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Chem Lec 2

The document covers food preservation methods, particularly pasteurization, which involves heating liquids like milk to eliminate harmful bacteria while retaining nutrients. It also discusses types of mixtures—solutions, suspensions, and colloids—highlighting their characteristics and examples. Additionally, it provides an overview of the periodic table, periodic trends, properties of metals and non-metals, reactivity of metals, and the elemental composition of the Earth's crust.

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0% found this document useful (0 votes)
20 views12 pages

Chem Lec 2

The document covers food preservation methods, particularly pasteurization, which involves heating liquids like milk to eliminate harmful bacteria while retaining nutrients. It also discusses types of mixtures—solutions, suspensions, and colloids—highlighting their characteristics and examples. Additionally, it provides an overview of the periodic table, periodic trends, properties of metals and non-metals, reactivity of metals, and the elemental composition of the Earth's crust.

Uploaded by

sohel.rana1995
Copyright
© © All Rights Reserved
We take content rights seriously. If you suspect this is your content, claim it here.
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Notes by Abhimanyu Kumar | B.Tech.

(CS), IIT Delhi | Rank 51, 68th BPSC

Food Preservation (Pasteurization) 🥛🧑‍🔬


● Food preservation ensures food safety by removing or killing harmful
microbes 🦠.
● Pasteurization is a heat-treatment process where liquids, particularly
milk, are heated to kill pathogenic bacteria while preserving nutrients.
○ High-temperature short-time (HTST) pasteurization heats milk to
72°C (162°F) for 15 seconds ⏱️ before cooling it rapidly to about
4°C ❄️.
○ This process kills harmful bacteria like E. coli 🦠 and Salmonella
🍳 without altering the taste of milk.
Pasteurization Methods 📊

Method Temperature Time Application

High-temp, short-time 72°C (162°F) 15 sec Milk, fruit juices 🧃


(HTST)

Ultra-pasteurization 135°C (275°F) 2–5 sec Dairy, cream 🥛


(UHT)

● Louis Pasteur 🧑‍🔬 pioneered this technique in the 19th century to prevent
the spoilage of liquids such as wine 🍷 and beer 🍺.
● It ensures safe consumption of perishable beverages like milk, extending
their shelf life by preventing the growth of microorganisms.

Types of Mixtures: Solution, Suspension, and Colloid 🧑‍🔬🧪


Mixtures can be classified into solutions, suspensions, and colloids based on
their particle size, homogeneity, and behavior. Let’s explore each type in detail.

This document is part of the Hunkar course of IAS Valley.


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Notes by Abhimanyu Kumar | B.Tech. (CS), IIT Delhi | Rank 51, 68th BPSC

1. Solution 💧🔬
● Definition: A solution is a homogeneous mixture where the solute is
completely dissolved in the solvent, resulting in uniform particle
distribution.
● Example: Salt water 🧂🌊 is a classic solution, where salt (NaCl) is
evenly distributed in water.

Key Characteristics of Solutions:

Characteristic Details

Homogeneity 🟰 solute particles are evenly distributed.

Particle Size 📏 between 0.01 to 1 nanometers.

Dissolution 🧂💧 Solute dissolves at the molecular or ionic level,


taking up space between solvent molecules.

No Filtration 🚫🔍 Particles do not settle down → cannot be


separated by filtration.

Light Scattering 🌟🚫 do not scatter light, particles are too small to


deflect light rays.

2. Suspension 🏖️⚗️
● Definition: A suspension is a heterogeneous mixture where the particles
are large and can be easily seen. These particles do not dissolve and
tend to settle at the bottom over time.
● Example: Chalk in water 🧂💦 represents a suspension, where chalk
particles are suspended in the water but eventually settle down.

Key Characteristics of Suspensions:

This document is part of the Hunkar course of IAS Valley.


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Notes by Abhimanyu Kumar | B.Tech. (CS), IIT Delhi | Rank 51, 68th BPSC

Characteristic Details

Heterogeneity ❌ not evenly distributed.

Particle Size 📏 large, typically greater than 1000 nanometers.

Separation on settle over time due to gravity, layer at the bottom.


Standing 🛑
Filtration ✅ Particles can be separated from mixture using filtration
methods.

Light Scattering Large particles scatter light, which can make the path of
🌟✅ a laser visible in the suspension (Tyndall effect).

3. Colloid 🥛🌀
● Definition: A colloid is a mixture that appears homogeneous but is
actually heterogeneous. The particles in a colloid are intermediate in size
between those in solutions and suspensions.
● Example: Milk 🥛 is a colloid, where fat droplets are dispersed
throughout the liquid but are not dissolved.

Colloid Types 🌐
Type Dispersed Dispersing medium Example
Phase

Emulsion Liquid Liquid Milk


🥛
Foam 🎈 Gas Liquid Shaving foam, whipped
cream 🍦
Gel 🍮 Liquid Solid Jelly, gelatin

This document is part of the Hunkar course of IAS Valley.


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Notes by Abhimanyu Kumar | B.Tech. (CS), IIT Delhi | Rank 51, 68th BPSC

Key Characteristics of Colloids:

Characteristic Details

Heterogeneity ❌🟰 Though it looks uniform, colloids are heterogeneous with


microscopic particles.

Particle Size 📏 1 to 1000 nanometers in size

No Separation on do not settle


Standing ❌
No Filtration 🚫🔍 cannot be separated by filtration.

Light Scattering 🌟✅ Colloids scatter light, causing the Tyndall effect. This is why a
beam of light is visible through milk.

Tyndall effect: Not in salt water (left glass); Yes in milk water (right glass)

Colloid Behavior in Daily Life 🌫️:


● Colloids are common in many everyday materials:
○ Paints 🎨: Pigment particles are suspended in a liquid base, forming a
colloid.

This document is part of the Hunkar course of IAS Valley.


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Notes by Abhimanyu Kumar | B.Tech. (CS), IIT Delhi | Rank 51, 68th BPSC

○ Medications 💊: Many pharmaceutical solutions are colloidal, where


active ingredients are dispersed in a medium for better absorption.

Comparison of Solution, Suspension, and Colloid 📊


Property Solution 💧 Suspension 🏖️ Colloid 🌀
Appearance Clear, Cloudy, Cloudy, particles not
transparent particles visible individually
visible

Particle Size 📏 0.01–1 nm >1000 nm 1–1000 nm

Homogeneity Homogeneous Heterogeneous Heterogeneous


(appears
homogeneous)

Separation on No Yes No
Standing 🛑
Filtration 🚫🔍 No separation Can be Cannot be separated
by filtration separated

Light Scattering No Yes Yes


(Tyndall Effect) 🌟

Chromatography 🧪🔍
● Chromatography is a laboratory technique used to separate components
of a mixture based on their movement through a stationary and mobile
phase.
● It relies on the affinity of different substances for the two phases:

This document is part of the Hunkar course of IAS Valley.


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Notes by Abhimanyu Kumar | B.Tech. (CS), IIT Delhi | Rank 51, 68th BPSC

○ Stationary phase 🏔️: A solid or liquid that stays in place (e.g.,


paper, gel).
○ Mobile phase 💧: A liquid or gas that moves over the stationary
phase (e.g., water, ethanol).

Periodic Table 📅🔬

● Periodic Table organizes elements by atomic number and electronic


structure.
● Elements in the same group have similar properties due to similar
valence configurations.
● Periodic trends in atomic size, ionization energy, electronegativity, and
electron affinity are crucial for understanding element behavior.
● Metals dominate the left and center, while non-metals are on the right,
with metalloids along the zig-zag line.
● Modern Periodic Law emphasizes the role of atomic number over atomic
mass in determining element properties.

This document is part of the Hunkar course of IAS Valley.


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Notes by Abhimanyu Kumar | B.Tech. (CS), IIT Delhi | Rank 51, 68th BPSC

Historical Development:

● Johann Dobereiner introduced Triads (groups of three elements with


similar properties).
● John Alexander Newlands proposed the Law of Octaves, noting
periodicity every eighth element.
● Dmitri Mendeleev developed the Periodic Law based on atomic weights,
predicting undiscovered elements.
● Henry Moseley established the Modern Periodic Law, arranging
elements by atomic number.

Periodic Trends:

● Atomic Radius:
○ Decreases across a period due to increasing nuclear charge.
○ Increases down a group as electrons are added to higher energy
levels.
● Ionic Radius:
○ Cations (+ve charged ions) are smaller than their parent atoms.
○ Anions (-ve charged ions) are larger due to electron repulsion.
● Ionization Enthalpy: energy required to remove an electron.
○ Increases across a period; decreases down a group.
○ Maxima at noble gases, minima at alkali metals.
● Electron Gain Enthalpy: energy change when an electron is added to a neutral
gaseous atom to form a negative ion.
○ Generally more negative across a period; less negative down a
group.
○ Halogens have highly negative electron gain enthalpies.
● Electronegativity: ability of an atom in a chemical bond to attract shared electrons
towards itself.
○ Increases across a period; decreases down a group.
○ Highest in fluorine.

This document is part of the Hunkar course of IAS Valley.


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Notes by Abhimanyu Kumar | B.Tech. (CS), IIT Delhi | Rank 51, 68th BPSC

Metals, Non-metals, and Metalloids:

● Metals: Majority of elements, good conductors, malleable, ductile.


● Non-metals: Poor conductors, brittle (solid), gaseous states common.
● Metalloids: Exhibit properties of both metals and non-metals (e.g.,
silicon, germanium).

Metals and Non-metals

Physical Properties of Metals

● State: Solid at room temperature (except Hg – mercury – which is liquid


at room temp.)
● Metallic Lustre: Pure metals have a shiny surface.
● Malleability: Ability to be hammered into thin sheets (gold and silver are
the most malleable metals).
● Ductility: Ability to be drawn into wires (Gold is the most ductile metal →
gold can form wires up to 2 km from 1g).
● Hardness: Varies among metals; generally hard.
● Melting and boiling points: High (except Caesium and Gallium which
have very low melting points)
● Conductivity:
○ Heat: Good conductors; silver and copper are the best.
○ Electricity: Good conductors; metals like copper are used in
electrical wires.
● Sonorous: Produce sound when struck (e.g., school bells made of metals).
● Sea of electrons: Metals consist of atoms that share electrons freely in
what is known as a sea of electrons → enable conduction

Physical Properties of Non-metals

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● State at Room Temperature: Mostly solids or gases, except bromine


(liquid).
● Lustre: Generally not shiny (except – iodine is lustrous).
● Hardness: Generally softer compared to metals.
● Electrical Conductivity: Poor conductors, except graphite which conducts
electricity.

⚡ Reactivity of Metals
● Reactivity of metals refers to how readily they participate in chemical
reactions, especially with oxygen, water, and acids.
● The more reactive a metal, the faster it reacts with other substances like
oxygen or water.

Reaction of Conclusion
Metals with

Air/Oxygen - Na, K: Doesn’t need to be heated + Reacts with oxygen


and catches fire + Kept in kerosene to prevent contact
with air
- Mg: Burns in air with a white dazzling flame
- Al, Zn, Fe, Cu: Reacts when heated. Copper doesn’t
burn → becomes black when heated in air (CuO)
- Au, Ag: don’t react with oxygen at all. Called Noble
metals.
- Amphoteric Oxides: Some metal oxides (e.g., Al₂O₃,
ZnO) exhibit both acidic and basic properties.

This document is part of the Hunkar course of IAS Valley.


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Notes by Abhimanyu Kumar | B.Tech. (CS), IIT Delhi | Rank 51, 68th BPSC

Water
- Na, K: React violently with cold water, producing metal
hydroxides and hydrogen gas.

Na + H20 → NaOH + H2

- Ca: Reacts with cold water to → But releases less heat than
Na, K
- Mg: Reacts with hot water
- Al, Fe, Zn: Reacts with steam
- Cu, Pb, Au, Ag: Do NOT react at all with water

Acids
- Metals above hydrogen in the reactivity series can displace
hydrogen from dilute acids, producing salts and hydrogen
gas.

Mg + 2HCl → MgCl₂ + H₂↑

- Metals like copper do not react with dilute hydrochloric acid.

Other metals
- Displacement Reactions: More reactive metals can displace
less reactive metals from their compounds.

Fe + CuSO₄ → FeSO₄ + Cu

🧪 Reactivity Series of Metals:


This document is part of the Hunkar course of IAS Valley.
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Notes by Abhimanyu Kumar | B.Tech. (CS), IIT Delhi | Rank 51, 68th BPSC

Elemental Composition of Earth 🌍🪨


● The Earth’s crust is composed of a mixture of different elements, but
some are far more abundant than others.
○ Oxygen 🧪 is the most abundant element, making up about 46.6%
of the crust by weight.
○ Silicon 🪨 is the second most abundant element, comprising 27.7%
of the crust.

Major Elements in the Earth's Crust 🌍


Element 🧪 Percentage by Weight

Oxygen (O) ⚛️ 46.6%

Silicon (Si) 🪨 27.7%

Aluminum (Al) ⚡ 8.1%

This document is part of the Hunkar course of IAS Valley.


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Notes by Abhimanyu Kumar | B.Tech. (CS), IIT Delhi | Rank 51, 68th BPSC

Iron (Fe) 🧲 5.0%

● These elements form the backbone of rocks and minerals in the Earth’s
crust, such as quartz (SiO₂) and feldspar.

This document is part of the Hunkar course of IAS Valley.


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