M1 Part A
M1 Part A
1.1 Introduction:
● "LASER" acronym for "Light Amplification by Stimulated Emission of Radiation”
● In 1917, Albert Einstein showed the process of stimulated emission and
● in 1960, T H Maiman achieved the laser action at optical frequencies in Ruby.
● After 1960 – rapid development of lasers.
● Applications of lasers slow in the first decade.
● Now new applications are found every day.
A laser is a device that emits light through a process of optical amplification based on the
stimulated emission of electromagnetic radiation. A laser differs from other sources of light
in that it emits light coherently.
Stimulated Absorption:
An electron in the lower energy level
E1, absorbs a photon and is excited to
upper energy level E2.
The photon is of frequency ν = ΔE / h
h – Planck’s constant. The black dot in the
fig. indicates the state of the atom before and after
the transition.
Energy level Diagram illustrating stimulated absorption.
Spontaneous Emission:
An electron in excited state (level E2)
may return to the ground state (E1) in a
random way, with the emission of a
photon.
Stimulated Emission: An
electron in excited state
(level E2) is triggered to
return to the ground state
(E1) by the presence of
stimulating photon. This
transition results in the
emission of a photon.
Stimulated emission process results in
coherent radiation, as the waves associated
with the stimulating and stimulated photons
have identical frequencies, are in phase,
have the same state of polarization and
travel in the same direction.
COHERENT EMISSION - Amplitude of an
incident wave can ‘grow’ as it passes
through a collection of excited atoms –
amplification process.
Stimulated emission and stimulated Under normal conditions (thermal equilibrium) Probability of
absorption processes are regarded spontaneous process occurring is much higher (>105).
as the inverse of one another. Spontaneous Emission results in incoherent radiation (due to
random transitions)
Einstein relations
All the 3 processes - Stimulated Absorption, Spontaneous Emission, Stimulated Emission,
described by the parameters – B12 , A21 , B21 – Einstein’s coefficients
are related through the requirement that
for a ‘system in thermal equilibrium’
the rate of upward transitions (from E1 to E2) must equal
the rate of downward transitions (from E2 to E1).
Upward transition rate (absorption rate) = N 1 ϱ ν B12 🡪 Eqn. A
N 1 = number of atoms with energy E1
ϱ ν – Energy density at frequency ν ; ϱ ν =Nhν
N – number of photons available at frequency ν
Total downward Transition rate (emission rate) = stimulated emission + spontaneous emission rates
= N 2 ϱ ν B21+ N 2 A 21 🡪 Eqn. B
N 2 = atoms per unit volume with energy E2
for a ‘system in thermal equilibrium’ Eqn. A = Eqn. B
N 1 ϱ ν B12 = N 2 ϱ ν B21+ N 2 A 21
Rearranging the above equation: N 1 ϱ ν B12 - N 2 ϱ ν B21=N 2 A 21
ϱ ν ( N 1 B12−N 2 B 21) =N 2 A 21
N 2 A 21
ϱν=
( N 1 B 12−N 2 B21 )
Dividing by N 2 B 21 ; A 21
B21
ϱν=
( )
B12 N 1 🡪 Eqn. C
–1
B21 N 2
Populations of the various energy levels of a system in thermal equilibrium are given by the
Boltzmann statistics as:
−E j /kT
gjN0e
N j= ❑
∑
❑
gi e−E / kT i
N1 ∑
❑
g i e−E /kTi
=
N2 ❑
N 1 g1 (E − E )/kT N 1 g1 (hν)/ kT
= e 2 1
( E 2−E1 )=hν = e
🡪 Eqn. D
N 2 g2 N 2 g2
A 21
B21
ϱν=
( )
Put Eqn. D in Eqn. C to get B12 g 1 hν/kT 🡪 Eqn. E
e –1
B21 g 2
g1
Note: generally =1 is often omitted.
g2
(e )
3
The system in thermal equilibrium gives 8 πh ν 1
ϱν=
rise to a radiation identical to black body c
3 hν/ kT
–1 🡪 Eqn. F
radiation, the radiation density of which is
g1 B12=g 2 B21 and
Comparing Eqn. E & Eqn. F, we get the A 21 8 πh ν 3
Einstein Relations = 3
B21 c
for a system in thermal equilibrium, the populations (N) of a 2 -level energy system is given in Fig.
1.4.1 wherein if E2 > E 1 then N 2 < N 1
But for laser action; N 2 > N 1 is required, i.e., produce a population inversion (shown in Fig. 1.4.2).
Fig.1.4.1 – 2- level energy system in Thermal Fig. 1.4.2 - required population inversion for
equilibrium: 2 N < N 1 laser action i.e., N 2 > N 1
To create a population inversion, ‘Pumping’ is required.
Pumping is an excitation process wherein a large amount of energy (pumping energy) is supplied to
the system, so that a large number of atoms are excited to upper level E2 .
Pumping produces a non-thermal equilibrium system.
Attainment of a ‘Population Inversion’ – In a 2-level system, even with intense irradiation of the
system (pumping), the best that can be achieved, is the equality of the populations of the 2 levels.
Hence use materials with 3 or 4 energy level systems. (possible as atomic systems have a large
number of energy levels.)
Pumping in a 3-level system
Fig. 1.4.3a & Fig.1.4.3b show the population of the energy levels before and after pumping.
Here E1is the metastable state. Population inversion is between E1 and E0 .
RUBY laser is an example of 3-level lasers.
Disadvantage: Requires very high pump powers.
• As the terminal level of the laser is the ground state, it implies that half of the ground state
atoms have to be pumped to upper state for population inversion
Fig. 1.4.3a : Boltzmann Distribution before Fig. 1.4.3b : Distribution after pumping & the
pumping transitions involved
Pumping in a 4-level System
• Much lower pumping requirements (as compared to 3-level system)
• If ΔE = (E1 – E0) – large compared to kT (operational temp);
• Populations of E1, E2, E3 small under thermal equilibrium conditions
• Atoms pumped to E3 – decay rapidly to E2 – metastable state (non – radiative process)
• Population inversion is between E2 & E1
• Short Lifetimes E3->E2 (enables the Population inversion between E2 & E1); & the Short
Lifetime E1->E0 (ensures E0 is replenished for pumping)
Spectral lines have a finite wavelength (or frequency) spread, i.e., they have a spectral width
– can be seen both in emission and absorption spectra.
The transmission versus frequency for the transition between two energy states E1 & E2
would result in a bell shape curve.
Emission curve would be the inverse of the transmission curve. The shape of these emission
curves is described by the ‘line shape function g(ν)’, which can also be used to describe a
frequency probability curve.
g(ν).dν - probability that a given transition between the two energy levels will result in the
emission (or absorption) of a photon whose frequency lies between ν and ν+dν.
∞
Doppler Broadening
We have
Rearranging
At threshold the small signal gain coefficient (kth) is given by
Einstein Coeff
Sub B21 :
Lasing threshold is achieved easily when g(νs)
is maximum. This is possible when νs = ν0 ->
Then, &
center of natural linewidth
Questions: 1. Calculate
the pumping power
required to reach the
threshold
2. Solve the rate
equations for the
particular system
Consider the ideal four level system shown in Fig. above. In the 4-level laser system shown, energy
levels E2 & E1 are involved in population inversion for laser action. Hence, the rate equations for the
change of populations in N2 & N1 are derived below.
Assume E1>>KT, i.e., Thermal Nth (= N2 - N1)th is small compared to Ground state (E0)
population of E1 negligible population so that during lasing operation, the latter, i.e., Ground
ℜ1 & ℜ2 – rate of pumping of state population (N0) is not affected (else affects replenishment seen in 3-level
atoms into levels E1 & E2 lasers – Ruby)
Assume that the system is being pumped at a steady rate then ; Eqn. 1 = Eqn. 2
ρν
neglecting , the Eqn. 3 is : 🡪 Eqn. 4
Eqn. 4 implies that population inversion (N2 – N1) increases linearly with pumping rate (ℜ2);
But insufficient inversion to maintain amplification (requires (N2 – N1) >1, but Eqn.4 numerator is < 1) and
most of the pump power appears as spontaneous emission
• A=
1
τ (
implies τ 10 < τ 21 ; In most lasers τ 21 ≫ τ 10 and 1−
A 21
A10 )
≅1
( )
At threshold, N 2−N 1 =N th: & ρ ν is negligible; A 21
1− ≅1
A10
N th
Rth =N th A 21=
τ 21