
aldehycdie"
canttin tempound ehqanie Given Reeuti
wcten Q nboil
(A+6)+| bethAolution Fehlings
prsent compound+ |Oaqanic
ghoup -CHO ppt. Red testiJolution|Eehling's
.
Aeagent chitf3
psegent Dbtained 2.mcAmpound
l 4 DAganie
qroup CHO colow Aok
Ieforanes test: kolution
Expesin&t Schiff
Obsevation (BCoCMatosy
teti