Metals and Non Metals
Metals and Non Metals
CHAPTER 3
The elements which can lose one or more electrons to become a positively charged cations are called METELS.
e.g. Sodium has the atomic number of 11 and so its electronic configuration is 2, 8, 1. It is ready to lose one electron to
become a unipositive cation and it becomes stable. So it is considered to be a metal.
Na ------→ 11 ------→ 2, 8, 1
Na - e- -----→ Na+
An element which can gain one or more electrons to become a negatively charged anion is known as a NON METAL.
e.g. chlorine atom has the atomic number 11 and its electronic configuration is 2, 8, 7. It is ready to gain one to become a
uninegative anion and attains stability. So it is considered to be a non metal.
Cl ------→ 17 ------→ 2, 8,7.
Cl + e- ------→ Cl -
Aluminium is the most abundant metal and oxygen is the most abundant non metal on the earth crust.
Mercury is the only metal and bromine is the only non metal which exists in the liquid state.
The element which can exhibit both metals and non metals is called metalloid. They are also known as semi metals.
There are seven metalloids. They are:
Boron ---- B
Silicon ---- Si
Germanium ---- Ge
Arsenic ---- As
Antimony ---- Sb (Stibium)
Tellurium ---- Te
Polonium ---- Po
PHYSICAL PROPERTIES OF METALS AND NON METALS.
The physical properties of mercury are mostly different from the physical properties of metals but it is considered to be a
metal as it is capable of losing the electron/s.
1) MALLEABILITY
The ability of the element with which it can be spread into thin sheet by applying the force is known as malleability
All metals are malleable and non metals are non malleable.
Gold is the highly malleable metal as a gold sheet of one square metre can be made from one gram of gold.
2) DUCTILITY
The physical property of the element by which it can be drawn into the thin wire is called ductility.
All metals are ductile and non metals are non ductile.
Gold is the metal which has the maximum ductility. A gold wire of length 2 Km can be drawn from 1g. of gold.
3) LUSTRE
The property by which the element has a shining surface is called luster.
All the metals are lustrous whereas the non metals are non lustrous.
Iodine and diamond (which is made up of carbon) are the two non metals which are lustrous. Lead has the minimum
luster.
4) SONORITY
Some elements produce sound when they are hit with a hard substance. This property is called sonority or sonorousness.
All metals are sonorous whereas the non metals are non sonorous.
5) DENSITY
The mass of unit volume of a substance is called density. DENSITY = MASS / VOLUME
Generally metals have high density and non metal has the low density.
Diamond is the non metal which has the high density.
6) HARDNESS
The ability to bear any kind of force which is given on the element is called hardness.
The metals are hard and non metals are soft normally.
Sodium and potassium are the soft metals and diamond is the non metal which is very hard. Diamond is the naturally
occurring hardest metal.
4. A copper wire is kept in between the clips and the key is closed.
5. It is observed that the bulb glows and it shows that copper wire conducts electric current.
5. The copper wire is replaced by a piece of coal (which is made up of carbon, a non metal).
6. The key is closed and it is observed that the bulb does not glow.
7. This activity shows that metal is a good conductor of electric current and the non mmetal is a poor conductor of electric
current.
10) STATE
The metals generally exist in solid state except mercury but non metals exist in any one of the three states.
e.g. Solid --- Carbon, Sulphur, Phosphorous
Liquid --- Bromine
Gas --- Oxygen, Hydrogen, Chlorine
11) COLOUR
Metals exist in any one of the following four colours.
Yellow --- Gold
Brown --- Copper
Silvery white --- Silver, Aluminium, Mercury
Grey --- Iron, Zinc, Tin
Non metals exist in any colour.
Black --- Carbon
White --- Phosphorous
Red --- Phosphorous
Yellow --- Sulphur
Greenish yellow -- Chlorine
Brown --- Bromine
Colourless --- Oxygen, Argon
CHEMICAL PROPERTIES OF METALS
1) WITH OXYGEN
When metals react with oxygen they form their corresponding metal oxides.
Metal + Oxygen ------→ Metal oxide
4Na + O2 ------→ 2Na2O
2Mg + O2 ------→ 2MgO
4Al + 3O2 ------→ 2Al2O3
All metal oxides are basic oxides as they form the corresponding bases when they are dissolved with water.
When magnesium reacts with water it forms magnesium oxide. If magnesium oxide is dissolved in water then it forms
magnesium hydroxide which changes red litmus to blue.
2Mg + O2 ------→ 2MgO
MgO + H2O ------- Mg(OH)2
Zinc oxide and aluminium oxide are called amphoteric oxide even though they are metal oxides. They can act as both
acidic and basic oxide.
ZnO + 2HCl ------→ ZnCl2 + H2O
Basic Acid Salt Water
ZnO + 2NaOH ------→ Na2ZnO2 + H2O
Acidic Base Salt [Sodium zincate] Water
Al2O3 + 6HCl ------→ 2AlCl3 + 3H2O
Basic Acid Salt Water
Al2O3 + 2NaOH ------→ 2NaAlO2 + H2O
Acidic Base Salt(Sodium aluminate) Water
2) WITH ACIDS
Generally metals react with acids and form their corresponding salts with the release of hydrogen gas.
Metal + Acid ------→ Salt + Hydrogen
Zn + 2HCl ------→ ZnCl2 + H2↑
Ca + H2SO4 ------→ CaSO4 + H2↑
Metals cannot release hydrogen gas when they react with nitric acid because nitric acid is a very good oxidizing agent and
so it converts the hydrogen into water. However magnesium and manganese release hydrogen when they react with nitric
acid as they are good reducing agents.
Mg + 2HNO3 ------→ Mg(NO3)2 + H2↑
The metals which are placed below hydrogen cannot react with acid. They are less reactive than hydrogen and so they will
be unable to replace hydrogen from the acid.
REACTIVITY SERIES
Reactivity series is a group of metals which are arranged in the decreasing order of their reactivity.
The reactivity series of metals is given as follows:
The metal which is placed at the top of the series is the most reactive metal and the metal that is placed at the bottom of
the series is the least reactive metal. Silver and gold are used to make ornaments as they are least reactive.
Hydrogen is introduced in the reactivity series of the metal even though it is a non metal as a reference metal. Moreover,
hydrogen is also capable of losing an electron like metals under some circumstances.
The elements which are placed above hydrogen are more reactive and the elements which are placed below hydrogen are
less reactive than hydrogen.
3) WITH WATER
Metals react with water and form the corresponding metal hydroxide and releases hydrogen.
Metal + Water ------→ Metal hydroxide + Hydrogen
The reaction of metals with water depends on the position of metals in the reactivity series of metals.
Since potassium and sodium are the most reactive metals they can react even with cold water and forms potassium
hydroxide and sodium hydroxide respectively with the release of hydrogen gas.
2K + H2O ------→ K2O + H2↑
2Na + H2O ------→ Na2O + H2↑
Medium reactive metals like zinc and calcium react with hot water and form their corresponding hydroxides with the
release of hydrogen.
Since only one electron is transferred during this bond formation the electrovalency of sodium chloride molecule is said to
be one.
FORMATION OF MgO MOLECULE
The atomic number of magnesium is 12 and its electronic configuration is 2, 8, 2. Since Mg has two valence electrons it is
ready to lose two electron to obtain octet configuration and forms a cation.
Mg -------→ 12 ------→ 2,8,2 (-2e-)
Mg - 2e- -------→ Mg2+
Oxygen atom is ready to gain two electrons as it has the electronic configuration of 2, 6 (at.no.of oxygn is 8). It obtains
octet configuration by gaining two electrons and forms an anion.
O -------→ 8 ------→ 2, 6 (+2e-) O + 2e- ------→ O2-
Two electrons are transferred from magnesium atom to oxygen atom and so an ionic bond is formed between them. Since
two electrons are transferred during this bond formation the electrovalency of MgO molecule is two.
The electron dot structure for the formation of MgO molecule is drawn as follows:
Electrolytic reduction is used to separate the high reactive metals from their ores. It is done in voltameter. It has three
components. They are a cathode, an anode and an electrolyte.
Sodium is extracted from sodium chloride by this process as follows:
1) Molten sodium chloride is taken in a voltameter.
2) A cathode and an anode are arranged.
3) They are connected in series with a battery and a key.
4) The key is closed and the electric current is allowed to pass.
5) When electric current passes, NaCl is ionized into sodium and chloride ions.
6) Sodium ion moves towards cathode and gains one electron to become neutral sodium metal and is settled on the
cathode.
7) Chloride ion moves to the anode where it loses one electron and form neutral chlorine atom. Two chlorine atoms
combine together and form chlorine gas which is released from the anode.
NaCl ------→ Na+ + Cl-
At cathode: Na+ + e- ------→ Na
At anode : Cl- - e- ------→ Cl
Cl + Cl ------→ Cl2
8) Any metal which is separated by electrolytic reduction process will be 99.9% pure.
5. Oxygen is available in the first test tube but water is not available in the first test tube. Water is available for the nail
taken in the second test tube but oxygen is not available. Oxygen and water are available for the nail taken in the third test
tube.
6. These test tubes are left undisturbed for few days.
7. It is observed that rust is formed on the iron nail taken in the first test tube but the other two iron nails are fresh.
8. This activity proves that both water and oxygen are necessary for the rusting of iron.
METHODS OF PREVENTING RUSTING
1. Rusting of iron can be prevented by painting which does not allow the iron to be exposed to the atmosphere.
2. It is avoided by oiling or greasing.
3. Galvanization is the process in which iron is coated with zinc which can form the zinc oxide layer and this layer is
capable of avoiding rusting of iron.
4. Iron is coated with chromium to avoid rusting and it is called chrome plating.
5. Alloying is also a very effective method to avoid rusting.
ALLOYS
An alloy is a homogeneous mixture of two or more metals or a metal with a non metal.
The following table gives an idea about some important alloys and their constituents.
No. ALLOY CONSTITUENTS
1 Steel Iron, Carbon
Iron, Carbon,
2 Stainless steel Nickel, Cobalt
3 Bronze Copper, Tin
4 Brass Copper, Zinc
5 Solder metal Lead, Tin
Ornamental Gold, Silver or
6 gold(22K) Copper
ANODISING
It is a method in which the aluminium articles are protected from corrosion. The aluminium undergoes corrosion by
reacting with oxygen in the atmosphere to form a layer of aluminium oxide.
4Al + 3O2 ------→ 2Al2O3
This is the reason why the cooking utensils are generally made up of aluminium even though it is a high reactive metal.
The oxide layer protects the reaction between the oil and the metal.
This oxide layer on the aluminium metal is thickened by doing electrolysis with sulphuric acid as the electrolyte. This
makes the aluminium to become more resistant to corrosion.
MgO
Mg -------→ 12 ------→ 2,8,2 (-2e-)
Q.8) Copper is used to make hot water tanks and not steel (an alloy of iron). Give reasons.
Ans: Copper is a better conductor of heat than steel.
Copper is less reactive as compared to steel.