KEY SHEET

PHYSICS
1) 2 2) 1 3) 3 4) 4 5) 2
6) 3 7) 3 8) 3 9) 3 10) 4
11) 1 12) 3 13) 1 14) 2 15) 4
16) 2 17) 3 18) 3 19) 4 20) 1
21) 4 22) 8 23) 1 24) 1 25) 2

CHEMISTRY
26) 1 27) 3 28) 3 29) 4 30) 4
31) 2 32) 4 33) 4 34) 1 35) 2
36) 2 37) 3 38) 1 39) 3 40) 2
41) 4 42) 1 43) 1 44) 2 45) 3
46) 7 47) 0 48) 5 49) 9 50) 4

MATHEMATICS
51) 1 52) 2 53) 2 54) 2 55) 3
56) 4 57) 3 58) 2 59) 3 60) 3
61) 3 62) 2 63) 3 64) 2 65) 4
66) 4 67) 3 68) 4 69) 2 70) 3
71) 1 72) 9 73) 5 74) 120 75) 1
 SOLUTIONS
PHYSICS
1. 2r 2r 2  10
V t   10sec
t V 2
2. Let ‘a’ be slit width, then YDSE for 10th maxima
10 D X 10
X  103  But 1    1
d D d
2
In single slit diffraction width of central maximum is  2    2
a
2 10
But  2  1   a  d / 5  0.2mm
a d
3. A K C

P  Q

D
M

d dy  dy dy u
 2  k 2  y 2 2  2y   Vm
dt dt y dt dt cos
4. L ax 2 bx 2 L aL2 bL2
dW  Fdx W   Fdx W   |O W  
O 2 3 2 3
5. 1 1 2K 2K
K IW 2 K  LW L  L
2 2 w 2 n
L1 K n L L
 1. 2 4 L2 
L2 K 2 n1 L2 4
6. x 10 x 1 V 10t1  10t 
 C V  sin C     C  sin 1  1 
t1 t2  C t2  t2 
7. p P P  r4 r 4   Pr 4 1 1 1 ll
1  2          l  12
reff R 8  l1 l2  8 l l l1 l2 l1  l2
8. 2 H  D
x V t x  2 gD , x  2 D H  D
g
9. Number of divisions  100R
Number of divisions 70S
Number of divisions 75S
x2  x3  x1
10. 1
Qcdd  Qhot 2000   20  m  80  5000  1  20
2
4
80m  8  10 m  1000 gm  1kg
mice  2  1  1 kg mwater  5  1  6kg
11. Q  CV Q  40  106 F
Q C V 0.1 0.2 1 2 
    Q     Q Q  2.4  106 F
Q C V 2.0 20  20 200 
12. Least count (L.C)
Pitch 0.5
   0.1 mm
no. of division on cirular scale 50
Zero error  5  0.1 mm
True reading  5  0.1mm  20  0.1mm  5  5.15mm
13. Correct measured value  MSR  VSD  LC   Zero error
 8.5   6  0.01  0.2  101  8.54 cm
14.   x2 
 
  kT 
Force of interaction between two atoms, F   e 
Since exponential terms are dimensionless
 x2  L2
    M 0 0 0
L T 
 M 0 L0T 0     M 1T 2
  kT    ML T
2 2

MLT 2  M 1T 2   
 F            M 2 LT 4
15. q  0 A
Capacitance, C  
t L
V  q  L V  q  L2 V q
 X  0L  L    I (current)
t A  V  t V L2 t t
16. mv 2 max
 T  mg cos  'T ' maximum for   O0
L
mv 2 mr 2 w2
 Tmax  mg  max  mg 
L L
mr 2  g    r 2 
 mg   
   w  g / L  mg  1    
L L
   
L
17. l
T  2
g
 g  15 g
When immersed non viscous liquid amt   g   
 16  16
l l 4
Now T '  2  2  T
0net 15 g 15
16
18. bt
 A  A0e 2m (where, A0  maximum amplitude)
 b 5 

According to the questions, after 5 second, 0.9 A0  A0e 2m ……….. (i)
b15

After 10 more second, A  A0e 2m …………………. (ii)
From eqns (i) and (ii) A  0.729 A0    0.729
19. When the ball is thrown upwards, at the point of throw  O  the linear momentum is
in upwards direction (and has a maximum value) and the position is zero. As the
time passes, the ball moves upwards and its momentum goes on decreasing and the
position becomes positive. The momentum becomes zero at time increases, the ball
starts moving down with an increasing linear momentum in the downward direction
(negative) and reaches back to its original position.
20. Here acceleration is same for both P and Q as block Q oscillates but not slip. The
 P  Q  system oscillates with angular frequency  . The spring is stretched by A.
k k
Angular frequency of the system,   
mm 2m
Maximum acceleration of the system in SHM
2
2  k  KA
amax  A  A    . This acceleration to the lower block is provided by
 2m  2m
 kA  kA
friction Maximum force of friction f max  mamax  m  
 2m  2
21. L  L4
dm   dx dm  0 xdx dI  dmx 2 dI  0 xdx x 2 I   dI   0 x3dx  I  0
0 4
22. 9
L.C  1MSD  1 VSD  1MSD  MSD  9MSD  10 VSD 
10
 9 1 1 
 1   MSD  MSD    1 mm  0.1 mm  1MSD  1mm 
 10  10  10 
Reading of side, l  MSR  VSR  LC   10 mm  1 0.1mm  10.1mm  1.01cm
mass m 2.736 g
Now, density     2.66 g / cm3
3 3
volume l 1.01
(Rounding off to 3 significant figures)
23. Let d   x S y f z  K  x S y f z where K is a dimensionless constant.
M 0 L1T 0  M x L3 x M yT  yT  z Equating dimensions both sides
1 1
M 0 L1T 0  M x  y L3 xT  y  z  x  y  0, 3 x  1 x   and y   n  3
3 3
24.  KE  PE
A/ 2
450
A T T
So, y   A sin t  t   or , x  8
2 8 x
25. 5 1 1
oscillation  oscillation  oscillation. Time taken to complete half oscillation
8 2 8
T 5 T T 7T
 , For oscillation t      7
2 8 2 12 12
26. a b c
F AaV b Dc  MLT 2    L2   LT 1   ML3 
       
a  c 11
C  1,  b  2, a  1  1
b 2
27. 2 2 2 2
E1 M1  L1   T2  E1 M1  L1   4T1  3E1
           E2 
E2 M 2  L2   T1  E2 3M1  2 L1   T1  4
28. Given, Height of the water, H  12 cm , Velocity of water coming out of hole,
2 H  h
v  2 gh . Range of water, R  vt  R  2 gh   2 h H  h
g

h
H

dR H
R For maximum range  0 h
dh 2
12
Range is maximum when h   6m
2
29. From momentum conservation in perpendicular direction of initial motion.
mu1 sin 1  10mv1 sin  2 ……………….. (i)
It is given that energy of m reduced by half. If u1 be velocity of m after collision,
1 1 1 u
then  mu 2   mu12  u1  . If v1 be the velocity of mass 10 m
2 2 2 2
2
1 2 1 u u
after collision, then  10m  v1  m  v1 
2 2 2 20
From equation (i), we have sin 1  10 sin  2
30. r1  3cm

r2  6cm Req

4T
Excess pressure inside bigger bubble 
r2
4T 4T
So, Excess pressure inside the smaller soap bubble P1  
r1 r2
The excess pressure inside the equivalent soap bubble
4T 4T 4T 4T rr
P2  P1  P2     Req  1 2
Req Req r1 r2 r1  r2
Putting r1  3cm, r2  6cm  Req  2cm
 CHEMISTRY
31. Zr and Hf have same radii due to lanthanide contraction.
32. Cryolite: Na3 AlF6 , Sphalerite: ZnS
33. Ti 4 has 3d 0 configuration.
34. O O
HO  S  O  S  OH
O O
 H 2S2O7 
35. Cr 2   Cr 3 3d 4  
36. EAN  Z  O.S  2  C.N
37. Cs has lowest I .P and hence it shows photo electric effect to the maximum extent.
38. Highest oxidation state of Mn is found in oxide not is fluorides  oxygen can form
double bond.
39. Conceptual
40. O
||
KMnO4 SOCl2 H / Pd BaSO
C6 H5  CH3  C6 H5  COOH 
 C6 H5  C  Cl 
2 4 C6 H5  CHO
 A  B
41. 2
 Zn  H 2O   and SiCl4  sp 3 (tetrahedral)
 4
42. 
 0  t
4
43. Cr  NH 3  
3
 d 3  3  3  2   3.87 BM
 6

CuF6 3  d 8  2  2  2   2.84 BM

44. Co3 : WFL : 3d 6 : 4 unpaired electrons
Co3 : SFL : 3d 6 : t26g : no unpaired electron
45. Solvate/hydrate
46. 30  alcohols reacts fastest.
47. -I group  Acidic nature
48. 
C6 H5OCH3  HI  C6 H5OH  CH3I
49. The more negative charge will give more electrons into  * MO of CO . So the bond
order decreases.
50. Haloform reaction.
51. C2 H 5

, , ,

H H

, ,
H H
H H
Cis  meso  Trans, enautiomers
52. Tetrahedral – no geometrical isomerism
53. H H H
B B
H H H

54.  RhCl  PPh3   ,1  4  5

 3
55.
t2g3  e1g 
56. Conceptual
57. Bronze: Cu , Sn; Brass: Cu , Zn :
German silver : Cu , Zn, Ni
11 2  4
58. H2N N NH 2

N N

NH 2

59. O
Cl
O OH
O

60. Ti3 3d 1 1 2
Cu  3d 10 0 0
Ni 2 3d 8 2 8
Fe3 3d 5 5 35
Mn 2 3d 5 5 35
Co 2 3d 7 3 15
 MATHEMATICS
61. 1
Given first term being A 
4
1 1 1 1
,  d ,  2d ,  3d
So, 4 roots in A.P. are
4 4 4 4
2
 2

Now given, x  2 x  m x  2 x  n  0 
We can see that the sum of the roots in both the factors is 2
1 1 1 1 1
Hence,   d   2d   3d  4  d 
4 4 4 4 2
1 3 5 7
Hence, roots are , , and .
4 4 4 4
3 5 1 7
Here,   2 and   2
4 4 4 4
3 5 15 1 7 7
Hence, n    And m   
4 4 16 4 4 16
62.  2c  c4
We have, x 2   x 0
c5  c5
 2c  c4
Let f  x   x 2   x  
c5  c5
So, f  0   0, f  2   0, f  3  0 must be satisfied simultaneously.
c4
Now, f  0   0  0 …………….(1)
c5
c  24
f  2  0  0 ……………. (2)
c 5

1 2 3

4c  49
And f  3  0  0 ……………….. (3)
c 5
 49 
Hence, 1   2    3  c   ,24 
 4 
So, the greatest integral value of c is 23.
63. ln
m
2
1
n
And l , G1, G2 , G3 , n are in G.P. r   4
l
 1 1 3
n n n
 G1  l   4 ; G2  l   2 ; G3  l   4
l l l
2 3
4 4 4 4 n 4 n 4 n
  G1   2  G2    G3   l    2l    l  
l l l
 2
 l 3n  2l 2n2  ln 3  nl l 2  2nl  n 2  nl  l  n   4m2nl 
64.

adj adj  adj  adjABCD   
4
 ABCD 
31 16 16 16 16 16
 ABCD  A B C D

 A
16
     
A
2 16
A
4 16
A
8 16

240
 A  k  240
65. Given system of equations
x  ky  3z  0
3x  ky  2 z  0
2 x  4 y  3z  0
Eliminating y from first two equations, we get
2 x  5z  0 or 2 x  5z  x  5 , z  2
From equation (iii), we have
xz  5  2 
10  4 y  6  0 or y      10
y2    2
66. 4x  3 y y
The equation of the bisectors of OC and OB are 
5 1
 4 x  3 y  5 y And 4 x  3 y  5 y
 x  2 y  0 and 2 x  y  0
From the diagram, line BC is parallel to the obtuse angle bisector which has slope
2 . Therefore, Slope of BC  2
2  2
Hence, the equation of line BC is y   2  x  
3  3
Or 2 x  y  2  0
y

4x  3 y  0
B 2 2
A
 , 
3 3

O x
C

67. The circle is x 2  y 2  4 x  8 y  5  0

Its centre is  2,4  and radius is 4  16  5  5
 If the circle intersects the line 3x  4 y  m at two distinct points, then the length of
the perpendicular from the centre is less than the radius, i.e.,
6  16  m
5  10  m  25
5
  25  m  10  25   35  m  15
68. Tangent at point P is ty  x  t 2 , where the slope of tangent is tan   1 / t .

   
1 1 3/2
Now, the required area is A   AN  PN   2t 2  2t   2t 3  2 t 2 , Now,
2 2
t 2  1, 4 . Then Amax occurs
When t 2  4 . Therefore, Amax  16
Y t 2 ,2t 
P

N
S 1,0  X
 2
A t ,0 

69. The combined equation of the pair of tangents drawn from 1,2  to the ellipse
3 x 2  2 y 2  5 is S12  S .S11

 3 x 2  2 y 2  5   3  8  5    3 x  4 y  5 2
 9 x 2  24 xy  4 y 2  .........  0
2 h 2  ab
If angle between these lines is  , then tan   ,
ab
Where a  9, h  12, b  4
12  12 
 tan      tan 1  
5  5
70.  x  32   y  12   4 x  3 y 2
2
2 2  4x  3y 
Or  x  3   y  1  25  
 5 
Or PS  5PM
Therefore, the directrix is 4 x  3 y  0 and the focus is  3, 1 .
So, the equation of transverse axis is
3
y  1   x  3  Or 3 x  4 y  13
4
71.
   
2
y  x2  1  2  ymin  2  log 0.5 x 4  2 x 2  3  1
 range [3 / 4,  )
72. f  x   ax 2  bx  c
 f 1  a  b  c  3 (given)
Now f  x  y   f  x   f  y   xy
Putting y  1, we get
f  x  1  f  x   f 1  x  f  x   x  3
Putting x  1, we get f  2   f 1  1  3  7
Putting x  2, we get f  3  f  2   2  3  12 and so on..
Now, S10  3  7  12  ....  tn ………….. (i)
S10  3  7  ......  tn 1  tn ………….. (ii)
Subtracting (ii) from (i), we get
tn  3  4  5  ....... upto n terms

 tn 
 n  2  n  3  3  n2  5n S n2  5n
n  tn  
2 2 2
1  n  n  1 2n  1 5n  n  1  n  n  1 n  8 
   
2 6 2  6
 S10  330
73. 2 2
Given relation is  x  a    y  b   c 2 , c  0 . Let x  a  c cos and
dx dy dy
y  b  c sin  . Therefore,  c sin  and  c cos    cot 
d d dx
Differentiating both sides with respect to  , we get
d  dy  d
  cot   Or    cos ec 2
d dy dx
 
d  dx  d dx  dx  d
d2y
Or
2
 c sin    cos ec 2
dx
d2y cos ec3
Or 
dx 2 c
3
  dy 2  2 3 3


1    
  dx   c 1  cot   2 c cos ec  2
 
2
 
2
  c

2 3
d y  cos ec   cos ec3
dx 2
Which is constant and is independent of a and b .
74. Clearly g  x  satisfies condition of LMVT
g  5  g  0 
  g '  c  , c   0,5 
50
f  5 f  0 

6 1  g ' c   5
   g ' c 
5 6
75. Let k be an integer.
2
 
f  k   0, f  k  0    k  1  k 2  1  2  2k

 
f  k  0  k 2  k 2  0
If f  x  is continuous at x  k , then 2  2k  0 or k  1 .
76. 2
xi2  xi  18000  960 
2
Variance        300  256  44
n  n  60  60 
77. dh
 2, r  10 cm
dt
dx
We have to find when h  4 ,
dt
Where x is the radius of the top surface.
2
From the figure r 2  x 2  10  h 
dx dh
 2 x  2 10  h 
dt dt
dx 10  h  dx 2 10  4  12
   2    
dt x dt x x
When h  4, then x 2  102  62  64 or x  8 .
dx 12 3
  
dt 8 2

O
10  h  r

h cm

78. x
is always differentiable.
1 x
Also  x  2  x  2   x  1 x  2  x  3 is not differentiable
At x  1, 3. So, f  x  is not differential at x  1,3.
79.  1  x 
Let y  sin 2 cot 1  
 1  x 
Put x  cos    cos1 x
 1  cos  1  
 y  sin 2 cot 1  2
  sin cot  tan 
 1  cos   2
      1  cos 1  x
 y  sin 2     y  cos 2    
 2 2 2 2 2
dy 1
 
dx 2
80. 2  a x b x  c x  2
lim  1
 ax  bx  cx  x x  0 3 x
lim   e 
x 0  3 

2  a x  b x  c x 3  2  a x 1 b x 1 c x 1 
lim   lim    
3 x 0 x 
 3 x 0 x x x 
e e
2  x
a 1 b 1 x
c x 1
 lim  lim  lim 
3  x 0 x x 0 x x 0 x  
e
2/3
 e    e     e     abc 
2/3 ln a  ln b  ln c 2/3 ln abc ln abc 2/3

81. Let F , B and C denote the set of men who received medals in football, basketball
and cricket, respectively.
Then n  F   38, n  B   15, n  C   20
n  F  B  C   58 and n  F  B  C   3
Therefore, n  F  B  C   n  F   n  B   n  C 
n  F  B   n  F  C   n  B  C   n  F  B  C  ,
Given n  F  B   n  F  C   n  B  C   18
Consider the Venn diagram as given in figure.
U
F a B
d
b c
C

d  n  F  B  C   3  a  d  b  d  c  d  18
 abc 9
82. 5  kx  5  7
Or 12  kx  2 where 6  x  1
k
Or 6  x  1 where 6  x 1
2
 k  2 [ range of h  x   domain of f  x  ]
83. dy 3 x 2
2 3
y   x   or 
dx 2y
Therefore, slope of the normal at  2,3 is
 dx  23 1 1
    
 dy  2,3 3  2 
2 2 4
Or   2
Also,  2,3 lies on the curve. Therefore,
9  8   or   16  9  7 or     9 .
84.  x, x 1
f  x   2
 x  bx  c, x 1
 1, x 1
 f ' x   
 2 x  b, x 1
f  x  is differentiable at x  1 .
Then, it must be continuous at x  1 for which
lim f  x   lim f  x 
x 1 x 1
Or 1  b  c  1 Or b  c  0
   
Also, f ' 1  f ' 1
Or lim f '  x   lim f '  x  Or 2  b  1 or b  1  c 1
 
x 1 x 1
85. x4 y2 zk
As the line   lies in the plane 2 x  4 y  z  7 , the point  4,2,k 
1 1 2
through which it passes must also lie on the given plane, and hence
2  4  4  2  k  7 or k  7
86. sum of quantities n / 2  a  l  1
Mean  x     1  1  100d 
n n 2
 1  50d
1
M .D.   xi  x
n
1
 25  50d  49d  48d  ....  d  0  d  ....  50d
101
2d  50  51  225  101
 .  d   10.1
101  2  50  51
87. f " x   g " x   0
Integrating, we get
f ' x   g ' x   c  f ' 1  g ' 1  c
 4  2  c  c  2  f ' x   g ' x   2
Integrating, we get
f  x   g  x   2 x  c1  f  2   g  2   4  c1
 9  3  4  c1  c1  2
 f  x   g  x   2x  2
At x  3 / 2, f  x   g  x   3  2  5
  
88. Let a  6iˆ  6kˆ, b  4 ˆj  2kˆ, c  4 ˆj  8kˆ
 

Then a  b  24iˆ  12 ˆj  24kˆ  12 12iˆ  ˆj  2kˆ 
 Area of the base of the parallelepiped
 1   1
 a  b  12  3  18
2 2
Height of the parallelepiped
 
   c .a  b 12  4  16  20
 Length of projection of c on a  b     
a b 36 3
20
 Volume of the parallelepiped  18   120
3
 
a b


c 
 b
a

89. xn  xn 
ex   2  ex 
1
 xn  e x  xn  e x
1
 3     1
2   3    3  
L  lim      lim  
x  n x  n
x x
xn n!
Now, lim  lim  0 (Differentiating numerator and denominator n times
x  e x x  e x
for L’ Hospital’s rule)
 xn 
  2  ex 
    1
xn   3  
Hence, L  lim  3 e x lim   lim 1
x  x  n x  e x
x
ex
 1  log  2 / 3  0  0
90.   x  2 x  2
 x2 x0  x  2 2  x  0
 
f  x    x 2  2 0  x  1 f  x    2
 x x 1 x  2 0  x 1
  x x 1
 
Discontinuous at x  1 , therefore number of points of discontinuity is 1.