1 | spocode: PB-03/15 | Series #-Succeed 03-25/15 roto. (| | TTT Sample Question Paper 08 Chemistry 12" (code 043) General Instructions —— Read the following instructions eateally | There are 33 questions in this question paper with internal choice. SECTION-A cons SECTION-B cons SECTION-C cons Time :3 Hrs. ts of 16 multiple-choice questions carrying l markeach ts of 5 short answer questions carrying 2 marks each, ts of7 short answer questions carrying 3 markseach, 4 5 z a ts of 2 case-based questions carrying 4 marks each. SECTION-E cons S. All questions are compulsory. Use of log tables and calculators is not allowed. ts of 3 long answer questions carrying § marks each, Section A The following questions are multiple-choice questions with one correct answer. Each question carries 1 mark. There is no internal choice in this section. 1. Glycogen is a polymer of a-D-glucose stored in the Rate (a) liver, kidney and brain of animals. Experiment | TAN) | (BLMD | (mot ts (b) kidney, lungs and stomach of animals. 1 ot 02 002 (6) brain, liver and muscles of animals. 2 02 02 008 (@) stomach, muscles and lungs of animals. 3 os 02 032 What will be the order of the reaction with respect to reactant A? ao (2 2. Consider the following reaction. H\_/CN ea (byt (a)3 Identify Aand B from the given options. (2) A= Acetone , B= Methyl cyanide (b) A= Hydrogen cyanide, B= Formaldehyde (©) A= Acetonitrile, B= Ethanal (a) A=Methanol , B= Methyl cyanide 3. Examine the following data for a reaction ‘A+ B—> P. Concentrations of reactant A is varied, while the concentration of reactant Bis kept constant. fnich of the following alkyl halides is hydrolysed by Sy.2 mechanism? (0) CH,CH,Br (b) CH, Br (a) (CHy)s CBr 5. Out of o-chlorophenol, o-bromophenol, oiodophenol and o-fluorophenol, which is most acidic? (@) o-bromophenot (©) oiodophenol (b) o-chlorophenol (d) o-fluorophenol6 Match the of 3 Magnetis 4.90 BM Zero Select the correct option, ©) O40, Gi-(G), Gi O09, G8), Ginpy, (9), (ii)-(p), (ii), (iv) DO), 0, Gey, G * Agas Xat1 atm is bubbled through a Solution containing a mixture of AY and MZ~ at 25°C If the order of reduction Potential is Z> > X then, (2) Y will oxidise both X and Z (©) ¥ will reduce both X and Z (©) Y will oxidise Z and not X (4) Y will oxidise X and not Z * Which of the following compound will not undergo azo coupling reaction with benzene diazonium chloride? (@) Aniline (b) Phenol (© Anisole (A) Nitrobenzene 8. What is “A”in the following reaction? CH,—CH=CH, Cr +HCI— a CH,~CH—CH, a @ CH,~CH,—CH,~C1 “OC Gus cH—cH, a © HCI—CH,—CH, @ oie | iSueceed Chemisty, 10. For a reaction A —> product, a plot of Jog ty/2 versus log apis shown in the Figure If the initial concentration of Ais Tepresenteg by dg, the order of the reaction is Tog @—> (two (d) one (a) zero (b) three 11. Which among the following compounds will give a secondary alcohol on reaction with Grignard reagent followed by acid hydrolysis? | (P)HCHO (Q)CH;CHO (R)CH;COCH,; —_(S)HCOOCH, Select the correct option. (a) Only (P) and (R)—_(b) Only (Q) and (5) (©) Only (P) and (Q) (a) Only (R) and (|) 12. Lanthanoids form complex with which of the following ligand? @r () Br (ocr @r | Assertion-Reason Direction (Q. Nos. 13-16) In the following questions as Assertion (A) is followed bya eorresponding Reason (R). Use the following keys f0 choose the appropriate answer. | (@) Both (A) and (R) are true and (R) is the correct explanation oft | (6) Both (A) and (R) are true but (R) is not the correct explanation of (A), (©) (A)is true but (R) is false. | (d) (A) is false but (R) is true. | Assertion (A) Acetaldehyde on reaction | with dil. NaOH forms aldol. Reason (R) Aldehydes and ketones having cchydrogen undergo aldol condensation, 13. 14. Assertion (A) Galvanised iron does not rust. Reason (R) Zinc has a more negative electrode potential than iron.sample Question Paper 03, 15. Assertion (A) Phenols give o and pnitropheno! on nitration with cone. HNO, and 1,80, mixture. Reason (R) —OH group in phenol is o> and pairecting 7 16. Assertion (A) Vitamins A, D, E and K are stored in liver and adipose tissues. Reason (Rt) These vitamins are soluble in water, Section B The section contains $ questions with intemal choice in one question. The following questions are very short answer type and carry 2 marks each, 17. (a) What is the relationship between osmotic pressure at 273 K, when 10 g of glucose (p, ) 10 x of urea (p, )and 10 g of sucrose (p3) are dissolved in 250 mL of water? (b) A solution containing 4 g of polyvinyl chloride in TL of dioxane was found to have an osmotic pressure of 6 10 atm at 300 K. Then, what will be the molar mass of polymer polyvinyl chloride? 18. Give reason for the following. (a) t-butyl bromide is more reactive towards S,y1 reaction as compared to 19. (a) Explain why cyclohexanone forms cyanohydrin in good yield but 2,2,6-trimethyl cyclohexanone does not. (b) How will you obtain tertiary butyl alcohol from acetone? 20. Carbon dating is used by archaeologists to date trees, plants, and animal remains as well as human artefacts made from wood and leather. If an archaeologist found that the percentage of carbon-14 in the remains of an animal ‘was 10% of that carbon-14 was in the mbutyl bromide. animal's body when the animal died, | (6) CH,CH,T undergoes Sx.2 reaction faster the age of this sample. (Given the half | than CH, CH, Br. carbon-14 = 5730 years) | Or (@) Ahydrocarbon C,H, gives only one | | monochlorination product. Identify the 21+ 18g of glucose Cgl120, (molar mass =1808 || | hydrocarbon. mol”) is dissolved in 1 kg of water in a j a a sauce pan. At what temperature will this | |) @youtor-K amt SAY solution boil? -1 which one undergoes faster reaction (Ky for water =0.52 K kg mol” and boiling towards S,1 mechanism? point of water =373.15 K) ise-03 short answer type and carry 3 marks each. 22, Answer the following questions. (a) By giving an example, explain the use of complex compounds in qualitative | analysis. | (b) Explain why are low spin tetrahedral | complexes not formed. | | | Section C 2 The section contains 7 questions with internal choice in one question. The following questions are (©) How many geometrical isomers can the tetrahedral complex [Ni(CO), ] have? 23. (a) Explain strong and weak electrolytes with examples. | (b) Calculate the emf of the cell. Mg(s)IMg?*(0.1M)I 1Cu2*(Lx10"'M)ICu(s)= Given : I 0.34V; ey ENaget ayy 7? (©) Arrange the following metals in the order in which they displace each other from the solution of their salts Al, Cu, Fe, Mg and Zn. 24, Write the chemical reaction for the following, (a) When ethanal is treated with ethyl magnesium bromide followed by hydrolysis. (b) Phenol is treated with cone. HO, and cone. HNO}. (©) Phenol kept open in the air. 25. An organic compound A(C,H,O3) on treatment with ethyl alcohol gives a carboxylic acid Band compound C. Hydrolysis of Cunder acidified conditions gives Band D. Identify A, B, Cand Dand write all the involved equations. 26. (a) What happens when glucose reacts with bromine water? (6) What is meant by inversion of sugar? (©) Write the function of maltase enzyme. Or Following reactions are taking place in test tubes (a)-(d). ALE Gicose o o Cone. HINO, T) w Glucose (ey ea Xi \ Identify and write the chemical equations involved of the reactions which proves that (i) Glucose molecule contains 6-C in straight chain (ii) Glucose molecule contains 5-hydroxyl groups. (iii) Glucose molecule have —CHO group. 27, The Wurtz coupling is one of the oldest organic reaction, and produces the simple dimer derived from two equivalents of alkyl halide. The intramolecular version of the reaction has also found application in the preparation of strained ring compounds Name the possible alkene which will yield toluene on their reaction with sodium and methyl chloride. Write the name of reaction, involved and its mechanism also. 28. A first order reaction is 20% complete in 10 minutes, Find the time required for 75% completion of the reaction. Section D The following questions are case-based questions. Each question has an internal choice and carries 4 (2+1+1) marks each. Read the passage carefully and answer the questions that follow. 29. Complex compounds play an important role in our daily life. These compounds contain central metal and ligands. Ligands can be negatively charged or neutral molecules. Ligands can be differentiated on the basis of the number of donor sites which is simply called as denticity. It can be monodentate, didentate, polydentate, ambidentate ligands, Polydentate ligands are more stable than monodentate ligands. Complex compounds are named according the IUPAC system. Many approaches have been put forth to explain the nature of bonding in complex compounds. These are valence bond theory (VBT), crystal field theory (CFT), ligand field theory (LFT) and Molecular orbital theory (MOT).sample Question Paper 03, Based on the above information, answer the following questions. (@) (@ What is the oxidation state of Cu in ICu(Ny), C1]? Gi) What is the TUPAC name of the complex INi(NIy ), JCI? (&) [Co(CN),]*" forms low spin complex. Why? (©) Whatis the magnetic property and number of unpaired electron in complex [Co(NH3 )g 1°"? Or What is the hybridisation and yybridisation and geomet of [Co(NH)¢]°* complex? " 30. The study of conductivity of electrolyti solution is important for the development of electrochemical devices, for the characterisation of the dissociation equilibrium of weak electrolytes. Typically the conductivity of electrolyte solution is measured for electrolytic solution with concentration in the range of 10° to 10 mol L?. Section E The following questions are long answer types and carry 5 marks each. All questions have an internal choice. | 31, Answer the following. (a) Why is the highest oxidation state is exhibited in oxo-anions of transition metals? (©) Why the transition elements show high melting points? (©) Why first ionisation enthalpy of Cr is lower than that of Zn? (a) Explain the observation, although Cr** and Co” ions have same number of unpaired electrons but the magnetic moment of Cr°* is 3.87 BM and that of Co?* is 4.87 BM. (e) What are the misch metals? Or (a) What happens when KMnO, reacts with nitrite ion? (b) What happens when a lanthanoid reacts with water? The molar conductivity of strong electrolyte solution can be given by Kohlrausch’s law equation, Ay = yy “®VE: The molar conductivity of weak electrolyte nthe other hand is depenclent on degree of dissociation of the electrolyte. Based on the above information, answer the following, questions. (a) (i) Why does the conduct solution decreases with (ii) Give an example of strong and weak electrolyte. (b) Derive the unit of molar conductivity. (0) Draw a graph Ay, versus CY? for strong and weak electrolytes. Or X and ¥ are two electrolytes. On dilution | molar conductivity of ’X’ increases 2.5 times, while that of Y increases 25 times. Which of the two is a weak electrolyte? Explain briefly. (© Why are alloys mostly prepared from transition metals? (A) Write the ionic equation for reaction of KI with acidified KMnO,. q (e) Write the outer shell electronic configuration of an element with atomic number 24. Why is this different from the elements that are adjacent to it in the periodic table? 32. (a) When 2 g of benzoic acid is dissolved in 25 g benzene, it shows a depression in freezing point equal to 1.62 K. Molal depression constant (K,) of benzene is, 4.9 K kg mol and molecular weight of benzoic acid =122 g/mol. What will be the percentage association of the benzoic acid 2 (Benzoic acid forms dimer when dissolved in benzene). UH25 mg of K,SO, was dissolved in 2 L solution. Find out its osmotic pressure, Taking into consideration that K$O, has dissociated completely. (R=0.082 L atm K mol) Or (@) What do you understand by elevation of boiling point? How it is related to molality? (b) Heptane and octane form an ideal solution. At373K, the vapour pressure of the two liquid components are 105.2 kPa and 46.8 kPa Tespectively: What will be the vapour Pressure of a mixture of 26.0 g of heptane and 35 g of octane ? 33. Write structures of different isomers corresponding to the molecular formula, CsHyN. Write IUPAC names of the isomers which will liberate nitrogen gas on treatment with nitrous acid. Or (a) Krishna took three amines U, Vand W. The three amines were added to Hinsberg’s a iSucceed Chemistry, — 1G AN reagent, The products were added to C NaOH and the observations were tab ula as follows _ = “___Obseraions ae the ag Jines the products formed to agit, Ane ine rose solutigns. Ne TW The product insolible inayat __The products insoluble in a. ig (i) Which of the amine(s) have the struct, formula of R-NH—R? (ii) What does the solubility of the produ formed in aq. alkali imply? (iii) Which of the following amines may be prepared by the Gabriel phthalimide process? Give a reason. (b) How will the following be converted ? (Give chemical equations) (i) Ethyl bromide to ethyl isocyanide. (ii) Aniline to benzene diazonium chlorideSolutions |i toppers sive sy commitment 1 affirm that 1am reviewing these solutions only after the soloed the Sample Question Paper 3. my ot tu purpose of looking the solutions is soley fo verify whether my anstersfsohutions were corrector not and to identify 4. (©) Glyengen is a polymer of a-D-ghucose stored in the liver, brain and muscles of animals and is also known fas animal starch. 2.0) Hy_UCN HCHO + HCN ——+ Sc. Formaldehyde Hydrogen, nou ® ‘sranide Formaldehyde a ‘Syanohydein 3. (c) For the reaction, A+ B——> P ‘The differential rate law is Rate = MAPLE Rate, =k(01)"(02)" Rate; =1(0.2)"(02)" Thus, Baez (22) 0.08 Rate, (0.1) ~0.02 = 422" ‘Taking log on both sides Jog 4=log(2)" => 2log2=xlog2 => Hence, order of the reaction with respect to reactant A is2. 4, (6) S,2 mechanism involves the back side attack and formation ofa transition state. Thus, less hindered alkyl halide readily undergoes Sy2mechanism. ‘Among the given haloalkanes, CHBr (methyl bromide) is less hindered, and hence, gets hydrolysed bySy2mechanism. 5. (b) o-chlorophenol will be most acidic. Here, e-fluorophenol is weakest acid due to strong {intramolecular H-bonding. The acidity of other halophenol decreases as the ~[effect of halogen decreases. 6. (6 The number of unpaired electrons in Cr°*, Mn**, Fe?" and Scare 3, 5, 4 and 0 respectively. By using, formula for magnetic moment, ic. w =/n(n"+2) where, ris number of unpaired electrons, the magnetic ‘moment of Cr?*, Mn2*, Fe?* and Sc** comes out to be 3.87 BM, 5.92 BM, 4.90 BM and 0 respectively. Thus the correct match is ()(q); (H)-(P) (ii) (iv). 7. (@) The given order of reduction potentials (ortendencies) is Z > Y > X. More the reduction potential easier to get reduced and less the reduction Potential easier to get oxidised. The metal having log(2)? = 1og(2)* xe2 fristakes in case my solutions were wrong or I could not solve that. 1". (a) higher reduction potential can oxidise the metal having lower reduction potential. ‘Thus, spontaneous reaction will have the following characteristics. Z.is reduced and Y is oxidised. Z is reduced and X is oxidised. Y is reduced and X is oxidised. Hence, Y will oxidised X and not Z. (d) Diazoniuim cation is a weak electrophile and hence it reacts with electron rich compounds containing ‘electron- p; (glucose) > p; (sucrose) (b) Given, a)=4g, V=1L T=300K, x=6% 10 atm uy, fe know, nV =“. RT We kno om 6104 x1=—4 0082 «300 Mg M,=16 10° g/mol i 18. (a) InSy1 reaction, reactivity depends upon the stability of intermediate carbocation formed, Let us consider the formation of carbocation of two given alkyl halides. CH, —CH,—CH—CH,— Br— butyl bromide CH, — CH,— CH,—@, (1° carbocation) a less stable ® cH, — a Se CH, cH, butyl bromide 3° carbocation) . hore sable Carbocation formed by tert-butyl bromide bei tertiary is more stable than butyl bromide whichis primary and hence, t-butyl bromide undergoes5,| reaction faster. a (6) AsI” ion is a better leaving group than Br~ ion, therefore iodides are more reactive than bromides. ‘Therefore, CH;—CH;—I is more reactive thn (CH, —CH,—Br towards$y2 reaction and thereby CH, —CH, —I would undergo $y? reaction fast than CH, —CH,—Br. a Or (@) Hydrocarbon, CsHy, which gives only one monochlorination product is, 2, 2-dimethylpropane. ca cH, oy, cH, —¢—cH, 5 CH, cory | cy crt, | Lo akan tates 2-dimethylpropanesample Question Paper 03 @) The reactivity towards Sy 1 reaction depends upon thestability of the intermediate carbocation atky halide gives fonisaton nan Tus, act « Toniation, K a AN alkyl ehtovie 3° caocaton a (onore stable) he Patky] doride 2 Concation (loss stable) As 3° carbocations are mote stable than a ar carbocations, therefor, AN. yi react * S ° HAC. hy cH, a cH, ee ¥ cydohiXanone a 13. @) 2.2,6-trimethyl cyclohexanone In 2264rimethyl cyclohexanone, three methyl groups are present at a-position with respect to the Ketonic (> C—O) group. Therefore, these. groups Cause stevie hindrance during the nucleophilic attack of CN" ion and cyanohydrin is not formed. Fiowever, due fo the absence of methyl groups in Gydlohexanone, there is no steric hindrance and Granchydrin is formed, @ (>) BSS 0+ cHyMgB: Be ae CH; CH, " | Hyco" Br 228 cH, — Fon CH CHs tentotanst 20. Since the concentration of ¥ C decays with time at a particular rate (which depends on initial concentration), the kinetics for first-order could be used to identify the time required to change in the concentration of C. As half-life = 2 a 3700 @ For first order reaction, = t =(2.303/ k) log (Ao / A) => £ =(2.303 x5730/ 0.693) log 100/10= 19042 ‘Thus, the age of the sample is 19042 years. w 21. Given, weight of glucose, 1, = 18g Molar mass of glucose, M, =180g mol” 63 Weight of water, W = Tkg = 1000 8, K, © 052K kg mot 1m, 1000 levation in boiling, point (AT) = Ky pe a Elevation in bolling point (NT) Keg. Af, =052> 18,100 _gos2k 180“ 1000 aheT, a (where, T, is boiling point of solution) (0052 = T, -373.15 7, =37315 + 0052 =37320K wo 22, (a) Ni?" is detected by the formation of a red complex with dimethyl glyoxime (OMG). Cobalt is detected as coordination compound of cenitroso-f-naphthol. o (©) For tetrahedral complexes, the crystal field stabilisation energy is lower than pairing energy, s© they are not formed in low spin state. ¢ (©) The relative positions of the unidentate ligands linked to the central metal atom are identical. Thus, no geometrical isomers will form for the specified coordination complex. @ 23, (a) Strong electrolytes These electrolytes are completely dissociate into ions at all concentrations. e.g. NaOH, NaCl, KClete. Weak electrolytes The electrolytes which do not ionise completely in aqueous as well as in molten state are called weak electrolytes. e.g, HCOs, HgCla, CH,COOH ete. @ () For the given cell half-ell reactions are ‘Atanode Mg(s) —> Mg**(aq) + 227 Ateathode Cu” (aq) + 2e° —> Culs) ng point of solution As we know, 2.303RT | [Mg?*] Fe tog OO Eee = Fea mF [cu] . 2303%RXT 01 Feet mts] 2.96500 '°8 [0.1] =034—(-237)-0 (clog 120) 1 Eq =271V @ ‘Gommon’” Choosing the wrong anode or cathode Mistake. of the cel while calculating standard electrode potential will make the answer incorrect. _ (©) The order in which the given metals displace each other from the solutions of their salts is Mg, Al, Zn, Fe, Cu @ When ethanal is treated with ethyl magnesium bromide, then unstable compound is Tormed which further on hydrolysis, gives final product, ie, butan-2-ol,64 f Osi eunatets leny—cn-Gh 1,0 CN) CHCl Mg(OHDBE t cnc, Pehanal on Butnn ot a) cone, H,SO, and conc. (b) When phenol is treated HNO, the nitration of phenol takes place and 2.4, 6-trinitrophenol is obtained. on on ON: No; Cone. H:S04¢ Cone HNO: Phenol NOx Pieri acid rnitrophenol 2.4, 64rinitrophenel) w (©) Phenol gets slowly oxidised to a pink coloured compound pbenzoquinone when exposed to ait OH oO O-a— Oe fe} Phenol p-benzoquinone w 25. ° ox,-& 8-0. co — cr coocyty CHsCOOH CHs—C~" “Emmanol——_—Ethylethanoate™Bthanoicacid § © ® ‘Acetic anhydride wy a (CH,COOC,Hs + Ho» any eeenoate (CH,COOH + CH,CH,OH Bthinoicacid Ethanol o @ Thus, A= (CH,CO),0, HjCOOH, C= CH,COOC;Hs, D= CH,CH,OH @ 26. (a) Glucose on reaction with bromine water, gets oxidised to form six carbon carboxylic acid, ie. sgluconic acid. i coon I (CHOH), 2“! (CHOH), onan” cHoH cH,0H Ghose luce a a ©) GHP +p > cao, + Cade tetieay stamy Hen ‘Sucrose is dextrorotatory. On hydrolysis, it gives an equimolar mixture of glucose and fructose, which are dextrorotatory and laevorotatory respectively. iSucceed Chemistry Further, the lnevo-rotation of fructose is moy, 9.4%) than the dextro-rotation of glucose “ts (ie. 152.5%), so that the mixture as a whole, laevorotatory. ‘Thus, on hydrolysis, the dextrorotatory suc, gradually changes into the laevorotatory my, im ‘This phenomenon is called inversion of supar equimolar mixture of glucose and fructosejy.* invert sugar. Maltase is used in hydrolysis of maltose inty glucose. © Or Reaction in test tube (c) Proves that, glucose molecule contains 6-C in a straight chain, HO (coor, + cry — Cs — CHa CHa — ch i) cHOH (ii) Reaction in test tube (d) Proves that glucose molecule contains 5-OH groups. HO ECON HO CHCO. (cHOF. = (CHOCOCH), CH;OH CH,OCOCH, Glucose pentaacerste (iii) Reaction in test tube (b) Confirms aldehyde gr, in glucose. CHO cooH I Bry I (cHom, —2__,, (CHO, Water cH,OH CH,OCOCH, 27. Chlorobenzene reacts with sodium and methyl chloride in the presence of dry ether to form toluene and sodium chloride. This reaction is known as War Fittig reaction. ()-c-2x-c1-cr, 2 Chorabenzene (\-a,-200 Toluene 1 Mechanism involved : la ~ oni 7 Jenact oF << AMERY — oyeme ot, CH Ore -Or a 28. For the first order reaction, 2.303, ka logsample Question Paper 03 2303, 10 10 8g 2303) a ato, 1-223 1og Ait) py substituting value of kfrom fg, () in 2.303 100 ENB) 10 “8 a5 10 8S 10 Tog 10-Togs “ a 9. Gi), trax xlog4 10 7 ~ ga 8? 10 “T=@x03010) 10 0097 a 28, (a) (Let the oxidation state of Cu in [Cu(NH),Chl x 2x03010 0.6020 = 62 mins x4 0x44(-1x2)=0 = x24 Thus, oxidation state of Cu is +2 qa) (i) TUPAC name of the complex [Ni(NHg),]Cly is hexaamminenickel (I) chloride. o (©) In the complex [Co(CN),}*", Co is in +3 oxidation state. The electronic configuration of Co°tis [Arhs3@*. The splitting of d-orbitals into two sets of orbitals in the given complex is represented as dya_ypdza Et () mH Be Aeydyztx 8) Since, CN~ is a strong field ligand and therefore pairing of electrons takes places giving rise to low spin complex. @ In the complex [Co(NH,).]*, the oxidation state of Co is +3. It has the electronic configuration as [Ar}e3d®. NH, ligand in this case behave as a strong, field ligand. 80, it causes pairing of electrons in 3d-orbital. ‘Asa result, there are no unpaired electrons present in the complex. So, the complex is diamagnetic in nature, © Or In, (Co(NH,),]*", Co is in +3 oxidation state. Its electronic configuration is [Ar}g34°. NF is a strong field ligand, which causes pairing of electrons in 3d orbitals. So, this complex involves dsp? hybri complex has octahedral geometry. tion. The @ 65 380, (a) (i) Conductivity of an electrolytic solution decreases with dilution because the number of fons per unit volume furnished by an electrolyte decreases with dilution, @ i) Strong electrolyte = Potassium chloride Weak electrolyte= Acetic acid @ 000 %« _ 10001 ©) An “ roy (©) Bon (Sex? mol“) x Gtrong electrolyte) 0 C(moms)®#— @ Or Y is a weak electrolyte. On dilution, complete dissociation of weak electrolyte occurs and thus, there is a steep increase in molar conductivity. However, in case of strong electrolyte, itis already dissociated completely and therefore on dilution, the rise in conductivity is not very much. ‘The ability of oxygen to form multiple bonds with transition metals is responsible for the high oxidation state of metal in oxoanions. @ Due to involvement of greater number of electrons in the interatomic bonding from (n-1)d-orbitals in addition to ns-electrons. ‘Thus, transition elements have large number of ‘unpaired electron which are responsible for high strength of metallic bond and hence high melting point. First, ionisation enthalpy of Cr is less than that of Zn because Cr” has stable d® configuration. In case of zinc, electron comes out from completely filled 4s-orbital. So, removal of electron from zine requires more energy as compared to the chromium. 31. @) ©) o © @ ‘Magnetic moment of any metal ion can be decided on the basis of spin as well as orbital contribution of electron, Due to symmetrical electronic configuration, there is no orbital contribution in Cr** ion, However, appreciable orbital contribution takes place inCo* ion. (a) o66 32. (0) Misch motal is an alloy which consists of a lanthanoid metal (= 95%), irom (upto'5%) and traces of SC, Ca and Al. Tt ie need in Mg baced alloy: to produce bullets, shell and lighter-flint a or 2MnOg + BNOS + 61 92Mn?*4 SNO} +314,0. (n) Nitateian (1) (0) When o Janthanoid reacts with water, it forms hydroxide, Ln+ 38,0—+ Ln (OH), + 1, a (©) The transition metals have almost similar radii Hence, alloys are readily formed by these metals. (1) (@) The ionic equation for the reaction between KI and acidified KMnO, is JOU + 2MnO, + 161% —s 2Mn?*+8H,0 451, (1) (©) The element with atomic number 24, Cr, has outer shell electronic configuration 43!,34°. This is a Sonsoquence of the fact that half-filled sets of Sé-orbital are relatively more stable and the energy Sap between 3¢ and 4s-orbitals is small. w @ Given, Wicosenst #28, Ky Wsenaene = 258, AT; Weenzsc acid *1000 Now, AT; = K,x—\Bewsiea Benscic cd XW penzene 4.92 1000 1.62=. Mpcaicsea *25 8 4.92 «1000 M, = =: L lneancnie =F og = 24198 g/mol 2C,H;COOH=*(C,H,COOH), At t=0 x o At I-x = 2 Hi xis the degree of association, (1-x) mole of benzoic acid is left undissociated and corresponding = as associated moles of CgHsCOOH at equilibrium, 50, total no, of moles of particles at equilibrium x Total number of moles of particles at equilibrium equals to van't Hoff factor (i). But we know that, Normal molecular mass "Abnormal molecular mass u u (2) (b)_ Given : Mass of solute (x) =25 m, Bs Volume of solution =21 %,, Temperature (1) =273+27=300 R= 0082 L atm K“'mof-t Lf ti RT Vem, 325% 10 10082 1399 ia = 00053 atm Or (0) Elevation of boiling point(A7;) On Mixing non-volatile solute in solvent, the vapoup Pron solution decreases Asa result boiling point of solution increas, increase in boiling point of solvents krone elevation in boiling point (A7,) i In mathematical form, AT, =T, - % where Tad Ts boiling point of solution ang solvent, respectively. Relationship between elevation molality Elevation in boiling point = K, xmolality where, K, =molal elevation constant. (©) Number of moles of octane in boiling po, (my=—Mass__ 35g “°° Molar mass ~ T1dg mol =(12«8)+ (1x18) [Molar mass of octane, CyH, 14g mol Number of moles of heptane [Molar mass of heptane, C; Hy, =(12%7)+ 16) =100g mol" Mole fraction of octane, (44-42 (0307 mol) Ng + "(0307+ 0.26) mol Mole fraction of heptane, (19)=—t#_=__@.26 mol) 4 +% (0307+ 0.26) mol ‘Vapour pressure of pure heptane (3) = 105.2 kPa ‘Vapour pressure of pure octane (pi,)= 46,8 kPa In the mixture of 260g heptane and 350g octane (Vapour pressure of heptane (jp) = p.x5 = (105.2 kPa x 0.459) = 48.18 kPa Vapour pressure of octane (Pa)= Ph ta = (46.8 KPa x 0.541) = 25.32 kPa (iii) Total vapour pressure of the mixture 4 (P)= Pi + Hh = 25.32+ 48.18=735 kPa 541 0.459ample Question Paper 03 NH, 33. CH, —CH; —CH;, —NH; ; CH, —CH—CH,; Popup amine Fromm zamine cH CH; —NH—C,H, ; Nevetigiethanamine ey Ci, —N—cH, CH,—CH—CH, NE on Propan2-smine Propan-d-l + Nat +HCI @) Or (@) (@) Amine Vand W have the structural formula of R-NH-R. @ (ii) The hydrogen attached to nitrogen in the product formed after the amine U reacts with 67 Hinsberg’s reagent is strongly acidic due to the presence of a strong electron-withdrawing sulphonyl group. Hence, itis soluble in aq. NaOH. However, amine Vand W do not contain any hydrogen atom attached to the nitrogen atom in the product formed and hence, insoluble in a7. NaOH. @ Git) Amine U is soluble in ag. NaOH. So, itis a primary amine. Gabriel phthalimide Synthesis is used for the preparation of primary amines. @ (b) (i) Ethyl bromide will react with alcoholic AgCN to give ethyl isocyanide (C;Hs—NO). w (CjHs—Br + AgcN “1824,C,H;—NC + AgBr (i) When aniline reacts with dil. HCl and aq, solution of sodium nitrite (NaNOz) at 273-278 K, it will form benzene diazonium chloride and the reaction is called diazotisation reaction. @ NH; Nx