Chem Lec 2
Chem Lec 2
● Louis Pasteur 🧑🔬 pioneered this technique in the 19th century to prevent
the spoilage of liquids such as wine 🍷 and beer 🍺.
● It ensures safe consumption of perishable beverages like milk, extending
their shelf life by preventing the growth of microorganisms.
1. Solution 💧🔬
● Definition: A solution is a homogeneous mixture where the solute is
completely dissolved in the solvent, resulting in uniform particle
distribution.
● Example: Salt water 🧂🌊 is a classic solution, where salt (NaCl) is
evenly distributed in water.
Characteristic Details
2. Suspension 🏖️⚗️
● Definition: A suspension is a heterogeneous mixture where the particles
are large and can be easily seen. These particles do not dissolve and
tend to settle at the bottom over time.
● Example: Chalk in water 🧂💦 represents a suspension, where chalk
particles are suspended in the water but eventually settle down.
Characteristic Details
Light Scattering Large particles scatter light, which can make the path of
🌟✅ a laser visible in the suspension (Tyndall effect).
3. Colloid 🥛🌀
● Definition: A colloid is a mixture that appears homogeneous but is
actually heterogeneous. The particles in a colloid are intermediate in size
between those in solutions and suspensions.
● Example: Milk 🥛 is a colloid, where fat droplets are dispersed
throughout the liquid but are not dissolved.
Colloid Types 🌐
Type Dispersed Dispersing medium Example
Phase
Characteristic Details
Light Scattering 🌟✅ Colloids scatter light, causing the Tyndall effect. This is why a
beam of light is visible through milk.
Tyndall effect: Not in salt water (left glass); Yes in milk water (right glass)
Separation on No Yes No
Standing 🛑
Filtration 🚫🔍 No separation Can be Cannot be separated
by filtration separated
Chromatography 🧪🔍
● Chromatography is a laboratory technique used to separate components
of a mixture based on their movement through a stationary and mobile
phase.
● It relies on the affinity of different substances for the two phases:
Periodic Table 📅🔬
Historical Development:
Periodic Trends:
● Atomic Radius:
○ Decreases across a period due to increasing nuclear charge.
○ Increases down a group as electrons are added to higher energy
levels.
● Ionic Radius:
○ Cations (+ve charged ions) are smaller than their parent atoms.
○ Anions (-ve charged ions) are larger due to electron repulsion.
● Ionization Enthalpy: energy required to remove an electron.
○ Increases across a period; decreases down a group.
○ Maxima at noble gases, minima at alkali metals.
● Electron Gain Enthalpy: energy change when an electron is added to a neutral
gaseous atom to form a negative ion.
○ Generally more negative across a period; less negative down a
group.
○ Halogens have highly negative electron gain enthalpies.
● Electronegativity: ability of an atom in a chemical bond to attract shared electrons
towards itself.
○ Increases across a period; decreases down a group.
○ Highest in fluorine.
⚡ Reactivity of Metals
● Reactivity of metals refers to how readily they participate in chemical
reactions, especially with oxygen, water, and acids.
● The more reactive a metal, the faster it reacts with other substances like
oxygen or water.
Reaction of Conclusion
Metals with
Water
- Na, K: React violently with cold water, producing metal
hydroxides and hydrogen gas.
Na + H20 → NaOH + H2
- Ca: Reacts with cold water to → But releases less heat than
Na, K
- Mg: Reacts with hot water
- Al, Fe, Zn: Reacts with steam
- Cu, Pb, Au, Ag: Do NOT react at all with water
Acids
- Metals above hydrogen in the reactivity series can displace
hydrogen from dilute acids, producing salts and hydrogen
gas.
Other metals
- Displacement Reactions: More reactive metals can displace
less reactive metals from their compounds.
Fe + CuSO₄ → FeSO₄ + Cu
● These elements form the backbone of rocks and minerals in the Earth’s
crust, such as quartz (SiO₂) and feldspar.