Module 1
Module 1
And Circuits
Code: 23B12EC311
Contents
• Course Description
• Course Outcomes
• Text Books
• Chapter 1
• Chapter 2
• Chapter 3
• Chapter 4
• Chapter 5
• Introduction to Course
Course Description
• Title : Semiconductor Devices And
• Code Circuits
• L-T-P : 23B12EC311
• Credits : 3 00
: 3
Course Outcomes
COURSE OUTCOMES COGNITIVE LEVELS
CO1 Recall the concepts of PN junction diodes and its applications. Remembering (Level I)
CO2 Understand the basic concept of MOS devices. Understanding (Level II)
CO3 Apply the theory of theses device in application of digital logics families. Applying (Level III)
CO4 Analyze and apply the semiconductor devices in the amplifier circuits. Analyzing (Level IV)
Text
1. D. Neamen, D. Biswas ,”Semiconductor Physics and Devices”, McGraw Hill Education; 4
Books
edition, 2017
2. S.M Sze. "Physics of Semiconductor Devices," Wiley 3 edition reprint (2018)
3. Thomas L. Floyd, “Digital Fundamentals”, 10th edition, Pearson. (2013)
4. S Salivahanan, N S. Kumar “Electronic Devices and Circuits”, McGraw Hill Education
PrivateLtd. 2018
Chapter 1: Fundamentals of Semiconductors
• Introduction to Semiconductor
• Semiconductor materials
• E K diagram
• Carrier Concentration
• Density of States
• Energy band diagram of Pn junction
• Tunneling mechanism
• Density of states
• Ideal Nonrectifying Barriers
• Fermi level
• Tunneling Barrier
• Carrier dynamics
• Heterojunctions
• Metal-Semiconductor Ohmic Contacts
• 13 contact hours
• Schottky barrier
Chapter 2: Introduction to Optoelectronic devices
• Optical Absorption :Generation and Recombination
• Photoluminence
• Electroluminance
• Light Emitting Diode
• Photodiode
• Photodetector
• Solar Cell
• 10 Contact Hours
Chapter 3: Introduction to the Special
Semiconductor Diode
• Schottky Diode
• Tunnel Diode
• Varactor Diode
• Gunn Diode
• Impatt Diode
• 4 Contact Hours
Chapter 4: Introduction to the Semiconductor
Power devices
• Power Bipolar Transistor
• Power MOSFETs
• Thyristors
Chapter 5: Introduction to Amplifier
• The basic Classification of the Logic Families is as follows:
• A) Bipolar Family
• B) Unipolar Family
• C) Hybrid Family.
• 9 Contact Hours
Assessment Tools
Examination (75 Marks):
T1 (20 Marks)
T2 (20 Marks)
End Term (35 Marks)
However all these device cane constructed by using small number of device building blocks
𝑝 − 𝑡𝑦𝑝𝑒 𝑛 − 𝑡𝑦𝑝𝑒
Metal Semiconductor
Semiconductor Semiconductor
Metal-Semiconductor Interface 𝑝 − 𝑛 junction
oxide
Semiconductor Semiconductor
Metal Semiconductor
A B
Heterojunction Interface Metal-Oxide Semiconductor Structure
Major Semiconductor Devices
Year Semiconductor Device Author/ Inventor
1874 Metal-Semiconductor Contact Braun
1907 Light Emitting Diode Round
1947 Bipolar Transistor Bardeen, Brattain, and Shockley
1949 𝑝 − 𝑛 junctions Shockley
1952 Thyristor Ebers
1954 Solar Cell Chapin, Fuller, and Pearson
1957 Heterojunction Bipolar Transistor Kroemer
1958 Tunnel Diode Esaki
1960 MOSFET Kahng and Atalla
1962 Laser Hall et al.
1963 Heterostructure Laser Kroemer, Alferov, and Kazarinov
1963 Transferred-electron diode Gunn
1965 IMPATT diode Johnston, DeLoach, and Cohen
Major Semiconductor Devices
Year Semiconductor Device Author/Inventor
1966 MESFET Mead
1967 Non-volatile semiconductor memory Kahng and Sze
1970 Charge-Coupled Device Boyle and Smith
1974 Resonant Tunnelling Diode Chang, Esaki, and Tsu
1980 MODFET (Modulation doped) Mimura et al.
1994 Room Temperature Single-electron memory cell Yano et al.
2001 20 nm MOSFET Chau
Historical Images
John Bardeen Walter Brattain
William Shockley
Images Heterojunction
Key Semiconductor Technologies
Year Technology Author/Inventor
1918 Czochralski Crystal Growth Czochralski
1925 Bridgman Crystal Growth Bridgman
1952 III-V Compunds (GaN etc.) Welker
1952 Diffusion Pfann
1957 Lithography Photoresist Andrus
1957 Oxide Masking Frosch and Derrick
1957 Epitaxial CVD Growth Sheftal, Kokorish, and Krasilov
1958 Ion Implantation Shockley
1959 Hybrid Integrated Circuit Kilby
1959 Monolithic Integrated Circuit Noyce
1960 Planar Process Hoerni
1963 CMOS Wanlass and Sah
Key Semiconductor Technologies
Year Technology Author/Inventor
1967 DRAM Dennard
1969 Polysilicon self-aligned gate Kerwin, Klein, and Sarace
1969 MOCVD Manasevit and Simpson
1971 Dry Etching Irving, Lemons, and Bobos
1971 Molecular Beam Epitaxy Cho
1971 Microprocessor (4004) Hoff et al.
1982 Trench isolation Rung, Momose, and Ngakubo
1989 Chemical mechanical polishing Davari et al.
1993 Copper Interconnect Paraszczak et al.
Images
Shell configurations Ga (2, 8, 18, 3) Zn (2,8,18,2) Ga (2, 8, 18, Cd(2, 8, 18, 18, 2) Cd(2, 8, 18, 18, 2)
K=1,L=2,M=3,N=4 As (2, 8, 18, 5) O (2,6) 3) S (2,8,6) Se (2,8,18, 6)
(2 𝑛 2) P (2,8,5)
Sub Shell Ga (4𝑠24𝑝1) Zn (3d10 4𝑠2) Ga (4𝑠24𝑝1) Cd (4𝑠24𝑝64𝑑105𝑠2) Cd (4𝑠24𝑝64𝑑105𝑠2)
configurations As (4𝑠24𝑝3) O (2𝑠2 2𝑝4) P (3𝑠23𝑝3) S (3𝑠23𝑝4) Se (4𝑠24𝑝4)
s=0, p=1, d=2, f=3,
g=4
Only outer shell
Acting as Ga-Conduction Zn-Conduction Ga-Conduction Cd-Conduction Cd-Conduction
As-Valence O-Valence P-Valence S-Valence Se-Valence
CRYSTAL STRUCTURES
1
BC Atom per unit cell = 1 + 8 × = 2 Interatomic spacing (a) in case of Si is 5.42 Å
8
C
Then the volume of atomic cube is
3
= 5.42 × 5.42 × 5.42
FC Å
1 1
C Atom per unit cell = 6 × +2 8 × =4 = 15.922 × 10−23 𝑐𝑚−3
8
Then number of atoms per unit volume
1 22 −3
=8× −23 = 5.02 × 10 𝑐𝑚
15.922 × 10
ENERGY BANDS
Energy Levels of Isolated Atoms
For an isolated atom, the electrons can have discrete energy levels. For example, the energy levels for an isolated hydrogen
atom are given by the Bohr model :
where m0 is the free-electron mass, q is the electronic charge, ε0 is the free-space permittivity, h is the Planck constant, and n
is a positive integer called the principal quantum number. The quantity eV (electron volt) is an energy unit corresponding to
the energy gained by an electron when its potential is increased by one volt. It is equal to the product of q (1.6 × 10^–19
coulomb) and one volt, or 1.6 × 10^–19 J.
instead of two levels, N separate but closely spaced levels are formed. When N is large, the result is an essentially continuous
band of energy. This band of N levels can extend over a few eV at the inter-atomic distance of the crystal. The electrons can no
longer be treated as belonging to their parent atoms. They belong to the crystal as a whole.
The Energy-Momentum Diagram
The energy E of a free electron is given by
where p is the momentum and m0 is the free-electron mass. If we plot E vs. p, we obtain a parabola
In a semiconductor crystal, an electron in the conduction band is similar to a free electron in being relatively free to move
about in the crystal. However, because of the periodic potential of the nuclei, Equation can no longer be valid. However, it
turns out that we can still use Equation if we replace the free-electron mass in Equation by an effective mass m n (the subscript
n refers to the negative charge on an electron), that is,
The electron effective mass depends on the properties of the semiconductor. If we have an energy-momentum relationship
described by the above equation, we can obtain the effective mass from the second derivative of E with respect to p:
A simplified energy-momentum relationship of a special
semiconductor with an electron effective mass of mn = 0.25 m0 in the
conduction band (the upper parabola) and a hole effective mass of
mp= m0 in the valence band (the lower parabola). Note that the
electron energy is measured upward and the hole energy is measured
downward. The spacing at p = 0 between these two parabolas is the
bandgap Eg.
Fermi Level
The number of charge carriers in an energy level depends upon the probability of occupation of charges to
density of the states
𝑛 𝐸 = 𝜌 (𝐸)× 𝐹(𝐸)
Where,
𝐹 𝐸 is the probability of occupying energy level 𝐸
𝜌(𝐸) is the density of states at energy level 𝐸
𝜌 𝑘 𝑑𝑘 = 𝜌 (𝐸) 𝑑E
Intrinsic Carrier Concentration
Carrier Concentration is vital for the operation of Semiconductor also to distinguish from Insulators and metals.
At any given temperature, a steady state semiconductor experience electron movement from valance to
conduction band and vice versa in exactly equal manner, called Thermal equilibrium condition.
Intrinsic semiconductor: have relatively small amount of impurities compared to thermally generated electron-
hole pairs.
𝐸
𝑡𝑜𝑝
𝐸
𝐸
𝑡𝑜𝑝 𝑛=ᶘ 𝑁 𝐸 𝐹(𝐸)𝑑𝐸
𝑛=ᶘ 𝑛 𝐸 𝑑𝐸 0
0
Carrier concentration
𝐸𝑐
meant electron Density
(number of electrons 𝐸𝑔
𝑛(𝐸) will depend upon the 𝐸𝑣
per unit volume) density of States (𝑁(𝐸)) and
probability of electron
occupying the sate
Please note: Electron will follow Pauli’s exclusion principle while occupying any state
Density of States Function (𝑁(𝐸))
We Kinetic energy of the particle: De-Broglie
know, 1 1 2 ℎ ℎ 2𝜋
Relation:
𝐸 = 𝑚𝑣2 = 𝑚2𝑣2 = 𝑝 𝑝 = = = ℏ𝒌
2 2𝑚 2𝑚 𝜆 2𝜋 𝜆
2𝑎
𝑘𝑦
2 2
𝐸= ℏ 𝒌
2𝑚
Then 𝜆𝑚𝑖𝑛 = 2𝑎
2𝜋 2𝜋 𝜋
𝑘 = = = =𝑘 =𝑘 𝒌 is wave vector which can exist in all dimensions
𝑥,𝑚𝑎𝑥 𝜆 𝑦,𝑚𝑎𝑥 𝑧,𝑚𝑎𝑥
2𝑎 𝑎
2
As states are discrete so is the wave vector 𝑘2 = 𝑘2 +𝑥 𝑘2 +𝑦 𝑘2 =𝑧 (𝑛2 +𝑥 𝑛2 +𝑦 𝑛2)( 𝑧 ) 𝜋 𝑘𝑥
2 𝑎
𝑛𝜋
𝑘 = , 𝑘𝑥 𝑦= ,𝑛𝑘𝑧𝜋 =
𝑛 𝜋
𝑥,𝑚𝑎𝑥 𝑎𝑦,𝑚𝑎𝑥 𝑧,𝑚𝑎𝑥 𝑎 𝑎
𝑘𝑧
Density of States Function (𝑁(𝐸))
So the distance between two Volume case
𝜋 3
neighbouring states 𝑉𝑘 =
𝜋 𝑎
𝑘𝑥+1 − 𝑘𝑥 =
𝑎
𝐸𝑐 − 𝐸𝐹 𝐸𝐹 − 𝐸𝑣
𝑛 = 𝑁 𝑐exp − 𝑘𝑇 𝑘𝑇 𝑝 = 𝑁 𝑣exp −
𝑁𝑣 is effective density of states in valance band and will also vary depending upon material
Material 𝑵𝒄 𝑵𝒗
𝑆𝑖 2.86 × 1019𝑐𝑚−3 2.66 × 1019 𝑐𝑚−3
𝐺𝑎𝐴𝑠 4.7 × 1017𝑐𝑚−3 7.0 × 1018𝑐𝑚−3
Intrinsic Carrier Concentration
𝐸
𝑡𝑜𝑝
𝑛=න 𝑁 𝐸 𝐹(𝐸)𝑑𝐸
0
∞
4𝜋(2𝑚∗𝑐)3/2 𝐸 − 𝐸𝐹 Taking 𝐸𝑡𝑜𝑝 → ∞
𝑛=න 𝐸 − 𝐸𝑐 × exp 𝑑𝐸
3 𝑘𝑇 As 𝐹 𝐸 → 0 as 𝐸 − 𝐸𝑐 ≫
0 ℎ −
𝑘𝑇
∞
2 −
3 𝐸 − 𝐸𝐹 1. 𝑁𝑐 is effective density of states
𝑛 = 𝑁𝑐 𝑘𝑇 𝐸 × exp − 𝑑𝐸 Where,
න
2 𝑘𝑇
𝜋 in conduction band and will vary
0
Let 𝑥 ≡ 𝐸/𝑘𝑇 depending upon material
∞
2. For simplicity assuming 𝐸𝑐 at 0, we will
2 𝐸𝐹 𝐸𝐹 reintroduce after calculations
𝑛= 𝑁𝑐 exp න 𝑥 × exp −𝑥 𝑑𝑥 = 𝑁𝑐 exp
𝑘𝑇 0 𝑘𝑇
𝜋
Intrinsic Carrier Concentration
𝐸𝐹
𝑛 = 𝑁 𝑐exp
𝑘𝑇
𝐸𝑐 − 𝐸𝐹 𝐸𝐹 − 𝐸𝑣
𝑛 = 𝑁 𝑐exp − 𝑘𝑇 𝑘𝑇 𝑝 = 𝑁 𝑣exp −
𝑁𝑣 is effective density of states in valance band and will also vary depending upon material
Material 𝑵𝒄 𝑵𝒗
𝑆𝑖 2.86 × 1019𝑐𝑚−3 2.66 × 1019 𝑐𝑚−3
𝐺𝑎𝐴𝑠 4.7 × 1017𝑐𝑚−3 7.0 × 1018𝑐𝑚−3
Intrinsic Carrier Concentration
𝐸 For every electron moved to conduction band there is vacancy created in
valance band called holes (𝒑)
𝐸𝑐 So that is
𝐸𝑔 𝑛 = 𝑝 = 𝑛𝑖
𝐸𝑣 Where, 𝑛𝑖 is intrinsic carrier density 𝑛2𝑖 = 𝑛𝑝
𝐸𝑐 − 𝐸𝐹 𝐸𝐹 − 𝐸𝑣
Then, 𝑛2 = 𝑐𝑁 𝑁 𝑣exp
𝑖 − −
𝑘𝑇 𝑘𝑇
Material 𝒏𝒊 𝑛2 = 𝑐𝑁 𝑁 𝑣exp −𝐸𝑐 + 𝐸𝐹 − 𝐸𝐹 + 𝐸𝑣
𝑖 𝑘𝑇
𝑆𝑖 9.65 × 109 𝑐𝑚−3 𝐸𝑣 − 𝐸𝐶
𝐺𝑎𝐴𝑠 6 −3 𝑛2 = 𝑐𝑁 𝑁 𝑣exp
2.25 × 10 𝑐𝑚 𝑖 𝑘𝑇 𝐸𝑔
𝑛𝑖 = 𝑁𝑐𝑁𝑣 exp
−
2𝑘𝑇
P-N Junction
Due to variation in charge gradient of
P N
electron and holes diffusion of
𝑁𝐴 𝑁𝐷 charges will start.
𝑛𝑝 𝑝𝑛
Huge number of
Huge number of
electrons are
holes are
present
present − +
𝑁𝐴 𝑁𝐷
𝑝𝑛0 = 𝑛2/𝑁𝐷
𝑛𝑝0 = 𝑛2/𝑁𝐴 𝑖
− +
𝐷
𝑁𝐴 𝑁 𝑖
−𝑥𝑝 0 𝑥𝑛
Conduction Band 𝑛′ = 𝑛 + 𝑁𝐷
As, 𝑁𝐷 is much higher in concentration, we ca write
𝐸𝑐
𝑛 ≈ 𝑁𝐷
𝐸𝑓
We
𝐸𝑐 − 𝐸𝐹
know, 𝑛 = 𝑁 𝑐exp 𝐸𝑐 − 𝐸𝐹 = 𝑘𝑇 ln(𝑁𝑐/𝑁𝐷)
𝐸𝑣 − 𝑘𝑇
Valance Band
𝐸𝐹 − 𝐸𝑣
𝑝 = 𝑁 𝑣exp − 𝑘𝑇 𝐸𝐹 − 𝐸𝑣 = 𝑘𝑇 ln(𝑁𝑣/𝑁𝐷)
Nondegenerate Semiconductor
𝐸𝑐 − 𝐸𝑖 + 𝐸𝑖 − 𝐸𝐹
𝑛 = 𝑁 𝑐exp − In a similar fashion
𝑘𝑇
𝐸𝑐 − 𝐸𝐹 𝐸𝐹 − 𝐸𝑖 𝐸𝐹 − 𝐸𝑖 + 𝐸𝑖 − 𝐸𝑣
𝑛 = 𝑁𝑐 exp exp 𝑝 = 𝑁 𝑣exp −
𝑘𝑇 𝑘𝑇 𝑘𝑇
−
𝐸
𝑔
𝐸𝐹 − 𝐸𝑖 𝐸 − 𝐸𝑣 𝐸𝑖 − 𝐸𝐹
𝑛 = 𝑁𝑐 exp − exp 𝑝 = 𝑁𝑣 exp − 𝑖 exp
𝑘𝑇 𝑘𝑇
2𝑘𝑇 𝑘𝑇
𝑁𝑐 ≈ 𝑁𝑣
𝐸𝑔 𝐸𝑖 − 𝐸 𝐹
𝑝 = 𝑁 𝑣exp exp
𝐸𝐹 − 𝐸𝑖 2𝑘𝑇 𝑘𝑇
𝑛 = 𝑛𝑖 exp −
𝑘𝑇
𝑁𝑐 ≈ 𝑁𝑣
𝐸𝑖 − 𝐸𝐹
𝑝 = 𝑛 exp
𝑖
𝑘𝑇
Carrier Transport
𝐽𝑑 = 𝜌𝑣𝑑
Valid only for low electric field regime
Carrier Drift: An electric field applied to a 𝐽𝑝𝑑 = (𝑞𝑝)𝑣 𝐽 = (−𝑞𝑛)𝑣𝑑𝑛
𝑑 𝑑𝑝 𝑛
semiconductor will produce a force on electrons
and holes so that they will experience net 𝑣𝑑𝑝 = 𝜇𝑝ℰ 𝑣𝑑𝑛 = −𝜇𝑛ℰ
movement and net acceleration. The current
generated by this net movement is called Drift 𝐽𝑝𝑑 = (𝑞𝑝)𝜇𝑝ℰ 𝐽𝑛𝑑 = (−𝑞𝑛)(−𝜇𝑛ℰ)
current
𝐽𝑑 = 𝑞 𝜇𝑛𝑛 + 𝜇𝑝𝑝 ℰ = 𝜎ℰ
𝑑𝑛 𝑙 is a
Carrier Diffusion: Diffusion is the process whereby
𝑓𝑙𝑜𝑤 =𝑛 −𝑣 𝑙 𝑡ℎ
𝑑𝑥 separation
particles flow from a region of high concentration
between two
towards a region of low concentration. The current 𝑑𝑛
𝐽𝑛𝑑𝑖𝑓 = −𝑞 × 𝑓𝑙𝑜𝑤𝑛 = 𝑞𝑣𝑡ℎ𝑙 collisions
generated by this net flow is called Diffusion 𝑑𝑥
current 𝑙 < 𝑣𝑡ℎ𝜏𝑐𝑛
𝑑𝑛 𝑑𝑝
𝐽𝑛𝑑𝑖𝑓 = 𝑞𝐷𝑛 𝐽𝑝𝑑𝑖𝑓 = −𝑞𝐷𝑝
𝑑𝑥 𝑑𝑥
Total Current density
𝑑𝑛
𝐽𝑛 = 𝐽𝑛 + 𝐽𝑛 𝐽𝑛 = 𝑞 𝜇𝑛𝑛ℰ + 𝐷𝑛
𝑑𝑟𝑖𝑓𝑡 𝑑𝑖𝑓𝑓 𝑑𝑥
𝑑𝑝
𝐽𝑝 = 𝐽𝑝 + 𝐽𝑝 𝐽𝑝 = 𝑞 𝜇𝑝𝑝ℰ − 𝐷𝑝
𝑑𝑟𝑖𝑓𝑡 𝑑𝑖𝑓𝑓 𝑑𝑥
𝑑𝑛 𝑑𝑝
𝐽=𝐽 +𝐽 𝐽=𝑞 𝜇𝑛𝑛ℰ + 𝜇𝑝𝑝ℰ + 𝐷𝑛 − 𝐷𝑝
𝑑𝑟𝑖𝑓𝑡 𝑑𝑖𝑓𝑓 𝑑𝑥 𝑑𝑥
𝑘𝑇 1 𝑑𝑁𝑑
Relation between 𝐷𝑝, 𝐷𝑛, 𝜇𝑛, 𝑎𝑛𝑑 𝜇𝑝 can be found using current relation along with ℰ=− 𝑞 𝑁𝑑 𝑑𝑥
Under thermal 𝑑𝑛 𝑛 ≈ 𝑁𝑑 𝑑𝑁𝑑
𝐽𝑛 = 0 = 𝑞 𝜇𝑛𝑛ℰ + 𝐷𝑛 0=𝑞 𝜇𝑛𝑁𝑑ℰ + 𝐷𝑛
Equilibrium 𝑑𝑥 𝑑𝑥
𝐷 𝑘𝑇 𝐷𝑛 𝑘𝑇
𝑝 Einstein Relation =
Similar result can be found:
𝜇𝑝 = 𝑞 𝜇𝑛 𝑞
𝑝 − 𝑛 Junction Band Diagram
P N
𝐸𝑐 𝐸𝑐
𝐸𝑓
𝐸𝑓
𝐸𝑣 𝐸𝑣
Valance Band Valance Band
P-N Junction Band Diagram
Steps:
Conduction Band
1. As we have established under
𝐸 Conduction Band thermal equilibrium there will be
𝑐,𝑝
net flow of charges. Thus fermi
𝐸
𝑐,𝑛 level will not change with distance
𝐸 𝑥.
𝑓,𝑝 𝐸
𝑓,𝑛 2. Align both fermi levels
𝐸 3. But what about the conduction
𝑣,𝑝 Valance Band 𝐸𝑣,𝑛
and Valance bands?
Valance Band
P-N Junction Band Diagram
Steps:
Conduction Band
1. As we have established under
𝐸 thermal equilibrium there will be
𝑐,𝑝
𝐸𝑐,𝑛 net flow of charges. Thus fermi
level will not change with
𝐸𝑓 𝐸𝑓 distance
𝐸 𝑥.
𝑣,𝑝
Valance Band 𝐸𝑣,𝑛 2. Align both fermi levels
3. But what about the
conduction and Valance
bands?
4. Conduction Band and Valance
band will also be joined with their
counterparts but there should not
be any abrupt behaviour
5. What happened at interface?
P-N Junction Band Diagram
Depletion Region Steps:
Conduction Band
1. As we have established under
𝐸 thermal equilibrium there will be
𝑐,𝑝
𝐸𝑐,𝑛 net flow of charges. Thus fermi
level will not change with
𝐸𝑓 𝐸𝑓 distance
𝐸 𝑥.
𝑣,𝑝
Valance Band 𝐸𝑣,𝑛 2. Align both fermi levels
3. But what about the
conduction and Valance
𝑛 − 𝑅𝑒𝑔𝑖𝑜𝑛 bands?
𝑝 − 𝑅𝑒𝑔𝑖𝑜𝑛 𝑥𝑝 𝑥𝑛 4. Conduction Band and Valance
To maintain the neutrality band will also be joined with their
counterparts but there should not
𝑁𝐴𝑥𝑝 = 𝑁𝐷𝑥𝑛
be any abrupt behaviour
𝑥𝑝 + 𝑥𝑛 = 𝑊 5. What happened at interface?
Effects in Interface
𝑁𝐷 − 𝑁𝐴 = 𝜌
Poisson’s Equation:
𝜕2𝑉 𝜕ℰ 𝜌
=− =− −𝑥 𝑝
𝜕𝑥2 𝜕𝑥 𝜖
𝑥𝑛
ℰ
Electric Field ℰ = න 𝜌𝑑𝑥
−ℰ𝑚
𝑉
Potential 𝑉 = න ℰ𝑑𝑥
𝑉
𝑏𝑖
Extracting Values for Band Diagram
𝐸
𝑖,𝑝
𝑁𝐷
𝐸𝑖,𝑛 = −𝑘𝑇 ln + 𝐸𝐹 𝑞𝑉 = 𝐸 − 𝐸 𝑖,𝑛
𝑛𝑖 𝑏𝑖 𝑖,𝑝
𝐸
𝑖,𝑛
𝑁𝐴
𝐸𝑖,𝑝 = 𝑘𝑇 ln + 𝐸𝐹
𝑛𝑖 1
𝑉𝑏𝑖 = 𝐸 −𝐸
𝑞 𝑖,𝑝 𝑖,𝑛
Then,
𝑘𝑇 𝑁𝐴 𝑁𝐷
𝑉𝑏𝑖 = 𝑞 ln + ln
𝑛𝑖 𝑛𝑖
𝑘𝑇 𝑁𝐴𝑁𝐷 An 𝑘𝑇
𝑉𝑏𝑖 = 𝑞 ln = 𝑉𝑜 d 𝑉𝑇 =𝑞
2
𝑛𝑖
Working of P-N Junction
Under Thermal Equilibrium
𝐼
(𝑚𝐴)
𝑉 (𝑉)
(𝑝𝐴)
Working of P-N Junction - Reverse Bias
Applying Reverse
Bias
On
Of
f
- -
+ +
𝑬𝒄 1. Electrons and holes will face
Considering Semiconductor high potential in order to go
pool of water: 𝑬𝒇 their preferred locations
1. Electrons will replicate 2. The reverse saturation current
the behaviour of Stone will be achieved due to flow of
2. Holes will replicate 𝑬𝒗 minority carriers
behaviour of air Bubble
Working of P-N Junction - Forward Bias
Applying Forward
Bias
On
Of
f
+ +
- -
On
Of
f
- -
+ +
1. Conduction band of 𝑛 − 𝑡𝑦𝑝𝑒 material and Valance band of
𝑝 − 𝑡𝑦𝑝𝑒 material aligns.
2. Due to high field electrons are generating more electron
hole pairs due to impact ionization.
3. In case of Avalanche Breakdown electric field plays
important constraint. Thus making changes in crystal
behaviour or even completely modifying the 𝑝 − 𝑛 junction
interface
𝑒 − ℎ Density
𝑝𝑝𝑜 → Holes (𝑝) concentration in (𝑝) type semiconductor under thermal equilibrium (𝑜)
𝑝𝑛𝑜 → Holes (𝑝) concentration in (𝑛) type semiconductor under thermal equilibrium (𝑜)
𝑛𝑝𝑜 → Electrons (𝑛) concentration in (𝑝) type semiconductor under thermal equilibrium (𝑜)
𝑛𝑛𝑜 → Electrons (𝑛) concentration in (𝑛) type semiconductor under thermal equilibrium (𝑜)
Now, we have estimated the built in potential and we can extend same to calculate hole
and electron densities
𝑝𝑝𝑜 ≈ 𝑁𝐴 𝑛 ≈𝑁 𝑛 𝑝 = 𝑛2 =𝑖 𝑝 𝑛
𝑛𝑜 𝐷
and 𝑛𝑜 𝑛𝑜 𝑝𝑜 𝑝𝑜
𝑘𝑇 𝑁𝐴𝑁𝐷 𝑘𝑇 𝑝 𝑛 𝑘𝑇 𝑛 𝑘𝑇 𝑝
𝑝𝑜 𝑛𝑜
𝑉𝑏𝑖 = = 𝑉𝑜 = ln = 𝑛𝑜
ln 𝑛 𝑝𝑜 = ln 𝑝𝑝𝑜
ln 𝑞 𝑛
2𝑖 𝑞 𝑛
2𝑖 𝑞 𝑞 𝑛𝑜
𝑒 − ℎ Density
Hole density as minority carrier
𝑞𝑉𝑏𝑖
𝑝 =𝑝 exp − 𝑘𝑇
𝑛𝑜 𝑝𝑜
𝑞𝑁 𝐷𝑥
𝑞𝑁 𝑞𝑁 ℰ𝑛 𝑥 + 𝐶1 = 0
ℰ𝑛 𝑥 =𝜖 𝐷 න 𝑑𝑥 =𝜖 𝐷 𝑥 + 𝐶 1 𝜖 𝑠𝑖 Using
=𝑛 𝑛
𝑠 𝑠𝑖 𝑞𝑁𝐷𝑥𝑛 BC4
𝐶1 =− 𝜖
𝑠𝑖
𝑞𝑁𝐴 𝑞𝑁𝐴
ℰ𝑝 𝑥 = න 𝑑𝑥 = − 𝑥 + 𝐶2
𝜖𝑠 𝜖 𝑞𝑁𝐴𝑥𝑝
− 𝑠𝑖 ℰ𝑝 −𝑥𝑝 = + 𝐶2 = 0 Using
𝜖 𝑠𝑖
BC4
𝑞𝑁𝐴𝑥𝑝
𝐶1 = −
𝜖 𝑠𝑖
Then,
𝑞𝑁 𝑞𝑁
ℰ𝑝 𝑥 = −𝜖 𝐴 (𝑥 + 𝑥 )𝑝 ℰ𝑛 𝑥 =𝜖 𝐷
(𝑥 − 𝑥𝑛 )
𝑠𝑖 𝑠𝑖
Electric Field
At 𝑥 = 0
ℰ𝑝 0 = ℰ𝑛(0) Using
BC1
𝑞𝑁𝐴 𝑞𝑁 𝐷
− 𝜖 𝑥𝑝 = (−𝑥 )𝑛
𝜖
𝑠𝑖 𝑠𝑖
𝑥𝑝 𝑥𝑛
𝑁𝐷 = 𝑁 𝐴
𝑥𝑝𝑁𝐴 = 𝑥𝑛𝑁𝐷
Potentials
𝜕2𝑉 𝜕ℰ𝑛 𝜌 𝑞𝑁𝐷
From Poisson’s equation = − = − 𝜖𝑠
=− 𝜖
𝜕𝑥2 𝜕𝑥
𝜕𝑉
= −ℰ 𝑉 = − න ℰ𝑑𝑥
𝜕𝑥
Then,
𝑞𝑁𝐴 𝑞𝑁𝐴 1
𝑉𝑝 𝑥 =න 𝑥+𝑥 𝑑𝑥 = 2
𝜖 𝜖
𝑝
2 𝑥 + 𝑥𝑥 +𝑝 𝐶 3
𝑠𝑖 𝑠𝑖
𝑞𝑁𝐷 𝑞𝑁𝐷 1
𝑉𝑛 𝑥𝑛 =−න𝜖 𝜖𝑥 − 𝑥𝑑𝑥 = −
2
2 𝑥 − 𝑥𝑥 +𝑛 𝐶 4
𝑠𝑖 𝑠𝑖
Potentials
Using 𝑉𝑝 0 = 𝑉𝑛(0)
BC1,
𝑞𝑁𝐴 1 𝑞𝑁𝐷 1
2 2 𝐶3 =
𝜖 2 𝑥 + 𝑥𝑥 𝑝 + 𝐶3= − 𝜖 2 𝑥 − 𝑥𝑥 +𝑛 𝐶 4 4
𝑠𝑖 𝑠𝑖 𝐶
Using 𝑉𝑝 −𝑥𝑝 = 0
BC3
𝑞𝑁𝐴 12 2
𝑉𝑝 −𝑥𝑝 =0= x −px + C3
𝜖 2 p
𝑠𝑖
1 qNA
C3 xp2 =4
= 2 𝜖𝑠𝑖 𝐶
Then,
𝑞𝑁𝐴 1 2 1 2 𝑞𝑁𝐴 𝑞𝑁𝐴 2
𝑥2 + 𝑥2 + 2𝑥𝑥 𝑥 + 𝑥𝑝
𝑉𝑝 𝑥 =𝜖 𝑠𝑖 2 𝑥 + 2 𝑥𝑝 +𝑝 = 𝑠𝑖 𝑝 𝑝 = 𝑠𝑖
2𝜖 2𝜖
Width of Depletion Region
Similarly
, 𝑞𝑁𝐷 1 1 qNA 𝑞𝑁 𝐷 1 𝑁𝐴
𝑉𝑛 𝑥 2 xp2 = − 2 𝑥 𝑝2
= −𝜖 2 𝑥 − 𝑥𝑥 +𝑛 2 𝜖𝑠𝑖 𝜖 2 𝑥 − 𝑥𝑥 −𝑛 𝑁𝐷
𝑠𝑖 𝑠𝑖
1 2 1 2𝜖𝑠
𝑠 𝑁𝐷 𝑉 − 𝑁 𝑥2
𝑥𝑝2 = 𝑉𝑏𝑖 − 𝑁𝐷𝑥𝑛 2
𝑥 𝑛 𝐴= 𝑁 𝑞
2 𝑏𝑖 𝐷
𝑁2𝜖𝐴 𝑞 𝑁2 𝐴
𝑛
Width of Depletion Region
𝑁𝐴 1 𝑁𝐴 1
𝑥𝑛 2𝜖𝑠 𝑥 𝑁𝐴 = 2𝜖𝑠
𝑞 𝑉 𝑏𝑖 𝐷 𝑁𝐷 + 𝑁𝐴 𝑝 𝑞 𝑉 𝑏𝑖 𝐷 𝑁𝐷 + 𝑁𝐴
= 𝑁 𝑁𝐷 𝑁
2𝜖𝑠 𝑁 1 2𝜖 𝑠 1 𝑁𝐴 𝑁𝐷
𝑉𝑏𝑖 𝐷 𝑊=𝑥 + 𝑥𝑝 = 𝑉
𝑁𝐷 +
𝑛
𝑥𝑝 =
𝑞 𝑁𝐴 𝑁𝐷 + 𝑞 𝑏𝑖 𝑁𝐷 + 𝑁𝐴 𝑁𝐴
𝐴
𝑁
2𝜖 𝑠 1 𝑁𝐴 + 𝑁𝐷
𝑊 = 𝑥𝑛 + 𝑥𝑝 = 𝑉𝑏𝑖
𝑞 𝑁𝐷 + 𝑁𝐴 𝑁𝐴𝑁
Under Thermal Equilibrium 𝐷 Where, 𝑁𝐵 is the
2𝜖
2𝜖𝑠 𝑁𝐷 + 𝑁𝐴 𝑊=𝑥 𝑛 + 𝑥 𝑝≈ 𝑠 𝑏𝑖 lightly doped side
𝑊 = 𝑥𝑛 + 𝑥𝑝 = 𝑉 𝑞𝑁𝐵 𝑉
𝑞 𝑏𝑖 𝑁𝐷𝑁𝐴 (𝑝 𝑜𝑟 𝑛)
𝜖𝑠
𝐶𝑗 = 𝐹/𝑐𝑚2
𝑊
1 2
= (𝑉𝑏𝑖−𝑉)
𝐶𝑗 𝑞𝜖 𝑁
𝑠
𝐵
1 2
2 = (𝑉𝑏𝑖−𝑉)
��
𝑗 𝑞𝜖 𝑁
𝑠
𝐵
This method is generally employed to find the width of the
depletion region
Metal Semiconductor Junction
𝑉𝑏𝑖 is the built in potential 𝑉𝑏𝑖 = 𝜙𝐵0 − 𝜙𝑛 Thus, 𝑉𝑏𝑖 also depends upon semiconductor doping slightly
Schottky Barrier Operation
Tunnelling Barrier
The width of the depletion
region decreases as the doping
concentration in the
semiconductor increases;
Thus, as the doping
concentration increases, the
probability of tunneling through
the barrier increases.
𝑞𝜙𝐵𝑛 −𝑞𝜙𝐵𝑛
𝐽𝑠𝑇 ∗ 2
= 𝐴 𝑇 exp − where 𝑞ℏ 𝑁𝑑
𝑘𝑇 Now tunnelling occurs and 𝐽𝑡 ∝ exp(𝐸𝑜𝑜) 𝐸𝑜𝑜 =
2 𝜖𝑠𝑚𝑛 ∗
electron transfers without
thermionic emission
Heterojunctions
𝑝 − 𝑆𝑖 𝑛 − 𝑆𝑖
Semiconductor is homogenous throughout the structure (𝑝 − 𝑆𝑖 to 𝑛 − 𝑆𝑖). The junction formed by this kind
of semiconductors are called Homojunction
Isotype heterojunction
𝑛 − 𝐺𝑎𝐴𝑠 𝑛 − 𝐴𝑙𝐺𝑎𝐴𝑠
Heterojunction Materials
Ge/GaAs – Lattice
variation of 0.13%
GaAs/AlGaAs –
Lattice Variation of
0.14 %
Band-Diagram
For the Heterostructure, there will be one narrow band semiconductor and another one is wide band
semiconductor
Depending upon the electron affinity of the semiconductor, energy band may align in three patterns
𝑝𝑁
Anisotype
𝑛𝑃
Band-Diagram
𝑝𝑁 type (anisotype)