298 𝐾

𝑃𝑟𝑜𝑑 𝑟𝑒𝑎𝑐𝑡
̅𝑓° |298𝐾 − ∑ 𝜇𝑖 Δ𝐻
Δ𝐻𝑅 |298𝐾 = ∑ 𝜇𝑖 Δ𝐻 ̅𝑓° |298𝐾
𝑖 𝑖
𝑖 𝑖

𝑅/𝑃 𝑅/𝑃
𝑇𝑎𝑙𝑡𝑎 𝑇𝑏𝑎𝑗𝑎
𝛥𝐻𝑐𝑎𝑙 = ∫ ∑ 𝑛𝑖 𝐶𝑝𝑖 𝑑𝑇 𝛥𝐻𝑒𝑛𝑓 = ∫ ∑ 𝑛𝑖 𝐶𝑝𝑖 𝑑𝑇
𝑇𝑏𝑎𝑗𝑎 𝑖 𝑇𝑎𝑙𝑡𝑎 𝑖

𝑃𝑟𝑜𝑑 𝑟𝑒𝑎𝑐𝑡
𝐶𝑝𝑖° = 𝑎𝑖 + 𝑏𝑖 𝑇 + 𝑐𝑖 𝑇 2
𝛥𝐶𝑝𝑅° = ∑ 𝜇𝑖 𝐶𝑝°𝑖 − ∑ 𝜇𝑖 𝐶𝑝°𝑖
𝑖 𝑖

2
𝛥𝐶𝑝𝑅° = 𝛥𝑎𝑅 + 𝛥𝑏𝑅 𝑇 + 𝛥𝑐𝑅 𝑇

𝑇
Δ𝐻𝑅° | 𝑇 = Δ𝐻𝑅 |298𝐾 + ∫ Δ𝐶𝑝°𝑅 𝑑𝑇
298𝐾

𝑇 𝑃𝑟𝑜𝑑 𝑟𝑒𝑎𝑐𝑡
∫𝑇 (𝑎𝑖 + 𝑏𝑖 𝑇 + 𝑐𝑖 𝑇 2 )𝑑𝑇
2
°
°
𝐶𝑝𝑚 = 1 𝛥𝐶𝑝𝑚 𝑖
= ∑ 𝜇𝑖 𝐶𝑝𝑚 °𝑖 − ∑ 𝜇𝑖 𝐶𝑝𝑚 °𝑖
𝑖 𝑇2 − 𝑇1 𝑖 𝑖

Δ𝐻𝑅 |298𝐾 + 𝛥𝐻𝑐𝑎𝑙 = 0

𝑃𝑇 Δ𝑛
𝐾 = 𝑘𝜙 𝑘𝑛 ( )
𝑁𝑇
𝑘𝜙 = 1 → 𝑆𝑖 𝑒𝑠 𝑖𝑑𝑒𝑎𝑙

𝑃𝑟𝑜𝑑 𝑟𝑒𝑎𝑐𝑡
𝛥𝐺𝑅° | 𝑇 = −𝑅𝑇𝐿𝑛𝐾 Δ𝐺𝑅° |298𝑘 ̅ °𝑓 |298𝐾 − ∑ 𝜇 Δ𝐺
= ∑ 𝜇𝑖 Δ𝐺 ̅ °𝑓 |298𝐾
𝑖 𝑖 𝑖
𝑖 𝑖

𝑇 𝑇 𝑇
𝛥𝐺𝑅° | 𝑇 = °
Δ𝐺°𝑅 |298𝑘 + [Δ𝐻𝑅 |298𝐾 − 298𝛥𝐶𝑝𝑚 ] (1 − °
) + 𝛥𝐶𝑝𝑚 𝑇𝐿𝑛 ( )
298 𝑖
298 𝑖
298

𝑃𝑟𝑜𝑑 𝑟𝑒𝑎𝑐𝑡

𝑙𝑜𝑔𝐾𝑓 = ∑ 𝜇𝑖 𝑙𝑜𝑔𝐾𝑓 − ∑ 𝜇𝑖 𝑙𝑜𝑔𝐾𝑓

𝑖 𝑖
𝑖 𝑖

𝑑𝐿𝑛(𝐾 ) Δ𝐻𝑅° 𝑘1 Δ𝐻𝑅° 1 1

= 𝐿𝑛 ( )= ( − )
𝑑𝑇 𝑅𝑇 2 𝑘2 𝑅 𝑇2 𝑇1
 𝑛𝑠𝑎𝑙𝑒 = 𝑛𝑒𝑛𝑡𝑟𝑎 ± 𝜇𝜀 𝛥𝐻𝐸 + 𝑄𝑆𝑒𝑟𝑣𝑖𝑐𝑖𝑜 = 𝛥𝐻𝑆 + 𝑄𝑅𝑒𝑎𝑐𝑐𝑖ó𝑛

𝜇𝑅𝐿 ∗ 𝜀
%𝜂 = ∗ 100 𝑃𝑀𝑚𝑖𝑥 = ∑ 𝑃𝑀𝑖 ∗ 𝑦𝑖
𝑛𝑅𝐿

𝑚𝑇
𝑁𝑇 =
𝑃𝑀𝑚𝑖𝑥

𝑗 𝑎𝑡𝑚 𝐿 𝑐𝑎𝑙
𝑅 = 8.3140 𝑅 = 0.0821 𝑅 = 1.9872
𝑚𝑜𝑙 𝐾 𝑚𝑜𝑙 𝐾 𝑚𝑜𝑙 𝐾