Page 1/7

Safety data sheet

according to 1907/2006/EC, Article 31
Printing date 10.01.2017 Version number 5 Revision: 10.01.2017

SECTION 1: Identification of the substance/mixture and of the company/

undertaking
· 1.1 Product identifier
· Trade name: Nullifire FS702
· MSDS code: TK-N-FS702
· 1.2 Relevant identified uses of the substance or mixture and uses advised against
No further relevant information available.
· Application of the substance / the mixture Sealant
· 1.3 Details of the supplier of the safety data sheet
· Manufacturer/Supplier:
tremco illbruck Dış Ticaret A.Ş.
Ömerli Mah. Yamaç Sok. No: 7 A-Blok Arnavutköy, Istanbul
T: +90 (0) 2126232191, F: +90 (0) 2126232190
info.tr@tremco-illbruck.com
· Further information obtainable from:
tremco illbruck Ltd
Torrington Avenue, Coventry, CV4 9TJ
T: +44 (0) 2476855000, F: +44 (0) 2476469547
www.nullifire.com, protect@nullifire.com
· 1.4 Emergency telephone number:
During office hours tel.: +44 (0) 2476855000. At all other times please contact your national poisoning
centre.

SECTION 2: Hazards identification

· 2.1 Classification of the substance or mixture
· Classification according to Regulation (EC) No 1272/2008
The product is not classified according to the CLP regulation.
· 2.2 Label elements
· Labelling according to Regulation (EC) No 1272/2008 Void
· Hazard pictograms Void
· Signal word Void
· Hazard statements Void
· Supplemental information:
EUH208 Contains CIT [EC 247-500-7] : MIT [EC 220-239-6] (3:1). May produce an allergic reaction.
EUH210 Safety data sheet available on request.
· Regulation (EC) No 528/2012 on biocidal products Contains a biocidal product: C(M)IT/MIT (3:1)
· 2.3 Other hazards
· Results of PBT and vPvB assessment
· PBT: Not applicable.
· vPvB: Not applicable.

SECTION 3: Composition/information on ingredients

· 3.2 Mixtures
· Description: Mixture of substances listed below with non-hazardous additions.
· Dangerous components: Void
· Additional information: For the wording of the listed hazard phrases refer to section 16.
(Contd. on page 2)
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 Page 2/7
Safety data sheet
according to 1907/2006/EC, Article 31
Printing date 10.01.2017 Version number 5 Revision: 10.01.2017

Trade name: Nullifire FS702

(Contd. of page 1)
· Regulation (EU) No 528/2012 Biocidal Products Regulation
55965-84-9 CIT [EC 247-500-7] : MIT [EC 220-239-6] (3:1) PT6

SECTION 4: First aid measures

· 4.1 Description of first aid measures
· General information: Immediately remove any clothing soiled by the product.
· After inhalation: Supply fresh air; consult doctor in case of complaints.
· After skin contact:
Immediately wash with water and soap and rinse thoroughly.
If skin irritation continues, consult a doctor.
· After eye contact:
Rinse opened eye for several minutes under running water. If symptoms persist, consult a doctor.
· After swallowing:
Rinse out mouth and then drink plenty of water.
Do not induce vomiting; call for medical help immediately.
· 4.2 Most important symptoms and effects, both acute and delayed
Sensitising effect by skin contact is possible by prolonged exposure.
· Information for doctor: No further relevant information available.
· Hazards No further relevant information available.
· 4.3 Indication of any immediate medical attention and special treatment needed
No further relevant information available.

SECTION 5: Firefighting measures

· 5.1 Extinguishing media
· Suitable extinguishing agents:
CO2, powder or water spray. Fight larger fires with water spray or alcohol resistant foam.
Use fire extinguishing methods suitable to surrounding conditions.
· 5.2 Special hazards arising from the substance or mixture
Formation of toxic gases is possible during heating or in case of fire.
Carbon dioxide
Carbon monoxide (CO)
· 5.3 Advice for firefighters
· Protective equipment:
Wear self-contained respiratory protective device.
Wear fully protective suit.
· Additional information Cool endangered receptacles with water spray.

SECTION 6: Accidental release measures

· 6.1 Personal precautions, protective equipment and emergency procedures
Wear protective clothing.
· 6.2 Environmental precautions: Do not allow to enter sewers/ surface or ground water.
· 6.3 Methods and material for containment and cleaning up:
Absorb with liquid-binding material (sand, diatomite, acid binders, universal binders, sawdust).
· 6.4 Reference to other sections
See Section 7 for information on safe handling.
See Section 8 for information on personal protection equipment.
(Contd. on page 3)
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 Page 3/7
Safety data sheet
according to 1907/2006/EC, Article 31
Printing date 10.01.2017 Version number 5 Revision: 10.01.2017

Trade name: Nullifire FS702

(Contd. of page 2)
See Section 13 for disposal information.

SECTION 7: Handling and storage

· 7.1 Precautions for safe handling Avoid contact with the eyes and skin.
· 7.2 Conditions for safe storage, including any incompatibilities
· Storage:
· Requirements to be met by storerooms and receptacles:
Store only in unopened original receptacles.
· Information about storage in one common storage facility: Protect from heat and direct sunlight.
· Further information about storage conditions:
Store in cool, dry conditions in well sealed receptacles.
Storage temperature: +5 °C to +35 °C
· 7.3 Specific end use(s) No further relevant information available.

SECTION 8: Exposure controls/personal protection

· 8.1 Control parameters
· Ingredients with limit values that require monitoring at the workplace:
The product does not contain any relevant quantities of materials with critical values that have to be
monitored at the workplace.
· Additional information: The lists valid during the making were used as basis.
· 8.2 Exposure controls
· Personal protective equipment:
· General protective and hygienic measures:
The usual precautionary measures are to be adhered to when handling chemicals.
Wash hands before breaks and at the end of work.
Avoid contact with the eyes and skin.
· Respiratory protection: Use only in well-ventilated areas.
· Protection of hands:

Protective gloves

The glove material has to be impermeable and resistant to the product/ the substance/ the
preparation.
· Material of gloves
Rubber gloves
The selection of the suitable gloves does not only depend on the material, but also on further marks of
quality and varies from manufacturer to manufacturer. As the product is a preparation of several
substances, the resistance of the glove material can not be calculated in advance and has therefore to
be checked prior to the application.
· Penetration time of glove material
The exact break through time has to be found out by the manufacturer of the protective gloves and
has to be observed.
· Eye protection: Safety glasses
(Contd. on page 4)
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 Page 4/7
Safety data sheet
according to 1907/2006/EC, Article 31
Printing date 10.01.2017 Version number 5 Revision: 10.01.2017

Trade name: Nullifire FS702

(Contd. of page 3)
· Body protection: Protective work clothing

* SECTION 9: Physical and chemical properties

· 9.1 Information on basic physical and chemical properties
· General Information
· Appearance:
Form: Pasty
Colour: According to product specification
· Odour: Mild
· pH-value at 20 °C: 8.2 - 9.5
· Initial boiling point and boiling range: >100 °C
· Flash point: >100 °C
· Explosive properties: Product does not present an explosion hazard.
· Density at 20 °C: 1.52 g/cm³
· Solubility in / Miscibility with
water: Fully miscible.
· Solvent content:
VOC (EU) 6.3 g/l
VOC (EC) < 0.5 %
· 9.2 Other information No further relevant information available.

SECTION 10: Stability and reactivity

· 10.1 Reactivity Stable
· 10.2 Chemical stability
· Thermal decomposition / conditions to be avoided:
No decomposition if used according to specifications.
· 10.3 Possibility of hazardous reactions No dangerous reactions known.
· 10.4 Conditions to avoid No further relevant information available.
· 10.5 Incompatible materials: No further relevant information available.
· 10.6 Hazardous decomposition products: No dangerous decomposition products known.

SECTION 11: Toxicological information

· 11.1 Information on toxicological effects
· Acute toxicity Based on available data, the classification criteria are not met.
· Primary irritant effect:
· Skin corrosion/irritation Slight irritation possible.
· Serious eye damage/irritation Slight irritation possible.
· Respiratory or skin sensitisation May cause allergic skin disorders in sensitive individuals.
· CMR effects (carcinogenity, mutagenicity and toxicity for reproduction)
· Germ cell mutagenicity Based on available data, the classification criteria are not met.
· Carcinogenicity Based on available data, the classification criteria are not met.
· Reproductive toxicity Based on available data, the classification criteria are not met.
(Contd. on page 5)
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 Page 5/7
Safety data sheet
according to 1907/2006/EC, Article 31
Printing date 10.01.2017 Version number 5 Revision: 10.01.2017

Trade name: Nullifire FS702

(Contd. of page 4)
· STOT-single exposure Based on available data, the classification criteria are not met.
· STOT-repeated exposure Based on available data, the classification criteria are not met.
· Aspiration hazard Based on available data, the classification criteria are not met.

SECTION 12: Ecological information

· 12.1 Toxicity
· Aquatic toxicity: No further relevant information available.
· 12.2 Persistence and degradability No further relevant information available.
· 12.3 Bioaccumulative potential No further relevant information available.
· 12.4 Mobility in soil No further relevant information available.
· Ecotoxical effects:
· Other information:
This product contains no substances in Annex I to Directive EC 1005/2009 concerning ozone
depleting substances
· Additional ecological information:
· General notes:
Not known to be hazardous to water.
Recommendation:
Do not allow undiluted product or large quantities of it to reach ground water, water course or sewage
system.
· 12.5 Results of PBT and vPvB assessment
· PBT: Not applicable.
· vPvB: Not applicable.
· 12.6 Other adverse effects No further relevant information available.

SECTION 13: Disposal considerations

· 13.1 Waste treatment methods
· Recommendation Disposal must be made according to official regulations.
· Waste disposal key: UK (WM3) : n/a
· European waste catalogue
08 04 10 waste adhesives and sealants other than those mentioned in 08 04 09
· Uncleaned packaging:
· Recommendation:
Dispose of packaging according to regulations on the disposal of packagings.
Empty contaminated packagings thoroughly. They may be recycled after thorough and proper
cleaning.
Packagings that may not be cleansed are to be disposed of in the same manner as the product.

SECTION 14: Transport information

· 14.1 UN-Number
· ADR, ADN, IMDG, IATA Void
· 14.2 UN proper shipping name
· ADR, ADN, IMDG, IATA Void
(Contd. on page 6)
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 Page 6/7
Safety data sheet
according to 1907/2006/EC, Article 31
Printing date 10.01.2017 Version number 5 Revision: 10.01.2017

Trade name: Nullifire FS702

(Contd. of page 5)
· 14.3 Transport hazard class(es)
· ADR, ADN, IMDG, IATA
· Class Void
· 14.4 Packing group
· ADR, IMDG, IATA Void
· 14.5 Environmental hazards:
· Marine pollutant: No
· 14.6 Special precautions for user Not applicable.
· 14.7 Transport in bulk according to Annex II of
Marpol and the IBC Code Not applicable.
· UN "Model Regulation": Void

* SECTION 15: Regulatory information

· 15.1 Safety, health and environmental regulations/legislation specific for the substance or
mixture
"CLP" Regulation (EC) No 1272/2008 (OJ L 353, 31.12.2008, p.1).
"REACH" Regulation (EC) No 1907/2006 (OJ L 396, 30.12.2006, p.1, with subsequent amendments).
"BPR" Regulation (EU) No 528/2012 of the European Parliament and of the Council of 22 May 2012
concerning the making available on the market and use of biocidal products.
Regulation (EU) 2016/131 of 1 February 2016 approving C(M)IT/MIT (3:1) as an existing active
substance for use in biocidal products for product-types 2, 4, 6, 11, 12 and 13.
COMMISSION REGULATION (EU) 2015/830 of 28 May 2015.
· National regulations:
· Additional classification according to Decree on Hazardous Materials, Annex II:
No further relevant information available.
· Information about limitation of use: No further relevant information available.
· Other regulations, limitations and prohibitive regulations
· Substances of very high concern (SVHC) according to REACH, Article 57 Not applicable.
· 15.2 Chemical safety assessment: A Chemical Safety Assessment has not been carried out.

SECTION 16: Other information

This information is based on our present knowledge. However, this shall not constitute a guarantee for
any specific product features and shall not establish a legally valid contractual relationship.
· Abbreviations and acronyms:
ADR: Accord européen sur le transport des marchandises dangereuses par Route (European Agreement concerning the
International Carriage of Dangerous Goods by Road)
IMDG: International Maritime Code for Dangerous Goods
IATA: International Air Transport Association
GHS: Globally Harmonised System of Classification and Labelling of Chemicals
EINECS: European Inventory of Existing Commercial Chemical Substances
ELINCS: European List of Notified Chemical Substances
CAS: Chemical Abstracts Service (division of the American Chemical Society)
VOC: Volatile Organic Compounds (USA, EU)
PBT: Persistent, Bioaccumulative and Toxic
(Contd. on page 7)
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 Page 7/7
Safety data sheet
according to 1907/2006/EC, Article 31
Printing date 10.01.2017 Version number 5 Revision: 10.01.2017

Trade name: Nullifire FS702

(Contd. of page 6)
SVHC: Substances of Very High Concern
vPvB: very Persistent and very Bioaccumulative
· * Data compared to the previous version altered.
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