12.25 1.

54A
Xe 0.154mm

1 7.954
12,25

f 7 954 1 63.5 V

Maximum B P azeotropes exhibit Ve deviation from

Raoult's law Hence CHC 3 CHzCOCH is answer
Ve deviation means less v P than expected from Raoult's
law Henle B P is greater than constituents
Mnog has pink colour due to chargetransfer phenomenon
e are transferred from Oxygen to Mn
 CHzCHL E NHz
CHz CHz NHL
CHz H2 CN

Colt CIO

Cotts OH

CGH NH

C2Hs the He
casts CH2 0H

C2HtCN

CHzNHz
CHz 0H

CHz E NHz
CGHS CN
Cotts 1h2NHz

CGHT NIL Colts 510

CGH5NÉ10

Cotto
CGHS NH
501
A B D E F G H I J K L m Nt 2
7 0 Po o o o o

t t Po n a n a 2 a

2
Pt Po a 252 Pt Po 24K
242 Pt Po a Pt Po
26
K
Po
2.7036g
Po x
Po
k 2230369 Po
Pipo
2 303 Po
K log
t 2410 Pt Po
24
K 2.303 Log 24 Po
t 25 Po Pt

disc casnf.tt I C's I 0

1 htaummencn't3an d
2
A

2CHz I OH Ca CH
osca Yination CH citz facoz
43
3
C
8
12 Hz Cha cha e
In Hg Hcl
CHz CH 3 42 Hz
Clemensenreduction 1 all CHz
CHz
Sol
CHO
NaBH4 CHLOH PBV CHIB

CHIBV Mg CH2 M9Bv Co2

dryether
OMgBr CHz OH
CH2 got
Sol Co 60
Henle Congo is phenol
5645
OH
OH

6 Feel Fe Ph 076 3H11

P violet colour
OH 0H
CHO
CHC 3 4 NaOH Q
Reimer Tiemann
rech Salicylaldehyde
0H 0H
CHz 0H PCC CHO
Mild O A

Sol
Glucose donot give the schiff's base test due to absence of
Freealdehydic group
Glucose do not addition product with Na
give So due to

absence of free aldehydi group

 O CH CH
CHz CHz

CHz 0 CHz
CHz

onat
no
offistfftiano
that
no

ooo
CH Br

CHz

set f
oot togettftch.co
to
go
 Phenoxide ion is less stable than Carboxylate ion
Carboxylicacids are more acidic than phenol
In carboxylate ion the v1 charge is delocalised over

two Onygen atoms

A
R C D R C R C

Sol
Sol

Sol
920 Rn 5736d 752
Sol
 odR

Mist stub Mig IE Mtg

If MY
Pt Rts
In the presence of phenolphthalein indicator onlyNazco neutralise
Natteo Nacl by mole
Nasco HCl Hph
No of eq of Nazcoz No of eq of I
5 0.1 5mi Consumed
0.5

In the presence of Methyl orange indicator

Med 2N act 2420 2002
2NaHC03 2H11
No of eq of Nattroz No of eq of HCl
15 N 10m Consumed
0.1 10

10 0.066 ear
N 0.1
1000
mass of Nancy N qq.tw ml

wt N x GEWX mi

1000

wt 0.066 87 5001
1000

2 89
 M
sol reactivity α
M

C Cl
CI
107
A 79 AI
CI CI CI

Eat Gd 3 3
Sol Lat Cet Pr's Nd's Pmt'sSmt
3
Dyt3 Hot Ert Tm 5 Luts
Across the period I R decreases
 2512 52 Ka Kaz H 52
Ksp of 2ns
1 25
2 Ksp of 2ns
5 2
252 1520 At 1519

52 152 5 2
0.01 at 152
PH 1

Sol
Sol

Sol
Sol I c 05 42504 CI 4505 Is
GI 705 642504 CI GHSOG 312 342
 12
Sol mass of 126

mass of Y 144
when 2 atoms are replaced by C 4atoms gain in wt 3kg
Let the mass of C in the body x kg

The wt gained due to replacement of 2 by c 24 Per

each C atom
The total wt increased in body 3kg
which corresponds to the 2 U increase per carbon atom
i The mass of carbon in the body
31 4 18kg

of Carbon in the body 24

 ΔU ox it 20491
ÉÉ
2x
AU 8 75 0.312 99
ΔH 8 314 153 300
245.7 3
ΔU 245.7kt mol
ΔH 241.95 Ks mol
U 245 7 15 mol

Sol N2 342 2 NH
at calm
t 0 2 0
22 0 8
eq 1 x 2 32 22
a 0.4 mole

at calm MN 1 0.6 0 6 mole

MHz 2 3 0.4 0 8mole

Hi 0.8 mole lit
1 of
 Dng 1 Dng 1
Dng 2 Dng 4

Kp K RT

RT If ang the then is man

ve then
If Dng
I is min

2504 4173 HSOG NHI

5 A S B w 1 b W 1 A

favours F R

HCOJ 5052 505 052

5 c b g c A 5 CA S C b
W A W B

Favours B R
 CN H HCN
As H Conl increases fort pH decreases
solubility of CN increases due toformation of HCN

62 H 124 H 62 H 92 H

CI
3 chloro G methyl cyclopentanol
CHz

THz NHL amino 3 Bromo 2 henanone

CHz 1H CHE CH
Bu

CHz Hz CHz CH CHz 1H OH 4 Bromo heptan 2 01

Br ditz
 soona
Pb CH Coo 2t Nazs Pbs 2H
Black Ppt

M P α Branching
 Bv Bv Bv
Br
Fe
Br

Br Minor
Majry
In electrophilic substitution reactions like
Bromobenzene M effect only favours but not I

Cn tanto 31 02 n coz 7 1 20

02 2 KOH K2C03 120

 No of moles of Kott 2
3000 0.6 moles

0.3 mules
No of moles of CO2 produced E

CnH2nto2 31 02 n coz 7 1 20

Imole of H C n'moles of 102

4 3 mole
12nt2n 2

4 3
7 0.3
14h 2

4 3h 0 3 147 2

4 3 n 4 2n 0.6
0 In 0.6
n G

F
F F F F
E F se xe
F F F O
F O F F

F
I go
F
E F c
F C1
C c c
F
FF
F
 DU 9 W

In Cyclic process DO 0 9 W

heat absorbed 20 4.2 84J

heat released 60J
W 92 9 60 84 24J

1H21 Bv2
Call
CHz CHI CH chg chz
569 1609
y
3009 857.149
Theoritical Yield 300 857.149 1157.149
Actual yield 4189
418 100 30
Yield 1157.14

C 2 HBr
CHz 2
1 butene yooo 2Hs H2O NEB 4 040
CH
aq 12504
CHz CH 143 Ha ni will give Same products
NBS hu
Sol Ksp s 15 s S M 152M
on addition of HCl 4 5052 Acog hence solubility
of Caloz increases
Ksp donot affected by Common ion
4
Qsp 156 Ksp 10 Hence Ppt is formed
K2COz Hz 506 dil Kasout H2O 02,9
K2S 250g dit 122504 Hasps
3K NO H250g dil K250ytKN0z 2ND g H2O
2KN 03 42504 dil No reaction

9 110 3
CEC CH
CHz c c p
2 Butyne Frans g
2 butene

CHz CHz
Bry CCly
ch Anti addition Q
H CH
trans 2 butene a

93 CH
CHS
CH d.dil.alk.KMnOyHy co OH 110

H CH
CH CH
 43 I
c
4
c
CH H H 45
Trans Cis Cis cis
O I A

as a
C C c c
H a a
cis trans trans trans
isomers
cis trans isomers 2
optical isomers 2 Total L

PO Ps solute solute
Popps
po nsolvent N solulé

Po Ps Ps I
872 Po 5
po
Ps 5
po
Po
p
Addition of NaOH H OH 20 F R favours

Addition of NHyCI NHI H2O NHUOH H

Favours B R

Addition of 1 250 H 032 HCO F R favours

Addition of Nacl donot have impact on eqlm

R2 02
H Br
dition
In
O A O I A

No of radial nodes n 1 1

for 45 4 0 1 3
2
for 4P 4 1 1

for 41 4 2 1 1
for 47 4 3 1 0
 C H N O
i 13 08 5
0.93 14 0.93
073 5.6 4.9 4.07
74

11 6
4 5
3 1

E F COHINO
5 1 14 1 16
E F mass 6 12 1

72 5 14 6 1 07

Sulphur nucleophile OxygenNucleophile

Among Oxygen Nucleophiles reactivity α size
Nitrogen Nucleophiles Oxygen Nalleophile
 CHz CHS
claffe ct
sit
a
P Q R c
Chz c
Ck
hu
s
Sit COOH
Mnoy
a OH C

Sol Ecell 0.059 Xp't

Eee 0 059 4

Erell 0 2364 Reduction potential

0.2364 oxidation potential
Ecell
 OH
OH
1 2.3 trihydroxybenzene Pyrogallol
0H GHz OH

Sol In an irreversible isothermal expansion

heat 9 transferred from system to surroundings
hence entropy of the surroundings increases

25021g 04g 2503191

Hr Hf Products Hf Reactants

2 y 2 a to

29 22

2x 2y k.cat
 911 10
CHS CHz CH CH HC CH CHz CHz CHICH CHz
Gy 1 butene

Cis 2 butene trans 2 butene

1.4 5 2
N 300.70 60

A N.A A AA
1
Nicly 318 eg tag Tetrahedral
Nj TUTT 2 C

2 Ni CN Nith 318 tzg6eg Paired

sq.p oé

3 N H2O Nitz 318 t2gbeg unpaired

oh 2é

i Total no of unpaired e 2 0 2 4

5
 31 Yes
19
At t o a o x
At 1 30 min a 3in X Y
i a 3in x

322 a

2 the he the 12
Is 15 3
5 112

5 112 30
t.ly 6min

is 9 229
o

1 2 a 22

at equilibrium Py 122 a 2x 6
21 atmp
2

Py 2 atmp Pz 2 2 4 atmp

Kp Py Pz 2x 4 32 atmp
 Find the pit when looms of 0.01M Hcl is added in a

solution Containing o.im moles of Haltco solution of

negligible volume Initial pH 9 Ka 157 Kaz 75
for H2 03
P'tinitial 9

HCI H2coz Cl
HCG
Mari Mof 102 100 153moles I millimoles
1000

no of millimoles of Nattcoz 0.1

The no of millimoles of HCI remaining 1 0.1 0.9m moles
9 10 4 moles
9 154 1000
1000
M N H
V
9 153
100

Final pH log Ht log 9 153 21093 3

i 9 093
21093 3 6 2
Δp
Q 500mL of 2M impure Hason Sample Can completely react with
1 slit of 1M Naoh solution Then find α
where α wt of 42504
25
12504 2NaOH Nazsoyt2H20
No of eq of 42504 No of eq of Naolt
no ofmoles Valency fator M x Vx n factor
2 1 1.5 1
w wt of 2504
1.5 25
9 2

wt 1 5 49
1.5219
2.94 3
 Total no of β keto mono carboxylic acids includingstereoisomers
which on heating give 11
salts

11 52hr
COOH
60 t
2
HOOC
I Caltt
2 2 2 6
Total no of Compounds
2 2
In aqueous medium Size of ions
Lita Hapag Kay
Order of reactivity of R x towards SN2 mechanism
CHz CHz H2 x CH3 3 CHz
 OH OH I
7
Ht
l

ving
expansion
NHz NICI 0H
N
HO CHz
N p
Nanoz

to c
CHz
 3

Anti Aromatic AA Aromatil NonAromati

Non Aromatil Anti Aromatic

 dil Hasoy coz
Calott 2 Cacoz
Coj
turns lime water into milky

CH o
c CHO

croak 430
2w OH2C12
CS2

C Cy Cy Cy

C 12
Sucrose
Order of Covalent radii among 16th group elements
O S Se Te Po

A D are Anti aromatic B is Non Aromatic

C is Aromatic
order of stability
Aromatic Non Aromatic Anti Aromatic
Sol

Order of F N among 13ᵗʰ group elements is

BIT In Ga
2 0 18 17 1.6 A

D I RH he he 912A 91.2hm

RH 22 152

RH
RHX

91.2 1209 434.2hm

 54 3 2 a 54 3 21

3 6 54 3 2
6 54 21

NH É

NHz

Bra
Mg't o c omg o C NHL
Clahu Mg go y
dryether Ntuc
mgi
 H2 143
CH COC Zn Hgt al
anhy All 3 reagent x

12h0

c2Hso0Nat it en
I HSHO
In
03
2715017

90
2HCHO HCOONA CH3OH
Cannizzaro rean

CHO CH CH
CH dil NaOH

reagent y
 2Nd Not
Hat
X

CH3C
Not
Hat o Nat
HCOOH

017

Noz NHz 142 10

Cons NO Nano HCI
Cont 42504

208 Ix
 NICI
NICI OH
420 N N Of
warm Naott
Orange dye
1 1 PH 7

Sol
 18 KJ

Ksp Nitz OH_ Naoh Natton

Ksp S 0.1 0 IM 0.1m o.IM

2 1515 5 152

5 2 1513

Z 2
Sol

8cm

Distance moved by Sample 0 8 8 15

Rf Distance moved by eluant
Sol
H 2

t of
7 65 3 2 2 H2O
r
3 5
1 allylil Carbocation a
3 alky
more stable

Sol
sol rate r K C
n log C
log rate log k
slope of the graph n As modulus of slope is high
then order of reaction is high

Sol 73 4 Xe 477
Eut Xe 477

Sol

20 0.5
PH pka log
s
4.76 log 100
Nava 10 1
100

p 4.76 log 4.76

 1 777

1.585A

Order of strength of ligands

5 F L causes large splitting of d subshell

CH 2H50
ptt't
I CH

Hg cuz am

É CH

CHz CH

Ethylidene chloride 1,1 dichloroethane

Sol

Yanti

H
Inversion Syn
 Y is 2Big t Gs
is Agt 24g
N 2nt2y 2nt2y Y

KP PA x PB KP PB XP
KP x 2ntzy kpz zatzy 2y

Kp 9 10 2K2gr
KP2 4.5 y

2y
 29 9 153
Kp a 2

2y 2 2y zy 9 153

29 Gy 9 153
7293 9 103
93 5
9
y
13 231
103

y 22 0.05

2 2y 2 0.05 0 1

Pt Pa PB P
0.1 2 0.1 2 0.05 0 05
0 lt 0 2 0.1 0.05
0 45

Sol
Sol
 C
anhy Alc 3 I

C1
2n Hg
Cotto
HCI
anhy.at3

Intramolecular Friedel Craft acylation

0 1 2 77

9 74
Sol
19 E OH
04 17

1
0H OH
anhy Alel
F 1 acylation

sock
8 anhy
E cl
A1 13
Intramolecular
F i acylation

In Hg Conc All
Reduction
14
Solubility of Agel in 0 2M Agnoz 53 C I E

S 0 5M HC Sy CI E
H2O
0.3M Ball C I E S 53754 52
Order of reactivity towards electrophilic addition reaction
is M H C Cots X M
 0H
chclztaq.ua oh Cho
Ht
0H CHO
OH to
cyo
Endust
on zno

CHO
E a CHO
Hz
Pd Basoy

C N CH2 NHz
Sncbt Ha

CHz CHO
Cr02Cl2 S2
130
C's CH CH 81 CHO
HBS a Ko
2eq H2O
Order of reactivity M H C S Colts M
 0 Mg Br
CI CHSMg Bu
CH
dry ether CH
CH

C1 Br
Mg
 GTM-12 (06-01-2025)

Sec: SR.IIT_*CO-SC(MODEL-A& APEX) GTM-12 Date: 06.01.2025

Time: 3.00Hrs. JEE MAIN MODEL Max. Marks: 300

PHYSICS MAX.MARKS: 100

SECTION – I
(SINGLE CORRECT ANSWER TYPE)
This section contains 20 multiple choice questions. Each question has 4 options (1), (2), (3) and
(4) for its answer, out of which ONLY ONE option can be correct.
Marking scheme: +4 for correct answer, 0 if not attempted and -1 if not correct.

1. The electric field inside a sphere having charge density related to the distance from
the centre as    r (  is a constant) is

 r3  r2  r2
A) B) C) D) none of these
4 0 4 0 3 0
2. A uniform disc of mass 2 kg and radius 50 mm is released from rest on a smooth fixed
incline plane as shown. If the length of incline equals 160 cm, the time taken by the
disc to arrive at bottom equals (Take: g  10 ms 2 )

Page | 1
GTM-12 (06-01-2025)

25. Net magnetic field at the centre O of circle due to current carrying loop as shown in

figure is

 0i x x    where x is
2 x R

CHEMISTRY MAX.MARKS: 100

SECTION – I
(SINGLE CORRECT ANSWER TYPE)
This section contains 20 multiple choice questions. Each question has 4 options (1), (2), (3) and
(4) for its answer, out of which ONLY ONE option can be correct.
Marking scheme: +4 for correct answer, 0 if not attempted and -1 if not correct.

26. The value of  f G 0 for formation of Cr2O3 s  is – 540 kJmol 1 and that of Al2O3 s  is

827 kJmol 1. What is the value of  r G 0 for the reaction?

4 2 2 4
Al s   Cr2O3 s   Al2O3 s   Cr s  .
3 3 3 3
A) 574 kJ mol 1 B) 191.33kJ mol 1 C) 574 kJ mol 1 D) 287 kJ mol 1
27. Which of the following statements is incorrect?
A) [Ag(NH 3)2]+ is linear with sp hybridized Ag+.

B) NiCl 2 ,VO3 and MnO  have tetrahedral geometry.

4 4 4
C) [Cu(NH3)4]2+, [Pt(NH3)4]2+ and [Ni(CN)4]2- have square planar geometry.
D) Fe(CO)5 has trigonal bipyramidal structure with sp3d hybridized iron.

Page | 9
GTM-12 (06-01-2025)

Cl
2SbCl5
P , P will be
28.
Cl

2 2 2 SbCl6
A) B) C) D) mixture of A and B
29.

A) B) C) D)
30. The solubility of a specific non-volatile salt is 4g in 100g of water at 250 C . If 2.0g,
4.0g and 6.0gm of the salt is added to 100g of water at 250 C , in the systems X ,Y
and Z . The vapour pressure would be
A) X  Y  Z B) X  Y  Z C) Z  X  Y D) X  Y  Z
31. 0.1M formic acid solution is titrated against 0.1M NaOH solution, what would be the
1 4
difference in pH between and stages of neutralization of acid?
5 5
3 1 1
A) 2log B) 2log C) log D) 2log 4
4 5 3
32. Given below are two statements one is labeled as Assertion (A) and other is labeled as
Reason (R)
Assertion: The miscibility of ethers with water resembles those of alcohols of the
same molecular mass, both ethoxyethane and butan-1-ol are miscible to almost the
same extent i.e.,7.5 and 9 g per 100 mL water.
Page | 10
GTM-12 (06-01-2025)

Reason : Just like butan-1-ol, oxygen of ethoxyethane can also form hydrogen bonds
with water molecule as shown.

In the light of the above statements, choose the most appropriate answer from the
options given below:
A) Both (A) and (R) are true and (R) is the correct explanation of (A).
B) Both (A) and (R) are true but (R) is not the correct explanation of (A).
C) (A) is true but (R) is false.
D) (A) is false but (R) is true.
33. Which of the following will react faster with Ag  ?

Cl

A) B)

Cl

C) COOH D)
34. Which of the following reactions will yield racemic mixture?

Page | 11
GTM-12 (06-01-2025)

A) (I), (III), (V) B) (I), (II), (V)

C) (I), (II), (IV) D) (III), (IV), (V)
35. Arrange the below mentioned bromine atoms in decreasing order of their reactivity
towards hydrolysis through SN1 path

A) 2 >1 > 4 > 3 B) 2 > 1 > 3 > 4 C) 2 > 4 > 3 > 1 D) 4 > 2 > 1 > 3
36. Identify the reactions where the final product contains ketone functional group.

a) b)

Page | 12
GTM-12 (06-01-2025)

c) d)

A) (a) and (d) only B) (a), (c) and (d) only

C) (b), (c) and (d) only D) (a), (b), (c) and (d)
W 
37. A 75 gm 4%   aqueous NaOH solution is distilled for some time. The water
W 
collected has a mass of 25 gms. To this distilled solution X gms of KOH(s) is added,
so that molality of OH– ion in the resulting solution becomes 5. Find X?
A) 6.62 g B) 8.96 g C) 17.92 g D) 13.24 g
38. Which of the following bromides is the major product of the reaction shown below,
assuming that there are no carbocation rearrangement?

A) B) C) D)

39. Which of the following reaction satisfies the given graph?

A) N 2(g)  3H 2(g)  2NH 3(g) B) NH 4 HS( s )  NH 3(g)  H 2 S ( g )

Page | 13
GTM-12 (06-01-2025)

C) CaCO3(s)  CaO(s)  CO 2( g ) D) CuSO4 .5 H 2O( s )  CuSO4 .2 H 2O( s )  3H 2O( g )

40. An aqueous solution containing a non volatile solute is heated in an open vessel till the
boiling point is reached. Thereafter, the boiling is continued and the temperature & the
vapour pressure of the solution are recorded at 5 min, 10 min, and 15 min. The
corresponding temperatures and pressures are T 5, T 10, T 15 and P 5, P 10, P 15,
respectively. The correct relationship among them is:
A) T5 < T10 < T15 and P5 = P10 = P15 B) T5 = T10 = T15 and P5 = P10 = P15
C) T5 = T10 = T15 and P5 < P10 < P15 D) T5 < T10 < T15 and P5 < P10 < P15

41. P4  3O2  P4O6 , H  1500kJ . Bond enthalpies of O  O , P  O are 500kJmol 1

and 350kJmol 1 respectively. What is ' P  P ' bond energy?

A) 300kJmol 1 B) 200kJmol 1 C) 100kJmol 1 D) 400kJmol 1
42. The order of boiling points of hydrides of VIA group elements.
A) H 2O  H 2Te  H 2 Se  H 2 S B) H 2Te  H 2O  H 2 Se  H 2 S
C) H 2O  H 2 S  H 2 Se  H 2Te D) H 2O  H 2 S  H 2 Se  H 2Te
43. Match List-I with List-II
List-I List-II
(P)  MO   A  B (I) Dipole moment
(Q)  Q  r (II) Bonding molecular orbital
(R) Nb  Na (III) Anti-bonding molecular
2 orbital
(S)  MO   A   B (IV) Bond order
A) (P)-(II), (Q)-(I), (R)-(IV), (S)-(III)
B) (P)-(III), (Q)-(IV), (R)-(I), (S)-(II)
C) (P)-(III), (Q)-(I), (R)-(IV), (S)-(II)
Page | 14
GTM-12 (06-01-2025)

D) (P)-(III), (Q)-(IV), (R)-(II), (S)-(I)

44. The IUPAC name of the following compound is

A) 3-Ethyl-4-methylhex-4-ene B) 4, 4-Diethyl-3-methylbut-2-ene
C) 4-Methyl-3-ethylhex-4-ene D) 4-Ethyl-3-methylhex-2-ene
45. The difference between amylose and amylopectin is
A) Amylopectin have 1 → 4 - glycosidic linkage and 1→ 6 - glycosidic linkage
B) Amylose have 1 → 4 - glycosidic linkage and 1→ 6 - glycosidic linkage
C) Amylopectin have 1 → 4 - glycosidic linkage and 1→ 6 - glycosidic linkage
D) Amylose is made up of glucose and galactose
SECTION-II
(NUMERICAL VALUE ANSWER TYPE)
This section contains 5 questions. The answer to each question is a Numerical value. If the
Answer in the decimals , Round off to the nearest Integer only. Have to Answer all 5
questions and question will be evaluated according to the following marking scheme:
Marking Scheme: +4 for correct answer, 0 if not attempted and –1 if not correct.

46. In the scheme given below, the total number of sp2 hybridised carbon atoms in the
final major product is

1.O3 1.NaOH  aq 
Y
2.Zn, H 2O 2.heat

47. A hydrogen gas electrode is made by dipping platinum wire in a solution of HCl of
pH = 10 and by passing hydrogen gas around the platinum wire at one atm pressure.
The oxidation potential of electrode would be in terms of x  102 V . What is x?
2.303RT
(Give:  0.059 )
F

Page | 15
GTM-12 (06-01-2025)

48. Total number of geometrical isomers for the complex  RhCl  CO   PPh3  NH 3   is

49. An organic compound containing nitrogen with molecular mass 180 is acylated with
CH3COCl in the presence of pyridine to get a compound with molecular mass 390.
The number of amino groups present per molecule of the former compound is____.
50. For a reaction A 
 2 B  C the half-lives are 100 s and 50 s when the concentration
of reactant A is 0.5 mol L–1 and 1.0 mol L–1 respectively. The order of the reaction is
_________

MATHS MAX.MARKS: 100

SECTION – I
(SINGLE CORRECT ANSWER TYPE)
This section contains 20 multiple choice questions. Each question has 4 options (1), (2), (3) and
(4) for its answer, out of which ONLY ONE option can be correct.
Marking scheme: +4 for correct answer, 0 if not attempted and -1 if not correct.

51. The series of natural numbers is divided into groups as (1), (2, 3, 4), (3, 4, 5, 6, 7),
(4, 5, 6, 7, 8, 9, 10),.......... . The sum of elements in the 20th group is
A) 1368 B) (38)2 C) (39)2 D) 38  39
y z
52. The lines L1 : x = y = z, L2 : x = = and a line L3 is passing through (1, 1, 1) form a
2 3
triangle of area 6 units, (1, 1, 1) being one of the vertices of the triangle. Then the
point of intersection of the L3 with L2 is
4 8 
A) (1, 2, 3) B)(2, 4, 6) C)  , , 4  D)(1, 5, 7)
3 3 
53. The combined equation of 2 altitudes of an equilateral triangle is
x 2  3 y 2  4 x  6 3 y  5  0. The third altitude has equation

A) x + 2 = 0 B) y= 3 C) x = 2 D) None of these
Page | 16
 GTM-12 (06-01-2025)

SR.IIT_*CO-SC(MODEL-A& APEX) GTM-12 Date: 06.01.2025

Time: 3.00Hrs. Max. Marks: 300
KEYSHEET
PHYSICS
1 2 3 4 5 6 7 8 9 10
B B A D A C D B A A
11 12 13 14 15 16 17 18 19 20
A D C C A D B B C D
21 22 23 24 25
252 9 17 80 3

CHEMISTRY
26 27 28 29 30 31 32 33 34 35
B D B C D D A B B C
36 37 38 39 40 41 42 43 44 45
B B B B A B A C D A
46 47 48 49 50
3 59 3 5 2

MATHEMATICS
51 52 53 54 55 56 57 58 59 60
C B C D A A A B D D
61 62 63 64 65 66 67 68 69 70
C D A B D B C D A A
71 72 73 74 75
4 4 1 1 30

Page | 1
GTM-12 (06-01-2025)
2
 
 T   
k
2
 420 
  0.2   
 21 
 80N
25. r  R cos 60o

Bnet  B1  B2
 0i i 
  sin   sin    0  
4 r 2r  2 
0i  sin 60o  sin 60o  0i  2 / 3 
   
4 R cos60o 2 R  2 
i

 0i 3  0i

2 R 6 R
 0 3 3  .
6 R
 

CHEMISTRY
26. The two equation are :
4 2 2
Al  s   O2  g   Al2O3  s  ,  f G o    827kJ mol1 …(i)
3 3 3
4 2 2
Cr  s   O 2  g   Cr2O3  s  ,  f G o    540kJ mol 1 …(ii)
3 3 3
Subtracting equation (ii) from equation (i) we have,
4 2 2 4
Al  s   Cr2O3  s   Al2O3  s   Cr  s  ,  rG o
3 3 3 3
2
 287kJ mol1   191.
3

27. In Fe  CO 5 , Fe is dsp3 hybridized.

28. SbCl5 act as a Lewis acid.

Page | 8
GTM-12 (06-01-2025)

29. Reduction of ketone to alcohol by hydrogen nickel followed by acidic dehydration

of alcohol to give alkene.

30. More is the non-volatile solute added, lesser is the vapour pressure. After solubility
precipitate formation takes place.

1/ 5
31. pH1  pK A  log
4/5
4/5
pH 2  pK A  log
1/ 5
1
pH1  pH 2  log  log 4
4
pH  2log 4 .

32. Conceptual

33. CH2 form after removal of Cl is more stabilized.

34. Trans compound + syn addition → gives racemic mixture.

35. Carbocation stability order is 3o> 2o> 1o.

36. Conceptual

37. Wsolute  3 gms, Wsolution  50 gm  75  25

3 X
WOH  + . m  5  40

3 X 
56  1000
40 56 47
X  9.
38. 3o carbocation is more stable.
2HSO4   H 2S2O8  2e .
K p  K c  RT 
n
39.
K 
log  P   n log RT  n  2.
 KC 
Page | 9
GTM-12 (06-01-2025)
40. When a solution containing a non volatile solute is heated in a open vessel, the
solution boils at a pressure equal to atmospheric pressure which remains constant.
Due to increase in concentration of solution boiling point increases.

41. H  1500 kJ
6  H P  P  3  H O  O  12  H P  O
1500  6  x  3 500  12  350 
x  200.

42. H 2O has H-bonding while H2Te has higher Vander wall forces than H2Se > H2S.
43.
List-I List-I
(P)  MO   A   B (III) Anti-bonding
molecular orbital
(Q)  Q  r (I) Dipole moment
(R) Nb  Na (IV) Bond order
2
(S)  MO   A   B (II) Bonding
molecular orbital

44.

45. It is a fact that Amylopectin have 1 → 4 -glycosidic linkage and 1→ 6 -

glycosidic linkage
46. Ozonolysis of double bond to give diketone and then aldol condensation to give a
product with 7 member and 5 member ring.
H 2  2H   2e 
47.
1 atm 10 10

EH 0
0.059
log
10 
10 2


2 /H
2 1
EH /H  0.59 V.
2

Page | 10
GTM-12 (06-01-2025)

48. (2 cis and 1 trans)

390  180
49. Number of amino groups  5
42

50. For zero order, t1/2 decrease with decrease in concentration of reactions.
For first order, t1/2 is independent of concentration of reaction.
For second order, t1/2 increase with decrease in concentration of reactant.
1 n
 t1/2 1   A0 2  100  0.5 
1 n

    
 t1/2 2   A0 1  50  1.0 
1 n
1
2   2  2n 1  n  1  1  n  2.
2
MATHEMATICS
th
51. First element in 20 group is equal to ’20;.
(20, 21, ….. upto 39 terms)
39
 Sum =
2
 2  20   39  1  1
39
  40  38    39  .
2

52.

6 6
cos   sin   (where  is the angle between L1&L2)
42 42
1
Area OAB   OA  OB  sin 
2


1
2
   
3  14
6
42
 6    2.

53.

Page | 11
 3 R
Sn2 reactivity order CHzx 1 R x 2 R x

due to availability of vacant orbitals

out of plane
K K x Kax K3 1 2 4 8
 SRI CHAITANYA IIT ACADEMY, INDIA 18-12-2024_Sr.S60_Elite, Target & LIIT-BTs_2nd Year Syllabus_Jee-Main-GTM-06/01_KEY &SOL’S

CHEMISTRY
51. Aliphatic carboxylic acids upto nine carbon atoms are colorless liquids at room
temperature with unpleasant odours.
52. NaHSO3 does not react with glucose
53. Ni  CO  4 - Tetrahedral
 NiCl2 Br2 2 - Can’t show G.I
54. S  200
F  333
Cl  349
Ne = +ve value
2
55. 4CH 3COONH 4
PbSO4    Pb  CH 3COO  4 
56. HF has H.B but not HCl.
RMgX
57. R  OH  R  H
58.
A=
HO CN

B=
HO COOH

C=
HO OH
59. SN 1 rate  C  stability
60. 1) ArSN 2
3) Aniline does not undergo F.C alkylation
61. 1o R  OH  2o R  OH  3o R  OH
boiling point order
62. Aldehydes are more reactive than ketones
63. NP & PU Show +3 to +7
64. x  K 2 MnO4 , y  KMnO4 , z  MnO2
65.
NO2 NH2

OH OCH3
X= Y= P= R=

66. Tyrosine – Y
67.
O
O

O3
OH
Z n - H 2O 
CHO

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 SRI CHAITANYA IIT ACADEMY, INDIA 18-12-2024_Sr.S60_Elite, Target & LIIT-BTs_2nd Year Syllabus_Jee-Main-GTM-06/01_KEY &SOL’S
o
68. 3 R  X Can’t undergo G.T.S
69. In 100gm solution
nMgCl2  0.1 nNaCl  0.1
After dissociation total moles  0.1  3  0.1  2 = 0.5
Wwater  100  9.5  5.85 = 84.65 gm
1000
Tb  0.52  0.5   3.07o C  Tb  103.07 o C
84.65
70.
71.

O
X
O

72. 28
73. 83
74. 3, 4, 5, 6, 7, 9
75. AgBr( s )  Ag   Br 
 s10 
7 s

s 2  107 s  20  1014  0
107  1014  80  1014
s  4  107
2
 Ag   5  10 M
 7

 Br    4  107 M
 NO3   1  107 M
 
K
o   K 1Ag   6  103  1000  5  107
1000C
 30  107 s  m 2 / mol
K 1NO  7  1  107 sm2 / mol
3

K 1Br   8  4  157 sm 2 / mol  32  107

1
K total  69  107 sm 2 / mol
Sec: : Sr.S60_Elite, Target & LIIT-BTs Page 9
 SRI CHAITANYA IIT ACADEMY, INDIA 18-12-2024_Sr.S60_Elite, Target & LIIT-BTs_2nd Year Syllabus_Jee-Main-GTM-06/01_KEY &SOL’S

CHEMISTRY
51. Aliphatic carboxylic acids upto nine carbon atoms are colorless liquids at room
temperature with unpleasant odours.
52. NaHSO3 does not react with glucose
53. Ni  CO  4 - Tetrahedral
 NiCl2 Br2 2 - Can’t show G.I
54. S  200
F  333
Cl  349
Ne = +ve value
2
55. 4CH 3COONH 4
PbSO4    Pb  CH 3COO  4 
56. HF has H.B but not HCl.
RMgX
57. R  OH  R  H
58.
A=
HO CN

B=
HO COOH

C=
HO OH
59. SN 1 rate  C  stability
60. 1) ArSN 2
3) Aniline does not undergo F.C alkylation
61. 1o R  OH  2o R  OH  3o R  OH
boiling point order
62. Aldehydes are more reactive than ketones
63. NP & PU Show +3 to +7
64. x  K 2 MnO4 , y  KMnO4 , z  MnO2
65.
NO2 NH2

OH OCH3
X= Y= P= R=

66. Tyrosine – Y
67.
O
O

O3
OH
Z n - H 2O 
CHO

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 SRI CHAITANYA IIT ACADEMY, INDIA 18-12-2024_Sr.S60_Elite, Target & LIIT-BTs_2nd Year Syllabus_Jee-Main-GTM-06/01_KEY &SOL’S
o
68. 3 R  X Can’t undergo G.T.S
69. In 100gm solution
nMgCl2  0.1 nNaCl  0.1
After dissociation total moles  0.1  3  0.1  2 = 0.5
Wwater  100  9.5  5.85 = 84.65 gm
1000
Tb  0.52  0.5   3.07o C  Tb  103.07 o C
84.65
70.
71.

O
X
O

72. 28
73. 83
74. 3, 4, 5, 6, 7, 9
75. AgBr( s )  Ag   Br 
 s10 
7 s

s 2  107 s  20  1014  0
107  1014  80  1014
s  4  107
2
 Ag   5  10 M
 7

 Br    4  107 M
 NO3   1  107 M
 
K
o   K 1Ag   6  103  1000  5  107
1000C
 30  107 s  m 2 / mol
K 1NO  7  1  107 sm2 / mol
3

K 1Br   8  4  157 sm 2 / mol  32  107

1
K total  69  107 sm 2 / mol
Sec: : Sr.S60_Elite, Target & LIIT-BTs Page 9
 SRI CHAITANYA IIT ACADEMY, INDIA JEE MAIN 2025 BRAHMANDA PRACTICE MATERIAL-2

CHEMISTRY
RPTM-01
(SINGLE CORRECT ANSWER TYPE)
This section contains 20 multiple choice questions. Each question has 4 options (1), (2), (3) and (4) for its answer, out of which ONLY ONE option can be
correct.
Marking scheme: +4 for correct answer, 0 if not attempted and –1 in all other cases.

1. In  321 the sum of angular momentum, spherical nodes and angular nodes is ________
6h 8h  6 6h  4 8h  4 
1) 3 2) 3) 4)
2 2 2 2
Key: 3
h h 6h
Sol: Angular momentum = l  l  1  2  2  1 
2 2 2
No. of spherical nodes = n  l  1  3  2  1  0
No. of angular nodes = l =2

6h 6h  4
Sum of the above = 2 
2 2
2. The minimum energy needed for excitation of an electron present in the ground state of
H-atom is _____
1) + 13.6 eV 2) + 3.4 eV 3) + 12.09 eV 4) + 10.2 eV
Key: 4
Sol: Minimum energy needed is excitation of electron from ground state to 2 nd orbit
-3.4
-13.6

n =1

n =2

 E  E2  E1  3.4   13.6   3.4  13.6  10.2 eV

3. Statement-I: In H-atom 4p and 4d orbitals are degenerate orbitals
Statement-II: In multi electron atom, all the orbitals in a given shell are degenerate
orbitals
1) Statement I is true, Statement II is true 2) Statement I is true, Statement II is false
3) Statement I is false, Statement II is true 4) Statement I is false, Statement II is false
Key: 2
Sol: In H-atom, energy depends only on principal quantum number n-only

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 SRI CHAITANYA IIT ACADEMY, INDIA JEE MAIN 2025 BRAHMANDA PRACTICE MATERIAL-2
In multi electron atom, energy depends on both PQN &AQN  , n and l -values

4. Given below are two statements one is labelled as Assertion(A) and the other is labelled
as Reason(R).
Assertion(A): In the photo electric effect electrons are ejected from the metal surface as
soon as the bulb of light of frequency is greater than the threshold frequency strikes the
surface.
Reason(R): When the photon of any energy strikes an electron in the atom, transfer of
energy from photon to the electron takes place.
In the light of the above statements, choose the appropriate answer from the options
given below.
1) Both A & R are correct, and R is the correct explanation of A
2) Both A & R are correct, but R is not the correct explanation of A
3) A is correct but R is not correct
4) A is not correct but R is correct
Key: 3
Sol: Conceptual
(NUMERICAL VALUE TYPE)
Section-II contains 10 Numerical Value Type questions. Attempt any 5 questions only. First 5 attempted questions will be considered if more than 5
questions attempted. The Answer should be within 0 to 9999. If the Answer is in Decimal then round off to the nearest Integer value (Example i,e. If
answer is above 10 and less than 10.5 round off is 10 and If answer is from 10.5 and less than 11 round off is 11).
Marking scheme: +4 for correct answer, 0 if not attempt and -1 in all other cases.
th
5. In H-atom an electron jumps from 5 orbit to first orbit. The number of visible lines
emitted are _________
Key: 3
Sol: Visible lines means Balmer series.

5
4 Brackett=1
3 Pascher=2

2 Balmer = 3

1
Lyman=4

Total no. of spectral lines emitted =

 n2  n1  n2  n1  1
2

 5  1 5  1  1 45
=   10 lines
2 2
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 SRI CHAITANYA IIT ACADEMY, INDIA JEE MAIN 2025 BRAHMANDA PRACTICE MATERIAL-2
In which Balmer = 3

6. In an atom an electron is moving with a speed of 600 m/sec with an accuracy of 0.005%
3
certainty with which the position of electron can be located as x  10 m . Then x is
______) (Nearest integer)
Key: 2
Sol:  V  600 m / s

0.005
Accuracy = 0.005% of 600 = 600   0.03
100
h 6.625  10 34
x    1.9  2
4   mV 22
4   9.11  10 31  0.03
7
7. Maximum number of electrons that can be accommodated in a P-orbital is ________
Key: 2
Sol: Any orbital can accommodate a maximum of two-electrons only. With opp. spin.
0
8. The shortest wavelength in Lyman series is 912 A . The longest wavelength in Balmer

series is ____ 10 A (nearest integer)

3 0

Key: 7
Sol: Lyman: n1  1, n2  
1 1 1
 Z 2R  2  2 
  n1 n2 
1 1 1 
 z2 R  2  2 
912 1   …..(1)
Balmer: n1  2, n2  3
  1 1  5
 z2 R  2  2   Z 2
R 
 2 3  36 ……..(2)
(1) by (2)

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 SRI CHAITANYA IIT ACADEMY, INDIA JEE MAIN 2025 BRAHMANDA PRACTICE MATERIAL-2
1
912  Z R  1    36    6566 A0  6.566  103 A0  7  103 A0
2

1 5 912 5
Z 2R 
 36
9. C5H10 O is a carbonyl compound, the number of structural isomers possible for this
molecular formula are
Key: 7
CH 3  CH 2  CH  CHO

CH 3
Sol: (1) CH 3  CH 2  CH 2  CH 2  CHO (2)

CH 3
CH 3  CH  CH 2  CHO
CH 3  C  CHO

CH 3 CH 3
(3) (4)

(5) CH 3  CH 2 COCH 2 CH 3 (6) CH 3COCH 2CH 2  CH 3

CH 3CO  CH  CH 3

CH 3
(7)

10.
H 2 / Ni Cl2 / hv
M
 Alkyne 

N
(No. of mono-chloro
structural products)

M – possible alkynes, Write the sum of value of M + N.

Key: 9
b d
a f
e
Sol: M - c c
(6) Monochloro structural products
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 SRI CHAITANYA IIT ACADEMY, INDIA JEE MAIN 2025 BRAHMANDA PRACTICE MATERIAL-2
(3+6) =9
11. Find the sum of the locants of substituent’s as per IUPAC naming for the given
compound.
OH

CN
Br
Key: 7
Sol: Principal functional group is CN, OH, Br are substituents
OH
5
4
3
2 1 CN
Br 257
12. In Duma’s method for estimation of nitrogen, 0.29 g of an organic compound gave 50 ml
of Nitrogen collected at 300 K temperature and 715 mm pressure. Calculate the
percentage composition of nitrogen in the compound. (Aqueous tension at 300 K = 15
mm)
Key: 18
Sol: Volume of Nitrogen collected at 300 K and 715 mm pressure is 50 ml.

Actual pressure = 715 – 15 = 700 mm

273  700  50
Volume of nitrogen at STP =  41.9 ml
300  760
22,400 ml of N 2 at STP weighs = 28 g
28  41.9
41.9 ml of nitrogen weighs = g
22400
28  41.9  100
Percentage of Nitrogen =  18.06%
22400  0.29

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RPTM-02
(SINGLE CORRECT ANSWER TYPE)
This section contains 20 multiple choice questions. Each question has 4 options (1), (2), (3) and (4) for its answer, out of which ONLY ONE option can be
correct.
Marking scheme: +4 for correct answer, 0 if not attempted and –1 in all other cases.
1. Atomic radii of fluorine atom and neon atom in angstrom units are respectively given by
1) 0.762, 1.60 2) 1.60, 1.60 3) 0.72, 0.72 4) 1.60, 0.762
Key: 1
Sol: rF  rNe
4 3
2. Hydrogen peroxide oxidises  Fe  CN 6  to  Fe  CN 6  in acidic medium but reduces
3 4
 Fe  CN 6  to  Fe  CN 6  in alkaline medium. The other products formed are,
respectively
1)  H 2O  O2  and  H 2O  OH   2) H 2O and  H 2O  O2 
3) H 2O and  H 2O  OH   4)  H 2O  O2  and H 2O
Key: 2
Sol: Chemical equations are given below:
4 3
2  Fe  CN 6    H 2O2  2 H   2  Fe  CN 6   2 H 2O

3 4
2  Fe  CN 6    H 2O2  2OH   2  Fe  CN 6   2 H 2O  O2

3. Considering the basic strength of amines in aqueous solution, which one has the smallest
pK b value?
1) C6 H 5 NH 2 2)  CH 3 2 NH 3) CH 3 NH 2 4)  CH 3 3 N
Key: 2
Sol:  CH 3 2 NH is a stronger base in aqueous medium than Me3 N . So its pKb value is smallest
4. Statement-1: The electron gain enthalpy of N is +ve while that of P is –ve.
Statement-2: This is due to the smaller atomic size of N in which there is a considerable
electron-electron repulsion and hence the additional electron is not accepted easily.
1) Statement-1 is True; Statement-2 is True; Statement-2 is correct explanation for
Statement-1.
2) Statement-1 is True; Statement-2 is True; Statement-2 is NOT a correct explanation
for Statement-1.
3) Statement-1 is True; Statement-2 is False.
4) Statement-1 is False; Statement-2 is True.
Key: 1
Sol: Statement-2 is the correct explanation for Statement-1.
5. Which of the following pairs is chemically similar?
1) Zr  Hf 2) Cu  Ag 3) Fe  Au 4) Hf  La
Key: 1

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Sol: Zr and Hf have almost equal ionic radi due to Lanthanide contraction. Thus their
chemical properties will almost similar
6. The bond dissociation energies of H–H, C–C and C–H bonds respectively are 104  2, 83 1
and 98  8 kcal mol 1 . The electro negativity of carbon is
1) 2.6 2) 2  51 3) 2  50 4) 2  52
Key: 1
Sol:   EC  H  EH  H  EC C

xC  xH  0  208 

xC  xH  0  208   0.208  5.75 

1/ 2
 0.498

xC  0.498  2.1  2.598  2.6

(NUMERICAL VALUE TYPE)

Section-II contains 10 Numerical Value Type questions. Attempt any 5 questions only. First 5 attempted questions will be considered if more than 5
questions attempted. The Answer should be within 0 to 9999. If the Answer is in Decimal then round off to the nearest Integer value (Example i,e. If
answer is above 10 and less than 10.5 round off is 10 and If answer is from 10.5 and less than 11 round off is 11).
Marking scheme: +4 for correct answer, 0 if not attempt and -1 in all other cases.
7. How many of the following are more acidic than benzoic acid?
COOH COOH COOH COOH

CHO NO2 Cl NH 2
Key: 3
Sol: – I effect increases the Acidity
8. The total number of   hydrogen’s contributing structures showing hyperconjugation
(involving C – H bonds) for the following carbocation is
H 3C CH 2CH 3

Key: 6
(a) (b)
H 3C CH 2CH 3
(c)

a3 Hyperconjugative H'S

b2 Hyperconjugative H'S

Sol: c 1 Hyperconjugative H'S

9. How many –I groups are present in the following?

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COO , O ,  NO2 , COOH , CH 3 ,  F , CH 2 R
Key: 3
Sol: Conceptual
10. How many of the following are stronger acids than phenol?

Key: 3
Sol: - I effect
11. How many pairs in their first species have lower ionization energy than second species?
a) N and O b) Li and Li  c) O and S d) Sr and Ba.
Key: 1
Sol: Conceptual
12. I.E. and E.A. of an element are 13 eV and 3.8 eV respectively. The electronegativity of
the element on Pauling’s scale is.
Key: 3
13  3.8 16.8
Sol: On Mulliken Scale E.N .    8.4 eV
2 2

E.N . Mulliken 8.4

On Pauling’s Scale E.N .    3 eV
2.8 2.8
13. The molarity of 33.6V of H 2O2 of solution is____
Key: 3
1
Sol: H 2O2  aq   H 2O1  O2 g 
2

1M  0.5 mol of O2  11.2 L (STP)

33.6
Hence, molarity   3M
11.2
14. Find the total number of species having magnetic moment value of 5.9 B.M. from
following species. Fe 2 , Cr , Cr 3 , Fe3 , Ti 2 , Mn 2 ,V 3
Key: 2
Sol: Fe3 , Mn2

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RPTM-03
(SINGLE CORRECT ANSWER TYPE)
This section contains 20 multiple choice questions. Each question has 4 options (1), (2), (3) and (4) for its answer, out of which ONLY ONE option can be
correct.
Marking scheme: +4 for correct answer, 0 if not attempted and –1 in all other cases.
1. Assuming 2 S  2 P mixing is not operative. The paramagnetic species among the following
1) Be2 2) B2 3) C 2 4) N 2
Key: 3
Sol: C2 is paramagnetic

2. Given below are two statements: One is labeled as Assertion (A) and the other is labeled
as Reason (R)
Assertion (A) Treatment of bromine water with propene yields 1-bromopropan-2-ol.
Reason (R) Attack of water on bromonium ion follows Anti Markovnikov rule and
results in the formation of 1-bromopropan-2-ol.
In the light of the above statements, choose the most appropriate answer from the options
given below.
1) Both Assertion and reason are true, but reason is not the correct explanation of
assertion.
2) Assertion is false, but reason is true.
3) Both assertion and reason are true, and reason is the correct explanation of assertion.
4) Assertion is true, but reason is false
Key: 4
Sol: Both Assertion and Reason are true and Reason is correct explanation of Assertion.

Br
CH 3CH  CH 2 
Br2
 CH 3  CH  CH 2 
H O
 CH 3  CH  OH   CH 2 Br
2

Markownikoff product
(NUMERICAL VALUE TYPE)
Section-II contains 10 Numerical Value Type questions. Attempt any 5 questions only. First 5 attempted questions will be considered if more than 5
questions attempted. The Answer should be within 0 to 9999. If the Answer is in Decimal then round off to the nearest Integer value (Example i,e. If
answer is above 10 and less than 10.5 round off is 10 andIf answer is from 10.5 and less than 11 round off is 11).
Marking scheme: +4 for correct answer, 0 if not attempt and -1 in all other cases.
3. Total number of covalent bonds between carbon and carbon atoms in C3O2 molecule is
____
Key: 4
Sol: O  C  C  C  O
4. The number of species given below that have two lone pairs of electrons on their central
atom is
SF4 , BF4 , ClF3 , AsF3 , PCl5 , BrF5 , XeF4 , SF6
Key: 2
Sol: SF4  1 L. P

BF4  O L. P

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ClF3  2 L. P

XeF4  2 L. P

5. Maximum number of planar atoms in SF6 molecule is___

Key: 5
Sol: SF6 Central atoms sulphur and four F atoms in same plane

*
6. Total number of e Present in ^ (pi*) molecular orbital of O2 , O2 , O2
Key: 6
O2  O2 
O2 
2 Pn1 2 p 1e 3e
Sol:
7. Number of molecules from the following which can exhibit hydrogen bonding is --------
(nearest integer)
NO2
CH 3OH ; H 2O; C2 H 6 ; C6 H 6 ; HF , NH 3

OH
Key: 5
NO2

CH 3OH ; CH 2O; ; 1F ; NH 3

Sol: OH
8. The number of different chain isomers possible for C6 H14
Key: 5
Sol: Total six different chain isomers for C6 H14 is possible. These are as follows.

Cl2  excess  / hv
 
9.
How many dichloro products are formed in the above reaction (including stereoisomers)?
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Key: 7
Cl
Cl Cl Cl

* Cl
Cl2  excess 
  * 
 3stereoisomers 
Cl
Sol:   3stereoisomers

10. 3-methylpent 2-ene on reaction with HBr in presence of peroxide forms an addition
product (A). The number of possible stereoisomers for ‘A’ is……..
Key: 4
Sol: The complete reaction is as follow
HBr * *
CH 3  CH  C  CH 2  CH 3 CH 3  CH  CH  CH 2  CH 3
Peroxide
CH 3
3  methylpent  2  ene Br CH 3
 A

Number of stereocenter  n   2

Number of possible stereoisomers  2 n  2 2  4

11. How many isomers with molecular formula C6 H12 gives Acetaldehyde in reductive
ozonolysis as one of product
Key: 6
Sol: C  C  C  C  C  C cis & trns
C

C  C  C  C  C cis & trns

C  C  C  C  C cis & trans

Total six isomers give acetaldehyde on reductive ozonolysis.

12. How many alkenes on catalytic hydrogenation given isopentane as a product?
Key: 3

H 2 Pt

H 2 Pt

H 2 Pt
Sol:
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RPTM-04
(SINGLE CORRECT ANSWER TYPE)
This section contains 20 multiple choice questions. Each question has 4 options (1), (2), (3) and (4) for its answer, out of which ONLY ONE option can be
correct.
Marking scheme: +4 for correct answer, 0 if not attempted and –1 in all other cases.
1. Statement–I: Sulphate of element ‘A’ has the formula ASO4
Statement –II: Nitride of same element has the formula A3 N 2
1) Statement – I is true, statement – II is true; Statement – II is correct is a correct
explanation for statement – I.
2) Statement – I is true, statement – II is true; statement – II is not correct explanation for
statement – I
3) Statement – I is true; statement – II is false
4) Statement – I is false; statement – II is true
Key: 1
Sol: The valency of ‘A’ Is +2 and Nitride is -3.
2. If 1.15% by mass of sodium is present in 500g of solution of NaOH in water. The
molality of the solution is
1) 0.15 2) 0.75 3) 0.25 4) 0.5
Key: 4
wt of solute 1000
Sol: m 
molecular weight of solute Weight of solvent
3. ' P ' gm of sodium hydrogen carbonate on strong heating gives ' Q ' gm of solid residue and
0.112 L of CO2 at S.T.P. The normality of solution obtained by dissolving solid residue
in
500ml water is
1) 0.5 2) 0.3 3) 0.1 4) 0.02
Key: 4

Sol: 2NaHCO3  Na2CO3  H 2O  CO2

weight 1000
Normality 
equivalent weight vol in ml
4. Choose the correct statement (s) regarding alkynes.
Statement-I: All alkynes are gases at room temperature
Statement-II: Except ethyne, alkynes are odorless
1) Statement-I and II are true 2) Statement-I is true II is false
3) Statement-I is false II is true 4) Statement-I and II are false
Key: 3
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C2  C4 gases  C13 Solids
C5  C12 Liquids
Sol:
(NUMERICAL VALUE TYPE)
Section-II contains 10 Numerical Value Type questions. Attempt any 5 questions only. First 5 attempted questions will be considered if more than 5
questions attempted. The Answer should be within 0 to 9999. If the Answer is in Decimal then round off to the nearest Integer value (Example i,e. If
answer is above 10 and less than 10.5 round off is 10 andIf answer is from 10.5 and less than 11 round off is 11).
Marking scheme: +4 for correct answer, 0 if not attempt and -1 in all other cases.
5. The mole fraction of sucrose  C12 H 22O11  in an aqueous binary solution is 0.2. the mass
percentage of sucrose in the solution is, _____ (nearest integer)
Key: 83

number of moles of sucrose

Sol: mole fraction of sucrose=
total number of moles
weight of sucrose
mass percent of sucrose=  100
total weight of solution
6. The degree of unsaturation for Naphthalene is ____
Key: 7

Sol: Degree of unsaturation = No of bond + number of rings

527

7. 0.6g of an organic compound (A) with 40% carbon will produce _______ 103 liter of
CO2 at STP on complete combustion (Molar volume  22.4 )
Key: 448

0.6 g  100% 0.6  40 12 g  22.4

Sol: ;  0.24;
?  40% 100 0.24  ?
8. How many different isomeric alkynes on catalytic hydrogenation can give 2,3,4, -
trimethyl heptane
Key: 8

6 *
5 * 2 2 H 2 / pt
4 * *
7 3 1
Sol:
4,5,6-trimethyl -1-hept ne

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* 2 2 H 2 / pt
* 1
7 6 5 4 3

4,5,6- Trimethyl hept – 2-yne

9. The density of 1.4M solution of sulphuric acid is 1.372 g/ml. the percentage by mass of
solution will be ____
Key: 10
% w / w  density  10
Sol: M 
mol.wt of solute
10. How many of the following are Meta directing groups in electrophilic substitution in
benzene nucleus is/are
O O O
O  C  CH 3 ,  C  O  CH 3 ,  NH  C  CH 3 ,  NH 2
Key: 1

O
C  O  CH3
Sol: is a meta directing group
11. One litre of an alkene with the formula C x H y [mol. wt- 56 ] reacts with ‘X’ litres of
oxygen for its complete combustion at STP. The value of ‘X’ is
Key: 6
Sol: C4 H 8  6O2  4CO2  4 H 2O
12. The number of atoms present in 32g of oxygen gas is [At wt of ' O '  16 ] A 1023
 N  6  1023  the value of ‘A’ is
 A 
Key: 12
Sol: moles  N A  2
cold dil alk KMnO4
1  Butyne A  CO2
13. The total number of SP 2 hybrid orbitals
present in
product A.
Key: 3

cold .dil.alk
CH 3  CH 2  C  C  H CH 3  CH 2  COOH  CO2
KMnO4
Sol:
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RPTM-05
(SINGLE CORRECT ANSWER TYPE)
This section contains 20 multiple choice questions. Each question has 4 options (1), (2), (3) and (4) for its answer, out of which ONLY ONE option can be
correct.
Marking scheme: +4 for correct answer, 0 if not attempted and –1 in all other cases.
1. The decreasing order of reactivity of the following compounds towards nucleophilic
substitution reaction is

1) (II>(III)>((I)>(IV) 2) (II)>(III)>(IV)>(I)
3) (III)>(II)>(IV)>(I) 4) (IV>(II)>(III)>(I)
KEY: 2
SOL: Conceptual

2. An 'Assertion' and 'Reason' are given below. Choose the correct answer from the
following options.

Assertion (A): Vinyl halides and Aryl halides do not undergo nucleophilic substitution
easily.
Reason (R): Even though the intermediate carbocation is stabilized by loosely held π-
electrons, the cleavage is difficult because of strong bonding.
1) Both (A) and (R) are wrong statements
2) Both (A) and (R) are correct statements and (R) is the Correct explanation of (A)
3) Both (A) and (R) are correct statements but (R) is not the correct explanation of (A)
4) (A) is a correct statement but (R) is a wrong statement.
KEY: 4
SOL: Conceptual
3.

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Cl
Br


Aqueous . KOH
 Product

NO2

The product mixer obtained is treated with AgNO3 solution correct statement is

1) A pale-yellow precipitate of AgBr is formed 2) A white precipitate of AgCl is formed

3) No precipitate is formed 4) It is a nucleophilic addition substitution reaction
KEY: 2
SOL: Conceptual
4. Ratio of mole of FeSO4 oxidized by equal volume of equimolar K 2Cr2O7 and KMnO4
solution in acidic medium is

1) 6: 5 2) 5 : 6 3) 5 : 3 4) 3 : 5

KEY: 1
SOL: Conceptual
(NUMERICAL VALUE TYPE)
Section-II contains 10 Numerical Value Type questions. Attempt any 5 questions only. First 5 attempted questions will be considered if more than 5
questions attempted. The Answer should be within 0 to 9999. If the Answer is in Decimal then round off to the nearest Integer value (Example i,e. If
answer is above 10 and less than 10.5 round off is 10 andIf answer is from 10.5 and less than 11 round off is 11).
Marking scheme: +4 for correct answer, 0 if not attempt and -1 in all other cases.
5. The total number of monohalogenated organic products in the following (including
stereoisomers) reaction is ….
( i ) H 2 / Ni / 
A ( ii ) X 2 / 

( simplet optically
active hydrocarbon alkene )

KEY: 8
SOL: Conceptual

6. Identify number of substrates those can give S N 1 and S N 2 reactions both:

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CH 3

H 3C Cl Br

CH 2 Br O Cl
CH 3 Br , Ph H 3C
, , ,
OTf
Br Cl

Cl
O CH 3 CH 2 Cl
, , , ,
Br

KEY: 6
SOL: Conceptual

7. CHCl3 Ag
powder
 ‘A’ 
5000 C
 ’B’ 
Cu red hot
CH 3COCl
AlCl3
 ‘C’ 
PCl5
 ‘D’ 
3 NaNH
 ‘E’ 2

 ‘F’   ‘G’ The number of oxygen atoms in ‘G’ are``

HgSO4 / H 2 SO4

CH 3 I

KEY: 1
SOL: Conceptual

8. Total number of species from the following which can undergo disproportionation
reaction is ……. H 2O2 , ClO3 , P4 , Cl2 , Ag , Cu 1 , F2 , NO2 , K 

KEY: 6
7 3 4
SOL: K MnO4  H 2 C2 O4  Mn 2  C O2 (Unbalanced) (n factor =5) (n factor = 1 2  2 n factor of
KMnO4

nKMnO4  Change in O.N. of Mn × no. of atoms in 1 molecule of KMnO 4=5×1=5

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N factor of H 2C2O4
n
H 2C2O4  changeinO.N .of C ×no. of atoms in 1 molecule of H 2C2O2 = 1  2  2

By law of equivalence:

Equivalents of KMnO4  Equivalents of H 2C2O4

N factor of KMnO4  moles of KMnO4 =n factor of H 2C2O4 = n factor H 2C2O4  moles of

H 2C2O4

5 milli moles of KMnO4 =2× mill moles of H 2C2O4

5× M KMnO 4  VKMnO4  (in mL )  2  M H 2C2O4  VH 2C2O4 (in mL )

5  M KMnO4  2mL  2  2 M  2mL

M KMnO4  8M

9. When 10 ml of an aqueous solution of KMnO4 was titrated in acidic medium, equal

volume of 0.1 M of an aqueous solution of ferrous sulphate was required for complete
discharge of colour. The strength of KMnO4 in grams per litre is …. 10 2 .

[Atomic mass of K = 39, Mn = 55, O = 16]

KEY: 316
SOL: In acidic medium MnO  of KMnO4 changes to Mn 2

MnO4  5e  Mn2 .....(i)

Fe2  Fe3  e ..........(ii)

eqn.(1)  1  eqn(2)  5

MnO4  5Fe2  pdt

M 1V1 M 2V2

1 5

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M 1 10 0.110

1 5

1 1
M1   KMnO4 is mol per litre
50 50

1
Thus KMnO4 is  158g per litre
50

Thus strength = 3.16 g/L

3.16 g/L

316×10-2 g/L


10. 2MnO  4  bI   x I 2  yMnO2  z O H . If the above equation is balanced with integer

coefficients the value of z is

KEY: 8
SOL: In a disproportionation reaction an element in one oxidation state is simultaneously
oxidized and reduced. (a) and (b) are disproportionation redox reactions.

11. One gram of metallic chloride was found to contain 0.835 g of chlorine. Its vapour
density is 85.5. If its molecular formula is M x Cl y , then what is value of ( x  y ) ?
KEY: 5
SOL: Molar mass of M 2 Cl y =85.5×2= 171 g/mol

(M)(x)+(35.5) (y) =171

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mass of chlorine 0.835 35.5 y
 
mass of metallic chloride 1 M ( x)  (35.5)( y )

On solving y = 4 and x = 1

X+y=5

12. When BrO3 ion reacts with Br  ion in acidic medium, Br2 is liberated. Calculate the ratio
of molecular mass and equivalent mass of KBrO3
KEY: 5
5 1 0
SOL: BrO3  Br   H   Br2 (l )

n-factor =5

M KBrO3
EKBrO3 
5

13. A sample of 28 ml of H2O2 (aq) solution required 10mL of 0.1 M KMnO4 (aq) solution for
complete reaction in acidic medium. What is the volume strength of H2O2 ?
KEY: 1
SOL: eq. of H 2O2  Eq of KMnO4

(25×M×2)=(10×0.1×5)

M=0.089

Volume strength =M×11.2=1

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RPTM-06
(SINGLE CORRECT ANSWER TYPE)
This section contains 20 multiple choice questions. Each question has 4 options (1), (2), (3) and (4) for its answer, out of which ONLY ONE option can be
correct.
Marking scheme: +4 for correct answer, 0 if not attempted and –1 in all other cases.
1. Consider the following table.
Gas a / k Pa ( dm6mol 2 ) 
b / d dm3mol 1 
A 642.32 0.05196
B 155.21 0.04136
C 431.91 0.05196
D 155.21 0.4382
a and b are van der Waals’ constants. The correct statement about the gases is:
1) Gas C will occupy lesser volume than gas A; gas B will be lesser compressible than gas D.
2) Gas C will occupy more volume than gas A; gas B will be more compressible than gas
D.
3) Gas C will occupy more volume than gas A; gas B will be lesser compressible than
gas D
4) Gas C will occupy more volume than gas A; gas B will be lesser than gas D.
Key: 2
 a 
Sol: . For 1 mole of real gas, the van der Waals’ equation is  p   (V  b )  RT
 V2 

The constant ‘a’ measures the intermolecular force of attraction of gas molecules and the

constant ‘b’ measures the volume correction by gas molecules after a perfectly inelastic
binary collision of gas molecules.

For gas A and gas C given value of ‘b’ is 0.05196 dm3 mol 1 .Here, a  intermolecular
force of attraction  compressibility  real nature  1/volume occupied value of
a / (kPa dm6 mol 1) for glass A (642.32)>gas C (431.91) So, gas C will occupy more
volume than gas A. Similarly, for a given value of a say 155.21kPa dm3 mol 1 for gas B
and gas D 1/b  intermolecular force of attraction  compressibility  real nature  1/
volume occupied

b/( dm3 mol 1 ) for gas B(0.04136)< gas D (0.4382)

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So, the gas B will be more compressible than gas D.

2. Two flasks I and II shown below are connected by a value of negligible volume.

When the value is opened, the final pressure of the system in bar is x  102 . The value of
x is ………… (integer answer) [Assume, Ideal gas, 1 bar = 105 pa, molar mass of
N 2  28.0 g mol 1; R  8.31 J mol 1k 1 ]
1) 34 2) 59 3)84 4) 14
Key: 3

Sol: .

On mixing the temperature of gas become T. Internal energy lost by has A is the internal
energy gained by gas B.

U A  U B

f f
n A RTA  nB RTB (As both gases are diatomic, f is same on both sides)
2 2

n ATA  nB TB

2.8 0.2
 T1  T   T  T2 
28 28

1 1
 300  T   T  60 
10 140

T  248K

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On mixing temperature becomes 284 K and volume becomes 3L and total number of
moles becomes  n A  nB   0.10 moles.

0.10  8.3  284

According to gas equation, pV   n A  nB  RT   84.13atm or 84.18 bar
3

This is final pressure of gas.

3. Which is valid at absolute zero?

1) KE of the gas becomes zero, but molecular motion does not become zero.
2) KE of the molecules becomes zero and the molecular motion also becomes zero.
3) KE of the gas decreases but does not become zero.
4) KE of the gas decreases but molecular motion increases.
Key: 2
Sol: A fact at zero Kelvin.
(NUMERICAL VALUE TYPE)
Section-II contains 10 Numerical Value Type questions. Attempt any 5 questions only. First 5 attempted questions will be considered if more than 5
questions attempted. The Answer should be within 0 to 9999. If the Answer is in Decimal then round off to the nearest Integer value (Example i,e. If
answer is above 10 and less than 10.5 round off is 10 andIf answer is from 10.5 and less than 11 round off is 11).
Marking scheme: +4 for correct answer, 0 if not attempt and -1 in all other cases.

4. An open steel vessel has an ideal gas at 270 C . The fraction of the gas escaped if the
vessel and its contents are heated to 1270 C is x  102 . (Neglect the expansion of the
steel). x value is ___
Key: 25
Sol: n1T1  n2T2

300
n2 
400

The fraction of gas escaped from vessel upon heating 1-3/4=1/4

5. A balloon has a maximum capacity of 20L. At one atmosphere pressure less than 10L of
air is filled in the balloon. It will burst when pressure is x  101 atm. (assuming
isothermal condition). x value is ___
Key: 5
Sol: The balloon would burst when V> 20 L

1 1  P2V2
PV

110  P2  20

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P2  0.5 atm (no bursting)

Thus, a pressure below 0.5 atm, it would burst.

6. Calculate the kinetic energy of 1 mole of oxygen molecules in cal mol 1 at 270 C is--------
---
Key: 900
3 3
Sol: KE  nRT   1  2  300 = 900
2 2
7. Two grams of hydrogen diffuse from a container in 10 minutes. How many grams of
oxygen would diffuse through the same container at the same time under similar
conditions?
Key: 8
nH 2 MO2
Sol: 
nO2 M H2

2
2
2  3  16  4
wO2 2
32

32
wO2   8 gm
4

8. How many structural cyclic ethers are possible for C 4H8O _________
Key: 6
Sol:

9. How many monohydric phenols are possible for the molecular formula C7 H8O _______
Key: 3
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OH OH OH

CH 3

CH 3

CH 3
Sol:
10. How many structural primary alcohols are possible for C5H12O ________
Key: 4
C

C  C  C  C  C  OH C  C  C  C  OH
Sol:

C C
CCCOH CCCOH
C C
11. How many given compounds can react with NaOH _______

C2H5OH,CH3COOH,C6H5OH,Picric acid
Key: 3
Sol: CH3COOH , C6 H5OH , Picric acid.

Because they are more acidic than water.

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RPTM-07
(SINGLE CORRECT ANSWER TYPE)
This section contains 20 multiple choice questions. Each question has 4 options (1), (2), (3) and (4) for its answer, out of which ONLY ONE option can be
correct.
Marking scheme: +4 for correct answer, 0 if not attempted and –1 in all other cases.
1. Which of the following statements is incorrect?
1) In equilibrium mixture of ice and water kept in perfectly insulated flask mass of ice
and water does not change with time.
2) The intensity of red colour increases when oxalic acid is added to a solution
containingiron (III) nitrate and potassium thiocyanate.
3) On addition of catalyst the equilibrium constant value is not affected
4) Equilibrium constant for a reaction with negative H value decrease as the temperature
increase
Key: 2
Sol: The red color intensity remains constant

2. Assertion (A): In the dissociation of PCl5 at constant pressure and temperature addition of
helium at equilibrium increases the dissociation of PCl5
Reason (R): Helium removes Cl2 from the equilibrium mixture.
1) Both A and R are true, and R is correct explanation of A
2) Both A and R are true, but R is not correct explanation of A
3) A is true but R is false.
4) Both A and R are false.
Key: 3
Sol: Conceptual
3. The major product of the following reaction is:
1)DIBAL  H
2)H 3O 

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OH

CHO

1) CH2-CHO 2) CH2OH

OH

3) CH2-CHO 4)
Key: 3
DIBAL  II
Sol: a ) R  CN   R  CHO
DIBAL  II
b) RCOOR '   R  CHO  R ' OH
1) AlH  i  Bu  2 ?
R C  N
2)H 3O 
4.
Consider the above reaction, when in reagent hydrogen atom is replaced by deuterium.
The product formed is
1) R  CHO 2) R  CONH 2 3) R  COND2 4) R  CDO

Key: 4
N-Al (i-Bu2)

D
Sol: DIBAL  D
R  C  N   R

5. Statement-(I): A buffer solution is the mixture of a salt and an acid or a base mixed in any
particular quantities.
Statement-(II) Blood is naturally occurring buffer solution whose pH is maintained by
H 2CO3 / HCO 3 concentrations
Choose the most appropriate answer from the options given below.
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1) Statement I is incorrect, but statement II is correct
2) Both statement I and statement II are incorrect
3) Statement-I is correct but Statement II is incorrect
4) Both statement -I and statement II are correct
Key: 1
Sol: Acidic buffer: solution of weak acid and its salt with strong base.

Basic buffer: solution of weak base and its salt with strong acid

(NUMERICAL VALUE TYPE)

Section-II contains 10 Numerical Value Type questions. Attempt any 5 questions only. First 5 attempted questions will be considered if more than 5
questions attempted. The Answer should be within 0 to 9999. If the Answer is in Decimal then round off to the nearest Integer value (Example i,e. If
answer is above 10 and less than 10.5 round off is 10 andIf answer is from 10.5 and less than 11 round off is 11).
Marking scheme: +4 for correct answer, 0 if not attempt and -1 in all other cases.
6. How many different aldehyde isomers (including stereo isomers) exist for C5 H10O
Key: 5

CHO
CHO CHO
* 3) 4)
1) CHO 2)
Sol:

3CH  CH 
Fe
 A 
CH 3Cl
B
1 2Cl2 / h X
7.  AlCl3
 2  H 2O / 
How many C-atoms are present in x
Key: 7
A  C6 H 6
Sol: B  C6 H 5CH 3
C  C6 H 5CHO

8. A buffer solution contains 0.2 mole of NH 4OH and 0.2 mole of NH 4Cl per liter. The P of kb

NH 4OH is 4.75 calculation the P H of the buffer (Round off to nearest integer)

Key: 9
salt 0.2
Sol: P kb  log  4.75  log
base 0.2

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 P  14  P
H OH
 14  4.75 =9.25
10. What is the sum of basicity of H3 PO4 , H3 PO2 , H 3 BO3 ,

 COOH 2 , H 2 S2O8 , H 2 SO3 , H 2CO3 , H 2 S , H 4 P2O5 , H 2 SO4

Key: 21
Sol: H 3 PO4  3, H 3 PO3  2, H 3 PO2,  1, H 3 BO3  1,  COOH 2  2

H 2 S2O8  2 H 2 SO4  2, H 2 SO3  2, H 2CO3  2, H 2 S  2, H 4 P2O7  4

11. If Ksp of Ag2CO3 is 8 1012 , the molar solubilities of Ag2CO3 in 0.1 M AgNO3 is___ 1010
Key: 8
2
Sol: K SP   Ag   CO32 

8  1012  0.1 CO32 

2

CO3 2   8  1010

OH

Pcc  excess 
OH  A

12.
Number of oxygen atoms in product ‘A’ is
Key: 2
O
OH
CHO

OH
PCC

Sol:
13. Vanillin compound obtained from vanilla beans. The ratio of number of SP 2 hybridised
carbon atoms and the number of pi bonds present in vanillin is “X”. Find the value of
4X?
Key: 7
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Sol:
14. Calculate the approximate PH of a 0.1M H 2 S  aq  solution. The first and second
dissociation constant of H 2 S are 1 10 7 and 1.3  1014 respectively
Key: 4
Sol:  H 2S   0.1  x  0.1
 H  HS   x Ka  Ka
  2
1 2

1 107  x2 / 0.1 , x  1 104   H  

 P H  4.
 NH 3  H 2 S is Kp  12
NH 4 HS 
15. If 250 C , the equilibrium constant for the reaction
s g g
A 10.0 liter flask is discharged with 1 atm of pure NH 3  g  at 250 c what is the minimum

mass in grams of NH4 HS , that must be added to the flask in order to achieve equilibrium?
(round off the nearest integer)
Key: 63
NH 4 HS  NH 3  H 2 S KP  PNH 3 .PH 2S
Sol: S  g g 12   p  1 p
p 1 p p  3 atm

Applying ideal gas equation for H 2 S

PV  nRP
3 10  n  0.0821 298, n  1.2262
 moles of NH 4 HS is =1.2262

Wt. of NH 4 HS  1.2262  51  62.54 g  63 g

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RPTM-08
(SINGLE CORRECT ANSWER TYPE)
This section contains 20 multiple choice questions. Each question has 4 options (1), (2), (3) and (4) for its answer, out of which ONLY ONE option can be
correct.
Marking scheme: +4 for correct answer, 0 if not attempted and –1 in all other cases.
1. Identify the reagents used for the following conversion

1) A  LiAlH 4 , B  NaOH  aq , C  NH 2  NH 2 / KOH , Ethylene glycol

2) A  DIBAL  H , B  NaOH  aq  , C  NH 2  NH 2 / KOH , Ethylene glycol

3) A  DIBAL  H , B  NaOH  aq , C  Zn / HCl ,

4) A  LiAlH 4 , B  NaOH  aq , C  Zn / HCl ,

Key: 2
OCH3
DIBAL-H CHO
O NAOH(aq)
OH CHO aldol
CHO OH
Sol: .

CHO

NH2NH2/KOH
ethylene glycol

OH
2. In the given reaction the main product will be

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1) 2)

3) 4)
Key: 1

CH MgBr

3

O O OMgBr



H

O O
Sol: Me
3. Reagent that can be differentiate 2-propanol from acetone is
3) Ce  NO3 4
 2
1) NaOH / I 2 2)  Ag  NH 3 2  4) Cu  NH 3 4 

Key: 3
Sol: Ce  NO3 4 is used to differentiate

4. Me3B, BH3 and BF3 are three Lewis acids, which one of the following is the correct
sequence of acid strength?
1) Me3 B  BH 3  BF3 2) Me3 B  BF3  BH3
3) BF3  BH3  Me3 B 4) BF3  Me3 B  BH3
Key: 4
Sol: Lewis acids are electron deficient species, A species with more deficient central atoms
will be a strong Lewis acid. F being an electron with drawing group, makes B more
deficient but on the other hand, it decreases the deficiency by back bonding. H is unable

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to do such a back bonding due to the absence of lone pair. Me is an electron releasing
group. Thus, makes the boron least electron deficient.
5. Assertion (A): The stability of superoxide’s of alkali metals follows the order
CsO2  RbO2  KO2

Reason (R): As the size of alkali metal ion increases the lattice energy increases and
hence the stability of super oxides increases
1) Both (A) and (R) are true and (R) is correct explanation of (A)
2) Both (A) and (R) are true but (R) is not correct explanation of (A)
3) (A) is true but (R) is not true
4) (A) is not true (R) is true
Key: 1
Sol: Both (A) and (R) are true and (R) is the correct explanation of (A)
(NUMERICAL VALUE TYPE)
Section-II contains 10 Numerical Value Type questions. Attempt any 5 questions only. First 5 attempted questions will be considered if more than 5
questions attempted. The Answer should be within 0 to 9999. If the Answer is in Decimal then round off to the nearest Integer value (Example i,e. If
answer is above 10 and less than 10.5 round off is 10 andIf answer is from 10.5 and less than 11 round off is 11).
Marking scheme: +4 for correct answer, 0 if not attempt and -1 in all other cases.
6. How many of the following can be used to distinguish acetaldehyde and benzaldehyde
(i) Tollen’s (ii) Fehling’s (iii) Benedict’s (iv) NaHSO3 (V) NaOI
(vi) 2,4-DNP (vii) CAN (viii) NaHCO3 (ix)NaOH/I2 (X) Lucas
reagent (xi) Neutral FeCl3
Key: 4
Sol: ii, iii, v, ix,  +ve test with Acetaldehyde
I, iv,vi,  +ve test with both Acetaldehyde and Benzaldehyde
Vii,viii, x, xi  -ve test with both

7.
Number of halogens, hydrogen and carbon atoms in the molecular formulae of compound
‘A’ are x, y, z respectively. Find x+ y- z value.
Key: 3
Sol: A is CHCl3
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X =3 , Y = 1 , Z = 1
X +Y –Z = 3 +1 – 1= 3

8.
Find the value of 2 x  3 y  ________
Key: 17
Sol: Butanone +4 KOH +3 I 2  CH I 3 

X=4,y =3
2x + 3y = 2 (4)+3(3) = 8 + 9 = 17
Cl

NBS Aq.KOH CrO3/py/HCl

C D
A B
NaNH2
(excess)

Cl Cl

CH3
9.
Calculate the number of SP 2 hybrid orbitals of carbon atoms in the structure of ‘D’
Key: 21
Cl

CrO3 / Pg / HCl
3NaNH2 NBS
Cl
Cl
CH3
CH2Br CH2OH O=C-H
CH3 (B) (C) (D)
Sol: (A)

Total no. of Sp 2 carbons in ' D '  7

1S  2 P  3SP 2

7  3  21

10. How many of the following undergo disproportionation on reaction with NaOH

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i) Cl2 ii) S iii) P( white) iv) B v) Si vi) Al vii) Hg
Key: 3
Sol: P4  s   3OH   aq   3H 2O(l )  PH 3  g   3H 2 PO2  aq 

S8  s   12OH   aq   4S 2  aq   2S 2 O32  aq   6 H 2O(l )

Cl2 ( g )  2OH   ClO   aq   Cl   aq   H 2O  l 

11. How many water molecules are associated with “EPSOM Salt”?
Key: 7
Sol:
12. How many of the following pairs show similarity in their radii?
Li  ; Mg 2 ; Na , Ca 2 ; K  , Sr 2 ; Be2 , Al 3 ; B , Si; N , S ; F , Ar ; Mg 2 , Al 3

Key: 2
Sol: MgSO4 7 H 2O

13. How many of the following salts gives Borax bead test.
1) Copper salts 2) Cobalt salts 3) Nickel salts 4) Aluminium salts
Key: 3
Sol: ‘3’ [Copper salt, cobalt salts, Nickel salts]
14. How many compounds given below are correctly matched with their uses?
1) Borax solution : Buffer
2) AlCl3 : Friedel-crafts reaction
3) Ca  OH 2 : Bleaching powder

4) CaCO3 : mild abrasive in tooth paste

5) B(OH )3 : Manufacture of heat resistant glasses
6) NaBH4 : Reducing Agent
Key: 6
Sol: All are correct

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RPTM-09
(SINGLE CORRECT ANSWER TYPE)
This section contains 20 multiple choice questions. Each question has 4 options (1), (2), (3) and (4) for its answer, out of which ONLY ONE option can be
correct.
Marking scheme: +4 for correct answer, 0 if not attempted and –1 in all other cases.
1. The correct statement among the following is.
1) ( SiH 3 )3 N is planar and more basic than  CH3 3 N

2) ( SiH 3 )3 N is pyramidal and more basic than  CH3 3 N

3) ( SiH 3 )3 N is planar and less basic than  CH3 3 N

4) ( SiH 3 )3 N is pyramidal and less basic than  CH3 3 N

Key: 3
Sol: In  SiH 3 3 N , “Si” has vacant d- orbital it’s overlap with lone- pair electron from
nitrogen, due to overlapping it is in planar

2. The increasing order of the acidity of the following carboxylic acids is?

1) III  IV  I  II 2) IV  III  I  II 3) II  I  IV  III 4) I  II  III  IV

Key: 1
Sol: Acidic strength of benzoic acid depends on nature of the substituent on benzene ring

Note: Ortho substituted benzoic acid is stronger acid (due to ortho effect)

3.
The major product is.
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1) 2)

3) 4)
Key: 2
Sol:

(NUMERICAL VALUE TYPE)

Section-II contains 10 Numerical Value Type questions. Attempt any 5 questions only. First 5 attempted questions will be considered if more than 5
questions attempted. The Answer should be within 0 to 9999. If the Answer is in Decimal then round off to the nearest Integer value (Example i,e. If
answer is above 10 and less than 10.5 round off is 10 andIf answer is from 10.5 and less than 11 round off is 11).
Marking scheme: +4 for correct answer, 0 if not attempt and -1 in all other cases.
4. The number of ions from the following that are expected to behave as oxidizing agent is
___
Sn 4 , Sn 2 , Pb 2 , Ti 3 , Pb 4 , Tl 
Key: 2

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2 3
Sol: Pb , Tl act asa a oxidizing agents (due to inert pair effect)

5. Total number of pi (  ) bonds in CO2 , C3O2 molecules _____________

Key: 6
Sol: CO2 O  C  O 2 Pi( )  bonds

C3O2 O  C  C  C  O 4 Pi( )  bonds

SIX Pi ( )  bonds

6. ‘CO’ forms carboxy hemoglobin on combining with hemoglobin. It is

X
‘X’ times stronger than oxy- Hemoglobin complex, then is _____________
2
Key: 150
Sol: Carboxy- Haemoglobin 300 times stable than oxy-Haemoglobin

7. How many moles of CO2 will released when following compound on heating?

Key: 4
Sol:  - Keto carboxylic acids undergo decarboxylation

8. Sodium benzoate
NaOH  CaO Conc  H 2 SO4

X 
Cl2 , FeCl3
310 320 K
 Y  
 Z ( Major product )
Gram molecular weight of the major product (in grams) is __________ (Nearest Integer)
Key: 193
Sol: Molecular weight = 192.5

9. How many bromine atoms are there in the final product in the reaction? __________
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Key: 3

Sol:
10. How many of the following reagents can be used to convert carboxylic acid to the
corresponding acid chloride?
i) NaCl ii) Cl2 iii) PCl3 iv) PCl5 v) SOCl2
Key: 3
Sol: PCl3, PCl5, and SOCl2 can be used for this conversion.

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RPTM-10
(SINGLE CORRECT ANSWER TYPE)
This section contains 20 multiple choice questions. Each question has 4 options (1), (2), (3) and (4) for its answer, out of which ONLY ONE option can be
correct.
Marking scheme: +4 for correct answer, 0 if not attempted and –1 in all other cases.
1. SbF5 reacts with XeF4 to form an adduct. the shape of cation and anion in the adduct are
respectively
1) Square planar, trigonal bi pyramidal 2) T-shaped, Octahedral
3) Square pyramidal, octahedral 4) Square planar, octahedral

Key: 2

Sol: XeF4  SbF5   XeF3  SbF6 

 

  XeF3   SbF6 
 

sp3d sp3d 2

T-shaped octahedral

2. The correct order of Cl–O bond length in ClO  , ClO2 , ClO3 , ClO4

1) ClO  ClO2  ClO3  ClO4

   
2) ClO4  ClO3  ClO2  ClO 

3) ClO3  ClO4  ClO2  ClO

   
4) ClO4  ClO3  ClO2  ClO 
Key: 2

Sol: Bond length is inversely proportional to bond order. Greater than delocalization of  e  (-
ve charge) shorter the bond length.

3. The major product (70% to 80%) of the reaction between m-dinitrobenzene with NH 4 HS
is

1) 2) 3) 4)

Key: 3

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Sol: With NH4HS, m-dinitrobenzene undergoes selective reduction to afford m-nitroaniline.
4. Which of the following gives positive Libermann–nitroso test?
1) 2–butanamine 2) N–ethyl–2–pentanamine
3) N–methylpiperidine 4) N, N–dimethylcyclohexylamine
Key: 2

Sol: 20 amine will give positive nitrosamine test.

CH3
|
CH3  CH 2  CH 2  C H  NH  Et
N-ethyl-2-pentamine)
2 0
a min e 

5. The product of a reaction between methyl isocyanate (MIC) and ethanol is urethane with
formula
1) CH 3  NHCOOC2 H 5 2) C 2 H 5  NHCOOCH 3

3) CH3  NHCOOCH3 4) C2H5  NH  COOC2H5

Key: 1
    CH3  N  C  OH 
Sol: CH3  N  C  O CH3 CH2 O H   |
 
Tautomerises

 OCH CH3
Methyl isocyanate 2


(NUMERICAL VALUE TYPE)

Section-II contains 10 Numerical Value Type questions. Attempt any 5 questions only. First 5 attempted questions will be considered if more than 5
questions attempted. The Answer should be within 0 to 9999. If the Answer is in Decimal then round off to the nearest Integer value (Example i,e. If
answer is above 10 and less than 10.5 round off is 10 andIf answer is from 10.5 and less than 11 round off is 11).
Marking scheme: +4 for correct answer, 0 if not attempt and -1 in all other cases.
6. 9.3 g of pure aniline upon diazotization followed by coupling with phenol gives an
orange dye. The mass of orange dye produced (assume 100% yield/conversion) is …….
g. (nearest integer)
Key: 20
Sol:

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1 mole of aniline give 1 mole of orange dye,

so  mol aniline   mol orange dye

9.3g mass of orange dye

1

93g mol 199g mol1

Mass of orange dye = 19.9 g = 20 g.

7. A compound (x) with molar mass 108 g mol1 undergoes acetylation to give product with
molar mass 192 g mol1 . The number of amino groups in the compound (x) is ….

Key: 2
O O
|| ||
Sol: R  NH 2  CH 3  C  Cl  R  NH  C  CH 3

Gain in molecular weight after acetylation with one  NH 2 Group is 42.

Total increase in molecular weight = 192 – 108 = 84

84
 number of amino groups  2
42
8. How many isomeric amines with the formula C7 H 9 N contain a benzene ring

Key: 5

Sol:
9. The number of moles of electrons involved in the reduction of one mole of nitrobenzene
by H 2 gas with Ni-catalyst is:

Key: 6
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Ni  catalyst
Sol: CH 3  NO2  6  H   CH 3  NH 2  2H 2O

10. Reaction of benzamide with Br2 in aqueous NaOH gives aniline, sodium carbonate and
sodium bromide. The stoichiometric coefficient of NaOH in the reaction is :
Key: 4
O
||
Sol: C6 H 5  C  NH 2  Br2  4NaOH  C6 H 5  NH 2  2NaBr  Na 2CO3  2H 2O

11. Cyclic trimer structure of SO 3 contains …… number of ‘S = O’ bonds.

Key: 6

Sol:
12. The sum of bond order in O 2 and O3 molecules is ……. (nearest integer)
Key: 4
Sol:

O=O
Bond order O 2 = 2, Bond order O3 = 1.5
13. The sum of lone pairs present in interhalogen BrF5 and IF7 is …….
Key: 37

Sol: BrF5 has 1 lone pair and IF7 has zero lone pair on central atom
F has 3 lone pairs
Total no. of lone pairs = [1 + 3(5)] + [0 + 7(3)] = 37
14. The ratio of number of p  p bonds to p  d bonds in XeO 3 is
Key: 0
Sol: p  p  0, p  d  3
15. What is covalency of chlorine atom in second excited state?
Key: 5
Sol: Conceptual

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RPTM-11
(SINGLE CORRECT ANSWER TYPE)
This section contains 20 multiple choice questions. Each question has 4 options (1), (2), (3) and (4) for its answer, out of which ONLY ONE option can be
correct.
Marking scheme: +4 for correct answer, 0 if not attempted and –1 in all other cases.
1. Ebonite is
1) Natural rubber 2) synthetic rubber
3) highly vulcanized rubber 4) poly propene
Key: 3
Sol: Huge cross linking substance

2. Statement 1: Glyptal is obtained by the condensation polymerization of ethylene glycol

and phthalic acid.
Statement 2: Glyptal is used in the manufacture of paints and lacquers.
1) Statement 1 is false, statement 2 is true
2)Statement 1 is true, statement 2 is true; statement 2 is not a correct explanation of
statement 1
3) Statement 1 is true, statement 2 is true; statement 2 is a correct explanation of
statement 1
4) Statement 1 is true, statement 2 is false
Key: 2
Sol: Due to cross links by Sulphur

3. Number of peptide linkages in the artificial sweetener “aspartame” is

1) 2 2) 21 3) 1 4) 11
Key: 1
Sol: Conceptual
4. How many base pairs are present in each full turn of the DNA double helix?
1) 4 2) 6 3) 8 4) 10
Key: 4
Sol: Conceptual
5. Isoelectric point is
1) the pH at which all molecular species are ionised and that carry the same charge
2) the pH at which all molecular species are neutral and uncharged
3) the pH at which half the molecular species are ionised (charged) and other half
unionized
4) the pH at which negatively and positively charged molecular species are present in
equal concentration
Key: 2
Sol: Conceptual
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6. (A): Lactose on hydrolysis gives glucose and galactose.
(R): Lactose is an example of disaccharide.
1) Both A and R are true and R is the correct explanation of A
2) Both A and R are true, but R is not the correct explanation of A
3) A is correct but R is not correct
4) A is not correct and R is correct
Key: 2
Sol: Conceptual
7. A. Ammonium salts produce haze in atmosphere.
B. Ozone gets produced when atmospheric oxygen reacts with chlorine radicals.
C. Polychlorinated biphenyls act as cleansing solvents.
D. 'Blue baby' syndrome occurs due to the presence of excess of sulphate ions in water.
Choose the correct answer from the options given below:-
1) A, B and C only 2) B and C only 3) A and D only 4) A and C only
Key: 4
 
Sol: B) C l  O3  O2  Cl O
(D) ‘Blue baby’ syndrome occurs due to the presence of excess of NO3 ions in water

8. (A): Polluted water may have a value of BOD of the order of 17 ppm.
(R): BOD is a measure of oxygen required to oxidize both the biodegradable and non-
biodegradable organic material in water.
1) Both A and R are true and R is the correct explanation of A
2) Both A and R are true, but R is not the correct explanation of A
3) A is correct but R is not correct
4) A is not correct and R is correct
Key: 3
Sol: A: Clean water should have B.O.D < 5ppm. While highly polluted water have

B.O.D > 17ppm.

R: Only Bio-degradable organic matter

(NUMERICAL VALUE TYPE)

Section-II contains 10 Numerical Value Type questions. Attempt any 5 questions only. First 5 attempted questions will be considered if more than 5
questions attempted. The Answer should be within 0 to 9999. If the Answer is in Decimal then round off to the nearest Integer value (Example i,e. If
answer is above 10 and less than 10.5 round off is 10 andIf answer is from 10.5 and less than 11 round off is 11).
Marking scheme: +4 for correct answer, 0 if not attempt and -1 in all other cases.
9. Sum of nitrogen atoms in the monomers of nylon-6 and nylon-6,6 is x and sum of carbon
y
atoms in them is y. Then is ___________
x
Key: 6
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Sol: C-atoms = 6 + 6 + 6 = 18 = y. (nylon – 6, Nylon – 6, 6)
N-atoms = 2 + 1 =3 = x
y/x = 18/3 = 6

10. In a polymer sample, 25% molecules have a molecular mass of 14,000, 50% have
molecular mass of 40,000 and rest have 50,000. Calculate the sum of mass average and
K
number average molecular masses = K then,  _____________(Nearest integer)
100
Key: 769
Sol: K = 76944
K/100 = 769.4

11. The total number of lone pairs of electrons in melamine is __________

Key: 6
Sol: Conceptual
12. How many compounds which is given below is isomer of D-Glucose?
a. D-Mannose, b. D-Fructose, c. D-Glucose, d. D-Idose, e. D-Galactose, f. D-Arabinose,
g. D-Ribose. ___________
Key: 5
Sol: a, b, c, d, e

13.
CH2OH
C=O

H OH

(i) NaBH4
HO H (P)
(ii) H+, H2O
H OH

CH2OH
D-sorbose
Numbers of stereoisomer of product (p) is: ____________
Key: 10
Sol: 241  2(4/2)1  10

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14. An atomic substance A of molar mass 12 g mol 1 has a cubic crystal structure with edge
length of 300 pm. The no, of atoms present in one unit cell of A is __________. (Nearest
integer). Given the density of A is 3.0 g mL1 and N A  6.02  1023 mol 1
Key: 4
d  N A  a3
Sol: Z
M
15. Atoms of an element B form hcp lattice and those of the element A occupy 2/3 rd of
tetrahedral voids. How many number of atoms of A and B (in total) are present in the
help lattice?
Key: 7
Sol: The ratio of A : B = 4 : 3
A4B3 A + B = 4 + 3 = 7

16. In CsCl with cubic structure, Cl- ions are located at each corner and Cs+ ions at the centre
 
of the unit cell. If rCs  and rCl  are 1.69 A and 1.81 A respectively. Find the value of edge
length of cube.
Key: 4
Sol: Body diagonal 3a  AB
2(rCs   rCl  )  3a

22(1.81  1.69)  3a
a  4.04 A

17. An element crystallizes into a structure which may be described by a cubic of unit cell
having one atom on each corner of the cube and two atoms on one of its diagonals.
Volume of the unit cell is 2.4 x 10-23 cm3 and density is 13.82 g cm-3. Number of atoms
present in 200 g of the element is y x 1023. What is the value of y?
Key: 18
ZM
Sol: d 3 30
g / cm3
N A  a  10
18. Calcium crystallizes in fcc unit cell with 0.556nm. Calculate the density in (g/cm3). It
contains 0.2% Frenkel defects and 0.1% Schottky defects. (Round off Nearest Integer)
Key: 2
Z eff  Aw
Sol: d
N A  a3

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RPTM-12
(SINGLE CORRECT ANSWER TYPE)
This section contains 20 multiple choice questions. Each question has 4 options (1), (2), (3) and (4) for its answer, out of which ONLY ONE option can be
correct.
Marking scheme: +4 for correct answer, 0 if not attempted and –1 in all other cases.
1. Henry’s law is valid for
A) Ammonia gas dissolution in water B) O2 gas dissolution in unsaturated blood
C) O2 dissolution in water D) Argon dissolution in water
1) A and B 2) B and C 3) C and D 4) B and D
Key: 3
Sol: For a gas is abey henry’s daw , it should not react with the liquid , Henry’s law is valid
for O2 and CO2 dissolution in water
2. What mass of non – volatile solute of urea to be dissolved in 100 g of water in order to
decrease it’s vapour pressure by 30% (consider solution is dilute)
1) 132.3 g 2) 100 g 3) 153.3g 4) 163.3 g
Key: 2
P 0  100 mm
P O  Ps  30 PO  P S
m1 W2
Sol:  X
100  Ps  30 PO m2 W1
p s  70
100  70 w2 x18

100 100 x60
w2 x18
0.3 
100 x 60

w2  100 g
3. The strength as oxidizing agent of following species in acidic medium decreases in the
order
2
2 2 
1) S 2O 8  Cr2O 7  MnO 4 2) C r2 O 2
7  S 2 O 8  M nO 4
 2 2
3) MnO4  Cr2O7  S2O8 4) S 2O8 2  MnO4  Cr2O72
Key: 4
Sol: S 2O82  2e  2So42 E 0  2.01V

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   2
MnO 4  8H  5e  Mn  4 H 2O E  1.77V O

Cr2o72  14 H   6e  2cr 3  7 H 2O E O  1.33V

The highest Eo value of atom is best oxidizing agent

4. The sum of the first three ionization energy of the lanthanoids Ce, Eu, Gd , Yb , Lu is
1) Ce > Eu > Gd > Yb > Lu 2) Yb > Lu > Eu > Gd > Ce
3) Yb > Eu > Lu > Gd > Ce 4) Yb > Eu > Gd > Lu > Ce
Key: 3

Sol: In lanthanoides from left to right size  I P 

Yb  Eu  Lu  Gd  Ce
5. Assertion (A): Zn 2 is diamagnetic nature.
Reason (R): The electrons are lost form 4s orbital to from Zn 2
Choose the correct option from following for above.
1) Both A and R are true, and R is the correct explanation of ‘A’
2) Both A and R true and R is not the correct explanation of ‘A’
3) A is true and R is false
4) A is false and R is true
Key: 2
Sol: Zn   Ar  3d 10 4s 2

Zn 2   Ar  3d 10 4 s 0
Zn 2 ion is diamagnetic nature due unpaired electrons absent in d orbitals both (A) and (R)

true and R is not the correct explanation of ‘A’

(NUMERICAL VALUE TYPE)
Section-II contains 10 Numerical Value Type questions. Attempt any 5 questions only. First 5 attempted questions will be considered if more than 5
questions attempted. The Answer should be within 0 to 9999. If the Answer is in Decimal then round off to the nearest Integer value (Example i,e. If
answer is above 10 and less than 10.5 round off is 10 andIf answer is from 10.5 and less than 11 round off is 11).
Marking scheme: +4 for correct answer, 0 if not attempt and -1 in all other cases.
6. 0.004M K 2 SO4 solution is isotonic with 0.01 M glucose solution. Percentage dissociation
of
K 2 SO4 is ______________ (Nearest integer)
Key: 75
Sol: Isotonic solution

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 K so   Glu cos e
2 4

i X 0.004 X RT  0.01 X RT
0.01
i   i  2.5
0.004
i  1  (n  1) 
For K 2 So4 ( for dissociation )   i  1  2.5  1  0.75
n 1 3 1
Dissociation = 75
7. How many of the following show positive deviation.
CS 2  CH 3  CO  CH 3 ; CS 2  CH 3  CO  CH 3 ; C6 H 6  C6 H 5CH 3 ;
CH 3  CO  CH 3  CHCl3 ; C2 H 5OH  H 2O ; C2 H 5 Br  C2 H 5Cl ;
C6 H 5OH  C6 H 5 NH 2 ; C2 H 5OH  CH 3  CO  CH 3
Key: 3
Sol: Positive deviation of Negative deviation
Of ideal solution of ideal solution.
H2 0  CH3COOH
H 2O  CH 3OH O

H 2O  C2 H 5OH CHCl3  CH3  C CH3
CHCl3  CCl4
H2O  HNO3
+ CH3OH
O

8. If Hg 2Cl2 is 100% ionized, then its vant’s Hoff’s factor is ______.

Key: 3
100
 1
100
Hg2cl2  Hg 2  2cl
n 3
Sol: i 1
 
n 1
i 1
1
3 1
2  i 1
i  1 2  3
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9. The number of moles of KMnO4 required to oxidise 20 moles of ferrous oxalate in acidic
medium is ______
Key: 12
Sol: The balanced reaction
1 0 F e C 2 O 4  6 K M n o 4  2 4 .H 2 S o 4  3 K 2 S o 4  6 M n S o 4
5 Fe( so3 )3  24 H 2o  2OOCO2

10 Fe c2o4 6 KMno4
20 mole s  x
206
x  12 moles
10
10. The sum of the sigma   and pie (  ) bonds are present in dichromate ion?
Key: 12
2
Sol: Dichromate ion Cr2o 7
O O
O O O
Cr Cr

O O
11. Total number for ions from the following with noble gas configuration is ___________
Sr 2 ( z  38) Cs  ( z  55) , La 2 ( z  57)
pb2 ( z  82) : Yb 2 ( z  70) , Fe 2 ( z  26)
Key: 2
Sol: Sr 2 ( z  38)   Kr  4s 0 ( noble gas )
Cs  ( z  55)  Xe 6s 0 (noble gas ).
12. Number of colorless lanthanide ions among the following is _______________
E u 3 , L u 3 , N d 3 , L a 3
Key: 2
Lu 3   Xe  4 f 14  f 14  n  o colourless
Sol:
La 3   Xe  4 f o  f o  n  o colourless
13. When HCl is passed over one mole of K 2Cr2O7 , the no moles of Cl2 formed is _______
Key: 3
K 2Cr2O7  14 HCl  2 KCl  2CrCl3  7 H 2O  3Cl2
Sol:
One mole of K 2Cr2O7 reacts HCl produces 3 moles of Cl2

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RPTM-13
SECTION-I (SINGLE CORRECT ANSWER TYPE)
This section contains 20 Multiple Choice Questions. Each question has 4 options (1), (2), (3) and (4) for its answer, out of
which ONLY ONE option can be correct.
Marking scheme: +4 for correct answer, 0 if not attempted and –1 in all other cases.
1. (A): The Daniel cell becomes dead after some time.
(R) : Oxidation potential of zinc anode increases and that of copper cathode decreases.
1) Both (1) and (R) are true and (R) is the correct explanation of (1)
2) Both (1) and (R) are true and (R) is not the correct explanation of (1)
3) (1) is true but (R) is false

4) (1) is false but (R) is true

Key: 1
0
Sol: Ecell becomes zero
2. Resistance of 0.2M solution of an electrolyte is 50 . The specific conductance of the
solution is 1.4 S m 1 . The resistance of 0.5M solution of the same electrolyte is 280 .

The molar conductivity of 0.5M solution of the electrolyte in S mol 1 is

1) 5  104 2) 5  103 3) 5  103 4) 5  102

Key: 1
1 1
Sol:   cm
k 1.4  102

l 1
 R   50  1.4  102 cm
a 

1
k  50  1.4  102  2.5  103 S cm1
280

k  1000 2.5  103  1000

^m  
M 0.5

5.5cm2mol 1  5  104 S m2mol 1

3. When aq. AgNO3 is subjected to electrolysis using inert electrodes, 10.8 grams of silver
is deptosited at cathode. Weight of oxygen liberated at anode will be

a) 1.6g 2) 3.2g 3) 0.8g 4) 0.4g

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Key: 3

WAg E Ag

WO2 E O2
10.8 108
Sol: 
WO2 8
WO2  0.8g
4. Statements are given below:
A) Leclanche cell -------- Reaction at anode Zn  Zn2  2e
B) Ni-Cd cell --------- Rechargeable
C) Fuel cell --------- Does not involve any ion in solution and is used in hearing
aids
D) Mercury cell --------- Converts energy of combustion into electrical energy
Choose the correct answer from the options given below:
1) A,B & C are correct 2) A and B are correct

3) A is correct 4) All are correct

Key: 2
Sol: A. Leclanche cell: It is commonly used dry cell in our clocks the cell consists of a zinc
container that also acts as anode and the cathode is a carbon (graphite) rod surrounded by
powdered managanese dioxide and carbon. The space between the electrodes is filled by
a moist paste of ammonium chloride and zinc chloride.

Anode reaction; Zn  s   Zn 2  2e 

Cathode reaction: MnO2  NH 4  e  MnO  OH   NH 3

B. Ni  Cd Cell: it is a rechargeable cell. It is more expensive to manufacture than lead

storage battery.

Cd  s   2 Ni  OH 3  s   CdO  s   2 Ni  OH 2  s   H 2O  l 

C. Fuel cell: these are galvanic cells that are designed to convert the energy of
combustion of fuels like hydrogen, methance methanol, etc. directly into electrical
energy.

D. Mercury cell:

Zn  Hg   HgO  s   ZnO  s   Hg  l 
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The cell potential is approximately 1.35 V and remains constant during its life as the
overall reaction does not involve any ion in solution whose concentration can change
during its life time.
5. Regarding the process involving discharge of lead storage battery, the correct statements
are
A) Lead sulphate is formed. B) Sulphuric acid is consumed.
C) Specific gravity of sulphuric acid decreases. D) Lead undergoes oxidation.
1) B and D only 2) A, B and D only
3) A, B, C and D 4) B and C only
Key: 3
Sol: During the discharge of lead storage battery,
0 4 2F 2
Pb  Pb O 2  2H 2 SO4  2 Pb SO4  2H 2O
6. The number of linkage isomers for the compound K 4  Fe Cl2  CN 2 C2O4  are
1) 4 2) 6 3) 3 4) 2
Key: 4
Sol: With respect to –CN two linkage isomers. (ambidentate)
SECTION-II
(NUMERICAL VALUE TYPE)
This section contains 5 Numerical Value Type Questions. The Answer should be within 0 to 9999. If the Answer is in
Decimal then round off to the Nearest Integer value (Example i,e. If answer is above 10 and less than 10.5 round off is 10
and If answer is from 10.5 and less than 11 round off is 11).
Marking scheme: +4 for correct answer, 0 if not attempt and -1 in all other cases
7. Molar conductivities at infinite dilution of KCl , HCl and CH 3COOK are 0.013, 0.038

and 0.009 Sm2mol 1 respectively at 291K. If conductivity of 0.001 M CH 3COOH is

2.72 103 Sm1 then find % degree of ionization of CH 3COOH .

Key: 8
 ^ 0M  ^ 0M  ^ 0M 
Sol: ^ 
0
M 
CH 3COOk HCl KCl 
  0.009  0.038  0.013 = 340S  cm2  mole1
^0M  K  103 / M  2.72 103 103 102 / 0.001  27.2S  cm2  mole1
   27.2 / 340   0.08  8%

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RPTM-14
SECTION-I (SINGLE CORRECT ANSWER TYPE)
This section contains 20 Multiple Choice Questions. Each question has 4 options (1), (2), (3) and (4) for its answer, out of
which ONLY ONE option can be correct.
Marking scheme: +4 for correct answer, 0 if not attempted and –1 in all other cases.
1. The reaction A  D goes in three steps:
Step-1: A  B Step-II B  C Step - III C  D
The energy profile diagram is shown below:

Choose the correct:

Number of Number of Rate determining
Intermediates Transition states Step
1) 3 2 II
2) 2 3 II
3) 2 3 I
4) 2 3 III
Key: 3
Sol: B and C are intermediates (2); number of peaks correspond to transition states (3);
step I  A  B  has highest activation energy, and is slowest step (rate determining
step).
2. In the back bonding in metal carbonyls, the orbitals involved are
1) Vacant metal d-orbital and  -orbital of CO having electron pair
2) Vacant metal d-orbital and  -orbital of CO having electron pair
*
3) Metal d-orbital having electron pair and vacant  orbital of CO
*
4) Metal d-orbital having electron pair and vacant  of CO
Key: 4
Sol: Back bonding or synergic bond in metal carbonyls involves metal d-orbital having
*
electron pair and vacant  of CO .
3. Mechanism of hypothetical reaction, X 2  Y2  2 XY , is given below:
(i) X 2  X + X (fast) (ii) X + Y  XY + Y (slow)2
(iii) X + Y  XY (fast)
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The overall order of the reaction will be
1) 2 2) 0 3) 1.5 4) 1
Key: 3
Sol: From the rate determining step (slow step, step-ii), rate  k ' X Y2 
2
From step-i, Kc 
 X
and  X    K c  X 2 
1/2
 X2 
 rate  k '  Kc  X 2 1/2 Y2  or rate  k  X 2 1/2 Y2  . Hence, order of reaction is
1.5
4. Low spin tetrahedral complexes are not formed because:
1) For tetrahedral complexes, the crystal field splitting energy is lower than pairing
energy
2) For tetrahedral complexes, the crystal field splitting energy is higher than pairing
energy
3) Electrons do not go to e-set in case of tetrahedral complexes
4) Tetrahedral complexes are formed by weak field ligands only
Key: 1
Sol: All tetrahedral complexes are weak-field complexes and t  P (pairing energy).
SECTION-II (NUMERICAL VALUE TYPE)
This section contains 5 Numerical Value Type Questions. The Answer should be within 0 to 9999. If the Answer is in
Decimal then round off to the Nearest Integer value (Example i,e. If answer is above 10 and less than 10.5 round off is 10
and If answer is from 10.5 and less than 11 round off is 11).
Marking scheme: +4 for correct answer, 0 if not attempt and -1 in all other cases

5. If x is number of successive stability constants for  Ag  NH 3 2  , and y is number of
3
successive stability constants for Co  NH 3 6  , then x  y  ________
 
Key: 8

Sol: In  Ag  NH3   , number of successive stability constants is 2, and in
 2
3
Co  NH3   , number of successive stability constants is 6.
 6

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RPTM-15
SECTION-I (SINGLE CORRECT ANSWER TYPE)
This section contains 20 Multiple Choice Questions. Each question has 4 options (1), (2), (3) and (4) for its answer, out of
which ONLY ONE option can be correct.
Marking scheme: +4 for correct answer, 0 if not attempted and –1 in all other cases.
1. Simplified absorption spectra of three complexes i ,ii and iii  of M n ion are

provided below; their max values are marked as A, B and C respectively. The correct
match between the complexes and their max values is:


 6 n  6n n
i)  M  NCS 6  ii)  MF6  iii)  M  NH 3 6 

1) A-(iii), B-(i), C-(ii) 2) A-(ii), B-(i), C-(iii)

3) A-(ii), B-(iii), C-(i) 4) A-(i), B-(ii), C-(iii)
Key: 1
Sol: Stronger the ligand, greater is splitting of d-orbitals and smaller will be wavelength of
light absorbed. According to spectro chemical series the splitting power of ligands is
NH 3  NCS   F  thus order of wavelength of light absorbed is NH 3  NCN   F 

2. Given below are two statements, one is labelled as

Assertion A and the other is labelled as Reason R.
Assertion A: The metal carbon bond in metal carbonyls possesses both  and 
character.
Reason R: The ligand to metal bond is a  bond and metal to ligand bond is a  bond.
In the above statements, choose the correct answer from the options given below:
1) A is false but R is true
2) A is true but R is false
3) Both (A) and (R) are true and (R) is the correct explanation of (A)
2) Both (A) and (R) are true and (R) is not correct explanation of (A)
Key: 2

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 
Sol: In metal carbonyls, L 
 M , M 
L

3. A heat engine absorbs heat Q1 at temperature T1 and heat Q2 at temperature T2. Work
done by the engine is (Q1 + Q2). This data
1) Violates 1st law of thermodynamics
2) Violates 1st law of thermodynamics if Q1 is -ve
3) Violates 1st law of thermodynamics of Q2 is -ve
4) Does not violate 1st law of thermodynamics.
Key: 4
Sol: According to first law of thermodynamics, energy can neither be created nor be destroyed
although it can be converted from one form to another. Hence, the given data does not
violate 1st law of thermodynamics but it violates 2nd law of thermodynamics.

SECTION-II (NUMERICAL VALUE TYPE)

This section contains 5 Numerical Value Type Questions. The Answer should be within 0 to 9999. If the Answer is in
Decimal then round off to the Nearest Integer value (Example i,e. If answer is above 10 and less than 10.5 round off is 10
and If answer is from 10.5 and less than 11 round off is 11).
Marking scheme: +4 for correct answer, 0 if not attempt and -1 in all other cases
4. 10 grams of argon gas is compressed isothermally and reversible at a temperature of 27oC
from 10 L to 5 L. Calculate the work done for this process in multiple of 10 2 calories
(R=2 cal. k-1 mol-1)
Key: 1
10
Sol: nAr   0.25
40
v 
W  2.303nRT log  2 
 v1 

5
 2.303 0.25 2  300log  
10 

10 
 2.303 0.25  2  300log  
 5 

 104 cal  1.04 102 cal

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5. Complexes  ML5  of metals Ni and Fe have ideal square pyramidal and trigonal

bipyramidal geometries respectively, the sum of the 90,120 and 180 L - M - L angles
in the two complexes is _____
Key: 20
Sol: (Trigonal bipyramidal)

L
L
M L
L
L
120  3, 90  6, 180  1 Total  10

L
L L
M

L L
(square pyramidal)

90  8, 180  2 Total  10

 Sum of 90,180,120 angles in both complexes = 20

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RPTM-16
(SINGLE CORRECT ANSWER TYPE)
This section contains 20 multiple choice questions. Each question has 4 options (1), (2), (3) and (4) for its answer, out of which ONLY ONE option can be
correct.
Marking scheme: +4 for correct answer, 0 if not attempted and –1 in all other cases.
1. For freezing of water
LIST-I LIST-II
A) Water at 100 C I) G  O
B) Water at 0 0 C II) G  ve
C) Water at 100 C III) G  ve
1) A  II , B  I , C  III 2) A  III , B  I , C  II
3) A  I , B  II , C  III 4) A  III , B  II , C  I
Key: 2
Sol: For spontaneous process,
For non-spontaneous process
At equilibrium
2. Which of the following lines correctly show the temperature dependence of equilibrium
constant K, for an endothermic process?
A
B
lnK

(0, 0)
C
1/T

1) A and B 2) A and C 3) B and D 4) C and D

Key: 4
Sol: For endothermic process the slope of the line is negative

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3. The entropy change associated with the conversion of 1Kg ice at 273K to water vapour at
373K is (specific heat of water liquid is 4.2 kJ k 1kg 1 ; heat of fusion of ice and

 373 
vaporization of water are 334kJ kg 1 and 2491kJ kg 1 respectively;  ln  0.31
 273 
1) 9.19 kJ kg 1k 1 2) 9.26 kJ kg 1k 1 3) 7.9kJ kg 1k 1 4) 8.49 kJ kg 1k 1
Key: 1
Ice S water S water S watervapour
Sol: 273 K 
1
273 K 
2
373 K 
3
373 K

334
S1   1.22
273
373
S 2  4.2ln  1.30
273
2491
S 3   6.67
373
4. Assertion: For every chemical reaction at equilibrium, standard Gibbs energy change of
reaction is zero.
Reason: At constant temperature and pressure, chemical reactions are spontaneous in the
direction of decreasing Gibbs energy.
1) Both Assertion and Reason are correct and Reason is a correct explanation of
Assertion
2) Both Assertion and Reason are correct and Reason is not correct explanation of
Assertion
3) Assertion is correct but Reason is incorrect
4) Assertion is incorrect but Reason is correct
Key: 4
Sol: At equilibrium G is zero but not G 0
5. Statement-1: Enthalpy and entropy of any elementary substance in the standard state are
taken as zero
Statement-2: The absolute value of enthalpy and entropy of chemical substance can be
determined by using 3rd law of thermodynamics.
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1) Both statement-1 and statement-2 are true
2) Statement-1 is true, statement-2 is false
3) Statement-1 is false, statement-2 is false
4) Both statement-1 and statement-2 is false
Key: 3 or 4
Sol: Enthalpy of elements in the standard state is taken as zero. The absolute value of entropy
can be determined by using 3 rd law of thermodynamics
6. K 2Cr2O7  X  conc H 2 SO4 
heat
 A 
NaOH
B.
In the above reaction, “A” is reddish brown gas soluble in NaOH forming yellow solution
of “B”. ‘X’ and ‘A’ are
1) NaCl , CrO2Cl2 2) CrO2Cl2 , Na2CrO4 3) SO2 , NO2 4) NaCl , Na2CrO4
Key: 1
Sol: It is chromyl chloride test
7. Statement-1: Addition of NH 4OH to an aqueous solution of BaCl2 in the presences of
NH 4Cl (excess) precipitate Ba  OH 2

Statement-2: Ba 2 belongs to group-III

1) Both Statement-1 and Statement-2 are true 2) Both Statement-1 and Statement-2 are
false
3) Statement-1 is true, Statement-2 is false 4) Statement-1 is false, Statement-2 is true
Key: 2
Sol: Ba 2 ion belongs to group-V
8. Statement-1: Sulphanilic acid gives esterification test for carboxyl group
Staement-2: Aniline gives carbylamine test
1) Both Statement-1 and Staement-2 are true 2) Both Statement-1 and Staement-2 are
false
3) Statement-1 is true, Statement-2 is false 4) Statement-1 is false, Statement-2 is true
Key: 4

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NH2

3 SO H
Sol: Sulphanilic acid is
9. Which of the following is a bactericidal antibiotic?
1) Ofloxacin 2) Tetracycline 3) Chloramphenicol 4) Erythromycin
Key: 1
Sol: Ofloxacin is a bactericidal antibiotic.
10. Which of the following is a cationic detergent?
1) Sodium Stearate 2) Sodium lauryl Sulphate
3) Cetyltrimethyl ammonium bromide 4) Glyceryl oleate
Key: 3
Sol: Cetyltrimethyl ammonium bromide is cationic detergent
11. Drugs used to bind to receptors, inhibiting its natural function and blocking a message are
called
1) Agonists 2) Antagonists 3) Anti histamines 4) Allosterists
Key: 2
Sol: Antagonist inhibits the natural function and blocks the message

SECTION-II (NUMERICAL VALUE TYPE)

This section contains 5 Numerical Value Type Questions. The Answer should be within 0 to 9999. If the Answer is in
Decimal then round off to the Nearest Integer value (Example i,e. If answer is above 10 and less than 10.5 round off is 10
and If answer is from 10.5 and less than 11 round off is 11).
Marking scheme: +4 for correct answer, 0 if not attempt and -1 in all other cases.
12. An organic compound Cx H 6O2 was treated with I 2 / NaOH consumes 6 moles of I 2 to
produce Iodoform and a dibasic acid salt. Which when treated with acidified KMnO4 ,
pink colour of KMnO4 gets decolourised with no organic compound left. The minimum
value of ‘x’ is
Key: 4

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Sol: CH 3  C  C  CH 3  6 I 2  CI 3  C  C  CI 3
|| || || ||
O O O O

NaOH

COONa
2CHI 3  |
COONa
13. Number of following metal ions are precipitated on reaction with NH 4Cl  NH 4OH  H 2 S

Cu 2 , Cd 2 , Mn 2 , Zn2 , Ni 2 , Hg 2 , Ba 2 , Ca 2 , Mg 2
Key: 6
Sol: Cu 2 , Cd 2 , Mn 2 , Zn 2 , Ni 2 and Hg 2 are precipitated
14. The number of chlorine atoms in bithionol is ____

Key: 4

Cl OH OH Cl

Cl
Sol: Cl

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CHEMISTRY
RPTM-01(N&S)
(NUMERICAL VALUE TYPE)
Section-II contains 10 Numerical Value Type questions. Attempt any 5 questions only. First 5 attempted questions will be considered if more than 5
questions attempted. The Answer should be within 0 to 9999. If the Answer is in Decimal then round off to the nearest Integer value (Example i,e. If
answer is above 10 and less than 10.5 round off is 10 and If answer is from 10.5 and less than 11 round off is 11).
Marking scheme: +4 for correct answer, 0 if not attempt and -1 in all other cases.
1. Total number of stereo isomers possible for the given structure.
OH Br

Cl F
Key :-16
Sol:- Total stereo centers 4
Total number of stereo isomers  24  16
2. Specific rotation of optically pure compound is 200 observed rotation of the mixture is
150 then optical purity of compound is x% then value of x is ______
Key :-75
15
Sol:- optical purity   100  75
20
3. Number of isomeric aldehydes with formula C5 H10O ( excluding stereo isomers )
Key :-4
O
O
H

H
Sol:- O C HO H

4. Find the Number of sp carbon atoms in benzyne is _____

Key :-0
Sol:- (0) sp hybrid orbitals in benzyne
5. The number of stereoisomers possible butane 2, 3 - diol is________
Key :-3
Sol:- Compounds with 2 Identical chiral atom having 3 stereo isomers
6. The ratio between “sigma” and “pi” bonds in 2-oxo hex-4-enal is_______
Key :-6
O
C H3 - C H= C H- C H2 - C - C - H
Sol:- 2-oxo hex-4-enal compound is O
15
Total number of  Bonds = 15, Total number of  Bonds = 3, 5 
3
7. Minimum number of carbon atoms required to exhibit metamerism in alkoxy alkane
Key :-4
Sol:- Ethers to exhibits metamerism required minimum 4 carbons
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RPTM-02(N&S)
(SINGLE CORRECT ANSWER TYPE)
This section contains 20 multiple choice questions. Each question has 4 options (1), (2), (3) and (4) for its answer, out of which ONLY ONE option can be
correct.
Marking scheme: +4 for correct answer, 0 if not attempted and –1 in all other cases.
1. Correct melting point order of following is?
I – Neopentane II – n – pentane
III – Isopentane
1) I > III > II 2) III > II > I 3) I > II > III 4) II > III > I
Key:- 3

M.P 256.4 K 113.1 143.3

Sol:-
(NUMERICAL VALUE TYPE)
Section-II contains 10 Numerical Value Type questions. Attempt any 5 questions only. First 5 attempted questions will be considered if more than 5
questions attempted. The Answer should be within 0 to 9999. If the Answer is in Decimal then round off to the nearest Integer value (Example i,e. If
answer is above 10 and less than 10.5 round off is 10 and If answer is from 10.5 and less than 11 round off is 11).
Marking scheme: +4 for correct answer, 0 if not attempt and -1 in all other cases.
2. How many stereoisomers are possible for following compound?
5 – (2-chloro – 1 – ethylpropyl) – 6 – ethyl non-3- ene
Key:-32

*
*
*
*

Sol:- Cl

3. Sum of the position of substitutions in the following compound is?

COOH
Br

CH3

Key:-9

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COOH
Br 1
6
2

5 3
CH3
Sol:- 4

4. How many hydrocarbons Cx H y  are possible having molecular weight 54

Key:-9
Sol:- M. F is C4 H 6
13. How many of the following are optically active?
CH3 H D

NO2 Cl D H
A) B)

C) CH 3  CH  C  CH  CH 3 D)
Cl

Br
E) F) CH 3  CH  C  C  CH  CH 3
Key:-4
Sol:- A, C, D & E are active
5. How many isomers are possible with molecular formula C3 H 6 BrCl (including stereo
isomers)
Key:-8

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Cl
Cl Cl
Br
* Br
Br *
Sol:-
Br
Cl
Br Cl
*
6. Maximum number of C – atoms present in one plane of following compound is?
CH 3  CH 2  CH  CH  C  C  CH  C  CH 2
Key:-9
H H

C C C C H
H C H C
C
C H C

H
H H
Sol:- H


Zn / H
C6 H13Cl  
( x)
7.
How many isomeric of ‘x’ satisfy above condition (including stereo isomers)
Key:-8
Cl
Cl

Sol:- Cl

Cl
8. Alkane (x) having molecular weight 100 converts into toluene on treating with Cr2O3 in
alumina at high temperature & pressure then how many isomeric x including stereo
isomers satisfy given condition?
Key:-4

Sol:- *

9. How many stereo isomers are possible for 5 – sec – butyl – 4 - isopropyldecane
Key:-8

* *

Sol:-

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RPTM-03(N&S)
(SINGLE CORRECT ANSWER TYPE)
This section contains 20 multiple choice questions. Each question has 4 options (1), (2), (3) and (4) for its answer, out of which ONLY ONE option can be
correct.
Marking scheme: +4 for correct answer, 0 if not attempted and –1 in all other cases.
1. Correct melting point order of following is?
I – Neopentane II – n – pentane
III – Isopentane
1) I > III > II 2) III > II > I 3) I > II > III 4) II > III > I
Key:- 3

M.P 256.4 K 113.1 143.3

Sol:-
(NUMERICAL VALUE TYPE)
Section-II contains 10 Numerical Value Type questions. Attempt any 5 questions only. First 5 attempted questions will be considered if more than 5
questions attempted. The Answer should be within 0 to 9999. If the Answer is in Decimal then round off to the nearest Integer value (Example i,e. If
answer is above 10 and less than 10.5 round off is 10 and If answer is from 10.5 and less than 11 round off is 11).
Marking scheme: +4 for correct answer, 0 if not attempt and -1 in all other cases.
2. How many stereoisomers are possible for following compound?
5 – (2-chloro – 1 – ethylpropyl) – 6 – ethyl non-3- ene
Key:-32

*
*
*
*

Sol:- Cl
3. Sum of the position of substitutions in the following compound is?
COOH
Br

CH3
Key:-9
COOH
Br 1
6
2

5 3
CH3
Sol:- 4

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4. How many hydrocarbons Cx H y  are possible having molecular weight 54
Key:-9
Sol:- M. F is C4 H 6
5. How many of the following are optically active?
H D
CH3

NO2 Cl D H
A) B)

C) CH 3  CH  C  CH  CH 3 D)
Cl

Br
E) F) CH 3  CH  C  C  CH  CH 3
Key:-4
Sol:- A, C, D & E are active
6. How many isomers are possible with molecular formula C3 H 6 BrCl (including stereo
isomers)
Key:-8
Cl
Cl Cl
Br
* Br
Br *
Sol:-
Br
Cl
Br Cl
*
7. Maximum number of C – atoms present in one plane of following compound is?
CH 3  CH 2  CH  CH  C  C  CH  C  CH 2
Key:-9

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H H

C C C C H
H C H C
C
C H C

H
H H
Sol:- H


Zn / H
C6 H13Cl  
( x)
8.
How many isomeric of ‘x’ satisfy above condition (including stereo isomers)
Key:-8
Cl
Cl

Sol:- Cl

Cl
9. Alkane (x) having molecular weight 100 converts into toluene on treating with Cr2O3 in
alumina at high temperature & pressure then how many isomeric x including stereo
isomers satisfy given condition?
Key:-4

Sol:- *

10. How many stereo isomers are possible for

5 – sec – butyl – 4 - isopropyldecane
Key:-8

* *

Sol:-

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GTM-01(N)
(SINGLE CORRECT ANSWER TYPE)
This section contains 20 multiple choice questions. Each question has 4 options (1), (2), (3) and (4) for its answer, out of which ONLY ONE option can be
correct.
Marking scheme: +4 for correct answer, 0 if not attempted and –1 in all other cases.
rd
1. Assertion: For Hydrogen atom degeneracy of 3 level is 3
Reason: Aufbau principle is not applicable for s, p, d, f subshells of same shell for single
electronic species
1) Both Assertion (A) and Reason (R) are the true and Reason (R) is a correct explanation
of Assertion (A)
2) Both Assertion (A) and Reason (R) are the true but Reason (R) is not a correct
explanation of Assertion (A)
3) Assertion (A) is true and Reason (R) is false
4) Assertion (A) is false and Reason (R) is true.
Key: 4
Sol: For H: 3s  3 p  3d  degeneracy  9
2. Statement-1: Emf of a cell is an extensive property
Statement-2: Larger cells (AA batteries) have more emf than smaller cells (AAA
batteries)
Statement-3: Fe cannot be used to protect Zn in Galvanization
Statement-4: For concentration cell ECell  0
1) 1 and 2 are correct 2) 1 and 3 are correct
3) 1 and 4 are correct 4) 3 and 4 are correct
Key: 4
Sol: 1 and 3 are correct
3. Complete reduction of benzene diazonium Chloride with Zn/HCl gives:
1) Aniline 2) Phenyl Hydrazine
3) Azobenzene 4) Hydrazobenzene
Key: 1
Sol: Gives Aniline

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4. Consider the oxides of group 14 elements SiO2, GeO2, SnO2, PbO2, CO & GeO . The
amphoteric oxides are
1) GeO, GeO2 2) SiO2,GeO2 3) SnO2,CO 4) SnO2, PbO2
Key: 4
Sol: SnO2 , PbO2 are amphoteric
5. Which of the following element will remain as liquid inside pure boiling water
1) Ca 2) Ga 3) Li 4) Br
Key: 2

Sol: Ga remains as Liquid upto 2000 C

6. The correct order of Bond dissociation enthalpy is:
1) Cl2  Br2  F2  I2 2) F2  Cl2  Br2  I2

3) Cl2  F2  Br2  I2 4) I2  Br2  Cl2  F2

Key: 1
Sol: BE order Cl2  Br2  F2  I 2
7. On adding small quantity of naphthalene, the boiling point of benzene will
1) Increase 2) remains same
3) first decrease and then increases 4) decrease
Key: 1
Sol: Fp: soln < Solvent
8.
COLUMAN –I COLUMNII-II
Species Dipole moment (D)
1 HF p 0.23
2 H2O q 1.47

3 NH3 r 1.78

4 NF3 s 1.85

Correct match is
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1) 1 s,2 q,3  s,4  p 2) 1r,2  s,3 q,4  p

3) 1 p,2 q,3 r,4  s 4) 1s,2 q,3 r,4  p

Key: 2
Sol: NCERT P/112
(NUMERICAL VALUE TYPE)
Section-II contains 10 Numerical Value Type questions. Attempt any 5 questions only. First 5 attempted questions will be considered if more than 5
questions attempted. The Answer should be within 0 to 9999. If the Answer is in Decimal then round off to the nearest Integer value (Example i,e. If
answer is above 10 and less than 10.5 round off is 10 and If answer is from 10.5 and less than 11 round off is 11).
Marking scheme: +4 for correct answer, 0 if not attempt and -1 in all other cases.

9. The value of  G   in KJ  for the conversion of 3 moles of oxygen to ozone at 298K

is______ (Kp for the reaction  3 O2 ( g )  O3 ( g )  is 2.5  10  29 & log 2  0.3
2 
1 1
ln x  2.3 log x & R  8.3 Jmol K
Key: 325
29
Sol: ci  2.3  8.3  298log2.510
 162700J =162.7 KJ =163
10. The total number of electrons present in HOMO (Highest Occupied Molecular Orbital) of
O2 is _________
Key: 2
Sol: HOMO For O2 is  2* p x  2* py  2e1
11. Number of polar molecules    0 among the following is ___________
Cl OH CN

, Cl OH CN , , CCl4, CH2Cl2
Key: 3
OH

CH 2Cl2
Sol: OH and are polar
AlCl O H O
CH 3CH 2CH 2Cl 
3 A 
2 B 
2 C  D
  major  peroxide H 2 SO4
12.
C gives Iodoform test. Then molecular weight of D in (g) is________
Key: 94

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CH3
CH3CHCH3 H3C C O OH OH
O
CH3CH 2CH 2Cl O H O
  
2 
2  + H3C C CH3
AlCl3
Sol: D C

13. A first order reaction is completed by 99.9% in 90 days. Half-life of the reaction (in days)
is__________ (lo g 2  0 .3 )

Key: 9
1
Sol: t 99.9 = 10t
2

14. PH of resultant solution formed when 100 ml of 0.1M H3PO4 reacts with 100 ml of 0.1


M NaOH is ________ Ka1H 3 PO4  2.5  10 3 , Ka2  10 8 , Ka3  10 13 
Key: 5

Pka1  pka2 3  log 2.5  8 11  0.4 10.6

Sol: pH  2     5.3
2 2 2
Nearest integer = 5.3
15. Density of 3M solution of NaCl is 1.25 g / mL1 . The molality of solution is________

moles kg  1 (at wt of Na = 23, Cl = 35.5)

Key: 3
Sol: MNaCl  3  58.5  175.5
m  1250 g mwater  1250  75.5  1074.5
Sol n

3
Molality   2.79 mole kg 1
1.0745
16. The number of ions which will be precipitated by H2S in acidic medium among

Cu 2 , Ni 2 , Mn2 , Pb 2 , Co 2 Al 3 , Hg 2  is________

Key: 3


Sol: Group2: Cu 2  , Pb 2  , Bi3 , Cd 2  , Hg 2  

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RPTM-04(S)
(SINGLE CORRECT ANSWER TYPE)
This section contains 20 multiple choice questions. Each question has 4 options (1), (2), (3) and (4) for its answer, out of which ONLY ONE option can be
correct.
Marking scheme: +4 for correct answer, 0 if not attempted and –1 in all other cases.
1. Given below statements which are correct .
CH 3

NO2

CH 3
a) The compound is optically active.
b) In Bromobenzene, the inductive effect of bromo group is more dominant than the
mesomeric effect in directing the incoming electrophile.
c) The halogen which is most reactive in the halogens of alkane under sunlight is Cl < Br
< I.
d) Vinyl halides do not undergo nucleophilic substitution only.
1) ab 2) bc 3) cd 4) ad
Key: 4
Sol: Conceptual.
2. Assertion: Alkynes are less reactive than Alkenes in electrophilic addition reaction
Reason: Terminal Alkynes have acidic Hydrogen
1) Assertion and Reason are true, reason is explanation of Assertion
2) Assertion and Reason are true, reason is not explanation of Assertion
3) Assertion is true but Reason is false
4) Assertion is false but Reason is true
Key: 2
Sol: Due to formation of highly strained bridged carbocation. (3 membered ring with double
bond)
K C H Br
Ph  CH 2  CH  CH3 ,  
2 5
( A)

3. OH
Product (A) in above reaction is
Ph  CH 2  CH  CH 3 (inversion)

1) OEt

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Ph  CH 2  CH  CH 3 , (retention)

2) OEt
Ph  CH 2  CH  CH 3 , (racemic)

3) OEt

4) Ph  CH  CH  CH 3
Key: 2
Sol: Retention product formed
4. In the following compound, arrange the reactivity of different bromine atoms towards
NaSH
in decreasing order :
Br(R)

Br(S) Br(Q)

Br(P)
O
O
1) P  Q  R  S 2) S  Q  P  R
3) Q  S  P  R 4) P  S  Q  R
Key: 3
Sol: The reactivity order with SH- , follows given order, Q>S>P>R, since

Towards sN2. The ‘BR’ indicated by R is at bridge –head so has least ease to undergo this
reaction.
5. Identify the correct statement about the following reaction?
D
OH
Br 
High concentration

H
H 3C
1) The product formed has R-configuration
2) The product formed has S-configuration
3) The product is formed with retention of configuration
4) The reaction takes place by S N 1 mechanism.
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Key: 1

Sol:
(NUMERICAL VALUE TYPE)
Section-II contains 10 Numerical Value Type questions. Attempt any 5 questions only. First 5 attempted questions will be considered if more than 5
questions attempted. The Answer should be within 0 to 9999. If the Answer is in Decimal then round off to the nearest Integer value (Example i,e. If
answer is above 10 and less than 10.5 round off is 10 and If answer is from 10.5 and less than 11 round off is 11).
Marking scheme: +4 for correct answer, 0 if not attempt and -1 in all other cases.
6. How many of the following statements are correct
i) Alkanes exhibit “alternation effect” with respect to melting point
ii) Among various chlorinated products of methane, only one product possess zero
dipolemoment
iii) Among isomeric pentanes, n – pentane possess high boiling point
iv) The percentage of n propyl chloride obtained in the chlorination of propane by sun
light is about 56%
Key: 3
Sol: All statement are correct
7. In how many of the following the percentage of enol content is more than that in
CH 3  COCH 2  COOC2 H 5
O
O O
CH 3
i)
H 3C ii)
O
H 3C CH 3
O O
O O
O
iii)
CH 3 iv)
v)

vi)

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Key: 4
Sol: ii, iii, iv, and v
  
8. The relative reactivity of 1 H ,2 H and 3 H in bromination reaction has been found to
be 1:82:1600 respectively in the reaction,
Br

hv Br
 Br2  
(A) (B)
The percentage yield of (A) and (B) are expected to be X and Y. Then X-Y is (nearest
integer)
Key: 99
Sol: X = 99.4% Y = 0.6%
9. How many reagents from the list below can be used to remove hydrogen as proton from
Terminal alkyne?
CH 3 MgBr , NaNH 2 , Na, NaHCO3 , KNH 2 , CH 3CH 2 Li
Key: 5
Sol:

10. Number of reagents that are added to alkene in syn addition

I . Br2 water II . H 2 / Ni III .KMnO4 / OH  ( Bayer ' s reagent )
IV . Na / NH 3 (l ) V .Ni2 B ( P  2 catalyst ) VI .OsO4 / NaHSO3
Key: 4
Sol: II,III,V,VI
11. Classify the following substitutes which are ortho, para directing groups towards
Substitution and also de-actives the benzene ring

Key: 4
Sol: a, d, e, i are ortho, para directing and deactivate the ring
12. Find the number of molecules which are easily participated in Friedal Craft’s Acylation
a) Nitrobenzene b) Phenol c) Anisole
d) Toulene e) Aniline f) Styrene
g) Trifluoro Benzene h) Isopropyl benzene i)Chlorobenzene
Key: 5
Sol: (a) is used as solvent in friedal craft’s reaction
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(e) gives very poor yields

13.
I

NaCN


x (major product )
60%

NO2
(89 g )
Find out weight of the major product ‘x’.
(given: C=12, O=16, H=1, N=14, I=127, F=19, Na=23).
(answer should be rounded off to nearest integer). ________
Key: 33

Sol:
14. Write the number of that site which is most reactive for SN1 reaction:
Cl

4 Cl

CHCH3
2
1
Cl
Cl

Key: 4
Sol: More stable carbocation is formed at 4.
15. The treatment of propyne with excess of CH 3 MgI releases 4.48ml of a gas at STP. The
mass of propyne (in mg) added is ___
Key: 8

Sol:
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RPTM-04/05(N&S)
(SINGLE CORRECT ANSWER TYPE)
This section contains 20 multiple choice questions. Each question has 4 options (1), (2), (3) and (4) for its answer, out of which ONLY ONE option can be
correct.
Marking scheme: +4 for correct answer, 0 if not attempted and –1 in all other cases.
1. In the following reaction ‘A’ is



H

 Major Product 'A'

OH

1) 2)

3) 4)
Key: 3
Sol: IUPAC name 7-Hydroxyheptan-2-one
(NUMERICAL VALUE TYPE)
Section-II contains 10 Numerical Value Type questions. Attempt any 5 questions only. First 5 attempted questions will be considered if more than 5
questions attempted. The Answer should be within 0 to 9999. If the Answer is in Decimal then round off to the nearest Integer value (Example i,e. If
answer is above 10 and less than 10.5 round off is 10 and If answer is from 10.5 and less than 11 round off is 11).
Marking scheme: +4 for correct answer, 0 if not attempt and -1 in all other cases.
2. Total number of cyclic isomers (including stereo isomers) possible for C4 H 8O which do
not liberate H 2 gas with Na metal is____
Key: 11

Sol:
3.

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Degree of unsaturation of A  B 
Key: 13
Sol: A= 4, B= 9
4. How many structures of final products are possible? (including stereo)


Conc. H 2 SO4


Br2 CCl4
 C4 H 8 Br2
OH

Key: 5


Conc. H 2 SO4

 
OH Cis Trans

Br2 CCI 4
Br2 CCI 4 Br2 CCI 4

Br
Racemic mixture Meso 
(2) (1)
Br
Sol: (2)

5. How many of the following compounds are aromatic

A) B) C)

D) E) F)
Key: 4
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Sol: B,D,E,F are aromatic
6. How many moles of AgNO3 will react with the given compound

Key: 5
Sol: Vinyl, Phenyl does not ppt
7. How many moles of formaldehyde is formed by the complete hydrolysis of following

compound with H 3O 

Key: 4
Sol: four moles is form

8. 25
Optically pure ( S )  (  ) -2- bromooctane,  D  36 , reacts with aqueous NaOH in

25
acetone to give optically pure (R)-(-)-2-octanol,  D  10.3 . With partially racemized
 
25
2 – bromooctane whose  D  30 , the  D
25
of the alcohol product is 6.0 .
Calculate the % of inversion?
Key: 70
Sol: Ref Scham Q 8.88
9. How many of the following are more reactive than benzene for electrophilc substitution
reaction?

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1) Anisole 2) Acetanilide 3) Cabolic acid 4) TNT

5)Mesitylene 6) Benzaldehyde 7) Acetophenone 8) Meta-Xylene

9) Ethyl benzoate
Key: 5
Sol: EDG increase reactions in EAS
RPTM-05/06(N&S)
(SINGLE CORRECT ANSWER TYPE)
This section contains 20 multiple choice questions. Each question has 4 options (1), (2), (3) and (4) for its answer, out of which ONLY ONE option can be
correct.
Marking scheme: +4 for correct answer, 0 if not attempted and –1 in all other cases.
1. A: Addition of HCl to acetylene in presence of HgCl2 give vinyl chloride
R: HgCl2 acts as positive catalyst.
1) If A and R both are correct and R is the correct explanation of A
2) Both A and R are true but R is not the correct explanation of A
3) A is true but R is false
4) A is false but R is true
Key: 1
Sol: HgCl2 act as negative catalyst
(NUMERICAL VALUE TYPE)
Section-II contains 10 Numerical Value Type questions. Attempt any 5 questions only. First 5 attempted questions will be considered if more than 5
questions attempted. The Answer should be within 0 to 9999. If the Answer is in Decimal then round off to the nearest Integer value (Example i,e. If
answer is above 10 and less than 10.5 round off is 10 and If answer is from 10.5 and less than 11 round off is 11).
Marking scheme: +4 for correct answer, 0 if not attempt and -1 in all other cases.
2. Identify the total number of compounds that give positive test with tollen’s reagent
O
O O CH 2
CH 3  C  H , H H CH 3  C  CH 3 , CH 3  C  CH 3
I II , III IV
OH OH
OH OH
OMe
O
, , , ,

V VI VII VIII IX
Key: 5
Sol: I , II ,VI ,VII ,VIII , IX , X give positive tollence test

3. How many compounds will show rearrangement during SN 1 reaction.

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Br
Cl
I

Br ,
,
,
I II III
IV

Br Cl Br

,
,
, Cl
VI VII
V VIII

Cl

, , CH 2  Cl
Cl
IX
X

XI

Cl

XII

Carbocations are stabilized generally by rearrange (or)ring expansion

Key: 8
Sol: I , II , IV ,V ,VI , IX , X , XI , XII compounds are rearrangement
4. Find out number of substrates those can undergo cannizzaro’s reaction.

O
O
O
CH 2
CH 3  C  H , H H CH 3  C  CH 3 , CH 3  C  CH 3
I II , III IV
OH OH OH
OH OH
OMe
, , , , , O

V IV VII VIII IX X
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Key: 1
Sol: I , II , IV ,V ,VIII , IX Gives cannizzario reaction
5.
H O 2 H / Ni hv / Cl Na / Et O
CaC2 
2  A 
2  B 
2  C 
2 D

Br / hv tertiary butoxide B H /THF Pcc

D 
2  E  F 
2 6

 G 
H
 H 2O2 / OH

No of hybridized orbitals in H (only carbon atoms are consider)

Key: 15
CHO
CaC2 
H2O
 HC  CH 
2 H2 / Ni
CH3  CH3 
hv/Cl2
CH3  CH2  Cl 
Na/ Et2O
CH3  CH2  CH2  CH3 
Br2 /hv
CH3  CH2  CHBr  CH3 
OK


B2H6 /THF

H O /OH  

OH Pcc

2 2
Sol:
6.

H  C  H  D  C  D  NaOH
cannizarro reaction

O O

How many different alcohols may be formed theoretically in this reaction

Key: 4
Sol: CH 3OH , CD3OH , CD2 HOH , CH 2OOH
7.
O

Zn Hg   2 4 1 N H / OH   
O   A   B   C  D
AlCl3 Con
+
H 3O HCl H 2 SO4  2 Se

Total no.of atoms in a plane in D=______

Key: 18
Sol: 18 atoms in a plane

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8. How many of the given ethers can be synthesized by Williamson ether synthesis in good
yield (major)

Key: 5
Sol: I , II ,V ,VI ,VII
9. Consider the following reaction.

Degree of unsaturation of A.

Key: 8

Sol:

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RPTM-06/07(N&S)
(NUMERICAL VALUE TYPE)
Section-II contains 10 Numerical Value Type questions. Attempt any 5 questions only. First 5 attempted questions will be considered if more than 5
questions attempted. The Answer should be within 0 to 9999. If the Answer is in Decimal then round off to the nearest Integer value (Example i,e. If
answer is above 10 and less than 10.5 round off is 10 andIf answer is from 10.5 and less than 11 round off is 11).
Marking scheme: +4 for correct answer, 0 if not attempt and -1 in all other cases.
1. Ratio of sigma bonds to pure orbital’s in benzene
Key: 1
Sol:  = 12, Pure = 12
2. Number of compounds more acidic than Benzoic acid
COOH

COOH OH

CH 3

OCH 3
A) formic acid B) C) D)
COOH COOH

COOH

E) CH3 F) H2O G) NO2 H) NO2

Key: 4
Sol: A, G, H
3. Structural aromatic isomers for C7H8O(containing Benzene ring)
Key: 5
CH 2OH OH OH OH
OCH 3

CH 3

CH 3

Sol: CH 3

4. Primary amines possible for C4H11N (including stereo isomers)

Key: 5

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Sol: C – C – C – C – NH2
NH 2 C C
| | |
C C  C C C  C  C  NH 2 C  C  NH 2
* |
C

5. Number of ethers prepared from Williamson synthesis

1) C6 H5 - O - C (CH3 )3 2) C6 H5 CH2 -O - C (CH3 )3
3) (CH3 )3 C - O – C (CH3 )3 4) CH2=CH-O-C6 H5

5)  CH3 3 C  O  C  C2 H 5 3 6) CH 3  O  C6 H 5

Key: 2
Sol: Number of ethers prepared from Williamson synthesis is 2,6
6. An organic compound A(mol wt-180) is acylated with CH 3COCl to get acylated
compound
as mol wt. 390. What is the number of amino groups present per molecule of the
compound A? (take mono Acylation on each amine group)
Key: 5
390  180 210
Sol:  5
42 42

7. The number of moles of electrons involved in the reduction of 1 mole of RCONH 2

to RCH 2 NH 2 is
Key: 4
o
|| 1
Sol: R  C  NH 2 
4 moles e
R  CH 2  NH 2

8. The number of the compounds which on nitration will give m-nitro derivative as major
product
i) Benzene sulphonic acid ii) aniline iii) phenol iv) cumene
v) Chloro benzene vi) Benzoic acid
Key: 2
Sol: Chloro benzene, Benzoic acid

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GTM-02(N)
(SINGLE CORRECT ANSWER TYPE)
This section contains 20 multiple choice questions. Each question has 4 options (1), (2), (3) and (4) for its answer, out of which ONLY ONE option can be
correct.
Marking scheme: +4 for correct answer, 0 if not attempted and –1 in all other cases.
1. The change in reduction potential of a hydrogen electrode when its solution initially at
pH=0 is neutralized to pH = 7 at constant pressure of Hydrogen gas (1atm) at 250 C is
1) Increase by 0.059V 2) decrease by 0.059 V
3) Increase by 0.41 V 4) Decrease by 0.41 V
Key: 4
Sol: E initial  0
0.0591   1 
E final   log    0.4137 V
1  107 
2. Select incorrect statement is:
1) Commercial bleaching solution contains 3.62 mass percentage of sodium hypo chlorite
in water
2) 10 percent (volume) ethanol solution contains 90 ml of water
3) 35 percent (volume) solution of ethylene glycol is used as anti freezer which lowers
the freezing point of water
4) Dissolved oxygen in sea water equals to nearly 5.8 ppb.
Key: 4
Sol: NCERT No. 52
3. Select correct statement :
1) Order of Henry’s constant : He < H 2 < N 2
2) Di ethyl ether shows higher K b than K f
3) In K 3CrO8 chromium shows +6 oxidation state
4) Order conductivity : copper > iron > Ge > graphite
Key: 2
Sol: NCERT P. No. 57
4. Assertion (A) : Bond energy of Cl – Cl bond is more than that of F – F bond
Reason (R) : Shorter the bond length, stronger the bond, more is the bond energy.
1) Both A and R are true and R is correct explanation of A
2) Both A and R are true and R is not correct explanation of A
3) A is true and R is false
4) A is false and R is true
Key: 2
Sol: Both A and R are true and R is not correct explanation of A
5. Which of the following is smallest anion
1) F  2) H  3) Cl  4) O 2
Key: 1
Sol: smallest anion F 
6. Given below are two statements :
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Statement – I : O2 , Cu 2 and Fe3 are weakly attracted by magnetic field and are
magnetized in the same direction as magnetic field.
Statement – II : NaCl and H 2O are weakly magnetized in opposite direction to magnetic
field. In the light of the above statements, choose the most appropriate answer from the
options given below :
1) Both Statement – I and Statement – II are correct
2) Both Statement – I and Statement – II are incorrect
3) Statement – I is correct but Statement – II is incorrect
4) Statement – I is incorrect but Statement – II is correct
Key: 1
Sol: O 2 , Cu 2 , Fe3 are paramagnetic NaCl, H 2O are diamagnetic
So both a statement are correct
(NUMERICAL VALUE TYPE)
Section-II contains 10 Numerical Value Type questions. Attempt any 5 questions only. First 5 attempted questions will be considered if more than 5
questions attempted. The Answer should be within 0 to 9999. If the Answer is in Decimal then round off to the nearest Integer value (Example i,e. If
answer is above 10 and less than 10.5 round off is 10 and If answer is from 10.5 and less than 11 round off is 11).
Marking scheme: +4 for correct answer, 0 if not attempt and -1 in all other cases.
7. Among the triatomic molecules/ions,
BeCl2 , N3 . N 2O, NO2 , O3, SCl2 , ICl2 , I3 and XeF2 ,
the total number of linear molecule(s) /ions(s) where the hybridization of the central
atoms does not have contribution from the d-orbital(s) is
(Atomic number S = 16, Cl = 17, I = 53 and Xe = 54)
Key: 4
Cl  Be  Cl sp linear 

  
..  .. 
: N  N  N : splinear 
Sol: 
  
O N N sp linear 

 
ONO sp linear 
Linear molecule/ion without involving d-orbital in their hybridization of central atom

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8. If the freezing point of a 0.01 molal aqueous solution of a cobalt (III) chloride-ammonia
complex (which have secondary valency of metal is 6 and it behaves as a strong

electrolyte) is 0.05580 C , the number of chloride(s) in the coordination sphere of the


complex is K f of water  1.86 K kg mol 1 
Key: 1
Sol: Tf  iK f m
0.0558  i 186  0.01
i3
Structure should be
Co NH3  Cl Cl2
 5 

9. For the octahedral complexes of Fe3 in SCN   thiocyanato  S  and CN  ligand

environments, the difference between the spin only magnetic moments in Bohr
magnetons (when approximated to the nearest integer is (Atomic number of Fe = 26)
Key: 4
3 3
Sol:  FeCN   FeSCN 
 6   6 

Fe3  3d 5 Fe3  3d 5
CN is S.F.L SCN is W.F.L
0  p p

  n n  2B.M

n = number of unpaired electron = 1, n = number of unpaired electron = 5

  1.73 B.M   5.92 B.M
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Difference = 5.92 – 1.73 = 4.19 = 4

10. Number of moles of NaOH required for complete neutralization of H  in which is

formed by complete hydrolysis of 1 mole of PCl5
Key: 8
Sol: PCl5  H 2O  H 3 PO 4  5HCl
 8 moles of NaOH is required

11. The enthalpy of hydration of Fe2 is 11.4k.cal/mol higher than would be expected, if
there were no crystal field stabilization energy. Assuming the aqua complex to be high-
2
spin, estimate the magnitude of  for  Fe  H 2O 6  . Report answer in k. cal/mol

Key: 29
Sol: CFSE for the d6 weak field is 0.4. The H hyd is higher because the energy of the

complex is lowered by that much is -11.4 k.cal/mol.

CFSE = -11.4 k.cal/mol
11.4 k.cal / mol  0.4 
11.4
  28.5 k.cal mol1
0.4
12. How many of the following will exhibit back bonding?
A) SiH 3 NCS B) OCl2 C) BF3 D) B  OC2 H 5 3
E) B  CH 3 3 F) PCl5 G) O  CH 3 2 H) O  SiH 3 2
I) PF3 J) BF4 K) CO2
Key: 6
Sol: SiH 3 NCS, OCl2 , BF3 , BOC 2 H 5 3 , PCl3 , O SiH 3 2 , PF3
0
13. A Hypothetical metal oxide has molecular formula ‘MO’. Bond distance is 2 A . Its
exp  3.2  1029 coulomb.mt. Then percentage ionic character in it is

Given 3.33 1030 coulomb. mt  1 debye

Key: 50
3.2 1029 100
Sol: Ionic   50%
2 1.602 1019  2 1010

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RPTM-08(S)
(SINGLE CORRECT ANSWER TYPE)
This section contains 20 multiple choice questions. Each question has 4 options (1), (2), (3) and (4) for its answer, out of which ONLY ONE option can be
correct.
Marking scheme: +4 for correct answer, 0 if not attempted and –1 in all other cases.
1. In the reaction sequence
Br

C6 H 5 C CH 3 Alc.KOH / 
C6 H 5  CH3  C C  CH 3  C6 H 5
CH 3 C C6 H 5

H
Product will be:
1) cis alkene 2) trans alkene
3) Mixture of cis and trans alkene 4) Mixture of diastereomers
Key: 1
Sol: Anti elimination in threo form gives cis alkene
2. Consider the following reaction:
O
CH 3  NH  CH 2  CH 2  CH 2  OH  CH 3  C  Cl
In the above reaction:
1) CH 3  CO  N  CH 3   CH 2  CH 2  CH 2  OH is the only product
2) CH 3  NH  CH 2  CH 2  CH 2  O  CO  CH 3 is the only product
3) CH 3  CO  N  CH 3   CH 2  CH 2  CH 2  OH is a major product and
CH 3  NH  CH 2  CH 2  CH 2  O  CO  CH 3 is a minor product
4) CH 3  NH  CH 2  CH 2  CH 2  O  CO  CH 3 is a major product and
CH 3  CO  N  CH 3   CH 2  CH 2  CH 2  OH is a minor product
Key: 3
Sol: Amino group is more reactive than alcoholic group for acetylation reaction because
3. Consider the following sequence of reaction’s
 NH 4 2 S NaNO2 / Conc.HCl H 2O / H   i  NaOH  F 
Sn / HCl CH 3COCl
A   B   C   E   G  H
 ii C2 H5 I Py
Compound A is dinitro benzene Compound (H) is
O O

C2 H5O NH  C  CH 3 CH 3 O NH  C  C2 H 5
1) 2)
OCOCH 3 OC2 H 5 O

COOH NH  C  CH 3

3) 4)
Key: 1
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Sol: A – para dinitro benzene ; B – para nitro aniline ; C-para nitro benzene diazonium
chloride;
E-para hydroxy nitro benzene; F-para ethoxy nitro benzene; G-para ethoxy aniline; H-
phenacetin
4. Assertion : (A) : Tropolone [X] is much more basic than most of the  ,  -unsaturated
ketones (Y)
Reason : (R ) : Conjugate acid of tropolone is less stable than the conjugate acid of  ,  -
unsaturated ketones.
O

CH 2 CH-C-R
(Y)

O
[X]
1) A and R are true and R is explaining A.
2) A and R are true and R is not explaining A.
3) A is true and R is false
4) A is false and R is true
Key: 3
Sol: Tropolone can from tropylium ion which is aromatic in nature so more basic
5. A Column chromatography packed with silica gel as stationary phase was used to
separate a mixture of compounds containing (A) Benzanilide (B) Aniline and (C)
Acetophonone. When the column is eluted with a mixture of solvents, hexane : ethyl
acetate (20:80) the sequence of obtained compounds is
1) B, C and A 2) B, A and C 3) C, A and B 4) A, B and C
Key: 3
Sol: Compounds which form strong H-bond with stationary phase will come last with mobile
phase
H-bonding order B>A>C
6. Compound A  C4 H10O  when made to react with Hydrogen halide gives B which on
reaction with alcoholic silver nitrite gives C. C on reaction with nitrous acid followed by
the addition of base gives red coloration. What is compound A
CH 3

CH 3  CH 3  CH  OH
1) CH 3  CH 2  CH 2  CH 2  OH 2)
CH 3

CH 3  C  CH 3
CH 3

OH CH 3  CH  OCH 3
3) 4)
Key: 1

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HI AlcAgNO2
CH 3  CH 2  CH 2  CH 2  OH CH 3  CH 2  CH 2  CH 2  I CH3   CH 2 2  CH 2  NO2

NO2 HNO2
NO2
NaOH CH3   CH 2 2  C  N  OH
CH3  CH 2 2  C  N  ONa

Sol: Red coloration

7. Assertion : (A) : Amino acids can be identified by the use of ninhydrin

Reason : (R ) : Ninhydrin is also used for identification of 1 ,2 ,3 amines
1) A and R are true and R is explaining A.
2) A and R are true and R is not explaining A.
3) A is true and R is false
4) A is false and R is true
Key: 3
Sol: 3 amines do not give ninhydrin test
8. Statement-I: In DNA the molar ratio of adenine to thymine and guanine to cytosine is
always one.
Statement-II: Two hydrogen bonds are possible between A and T and three between G
and C
1) Both I and II are true 2) Both I and II are false
3) I is true II is false 4) I is false and II is true
Key: 1
Sol: Both I and II are true
9. Statement-I: Primary and secondary alcohols having   CH 3 group give haloform
reaction.
O
CX 3  C  R
Statement-II: Haloform reaction takes place by the formation of
1) Both I and II are true 2) Both I and II are false
3) I is true II is false 4) I is false and II is true
Key: 1
OH

CH 3  CH  group
Sol: Generally the compounds , with haloform reaction
(NUMERICAL VALUE TYPE)
Section-II contains 10 Numerical Value Type questions. Attempt any 5 questions only. First 5 attempted questions will be considered if more than 5 questions attempted.
The Answer should be within 0 to 9999. If the Answer is in Decimal then round off to the nearest Integer value (Example i,e. If answer is above 10 and less than 10.5
round off is 10 and If answer is from 10.5 and less than 11 round off is 11).
Marking scheme: +4 for correct answer, 0 if not attempt and -1 in all other cases.

10. No.of sp 2 carbon in the oligopeptide

Alanylphenylalanyltryptophanylglycyltyrosylcysteine is _____
Key: 26
Sol: No.of sp 2 carbon in the oligopeptide
Alanylphenylalanyltryptophanylglycyltyrosylcysteine is 26.

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NH2

 i  AlH  i  Bu 2 CH 3CHO
(A) (B) Major produced
 ii  H 2O dil.NaOH


11. CN
The degree of unsaturation in B is ______
Key: 6
NH2 NH2 NH2

Reduction Aldol
conductation

CHO CH  CH  CHO
Sol: CN

12.
H 2O Hg 2 / H  Ba  OH  2 NaOCl
Mg 2C3 P S T U
333k Heat H 3O 
(4.0g) (Y g)
100% 80% 80%
The mass of U is ‘Y’ gm then 10Y is _______ . U gives brisk effervescence with
NaHCO3
Key: 32
O O

H 2O 2
Hg / H  Ba  OH 2
Mg 2c3 CH 3  C CH CH 3  C  CH 3  CH3 2 C = CH  C  CH 3
0.1 mole 0.1 mole 0.04

NaOH
O

CHCl3   CH 3 2 C  CH  C  OH
Sol: 0.032

Mass of y  0.032  100  3.2 So 10y = 32

13. Number of compounds which can be reacted with 3 moles of C6 H 5 NHNH 2 are
CH 3  CHOH  CHO,
II) Glucose, III) Fructose, IV) Mannose
(I )
Key: 4
Sol: All   hydroxy carbonyl compounds give this reaction.
14. Number of chiral carbons present in  - fructo frunose is_______
Key: 4
Sol: 4 chiral carbons
15. Glucose and fructose are treated with excess of HIO4 . The no.of moles of formic acid
formed is ‘x’ and the no.of moles of formaldehyde formed is ‘y’ then x-y is __________
Key: 5
5 HCOOH 3 HCOOH

Glucose Fructose
2 CH 2O
1 CO2
Sol: 1 H 2CO

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16. How many of the following are fat soluble vitamins, vitamin-A, Thiamine, Riboflavin,
vitamin-D, vitamin-E, Pyridoxin, vitamin-K.
Key: 4
Sol: Vitamins A, D, E and k
17. How many of the following compounds can be estimated by kjeldahls method is ‘x’ ,
then x is
NH 2 N 2 Cl 
NO2
N=N OH
, , , , NH 2
,
N

Key: 2
Sol: Nitro, azo and compound with N in ring do not give this test
18. In the estimation of Sulphur by carious method the amount of Barium sulphate formed is
0.466 from 0.64 gm of organic compound. The % of Sulphur is ____________
Key: 10
32 w.t of BaSO4 32 0.466
Sol: %S   100   100  10%
233 wt.of .oc 233 0.64

19. How many of the following gives the tollen’s test

HCHO, HCOOH , C6 H 5CHO, CH 3COCH 3 , CH 3COOH
O OH
OH
CH 3  CH  C  CH 3 , CH 3  CH  CH 2  CHO, HC  C  CH 3

Key: 6
Sol: Aliphatic and aromatic aldehydes,  - hydroxy ketones, ,  - hydroxy amines, terminal
alkynes, chloroform gives this test

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RPTM-07/09(N&S)
(SINGLE CORRECT ANSWER TYPE)
This section contains 20 multiple choice questions. Each question has 4 options (1), (2), (3) and (4) for its answer, out of which ONLY ONE option can be
correct.
Marking scheme: +4 for correct answer, 0 if not attempted and –1 in all other cases.
1. About CH 2 F2 the correct statement is.
1) The order of bond angles is HCH  HCF  FCF
2) The shape of the molecule is tetrahedral
3) All bond angle are equal
4) It is a non-polar molecule
Key: 1
Sol: The order of bond angles is HCH  HCF  FCF
2. The H – bonds in solid HF can be best represented as
H H H H
H F H F H F F F F F
1) 2)
F F
H
H H H F F F F
3) F 4) H H

Key: 3

F F
H H H
Sol: F
(NUMERICAL VALUE TYPE)
Section-II contains 10 Numerical Value Type questions. Attempt any 5 questions only. First 5 attempted questions will be considered if more than 5
questions attempted. The Answer should be within 0 to 9999. If the Answer is in Decimal then round off to the nearest Integer value (Example i,e. If
answer is above 10 and less than 10.5 round off is 10 and If answer is from 10.5 and less than 11 round off is 11).
Marking scheme: +4 for correct answer, 0 if not attempt and -1 in all other cases.
3. The ionization energy of lithium is 5.41 eV and electron gain enthalpy of chlorine is -

3.61 eV. The H in kJ mol 1 for the reaction: Li  g   Cl ( g )  Li   g   Cl   s  is

1.737  10 x kJ mol 1 .What is the value of x?

Key: 2

Sol: Li g   Lig  1E1  5.41ev

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-
Cl g   Cl g  EA  3.61ev
 Li g   Cl g   Lig   Clg   r H  1.8 E  eV
 r H  kJ mole 1   1.8  1.6  10 18  6.02  1023 10 3 kJ mole 1
 17.337  102  1.73 103
x  3  near integer 
O O

CH 3  C  CH 2  C  CH 3
4. 10 moles of are treated with 8 moles of CH 3MgBr
followed by hydrolysis. How many moles of diol will be obtained?
Key: 0
Sol: because of acidic hydrogen of CH 2  group 8 moles of CH 4 will be obtained
5. Assuming there is no 2s – 2p mixing, the number of paramagnetic species amongst
the following: H 2 , He2 , Li2 , Be2 , B2 , C2 , C22 , N 2 , N 2 , O2 , O2 , S2 & F2 are
____________.
Key: 6
Sol: With no 2s- 2p mixing the order of energy of MO’s would be
1s  *1s  2s *2s  2pB  2Px , 2p y  *2px , *2py 

H 2 (D), He 2 (P), Li 2 (D), Be 2 (D), C 2 (P), C 22  (D), N 2 (P), N 2 (D)

O 2 (P), O 2 (P),S2 (P), F2 (D).
6. CH 3  CH  CH  O  CH 2  CH 3  X  Y (Y gives positive haloform test)
dil acid
The number of possible isomers for X excluding stereo isomers and including X.
Key: 9
OH

CH 3  C  CH 2
Sol: SOL: CH 3  CH  CH  OH , , HO  CH 2  CH  CH 2 , CH 3  CH 2  CHO
O
O
O
CH 3  C  CH 3 OH , CH  O  CH  CH
, , , 3 2

7. Among the following, the number of aromatic compound(s) is.....

N
NH

N
N B S
H H CH3

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Key: 4
Sol: (1, 2, 4, 5)
8. Consider the orders,
a) Electron affinity F>Cl>Br>I
b) Size: Li   aq   K   aq   Rb   aq 
c) Acidic strength of N 2O3  P2O3  As2O3
d) Size of La 3  Lu 3
e) Number of electrons in the penultimate shell of Cu-atom < Zn – atom
f) Hydration energy of F   Cl   Br   I 
2
if ‘a’ and ‘b’ are number of correct and incorrect statements, then a  b is
Key: 4
Sol: a) EA : Cl  F  Br  1
b) Li  is hydrated more, so conducts less.
c) acidic str of non-metal oxide  E.N.
d) size of La 3  Lu 3 (lanthanide contraction)
e) both have 3d10.
1
f) Hydration energy   ch arg e is same 
size
9. Find out number of substrates those cannot undergo Cannizzaro’s reaction
O
O O
O
C  CH 3
H  C  H , Ph  C  H , H 3C  C  H , ,
O O O O O O O

H  C  C  H , Cl3C  C  H ,
Ph  C  C  Ph , Ph  C  C  H ,
CHO

O
C -H
NR2
O ,
Key: 5
O

C
O
CH 3
& H 3C C H

Sol: are cannot undergo Cannizzaro’s reaction

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RPTM-08/10(N&S)
(SINGLE CORRECT ANSWER TYPE)
This section contains 20 multiple choice questions. Each question has 4 options (1), (2), (3) and (4) for its answer, out of which ONLY ONE option can be
correct.
Marking scheme: +4 for correct answer, 0 if not attempted and –1 in all other cases.
10. Given below are two statements, one is labeled as Assertion (A) and the other is labeled
as Reason (R).
Assertion (A) Bromobenzene upon reaction with Br2 / Fe gives 1,4-dibromobenzene as
the major product.
Reason (R) In bromobenzene, the inductive effect of the bromo group is more dominant
than the mesomeric effect in directing the incoming electrophile.
In the light of the above statements, choose the correct answer from the options given
below.
1) Both Assertion and Reason are correct statements and Reason is the correct
explanation of the Assertion.
2) Both Assertion and Reason are correct statements but reason is not the correct
explanation of the Assertion.
3) Assertion is correct but Reason is incorrect.
4) Assertion is incorrect but Reason is correct.
Key: 3
Sol: Assertion is correct and Reason is incorrect.
Br Br Br

Br


Br2 / Fe
 +

Bromobenzene 1,2-dibromobenzene
(Minor)
Br
1,4-dibromobenzene
(Major)
Bromine orientation is controlled by its mesmeric effect (+M) and it also gives
stabilization to the adenium ion.
 M 
Br Br

Br 

Br H
Arenium ion
(NUMERICAL VALUE TYPE)
Section-II contains 10 Numerical Value Type questions. Attempt any 5 questions only. First 5 attempted questions will be considered if more than 5
questions attempted. The Answer should be within 0 to 9999. If the Answer is in Decimal then round off to the nearest Integer value (Example i,e. If
answer is above 10 and less than 10.5 round off is 10 and If answer is from 10.5 and less than 11 round off is 11).
Marking scheme: +4 for correct answer, 0 if not attempt and -1 in all other cases.
11. The half-life of most stable isotope of the element, Nihonium is____ seconds

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Key: 20
Sol: The half-life of most stable isotope of the element, Nihonium is 20 seconds
12. How many bases are weaker than TlOH Ga  OH 3 , In  OH 3 , B  OH 3
Key: 3
Sol: The bases weaker than TIOH are, Ga  OH 3 , In  OH 3 , B  OH 3
13. Equivalent weight (in g) of boric acid in water is....
(B=11, O=16, H=1)
Key: 62

Sol: H 3 BO3  H 2O   B  OH 4   H 
G 62
N factor =1, E    62
' n ' factor 1
14. The number of compounds which are more acidic than ethyne is....
CH 2  CH 2 , NH 3 , H 2O , CH 3  CH 3 , HF ,
CH 3CH 2  OH , CH 3  CH 2  SH ,

Key: 5
Sol: H 2O, HF , CH3CH 2  OH ,

CH3  CH2  SH and are

15. An optically active compound enriched with R-enantiomer (60% enantiomeric excess)
exhibited  D  90 . If the  D value of the sample is –1350 , the ratio of S and R
0

enantiomers would be .......

Key: 19
Sol: 60% R-enantiomer exhibit+900 optical rotation
Then, 100% R-enantiomer will exhibit
100
  900 
60
=+1500 optical rotation Hence, 100% S-enantiomer will exhibit – 1500 optical rotation.
If-1500 optical rotation corresponds to 100% S-enantiomer.
100
So, - 1350 optical rotation corresponds to   1350   90%
 150 0

S-enantiomer Hence, the rest 10% is an equal mixture of R and S enantiomeric forms.
Total S-enantiomer form   90%  5%   95% and total R- enantiomeric form=5%
 The ratio of S and R-enantiomers =95:5=19:1

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16. 12.0g of acetophenone on reaction with 76.2g of iodine in presence of aq. NaOH gave
solid A in 75% yield. Approximate amount of A obtained (in gram) in the reaction is
[atomic
wt of I  127] .......
Key: 30
Sol: Acetophenone  I 2  4 NaOH  CHI3
1 mole 3 mole 1 mole
120 g 762 g 394 g
12 g 76.2 g 39.4 g if yield is 100%.
75
Since yield is 75%, 39.4   29.55 g
100
17. The number of organic products which are possible for the given stereo selective and
regio selective reaction is .........
CH 3
 i  BH 3 .THF
 
 ii OH / H 2O2
Key: 2
Sol: In hydroboration-oxidation reaction of an alkene, both stereo and regioselectivity occurs
for addition of H (of B2H6) and OH (of H2O/H2O2)
CH 3 CH 3

H H
and
OH OH
H H
18. The number of reagents used for this conversion is........

R  N  C  R  NH  CH 3
1. H 2 / Ni /  2. Metal/ acid 3. LiAlH 4
4. Na/EtOH 5. P2O5 /  6. CHCl3 / Alc.KOH / 
Key: 4
Sol: Correct reagents (reducing agents) are,
I. H 2 / Ni / 
II. metal/acid
III. LiAlH 4
IV. Na/EtOH (Medius reaction)

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RPTM-09/11(N&S)
(SINGLE CORRECT ANSWER TYPE)
This section contains 20 multiple choice questions. Each question has 4 options (1), (2), (3) and (4) for its answer, out of which ONLY ONE option can be
correct.
Marking scheme: +4 for correct answer, 0 if not attempted and –1 in all other cases.
9. Which of the following order is incorrect?
1) NH 3  PH 3  AsH 3  SbH 3 : Bond dissociation enthalpy
2) Sb > Bi : Boiling point
3) Bi > Pb : Ionization enthalpy
4) N > P > As > Sb: Electronegativity (Pauling scale)
Key: 3
Sol: M.P : N < P < As < Sb < B, B.P : N < P < As < Bi < Sb
(NUMERICAL VALUE TYPE)
Section-II contains 10 Numerical Value Type questions. Attempt any 5 questions only. First 5 attempted questions will be considered if more than 5
questions attempted. The Answer should be within 0 to 9999. If the Answer is in Decimal then round off to the nearest Integer value (Example i,e. If
answer is above 10 and less than 10.5 round off is 10 and If answer is from 10.5 and less than 11 round off is 11).
Marking scheme: +4 for correct answer, 0 if not attempt and -1 in all other cases.
10. How many of the following are amphoteric oxides:
CO,GeO,SnO,PbO, PbO 2 ,SiO 2 ,GeO 2 , As 2O 3 ,Sb 2O 3
Key: 5
+ 
1) 3)

Sol:
2)
(d)

SnO, SnO2, PbO, PbO2 – amphoteric

11. How many of the following have density more than that of water?
Carbon, Silicon, Germanium, Tin , lead
Key: 5
Sol: (C, Si, Ge, Sn, Pb) > H2O : Density
12. SiF4 on hydrolysis gives two products X and Y. Sum of the oxidation states of silicon in
both compounds X and Y is +p, then the value of p is:
Key: 8
Sol: SiF4  H 2O  H 4 SiO4  H 2 SiF6
13. How many of the following are metalloids?
Phosphorus , Arsenic, Antimony, Bismuth, Lead, Nitrogen, Carbon
Key: 2
Sol: As, Sb
14. Value of ‘x’ in the given reaction

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i)x CH I
ii 3
) AgOH

N
H
Key: 3
Sol: Conceptual
15. The no.of stero isomers formed by the catalytic hydrogenation of both double bonds in
the given compound is :

Key: 3
Sol: Conceptual
16. In the given reaction no.of (CH2-OH) groups present in the product (P) is :
O

H3CCHH
CHO(excess)
 
NaOH
 P + Sodiumformate
Key: 4
Sol: Three aldol condensation followed by Cannizaro’s reaction.
CH2-OH

HO H2CCCH2 OH + Sodiumformate

CH2-OH
(P)

17.
Number of p  -d  bond
(consider hybridization)
NO2 x
NO3 Y
CO32 z
Then (x + y + z) is _____
Key: 0
Sol: NO2 ,NO3 ,CO32 : Al ions have zero pπ  dπ bonds

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GTM-03(N)
(SINGLE CORRECT ANSWER TYPE)
This section contains 20 multiple choice questions. Each question has 4 options (1), (2), (3) and (4) for its answer, out of which ONLY ONE option can be
correct.
Marking scheme: +4 for correct answer, 0 if not attempted and –1 in all other cases.
14. Match List-I with List-II.
List - II(Group in Qualitative
List – I (Metal Ion)
analysis)
2+
a) Mn i) Group - III
3+
b) As ii) Group - IIA
2+
c) Cu iii) Group - IV
3+
d) Al iv) Group - IIB
Choose the most appropriate answer from the options given below :
1) (a)-(i), (b)-(ii), (c)-(iii), (d)-(iv) 2) (a)-(iii), (b)-(iv), (c)-(ii), (d)-(i)
3) (a)-(i), (b)-(iv), (c)-(ii), (d)-(iii) 4) (a)-(iv), (b)-(ii), (c)-(iii), (d)-(i)
Key : 2
Sol : Mn2+ → III group
As3+ → II B group
Cu2+ → II A group
Al3+ → IV group
15. The major product of the following reaction is :

1) 2)

3) CH 3CH  CH  CH 2 NH 2 4)
Key : 2

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Sol :
16. The incorrect statement among the following is
1) Cr2O3 is an amphoteric oxide

2) Red color of Ruby is due to the presence of Co3

3) RuO4 is an oxidizing agent
4) VOSO4 is a reducing agent
Key : 2
Sol : Ruby red →Cr3+
(NUMERICAL VALUE TYPE)
Section-II contains 10 Numerical Value Type questions. Attempt any 5 questions only. First 5 attempted questions will be considered if more than 5
questions attempted. The Answer should be within 0 to 9999. If the Answer is in Decimal then round off to the nearest Integer value (Example i,e. If
answer is above 10 and less than 10.5 round off is 10 and If answer is from 10.5 and less than 11 round off is 11).
Marking scheme: +4 for correct answer, 0 if not attempt and -1 in all other cases.
17. Five moles of an ideal gas at 293K is expanded isothermally from an initial pressure of
2.1MPa to 1.3 MPa against at constant external pressure 4.3 MPa. The heat transferred in

this process is……….. kJ mol 1 (Rounded – off to the nearest integer)

Use R  8.314 J mol 1K 1

 
Key : 15
5  8.314  293 3 P2 V2 1.3  9.369 10 3
vf   9.369 10 , vi  
1.3 106 V1 2.1
Sol :
8.314  1 1 
w  Pext  V   4.3  5  6
 293     15.3
10  1.3 2.1 

18. For the reaction, A+B⇌2C the value of equilibrium constant is 100 at 298 K. If the initial
concentration of all the three species is 1 M each, then the equilibrium concentration of C

is x  10 1 M . The value of x is ___________ (Nearest integer)

Key : 25

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Sol :
2
 1  2x 
100   
 1 x 
 1  2x 
   10
 1 x 
3
x
4
  q.  1  2x
C e
 3
 1 2 
 4
 2.5M
25 101 M
19. The number of geometrical isomers possible in triamminetrinitrocobalt (III) is X and in
trioxalatochromate (III) is Y. Then the value of X + Y is _______.
Key : 2
Sol : Triamminetrinitrocobalt(III) →CoNO23NH33
trioxalatochromate(III) ion →CrC2O433− CoNO23NH33

CrC2O433−

X + Y = 2 + 0 = 2.0
20. EMF of the following cell at 298 K in V is x×10−2.
Zn|Zn2+0.1M||Ag+0.01M|Ag
The value of x is ________. (Round off to the nearest integer)
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2.303RT
[Given : E Zn2 / Zn  0.76 V; E Ag  / Ag  0.80 V;  0.059
F

Key : 147
Sol : Considering the given cell-representation:
Oxidation at anode:
Zn(s)→Zn2+(aq)+2e−
Reduction at cathode:
Ag+(aq)+e−→Ag(s)
E ocell  E oAg  / Ag  E oZn2 / Zn
E ocell   0.80   0.76   V  1.56V
Zn  s   2 Ag   aq   Zn  aq   2 Ag  s  n  2 
 Zn 2 
QR   2
 Ag  
0.059
E cell  E cell
o
 log Q R
n
0.059 0.1
 1.56  log
2 0.01
 1.56  0.08865
 1.47135 V
 147.135 102 V
 147 102 V

21. A 1 molal K4Fe(CN)6 solution has a degree of dissociation of 0.4. Its boiling point is
equal to that of another solution which contains 18.1 weight percent of a non electrolytic
solute A. The molar mass of A is_____ u. (Round off to the Nearest Integer).
 Density of water  1.0 g cm –3 
 
Key : 85
Sol : K 4 Fe(CN )6  4K   Fe(CN )6 4
Initial conc. 1 m 0 0
Final conc. (1 – 0.4)m 4 × 0.4 0.4m
= 0.6 m = 1.6 m
Effective molality = 0.6 + 1.6 + 0.4 = 2.6m
For same boiling point, the molality of another solution should also be 2.6 m. Now, 18.1
weight percent solution means 18.1 gm solute is present in 100 gm solution and hence,
(100 – 18.1 =) 81.9 gm water.
18.1 / M
Now, 2.6 
81.9 /1000
∴ Molar mass of solute, M = 85

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22. 0.8 g of an organic compound was analyzed by Kjeldahl's method for the estimation of
nitrogen. If the percentage of nitrogen in the compound was found to be 42%, then
__________ mL of 1M H 2 SO4 would have been neutralized by the ammonia evolved
during the analysis.
Key : 12
42
Weight of N  0.8 
100
Sol : 42
0.8 
Mol of N  100  2.4 mol
14 100
2.4
Moles of ammonia is mol.
100
2 NH 3  H 2 SO4   NH 4  2 SO4
2.4 1.2
mol mol
100 100

1.2
mol  1 V  l   12 ml
100
23. For the reaction Ag  Bg , the value of the equilibrium constant at 300 K and 1 atm is
equal to 100.0. The value of Δ r G for the reaction at 300 K and 1 atm in J mol 1 is
– xR, where x is ________. (Rounded off to the nearest integer).
 R  8.31J mol 1
K 1 and ln 10  2.3 
Key : 1380
 r G o   RT ln Keq
Sol :   R  300  2  2.3
 1380 R

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RPTM-12(S)
(SINGLE CORRECT ANSWER TYPE)
This section contains 20 multiple choice questions. Each question has 4 options (1), (2), (3) and (4) for its answer, out of which ONLY ONE option can be
correct.
Marking scheme: +4 for correct answer, 0 if not attempted and –1 in all other cases.
12. ‘A’ in the given reaction is
OH COOH
H H 
' A'
 Major

OH O

1) 2)

OH COOH
C

3) OH 4)
Key : 2
H
COOH
H OH H
C H
 C C 
OH C o
HO
H
H2O
H
C

Sol : C o

13. Identify the product formed (A and E)

Me

Br2 Sn / Hcl NaNO2 / HCl H 3 PO2 / H 2O  i  KMnO4 / KOH

  A   B   C   D  E
273-278 K ii ) H 3O   

NO2

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Me
COOH
Br
Br
, E
Br
Br
NO2
1) 2)
Me COOH
Br Br
A= , E=

NO2

Me COOH
Me
Me Br Br
Br Br A= , E=
A=
, E=
NO2

3) NO2
4) OH

Key : 2
Me Me Me Me
Br
Br Br

Br
 2
 
Sn/Hcl
N
 
aNO2 / HCl

273278K

NO2 NO2 NH2 N2Cl

 A  B  C

H3PO2 / H2O

COOH Me
Br
Br
 i KMnO4/KOH
 i H3O

Sol :  E  D

14. Given below are two statements:

Statement I: Upon heating a borax bead dipped in cupric sulphate in a luminous flame,
the colour of the bead becomes green.
Statement II: The green colour observed is due to the formation of copper(I) metaborate.
In the light of the above statements, choose the most appropriate answer from the
options given below:

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1) Both Statement I and Statement II are true.
2) Statement I is true but Statement II is false.
3) Both Statement I and Statement II are false.
4) Statement I is false but Statement II is true.
Key : 3
Sol : (Borax Bead Test)
On treatment with metal salt, boric anhydride forms metaborate of the metal which gives
different colours in oxidising and reducing flame.
For example, in the case of copper sulphate, following reactions occur.

 Cu  BO2 2  SO3
Non  hu min ous flame
 
CuSO4  B2O3 
 oxiding 

Two reactions may take place in reducing flame (Luminous flame)

(i) The blue-green Cu(BO2)2 is reduced to colourless cuprous metaborate as :

2Cu  BO2 2  2 NaBO2  C 

Lu min ous
flame

2Cu  BO2   Na2 B4O7  CO
(ii) Cupric metaborate may be reduced to metallic copper and bead appears red
opaque.
2Cu  BO2 2  4 NaBO2  2C  
Lu min ous
flame


2Cu  2 Na2 B4O7  2CO

(NUMERICAL VALUE TYPE)

Section-II contains 10 Numerical Value Type questions. Attempt any 5 questions only. First 5 attempted questions will be considered if more than 5
questions attempted. The Answer should be within 0 to 9999. If the Answer is in Decimal then round off to the nearest Integer value (Example i,e. If
answer is above 10 and less than 10.5 round off is 10 and If answer is from 10.5 and less than 11 round off is 11).
Marking scheme: +4 for correct answer, 0 if not attempt and -1 in all other cases.

15. How many of the following are acidic oxides?

SO2 , CO2 , Cl2O7 , Al2O3 , MgO , Mn2O7 , ZnO

Key : 4
Sol : SO2 , CO2 , Cl2o7 , Mn2O7 , CrO3 ,V2O5
16. The sum of lone pairs present in interhalogen BrF5 and IF7 is _______.
Key : 37

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Sol : BrF5 has 1 lone pair and IF7 ha "o " lone pair on central atom

‘F’ has 3 lone pairs  Total no of lone pairs = [1+3(5)] + [0+7(3)]=37

17. Number of compounds giving (i) red colouration with ceric ammonium nitrate and also
(ii) positive iodoform test from the following is _______

OH
CH 3 , OH , , ,
OH
OH

, , ,
OH

Key : 3

OH
OH

Sol : OH

18. How many of the compound will evolve methane gas on treatment with CH 3 MgBr__.
(A) H2O (B) CH3-OH (C) CH3COCH3 (D) CH3COOH
(E) CH3CONH2 (F) CH3COCl (G) CH3COOCH3 (H) CH3Cl (I) Ph-OH
Key : 5
Sol : H 2O, CH 3  OH , CH 3COOH , CH 3CONH 2 , Ph  OH

19. How many of the following properties of the elements chlorine, bromine and iodine
increase with increasing atomic number?
i) Ionization energy ii) Ionic radius
iii) Bond energy of the molecule X2 iv) Enthalpy of vaporization
Key : 2

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Sol : ii and iv are correct
20. The total number of molecules with zero dipole moment among
CH 4 , BF3 , H 2O, HF , NH 3 , CO2 and SO2_________.
Key : 3
Sol : Molecules with zero dipole moment = CO2, CH4, BF3

21. If IUPAC name of an element is “ Ununbium” then the element belongs to n th group of
periodic table. The value of n is__________.
Key : 12
Sol : 112 belongs to 12th group
22. On a thin layer chromatographic plate, an organic compound moved by 4.0 cm, while the

solvent moved by 5 cm. The retardation factor of the organic compound is ____ 101 .
Key : 8

Dis tan ce travelled by sampleorganic compound 4.0

Sol : Re tardation factor   8  101
Dis tan ce travelled by solvent 5
23. Sum of the bond orders of O-O bond in O2 and O3 is x.
Oxidation state of Oxygen in OF2 is y . Then 2x-y =________.
Key : 5
Sol : Bond order O2 = 2, Bond order O3 = 1.5,Ox. State ‘O’ in OF2 = +2

2x-y = 2(2+1.5)-2 = 7-2 = 5

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RPTM-10/13(N&S)
(SINGLE CORRECT ANSWER TYPE)
This section contains 20 multiple choice questions. Each question has 4 options (1), (2), (3) and (4) for its answer, out of which ONLY ONE option can be
correct.
Marking scheme: +4 for correct answer, 0 if not attempted and –1 in all other cases.
9. The correct Statements among the following
i) order of acidic character: HCOOH  C 6 H 5COOH  CH 3COOH
ii) Order of Basic character :

 
N N N
H H
iii) Order of Electrical conductivity:
0.1M CH 2Cl  COOH  0.01M CH 2Cl  COOH  0.1M CH 3COOH
IV) Order of boiling points :

O
CH3  CH2  CH2  CH2  OH   CH3 3 C  OH  CH3  C  CH 2  CH3  CH3  CH 2  O  CH 2  CH3
1) I, II and III 2) I, III and IV 3) I and IV 4) All
Key: 3
Sol: I, IV are correct

 
N N N

II) Basic character H H

1
III) Conductivity 
conc. of weak electrolyte
0.01M CH 2ClCOOH  0.1M CH 2Cl  COOH  0.1M CH 3COOH
(NUMERICAL VALUE TYPE)
Section-II contains 10 Numerical Value Type questions. Attempt any 5 questions only. First 5 attempted questions will be considered if more than 5
questions attempted. The Answer should be within 0 to 9999. If the Answer is in Decimal then round off to the nearest Integer value (Example i,e. If
answer is above 10 and less than 10.5 round off is 10 andIf answer is from 10.5 and less than 11 round off is 11).
Marking scheme: +4 for correct answer, 0 if not attempt and -1 in all other cases.
10. Among the following complexes how many have spin only magnetic moment of 2.83 BM
2
 Ni  CO 4  ,  Ni  CN  4  ,  NiCl2  H 2O 2  ,  NiCl 4  ,
2

 NiF  ,  Ni  NH 3  6  ,  Ni  en 3  ,  Ni  H 2O  6 
4 2 2 2
6

Key: 6
 
Sol: In NiCl2  PPH 3  2 ,  NiCl 4   SP3 , n  2
2
3d 8

In  NiF6  ,  Ni  NH 3 6  ,  Ni  en 3  ,  Ni  H 2O  6   SP 3d 2 , n  2 3d 8  
4 2 2 2

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11. “X” moles of KMnO 4 oxidizes one mole Ferrous oxalate in acidic medium and “Y”
moles of K 2Cr2O 7 oxidizes one mole of Ferrous oxalate in acidic medium. The value

 x  y102 will be

Key: 10
Sol: 3mole . KMnO 4  5 mole FeC2O 4
?  1 mole FeC 2O 4
30
 mole KMnO 4  0.6 mole KMnO 4  X  0.6 moles
5
3 moles K 2Cr2 O 7  6 moles FeC 2 O 4
3
?  1 mole FeC 2O 4   0.5 moles
6
 x  y100   0.1100  10 y  3 / 6  0.5 moles K 2Cr2O 7

12. The fusion of chormite ore with sodium carbonate in the presence of air leads to the
formation of “A” and Fe 2O3 along with evolution of “ CO 2 ”. The spin only magnetic
moment of transition metal ion in ‘A’ will be (In B.M)
Key: 0
Sol: 4FeC2O 4  8Na 2CO3  7O 2  8Na 2CrO 4  8CO 2 2Fe 2O3
Chromite ore  A

 
Na 2 CrO 4  Cr 6 3d o

n0
0
13. How many of the following are correct statements
i) The possible coordination Isomers are “3” for a compound [ Cr  en  3 ] [ Co  NO 2 6 ]

(excluding the given compound)

2
ii) The crystal field stabilization energy of  Mn  H 2O  6  is “Zero”
3
iii) The number of “ t 2g ” electrons in  Fe  H 2O  6  is “5”

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iv) The coordination number of d-block element in sodium nitro prusside is “6”.
v) The number of geometrical Isomers possible for [Ir  Cl Br   NH 3  Py ] is “3”

vi) The EAN of Mo  CO 6  is 54

vii) All Transition elements are ‘d’ block elements

Key: 6
Sol: I, II, IV, V, VI, VII are correct
3
In  Fe  H 2O  6  , Fe 3  3d 5 4s o 4p o

H 2O  Weak ligand = t 2g 3 eg 2

Number of electrons in t 2g  3

14. Excess of HIO 4 splits glucose and Fractose in to formic acid and Formaldehyde. The
ratio of formic acid to formaldehyde in glucose and fructose are “X” and “Y”
respectively. The value of "X  2y" will be
Key: 2
CHO

 CHOH 4 
HIO
 5HCOOH  1HCHO
4

5
CH 2 OH x
1

CH 2  OH

CO

 CHOH 4 
HIO
 3HCOOH  2HCHO
4

3
CH 2 OH Y 
2
3
X  2y  5   2  5  3  2
Sol: 2

The difference between spin only magnetic moment values of  CoF6  and
3
15.
3
Cr  H 2O 6  will be (In B.M)

Key: 1

CoF6  -n = 4,   4  4  2   24  5 B.M
3
Sol:
3
Cr  H 2 0 6  , n  3,   3 3  2   15  4

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RPTM-11/14(N&S)
(NUMERICAL VALUE TYPE)
Section-II contains 10 Numerical Value Type questions. Attempt any 5 questions only. First 5 attempted questions will be considered if more than 5
questions attempted. The Answer should be within 0 to 9999. If the Answer is in Decimal then round off to the nearest Integer value (Example i,e. If
answer is above 10 and less than 10.5 round off is 10 and If answer is from 10.5 and less than 11 round off is 11).
Marking scheme: +4 for correct answer, 0 if not attempt and -1 in all other cases.
10. XeF6 reacts with Silica to form a xenon compound X. The oxidation state of Xe in X is
…
Key: 6
SiO SiO SiO
Sol: XeF6 
2  XeOF 
4
2  XeO F 
2 2
2  XeO in XeO oxidation state of Xe  6
3 3
x

11. Number of metal ions characterized by flame test among the following is

Sr 2 , Ba 2 , Ca 2 , Cu 2 , Zn2 , Fe2
Key: 4

Sol: Sr 2 , Ba 2 , Ca 2 , Cu 2
12. Among PbS , CuS , HgS , MnS , NiS , CoS and SnS 2 . The total number of Black coloured
sulphides is ……….
Key: 5
Sol: Black ppt  PbS , CuS , HgS , NiS , CoS
H 3C
C H
CCl
 Br2 
4
Product (P)
C
13.
H 3C H

Consider the above chemical reaction. The number of stereoisomers formed as the
product (P) is……….
Key: 2
H 3C
C H
CCl
 Br2 
4
C
H 3C H
Sol: cis

Addition of Br2 is anti, thus

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CH 3

H C Br
P is and its enantiomer.
Br C H

CH 3

14. From the given compounds if X number of compounds are acidic in water.
CaO, SO2 , SO3 , Fe2O3 , Cl2O7 , CO2 , Na2O
Find the value of X .
Key: 4
Sol: Non - metal oxiderate acedic
15. Find number of yellow ppt. from given below:
AgCl , AgBr , PbCrO4 , Fe  SCN 3 , PbBr2 , Fe  OH 3

Key: 2
Sol: Yellow ppt.  AgBr , PbCrO4 , PbI 2
16. Find the oxidation number of chromium in product of given reaction:
2 H SO
Na2CrO4 
2 4  ..............

Key: 6
Sol: 2CrO42   2 H   Cr2O72   H 2O
17. Sum of p  d bonds in SO2 and SO3 is
g g

Key: 3
Sol: 2+1
18. Number of species having non-pyramidal shape among the following is
SO3 , NO3 , PCl3 , CO32  , SF6 , BF3
Key: 5
Sol: PCl3

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RPTM-12/15(N&S)
(NUMERICAL VALUE TYPE)
Section-II contains 10 Numerical Value Type questions. Attempt any 5 questions only. First 5 attempted questions will be considered if more than 5
questions attempted. The Answer should be within 0 to 9999. If the Answer is in Decimal then round off to the nearest Integer value (Example i,e. If
answer is above 10 and less than 10.5 round off is 10 and If answer is from 10.5 and less than 11 round off is 11).
Marking scheme: +4 for correct answer, 0 if not attempt and -1 in all other cases.
15. How many EDTA (ethylene diaminetetra acetic acid) molecules are required to make a
complex with a Ca 2 ion?
Key: 1
Sol: One molecule of EDTA combines with one ion of Ca 2
16. Actinoid ion Number of unpaired electrons
U 5  Z  92  A
Pu 6  Z  94  B
Then (A + B) is …….
Key: 3
Sol: U-electronic configuration  Rn  5f 3 6d1 7s 2

17.  
Number of lanthanoid ions Ln 3 having half filled f 7 configuration = x

 
Number of actinoid ions An 3 having half filled f 7 configuration = y

Then (x + y) is ………….
Key: 2
Sol: x = 1, y = 1
18. How many of the following statements are correct?
I) Lanthanoids are silvery white metals and tarnish in air
II) Actinoids are silvery in appearance
III) The chemistry of the actinoids is much more complicated than the lanthanoids
IV) Both La 3 and Lu 3 are yellow coloured in aqueous solutions
V) Among actinoids, the elements in the first half of the series frequently exhibit higher
oxidation states.
VI) The magnetic properties of the actinoids are more complex than those of the
lanthanoids
Key: 5

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3 3
Sol: La , Lu : colourless
19. How many of the following will form paramagnetic tri positive ions?
Dy, Ho, Tm, Er, Ac, La, Bk, Fm, No
Given that : Atomic numbers: No = 102, Fm = 100, Bk = 97, La = 57, Ac = 89,
Er = 68, Dy = 66
Key: 7
Sol: La 3 , Ac 3 : diamagnetic
20. XeO4 molecule is tetrahedral having 'x' number of p  d bonds. The value of ' x ' is.
Key: 4
Sol: Pu   Rn  4f 6 7s 2
21.

How many sp2 carbon atoms are present in the product?

Key: 3
Sol: When cylco pentanone reacts with dil. KOH and heat. It under goes in aldol condensation.
22. Find out number of substrates those cannot undergo cannizzaro’s reaction

Key: 4
Sol:

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Are can not undergo due to  H's

Are can not undergo due to sterically hindered

23.

The molecular weight of (B) is …………..

(Atomic masses F = 19, H = 1, C = 12, N = 14, O = 16, B = 11
Key: 123

Sol:

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GTM-04(N)
(SINGLE CORRECT ANSWER TYPE)
This section contains 20 multiple choice questions. Each question has 4 options (1), (2), (3) and (4) for its answer, out of which ONLY ONE option can be
correct.
Marking scheme: +4 for correct answer, 0 if not attempted and –1 in all other cases.
7. Given two statements below:
Statement- I : In Cl2 molecule the covalent radius is double of the atomic radius of
chlorine.
Statement- II : Radius of anionic species is always greater than their parent atomic
radius.
Choose the most appropriate answer from the options given below:
1) Both statement- I and statement-II are correct.
2) Both statement -I and statement- II are incorrect.
3) Statement -I is correct but statement- II is incorrect.
4) Statement- I is incorrect but statement- II is correct.
Key: 4
Sol: covalent radius will be smaller than atomic radius, as it involves in overlapping.

8. Consider the following reactions:

(i) Glucose+ROH  Acetal 

dry HCl x eq .of
 CH 3CO 2 O acetyl derivative

(ii) Glucose   A 

Ni / H2 y eq.of
 CH 3CO 2 O acetyl derivative

(iii) Glucose 

z eq.of
 CH 3CO 2 O acetyl derivative

'x', 'y' and 'z' in these reactions are respectively.

1) 4, 6 & 5 2) 5, 6 & 5 3) 5, 4 & 5 4) 4, 5 & 5
Key: 1

Sol:
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9. The increasing order of basicity of the following compounds is

1) (A) < (B) < (C) < (D) 2) (B) < (A) < (D) < (C)
3) (B) < (A) < (C) < (D) 4) (D) < (A) < (B) < (C)
Key: 2
Sol: Aliphatic amines are more basic than aromatic amines
∴ c is more basic.
‘B’ is least basic since the l.p electrosn on 'N ' atom involved in aromatricity.
(NUMERICAL VALUE TYPE)
Section-II contains 10 Numerical Value Type questions. Attempt any 5 questions only. First 5 attempted questions will be considered if more than 5
questions attempted. The Answer should be within 0 to 9999. If the Answer is in Decimal then round off to the nearest Integer value (Example i,e. If
answer is above 10 and less than 10.5 round off is 10 and If answer is from 10.5 and less than 11 round off is 11).
Marking scheme: +4 for correct answer, 0 if not attempt and -1 in all other cases.
10. Number of grams of bromine that will completely react with 5.0 g of pent-1-ene is

____________ 102 g . (Atomic mass of Br=80 g/mol) [Nearest Integer)

Key: 1143

Sol:
moles of Br2 = moles of C5H10
W 5
 
160 70
5 160
W g
70
 11.428g
 1142.8  10 2 g  1143  102 g
11.

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Consider the above reaction. The number of π electrons present in the product 'P' is____.
Key: 2
Sol: Number of π electron=2
substitution of OH done at any position will certainly need one pi bond, hence will
contain a pi bond, therefore two pi electrons.

12. The molartiry of HNO3 in a sample which has density 1.4 g/mL and mass percentage of
63% is ______ ( Molecular weight of HNO3  63 )
Key: 14

Sol: Mass percentage is 63% which means that 63 g of solute present in 100 g of solution.

Mass 100
Density  1.4 g / mL  volume  71.428 mL
Volume volume
Molarity is calculated as:
mass 1000 63  1000
molarity   molarity   14 M
molar mass volumein mL 63  71.428
13. Total number of possible stereoisomers of dimethyl cyclopentane is________

Key: 6
Sol:

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14. A solution containing 2.5  103 kg of a solute dissolved in 75  103 kg of water boils

at 373.535 K. The molar mass of the solute is ______ g mol 1 . [nearest integer]

(Given: Kb  H 2O   0.52 K Kg mol 1 and boiling point of water =373.15 K)

Key: 45
Sol: The molar mass of the solute is 45 g mol-1.
w  2.5 g , K b  0.52
w solvent  75 g, M  Mol. Wt. of solute
T  373.535 K
'
B

TBo  373.15 K TB  K b m  0.385

 2.5 1000  -1
0.385  0.52     M=45 g mol
 M 75 
15. Complexes  ML5  of metals Ni and Fe have ideal square pyramidal and trigonal

bipyramidal geometries, respectively. The sum of the 90 , 120 and 180 L-M-L angles

in the two complexes is____

Key: 20
Sol: ML5 with Square pyramid.

Contains eight 90° angle and two diagonal 180 angles (total=10).
ML5 with TBP structure.

Contains six 90° and three 120° and one 180°. So total = 10.
Sum in both = 10 + 10 = 20.
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RPTM-16(S)
(SINGLE CORRECT ANSWER TYPE)
This section contains 20 multiple choice questions. Each question has 4 options (1), (2), (3) and (4) for its answer, out of which ONLY ONE option can be
correct.
Marking scheme: +4 for correct answer, 0 if not attempted and –1 in all other cases.
15. Assertion (A): Methane and steam passed over a heated Ni catalyst produces hydrogen
gas.
Reason (R): Sodium nitrite reacts with NH 4Cl to give H 2O , N 2 and NaCl .
1) Both (A) and (R) are correct
2) Both (A) and (R) are incorrect
3) (A) is incorrect but (R) is correct
4) (A) is correct but (R) is incorrect
Key: 1
CH 4 ( g )  H 2O ( g ) Ni
1270 K
 CO ( g )  3H 2 ( g )
Sol:
Steam
NaNO2 ( aq )  NH 4Cl ( aq )  N 2 ( g )  NaCl (aq )  2 H 2O (l )
16. Assertion (A): Upon heating a borax bead dipped in cupric sulphate in a luminous flame,
the
colour of the bead becomes bluish green.
Reason (R): The bluish green colour observed is due to the formation of copper(II)
metaborate.
1) Both (A) and (R) are correct
2) Both (A) and (R) are incorrect
3) (A) is incorrect but (R) is correct
4) (A) is correct but (R) is incorrect
Key: 3
Sol: On treatment with metal salt, boric anhydride forms metaborate of the metal which gives
different colours in oxidizing and reducing flame.
CuSO4  B2O3 
Non-luminous flame
(Oxidising)
 Cu ( BO2 ) 2  SO3
Cupric metaborate
blue-green

Two reactions may take place in reducing flame (Luminous flame)

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2Cu ( BO2 ) 2  2 NaBO2  C 
 2CuBO2  Na2 B4O7  CO
luminous
flame
i)
Blue green Colourless
2Cu ( BO2 ) 2  4 NaBO2  2C 
luminous
flame
 2Cu  2 Na2 B4O7  2CO
ii)
Bead appears red opaque

17. For the solution of gases w, x, y and z in water at 298 K, the Henry’s law constants
( K H ) are 5, 20, 35 and 40 kbar respectively. The correct plot for the given data is :

1) 2)

3) 4)
Key: 1
Sol: According to Henry’s law
P  K H . X gas
 X gas  X H 2O  1  X gas  1  X H 2O
 P  K H (1  X H 2O )  P  K H  K H . X H 2O
y  c  mx ; m   K H  slope is negative and c  K H
Therefore, the intercept on Y axis increases from w to z.
18. 0.1M FeCl3 when treated with 0.1M KSCN gives red colour solution of Fe( SCN )3 .
The two solutions are separated as shown below:
[SPM: Semi Permeable Membrane]
FeCl3 KSCN

Side X SPM Side Y

Due to osmosis :
1) Red colour formation observed on side Y
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2) Red colour formation observed on side X
3) Molarity of FeCl3 solution is lowered
4) Molarity of KSCN solution is lowered
Key: 3
Sol: Only solvent molecules are allowed to pass through the SPM.
Water moves from KSCN to FeCl3 solution causing molarity of FeCl3 to decrease.
19. Correct statements from the following
A) The observed molar mass of acetic acid in benzene is more than the normal molar
mass
of acetic acid
B) Vapour Pressure of a solution depends on size of solute particle
C) By adding non volatile solute depression in freezing point decreases.
D) In reverse osmosis solvent flows from conc.solution to dil.solution
1) A and D are correct 2) A, C, D are correct
3) A, B, C are correct 4) All are correct
Key: 1
Sol: Acetic acid undergoes dimerisation in aprotic solvent
20. At 1000 C , the vapour pressure of a solution of 4.0 g of solute in 100g of water is
750mm . Boiling point of the solution is (Kb of water = 0.52 K=Kg/mol)
1) 1000 C 2) 100.040 C 3) 100.40 C 4) 104.00 C
Key: 3
10 4 18
Sol:  
760 M 100
M  54.72
0.52  4  1000
TB   0.4
54.72  100
21. A dilute solution contains n mole of solute ‘ A ’ in 1kg of a solvent with molal elevation
constant K b . The solute A undergoes dimerization as 2 A  A2 . If  Tb is elevation in
boiling point of the equilibrium constant, KC , for dimer formation is
K (n.K b  Tb ) K (n.K b  Tb )
1) b 2) b
(2.Tb  n.K b ) (2.Tb  n.K b ) 2
K b .n.Tb (n.K b  Tb )
3) 4)
(2.Tb  n.K b ) 2 ( n.Tb  2.K b ) 2
Key: 2

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n
n
Sol: Tb  2 kn
b
n
Tb 
1
kb n 2
(k n  Tb )
 2 b
kb n

Kc  2
n(1   )2
(kb n  Tb )
 2
 2(kb n  Tb ) 
1  
 kb n 
(kb n  Tb )
kb n
 2
 2k n  2Tb 
n 1  b 
 kb n 
kb n  Tb
kb n

(kb n  2kb n  2Tb ) 2
n
kb 2 n 2
k (k n  Tb )
 b b
(2Tb  kb n) 2

(NUMERICAL VALUE TYPE)

Section-II contains 10 Numerical Value Type questions. Attempt any 5 questions only. First 5 attempted questions will be considered if more than 5
questions attempted. The Answer should be within 0 to 9999. If the Answer is in Decimal then round off to the nearest Integer value (Example i,e. If
answer
is above 10 and less than 10.5 round off is 10 andIf answer is from 10.5 and less than 11 round off is 11).
Marking scheme: +4 for correct answer, 0 if not attempt and -1 in all other cases.
22. The number of interhalogens from the following having bent T-shaped structure is:
ClF3 , IF7 , BrF5 , BrF3 , I 2Cl6 , IF5 , ClF , IF3
Key: 3
Sol: AB3 species have bent T-shaped structure. Hence, ClF3 , BrF3 , IF3
23. Each of the compounds shown below has two aromatic ring, labeled as A and B. Identify
number of compounds in which ring B is more active than ring A for electrophilic
aromatic substitution reaction.

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Key: 4
Sol: Electronic donating groups increase the activity of the ring
24. Consider the following three compounds
(i) AX 2nn (ii) AX 3n (iii) AX 4nn , where central atom A is 15th group element and
their maximum covalency is 3n . If total number of proton in surrounding atom X is n .

and value of n is one, then calculate x3  y 2  z . (Where x, y and z are total number of
lone pair at central atom in compound (i), (ii) & (iii) respectively.
Key: 9
Sol: n  1, X  H ; A  N
(i ) NH 2 (ii ) NH 3 (iii ) NH 4
Lone pair x  2, y  1, z  0
x 3  y 2  x  (2)3  (1) 2  (0)  9
25. Total number of Fractions obtained by monochlorination of isopentane followed by
fractional distillation?
Key: 4
Sol: Conceptual

26. The normality of 1L orthosphoporic acid ( H 3 PO4 ) having 70% purity by weight
(specific gravity 1.54 g cm-3) is ………….. M (Molar mass of H 3 PO4  98 g mol 1 )
Key: 33
Sol: Given : V  1L  1000mL
Specific gravity  1.54 g / cm3
M  98 g / mol
Mass of solution  1.54 1000  1540g

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% of purity of H 3 PO4  70%
70
Weight of H 3 PO4   1540  1078 g
100
1078
No. of moles of H 3 PO4   11
98
11 3
Normality   33M
1
27. The density of 3M solution of NaCl is 1.1755 g mL1 . Molality of the solution is
……………. 102 m . (Nearest integer).(Given : Molar mass of Na and Cl is 23 and
35.5 g mol-1 respectively).
Key: 300
Sol: 3M NaCl solution = 3 mol of NaCl = (3  58.5) g  175.5 g of NaCl is present in 1000 ml
solution = 1000 g of solution. (as density = 1g/ml)
 Mass solvent = 1175.5 g  175.5 g  1000 g
3 1000
 Molality of the solution   3(m)
1000
28. A solvent containing 20g of an electrolyte AB2 in 100g of water boils at 101.04o C . The
degree of ionization of the electrolyte ( ) is ………… 101 . (Nearest Integer)
[Given : Molar mass of AB2  200 g mol 1 . Kb (molal boiling point elevation const. of
water) = 0.52 K mol 1 , boiling point of water  100o C ; AB2 ionizes as
AB2  A2  2 B  ]
Key: 5
Sol: Ionisation of AB2 occurs as :
AB2  A2 2 B 
1    2
i  1  2
Tb  kb im
10
1.04  0.52(1  2 )
20
10
1  (1  2 )  1  2    0.5
20
Hence,   5 101
29. An aqueous solution of volume 300cm3 contains 0.621 g of protein. The osmotic
pressure of the solution at 300K is 1.29mbar . The molar mass of the protein is
…….……  103 g mol 1 (Given : R  0.083 L bar K 1 mol 1 )
Key: 40
Sol:    CRT
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n RT w RT wRT
   M 
V M V M  V
0.621 0.083  300
M
1.29  103  300  103
M  399558 g / moL
 40  103 g / mol
30. When ' x ' mL methanol (molar mass = 32g; density  0.8 g / cm 3 ) is added to 100 mL
water (density = 1 g / cm 3 ), the following diagram is obtained

x  ………………….. (nearest integer)

[Given : Molal freezing point depression constant of water at 273.15K is
1.86 K kg mol 1 ]
Key: 10
w 1000 8
Sol: T f  2.5o C , 4.65  1.86   8, v mL  10
32 100 0.8
31. Solid Lead nitrate is dissolved in 1 litre of water. The solution was found to boil at
100.15o C . When 0.2 mol of NaCl is added to the resulting solution, it was observed that
the solution froze at 0.99o C . The solubility product of PbCl2 formed is ………. 104
at 298 K. (nearest integer)
Given : K b  0.5 K kg mol 1 and K f  1.8 kg mol 1 . Assume molality to be equal to
molarity in all cases
Key: 5
Pb( NO3 ) 2  Pb 2  2 NO3
Sol: Let a mole of Pb ( NO3 ) 2 be added,
a a 2a
Pb 2 (aq)  2Cl  (aq)  PbCl2 ( s )
Tb  0.15  0.5[3a ]  a  0.1 , t0 0.1 0.2 In
t (0.1  x ) (0.2  2 x )

final solution ; ions present  Pb 2 , Na  , NO3 , Cl 

 0.3  3 x  0.2  0.2 
T f  0.99  1.8    x  0.05
 1 
K sp  [ Pb ][Cl ]  0.05  (0.1)  5 104
  2 2

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RPTM-13/17(N&S)
(NUMERICAL VALUE TYPE)
Section-II contains 10 Numerical Value Type questions. Attempt any 5 questions only. First 5 attempted questions will be considered if more than 5
questions attempted. The Answer should be within 0 to 9999. If the Answer is in Decimal then round off to the nearest Integer value (Example i,e. If
answer is above 10 and less than 10.5 round off is 10 and If answer is from 10.5 and less than 11 round off is 11).
Marking scheme: +4 for correct answer, 0 if not attempt and -1 in all other cases.
10. Number of paramagnetic species among the following is ________
2 2  3 3
O2 , B2 , N 2 , PtCl4  , NiCl4  , Co  H 2O 6  , CoF6  
Key: 4
2 3
Sol: O2 , B2 ,  NiCl4  & CoF6 
11. No. of stereo isomers possible for Co  glyc 3 is _______
O

glyc= H2N CH2 C O-

Key: 4
Sol: 2 geometrical both are optically active  4 stereo
12. The total number of isomers (including stereo) possible for C8 H16 which contain six
membered ring is ______
Key: 10

Sol: 1 1
3 3 2

13. The number of fluorides that can be used in swart’s reaction among the following is
_____ AgF , Hg 2 F2 , CoF2 , SbF5 , ZnF2 , NaF , CaF2
Key: 3
Sol: AgF , Hg 2 F2 , CoF2 & SbF5
14. The total number of extensive properties from the following is _____
Volume, molar heat capacity, molarity, E 0cell , Gibbs Free energy change, molar mass,
mole
Key: 3
Sol: Volume, G & mole
15. During compression of a spring the work done is 12kJ and 2kJ escaped to surroundings
as heat. The change in internal Energy U  inkJ  is _______.
Key: 10
Sol: q  W  U  2  12  U  U  KJ
16. The difference between H and U  H  U  when the combustion of one mole of
heptane (l) is carried out at a temperature T is equal to  xRT . Then x  ?
Key: 4
Sol: C7 H16  11O2  7CO2  8 H 2O ng  7  11  4
l g g

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RPTM-14/18
(SINGLE CORRECT ANSWER TYPE)
This section contains 20 multiple choice questions. Each question has 4 options (1), (2), (3) and (4) for its answer, out of which ONLY ONE option can be
correct.
Marking scheme: +4 for correct answer, 0 if not attempted and –1 in all other cases.
10.
OH

NH 2

O Br / NaOH

2


product: The product of this Hoffmann bromide reaction is:

O
OH
Ph  CH
Ph  C  CH 3 NH 2
1) 2) Ph  CHO 3) 4) Ph  CH 2  NH 2
Key: 2
OH O OH O
Br2
Ph  CH  C  NH 2 
NaOH
Ph  CH  NH 2  Ph  C  H

Sol: (unstable)

MeO 
C 

OMe


11. Ph
The reaction proceds through
1) Bimolecular basic hydrolysis with acyl-oxygen heterolysis
2) Bimolecular basic hydrolysis with alkyl-oxygen heterolysis
3) Unimolecular basic hydrolysis with acyl-oxygen heterolysis
4) Unimolecular basic hydrolysis with alkyl-oxygen heterolysis.
Key: 2
Sol: SN 2 reaction
12. The correct order of melting point is......
1) C  Si  Ge  Sn  Pb 2) C  Si  Ge  Sn  Pb
3) C  Si  Ge  Pb  Sn 4) C  Si  Pb  Sn  Ge
Key: 3
Sol: The smaller atoms are more closely packed and require greater amount of energy to
overcome the force of attraction between them. As the atomic size increases down the
group the decrease in the melting point in that order is expected. But the melting point of
lead is more than that of tin but less than that of germanium.
13. In water  H  O  H  bond angle is 1050 .The distance between  O  H  is 0.94 A 0 .
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 of H 2O  1.85 D . Determine the magnitude of the charge on the oxygen atom and
hydrogen atom in water molecule  cos52.50  0.609
1) 3.2  10 10 esu,1.6  10 10 esu 2) 32  1010 esu,16  1010 esu
3) 3.2  109 esu,1.6  109 esu 4) 32  109 esu,16  109 esu
Key: 1
Sol:   1.85 D  1.85  10 18 esu.cm   q  d

H H
q2 0.94A0

1050 
q1
52.50
d


 H
q2

d
cos52.50  0
 d  0.609  0.94 A0
0.94 A
d  0.572 A0   q  d
 1.85 D 1.85  10 18 esu.cm
q1   
d 0.572 A0 0.572  10 8 cm
q1  3.2  10 10 esu q1  2 q2
q2  1.6  10 10 esu
14. The correct formula to calculate the hydroxyl ion concentration of an aqueous solution of
NH 4 NO3 is____
c  kw kw  kb c  kw ka  k w
1) 2) 3) 4)
kb c ka c
Key: 2
1/2
 k c  
Sol: Salt of strong acid and weak base  H   w 
 
 kb 
 H   OH    kw OH    kw OH    kw  kb
     1/2   c
 kw  c 
 
 kb 
(NUMERICAL VALUE TYPE)
Section-II contains 10 Numerical Value Type questions. Attempt any 5 questions only. First 5 attempted questions will be considered if more than 5
questions attempted. The Answer should be within 0 to 9999. If the Answer is in Decimal then round off to the nearest Integer value (Example i,e. If
answer is above 10 and less than 10.5 round off is 10 and If answer is from 10.5 and less than 11 round off is 11).
Marking scheme: +4 for correct answer, 0 if not attempt and -1 in all other cases.

15. The P H of an aqueous solution containing 1M benzoic acid ( p ka  4.20) and 1M sodium
benzoate is 4.5. The volume of benzoic acid solution in 600ml of this buffer solution is
_________ mL.(Given: log2  0.3 )
Key: 200
Sol: Total volume of mixture is 600 ml Let V ml of 1M benzoic acid is mixed with (600-V)
mL of 1M sodium benzoate solution.
Moles of benzoic acid  1M  Vml  Vm mol
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Mole of sodium benzoate  1M  (600  V )ml  (600  V )mmol
A mixture of benzoic acid (WA) and sodium benzoate is an acidic buffer.
[ salt ]
For acidic buffer P H  p ka  log
[ Acid ]
 600  V 
4.5  4.2  log    0.3
 V 
 600  V 
log    0.3
 V 
600  V
 2 V  200 ml
V
16. At 298k , the solubility of silver chloride in water is 14.34  103 g / L. The value of
 log k sp for silver chloride is (given mass of Ag is 107.9 g / mol and mass of Cl is
35.5 g / mol )
Key: 8
14.34  103
Sol: Solubility (s)   104 M
143.4
ksp ( Agcl )  ( s)  ksp ( Agcl )  108   log ksp  8
2

17. How many of the following are non electrolytes____

HCOONH 4 , CH 3COONa, C6 H 5CH 3 , C6 H12 O6 , NH 4 Cl , C6 H 6
Key: 3
Sol: Substance which do not furnish ions in water are non electrolyte.
0
18. The standard free energy change (  G 0 ) for 60% dissociation of N 2O4 into NO2 27 c
and 1atm pressure is  x J / mol .The value of x is __________
(Nearest integer)[Given R  8.31 J / k  mol , log 2.25  0.35218 ln10  2.3 ]
Key: 2019
 2 NO2
Sol: N2O4 g   (g)

Initial moles 1 __
At equilibrium 1  2
Total moles at equilibrium = 1    2  1  
P 2 NO2
Kp  P 2
PN 2O4 NO2 
1
1

1 
PN 2O4  1
1 
2 2

1   1   42 1
Kp   
1  (1  ) (1  )
1 
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 SRI CHAITANYA IIT ACADEMY, INDIA JEE MAIN 2025 BRAHMANDA PRACTICE MATERIAL-1
4  0.6  0.6 1
Given   0.6 K p  
1  0.6 1  0.6
1.44
Kp  K p  2.25 G 0  2.303 RT log K p
0.64
 2.303  8.31  300  log(2.25) G 0  2022
19. The vapour density of the equilibrium mixture of the reaction:
 SO2  Cl2 is 50. The percent dissociation of SO2Cl2 is ______
SO2Cl2( g )  (g) (g)

Key: 35
Dd
Sol:   Given; d  50
( n  1)d
135  MW  67.5  50
D  67.5 D      0.35
2  2  50(2  1)
% dissociation = 35%

20. No.of possible stereo isomers for Co  en 2  Cl 2  is....
Key: 3
Sol: Two cis and one trans-isomers. Each of the cis-isomer is chiral and optically active.
Trans-isomer has plane of symmetry and therefore should be achiral and optically
inactive but this isomer has optically active ligand (pn).Thus it would be optically active.
en en
en + en
+
+ +
N N N N
N Cl Cl N
N Cl Cl N
CO CO CO CO
N Cl Cl N N
N N N Cl Cl
Pn N N
pn Pn Pn
pn
Mirror cis-l-isomer
Cis-d-isomer Cis-d-isomer Mirror cis-l-isomer
+ +
Cl Cl
N N N
N
en Pn
Pn CO en CO
N N N N
Cl Cl

Mirror
Trans-d-isomer Trans-l-isomer

21. How many of the following do not establish equilibrium when carried in closed vessel

a) NaOH  HCl   NaCl  H 2O


 AgCl  NaNO3
b) AgNO3  NaCl 


 CH 3COOH  C2 H 5OH
c) CH 3COOC2 H 5  H 2O 


 2 NH 3
d) N 2  3H 2 


 2 SO3
e) 2 SO2  O2 


 SnCl4  2 FeCl2
f) SnCl2  2 FeCl3 


 BaSO4  2 NaCl
g) BaCl2  Na2 SO4 

Key: 4
Sol: Precipitation reactions are irreversible

JEE MAIN 2025 BRAHMANDA PRACTICE MATERIAL-1 Page 191

GTM-12 (06-01-2025)

Page | 18
 SRI CHAITANYA IIT ACADEMY, INDIA JEE MAIN 2025 BRAHMANDA PRACTICE MATERIAL-1

RPTM-15/19(N&S)
SECTION-I (SINGLE CORRECT ANSWER TYPE)
This section contains 20 Multiple Choice Questions. Each question has 4 options (1), (2), (3) and (4) for its answer, out of
which ONLY ONE option can be correct.
Marking scheme: +4 for correct answer, 0 if not attempted and –1 in all other cases.
1. Assertion: The Arrhenius equation explains the temperature dependence of rate of a
chemical reaction
1
Reason: Plots of log k versus are linear and the energy of activation is obtained from
T
such plots
1) If assertion is true but reason is false
2) If assertion is false but reason is true
3) If both assertion and reason are true and reason is the correct explanation of assertion
4) If both assertion and reason are true but reason is not correct explanation of assertion
Key: 3
Sol: If both assertion and reason are true and reason is the correct explanation of assertion
SECTION-II (NUMERICAL VALUE TYPE)
This section contains 5 Numerical Value Type Questions. The Answer should be within 0 to 9999. If the Answer is in
Decimal then round off to the Nearest Integer value (Example i,e. If answer is above 10 and less than 10.5 round off is 10
and If answer is from 10.5 and less than 11 round off is 11).
Marking scheme: +4 for correct answer, 0 if not attempt and -1 in all other cases.
2. How many of the following undergo re arrangements?


CH 2

i) ii) iii)

C CH 3

OH

CH 2 


O H 2C  C


iv) Me3C  CH 2  CH 2 v) vi) vii)

 Ph 
CH CMe2
H 2C  CH  CH 2
viii) ix) Ph
Key: 5
Sol: Conceptual
JEE MAIN 2025 BRAHMANDA PRACTICE MATERIAL-1 Page 192
 SRI CHAITANYA IIT ACADEMY, INDIA JEE MAIN 2025 BRAHMANDA PRACTICE MATERIAL-1
GTM-05(N)
SECTION-I (SINGLE CORRECT ANSWER TYPE)
This section contains 20 Multiple Choice Questions. Each question has 4 options (1), (2), (3) and (4) for its answer, out of
which ONLY ONE option can be correct.
Marking scheme: +4 for correct answer, 0 if not attempted and –1 in all other cases.
6. Consider the above reaction sequence, Product "A" and Product "B" formed respectively
are:

[where Et  C 2H5 tBu   CH3 3 C  ]

1) 2)

3) 4)
Key: 1
Sol:

7. For the cell Zn  s  | Zn 2   aq  || M x   aq  M  s  . different half cells and their standard

electrode potentials are given below:
M x   aq  / M  s  Au 3  aq  / Au  s  Ag   aq  / Ag  s  Fe3  aq  / Fe 2  aq  Fe 2   aq  / Fe  s 
E 1.40 0.80 0.77 -0.44
M x / M  
/ v

If EoZn2 /Zn  0.76V, which cathode will give a maximum value of E 0cell per electron
transferred ?
1) Fe3 / Fe2 2) Ag  / Ag 3) Au 3 / Au 4) Fe2 / Fe
Key: 2
Sol: The galvanic cell in which the given reaction takes place is depicted as: Zn(s) | Zn2+ (aq) || Ag+ (aq) | Ag(s)
(i) Zn electrode (anode) is negatively charged
(ii) Tons are carriers of current in the cell and in the external circuit, current from silver to Zinc.
(iii) The reaction taking place at the anode is given by, Zn(s) → Zn 2+(aq) + 2e-
The reaction taking place at the cathode is given, Ag+ + e- → Ag(s)

JEE MAIN 2025 BRAHMANDA PRACTICE MATERIAL-1 Page 193

 SRI CHAITANYA IIT ACADEMY, INDIA JEE MAIN 2025 BRAHMANDA PRACTICE MATERIAL-1

RPTM-16/21
SECTION-I (SINGLE CORRECT ANSWER TYPE)
This section contains 20 Multiple Choice Questions. Each question has 4 options (1), (2), (3) and (4) for its answer, out of
which ONLY ONE option can be correct.
Marking scheme: +4 for correct answer, 0 if not attempted and –1 in all other cases.
6. Assertion : The
ratio by volume of H 2 : Cl2 : HCl in a reaction
H2 g   Cl2 g   2HCl g  is
1 : 1 : 2.
Reason: In any given reaction the reactants react in such a way that their volume ratio is
in simple integers.
1)If both (A) and (R) are true, and (R) is the correct explanation of (A).
2)If both (A) and (R) are true but (R) is not the correct explanation of (A).
3)If (A) is true but (R) is false.
4) If (A) is false but (R) is true.
Key: 3
Sol: Conceptual
SECTION-II (NUMERICAL VALUE TYPE)
This section contains 5 Numerical Value Type Questions. The Answer should be within 0 to 9999. If the Answer is in
Decimal then round off to the Nearest Integer value (Example i,e. If answer is above 10 and less than 10.5 round off is 10
and If answer is from 10.5 and less than 11 round off is 11).
Marking scheme: +4 for correct answer, 0 if not attempt and -1 in all other cases
7. The weight % of N in the amino acid, Proline is ___(to nearest integer)
Key: 12
H

N
COOH
Sol: Proline is H
 C5 H9O2 N 
14
 wt % of N   100 =12.17=12
115
8. Consider the following reactions:
NaCl  K 2Cr 2O7  H 2 SO4   A  side products
 A  NaOH   B   side products
 B   H 2SO4  H 2O2   C   side products
The sum of the total number of atoms in one molecule each of A,B, and C is ___
Key: 18
Sol: A is CrO2Cl2
B is Na2CrO4

C is CrO5

 Total number of atoms in one molecule each of A, B and C is 18

JEE MAIN 2025 BRAHMANDA PRACTICE MATERIAL-1 Page 194

 SRI CHAITANYA IIT ACADEMY, INDIA JEE MAIN 2025 BRAHMANDA PRACTICE MATERIAL-1
RPTM-17/22
SECTION-I(SINGLE CORRECT ANSWER TYPE)
This section contains 20 Multiple Choice Questions. Each question has 4 options (1), (2), (3) and (4) for its answer, out of
which ONLY ONE option can be correct.
Marking scheme: +4 for correct answer, 0 if not attempted and –1 in all other cases.
2. Given below are two statements one is labelled as
Assertion (A) and the other is labelled as reason (R)
Assertion (A): The amphoteric nature of water is explained by using Lewis acid/ base
concept
Reason (R): Water acts as an acid with NH3 and as a base with H2S . In the light of the
above statements choose the correct answer from the options given below
1) both A and R are true but R is not the correct explanation of A
2) Both A and R are true and R is the correct explanation of A
3) A is false but R is true
4) A is true but R is false
Key: 3
Sol: Conceptual

JEE MAIN 2025 BRAHMANDA PRACTICE MATERIAL-1 Page 195

PHYSICS
1. Here y   A.B  .C  AB  C  A  B  C
y  0 if A  1, B  1 and C  0

2.

1242 1242
3. energy of photon E  eV   6.2eV
  in nm  200
E    Kmax
6.2  4.7  Kmax
Kmax  1.5 eV  eVs
Stopping potential Vs  1.5V
The electron will be ejected until potential of sphere equals to stopping potential
V  Vs  1.5V
4.

1 1 1 1 5
5.  2  2   1
0  2 3  0 36
1 1 1 1 3
  2  2      2
  2 4   16
eq.1  20 20
     0
eq.2 0 27 27

Page | 2
6. Conceptual
7. TEsurface  TEmax height
2
GMm 1  Ve  GMm
 m  
R 2 2 Rh
GMm 1 2GM GMm
 m 
R 2 4R Rh
2GM
Ve2 
R
R
On simplifying we get h 
3
8.

0 i 2RB
Magnetic field at centre B  i 
2R 0
Magnetic moment of loop
2RB 2 2BR3
M  iA  i R2  R   3102 Am2
0 0

1
E  mA2 2 i.e. E   A 
2
9.
2
 A11    A22 
2 2
or
2
10. PV 3  constant , PV  nRT
nRT
P
V
nRT 23
.V  constant
V
1

TV 3
 constant
As volume , temperature 

11. E V B 

EB
12. = I  Intensity of EMW 


Page | 3
13. By KVL & KCL
1
 1 2
14. Vrms  1   Vare
 x
1
3RT  1  2 8 RT
 1  
M  x M
22  3 1
 1
8 7 x

15. A   m  60
 A  m 
At minimum deviation i     60
 2 
16. 10 VSD=8 MSD
 1VSD = 1 MSD-1VSD
Now LC=1 MSD – 1 VSD
= MSD – 0.8 MSD
1
 0.2 MSD  0.2  cm  0.02cm
10
17.

Fnet = mg cos  or net acceleration of the bob is geff = g cos 

1 1
 Time period T = 2  2
geff g cos 
18. It can be seen that potential both at A and B are zero. When the charge is moved
from A to B, workdone by the electric field on the charge will be zero

Page | 4
19. When a disc rolls, it has two types of motion. It possesses translational and
rotational motion. For each type of motion, there is an angular momentum. Let LT
and LR represent them.
 L  LT  LR or L   Mv  R    I C 
Where C denotes centre of mass
MR 2 3
Or L  M  R  R   or L  MR 2
2 2
20. In the steady state condition, no current flows through the capacitor C along the
branch BE.

Apply Kirchhoff’s law to the closed mesh ACDFA,

2V  I  2 R   I  R   V  0 or V  3 IR
V
Or I 
3R

Apply Kirchhoff’s law to the mesh ABEFA, V  VC  IR  V  0 or VC  IR  

V  V
R 
 3R  3
V
 Potential difference across capacitor VC 
3
21.    i1  i2   A
 A   i1  i2   
 15  60   30  45
22. Condition of balanced bridge.

Here m  1 kg , F    t i   j    t i  j  N
   
23.
   

 dv  t  
As, F  m   t i  j  or v    t i  j dt
 

dt   0 

Page | 5
  t2   
v   i t j
2 
 t  t
 2    3  2  
Also, r   v dt    t i  t j dt ; r  t i  t j 
0 0 2  6 2 
Velocity of the body at t  1 s,
 1  1  
v   i  j  ms 1   i  2 j  ms 1
2  2 
Displacement of the body at t  1 s,
  
s  r  t  1s   r  t  0 s 
1 1  1 
  i j   0   i 3 j  m
6 2  6 
 1 2 2 10
s  1 3 
6 6
Torque on the body at t  1 s,
    1  1    
  r  F   i  j    i  j 
6 2   
1  
 1  
 1  1 1
  i  j    j i   k  k   k
6  2  6 2 3
 1
  Nm
3

L
24. For circle 2 R  L or R 
2
L2i
 Magnetic moment  iA  i   R 2  M 
4
25. The excess of pressure above atmospheric pressure, due to surface tension in a
4T
bubble 
r
4T 4  0.04
The surrounding pressure  P0  8
rA 0.02
PA  16 N / m 2
4T 4  0.04
PB  P0   8  12 N / m 2
rB 0.04
PV  nRT
4
16    0.02   nA RT
3

12     0.04    nB RT
4 3

3 

Page | 6
54.

q
 2
p
But a + b + c > 0
q
So,  0
q

55. P  G   Probability that he guess thechoice  1/ 4

Page | 14
 P  C   Probability that he copies the choice = 1/8
P  K   Probability that he knows the choice
AC  Event that answer is correct

56.

57. Le the equation of sides AB, BC, CD and DA of parallelogram ABCD are
respectively

Page | 15
  Area of parallelogram ABCD

58.

59.
 x
1  x x  0

f  x   0 x0
 x
 x0
1  x
x
y , x0
1 x
y
x  0  y   1,0 
1 y
Page | 16
 x y
Also y  , x 0 x  0
1 x 1 y
y   0,1
So, range = (-1,1)

60.

Passes through (1, 0) so c = 0

1 2
A  x  1 dx    x 2  1 dx  2
2
61.
0 1

Page | 17
62. SS 1  2ae sp  s1 p  2a

63. Let C  cos ,sin   : H  h, k  is the orthocenter of the ABC

64.

n 1
 1
65. T2  C1  a 13 
n

 
 a a   14a 5/2

n = 14

66.

Angle between two vectors

67.
Page | 18
      
a  b  a  b  a || b
  1
1
Hence f ' 1  sin 1
2

68. f  x   y  x  sin x
dy
 1  cos x
dx
dx 1
g ' y   
dy 1  cos x
 1
Where y    x  sin x
4 2

 x
4
 1  1
 g '   
4 2  1  1 
 
 2


2
2 1
 2  
2 1

2 2

69.

70.

Page | 19
 x 1 y  2 z  3
L1 :  
2 3 4
x2 y 4 z 5
L2 :  
3 4 5
Any point on
L1 : P  2r1  1,3r1  2,4r1  3
L2 : P  3r2  2,4r2  4,5r2  5 
PQ perpendicular to the lines
1 1
 r1  r2  
3 6
5 13   3 10 25 
P  , 3,  Q , , 
3 3 2 3 6 

71.

72.

Let one real root is k

Page | 20
73.

74. f   x   0  x  2, 1

0 2

A    2 x  3 x  12 x  dx   12 x  3 x 2  2 x 3  dx
3 2

1 0

75.

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***** ALL THE BEST *****

Page | 22