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Fe-W Phase Diagram

The document discusses the phase relationships in the Fe-V and Fe-W systems, highlighting anomalies and phase transformations observed through various analyses. It notes the influence of pressure on the stability of phases in the Fe-V system and presents a phase diagram for the Fe-W system, detailing intermediate phases and solubility limits. References to previous studies and findings are provided to support the observations made in the document.

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85 views2 pages

Fe-W Phase Diagram

The document discusses the phase relationships in the Fe-V and Fe-W systems, highlighting anomalies and phase transformations observed through various analyses. It notes the influence of pressure on the stability of phases in the Fe-V system and presents a phase diagram for the Fe-W system, detailing intermediate phases and solubility limits. References to previous studies and findings are provided to support the observations made in the document.

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ms23btech11025
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Fe-V the composition deviates from stoichiometry.

The so-called "650°C anomaly"


corresponds to the 550°C anomaly in the Fe-Co system and has been
observed in the ordered Fe-V alloys during continuous heating of homogenized,
quenched and annealed samples based on DTA and X-ray analysis by Seki
et al. [14].
The effect of pressure on the stability of the (a + 1') phase (Fig.95) and
the 0 phase transformation was studied by electron microbe am and X-ray
analysis of binary diffusion couples diffused under simultaneous conditions
of high pressures and temperature by Hanneman et al. [8]. The results show
that the region of solubility of the ophase increases with pressure and
the congruent transformation point of 0 is moved to higher temperatures,
which was already predicted by the application of the Clapeyron equation.

References
Hack, K.; Niissler, H.D.; Spencer, PJ.; Inden, G.: CALPHAD VIII, Stockholm,
May 1979, p. 244
2 Kubaschewski, 0.; Probst, H.; Geiger, K.H.: Z. Phys. Chern. 104 (1977) 23
3 Kenisarin, M.M.; Chekhovskoi, V.Ya.; Berezin, B.Ya.; Kats, S.A.: High Temp.
High Press. 8 (1976) 367
4 Fischer, W.A.; Lorenz, K.; Fabritius, H.; Schlegel, D.: Arch. Eisenhiittenwes. 41
(1970) 489
5 Wever, F.; Jellinghaus, W.: Mitt. Kaiser-Wilhelm-Inst. Eisenforschung Diissel-
dorf, 12 (1930) 317
6 Kato, E., Furukawa, T.: Tetsu To Hagane 61 (1975) 3050
7 Lisnik, A.G.; Skvorchuk, V.P.: Dopov. Akad. Nauk Ukr. RSR (1960) 1408
8 Hanneman, R.E.; Ogilvie, R.E.; Gatos, H.C.: Trans. Metal!. Soc. AIME 233
(1965) 685
9 Kovacova, K.; Kralik, F.: Kovove Mater. 11 (1973) 93 (in slovak)
10 Spencer, P.J.; Putland, F.H.: J. Iron Steel lust. 211 (1973) 911
11 Chiriac, M.; Inden, G.: To be published
12 Matveeva, P.M.: Akad. Nauk SSR (1955), cited by Vol, A.E.: Constitution and
Properties of Binary Metallic Systems II, 9-20, Moscow, 1962
13 Bungardt, K.; Spyra, W.: Arch. Eisenhiittenwes. 30 (1959) 95
14 Seki, J.I.; Hagiwara, M.; Susuki,T.: J. Mater. Sci. (1979) 2404
15 Smith, J.: Private information 1982

Fe-W Iron-Tungsten
Figs. 96,97

The present (Fig.96) phase diagram representing the phase relationships


in the Fe-W system is a combination of evidence presented by Sinha et
al. [1] (0-45 at. % W), Kirchner et al. [2] (equilibria between ferrite, austenite
and intermediate phases) and Takayama et al. [11] (a (Fe) solubility limits).
The 50-100 at. % W region has not been investigated fully.
The system belongs to the closed 'Y-Ioop type and entails two well established
intermediate phases, namely: A.(Fe 2W, MgZn 2-type structure, a Laves phase),
f.L(Fe3W2, rhombohedral, D8 5 structure), and probably a 0 phase around
50 at. % W. The solid solubility of Fe in W was found to be about 2.5 at. % at
1,640°C and does not seem to change much with temperature (Hansen
[A: Refs. 11, 18]). The melting point of W, (3,422 ± 8) °C is a secondary

164
O. K. von Goldbeck, IRON—Binary Phase Diagrams
© Springer-Verlag Berlin Heidelberg 1982
1600

1536 a(
'-'
0
1500
~
::l

E
QJ
c.
E 1400
~ 1392 °C

1300

Tungsten (ot. % )
Fig. 96. Fe-W

165

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