The document is a class test consisting of multiple-choice questions (MCQs) and descriptive questions covering various topics in chemistry, including molarity, quantum numbers, VSEPR theory, and thermodynamics. It is structured into three sections with questions carrying different marks: Q1 to Q10 for 1 mark each, Q11 to Q19 for 2 marks each, and Q20 to Q23 for 3 marks each. The total marks for the test are 40 and the duration is 2 hours.
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SN 11th Chem 2024
The document is a class test consisting of multiple-choice questions (MCQs) and descriptive questions covering various topics in chemistry, including molarity, quantum numbers, VSEPR theory, and thermodynamics. It is structured into three sections with questions carrying different marks: Q1 to Q10 for 1 mark each, Q11 to Q19 for 2 marks each, and Q20 to Q23 for 3 marks each. The total marks for the test are 40 and the duration is 2 hours.
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CLASS TEST
TIME:- 2 HRS M.M:-40
Q1 TO Q10 CARRY ONE(1) MARKS EACH (MCQ) :-
Q1. If the concentration of glucose (C6 H12 06 ) in blood is 0.9 g L-1 , what will be the molarity of glucose in blood? (a) 5 M (b) 50 M (c) 0.005 M (d) 0.5 M Q2.One mole of any substance contains 6.022 x 1023 atoms/molecules. Number of molecules of H2S04 present in 100 mL of 0.02 M H2S04 solution is __________ a)12.044 x 1020 molecules (b) 6.022 x 1023 molecules (c) 1 x 1023 molecules (d) 12.044 x 1023 molecules Q3. For which of the following sets of quantum numbers, an electron will have the highest energy? (a) 3, 2, +1, +1/2 (b) 4, 2, -1, +1/2 (c) 4,1,0, -1/2 (d) 5,0,0, +1/2 Q4. The correct order of increasing energy of atomic orbital is: (a)5p<4f<6s<5d (b) 5p<6s<4f<5d (c)4f<5p<5d<6s (d)5p<5d<4f<6s
Q5.The correct order of first ionization potential among following
elements, Be, B, C, N and O is:- (a) B < Be < C < O < N (b) B < Be < C < N < O (c) Be < B < C < N < O (d) Be < B < C < O < N Q6.The correct order of radii is :- (a) N< Be< B (b) ) F–<O2- N2- (c)Ni<Li<K (d)Fe3+<Fe<Fe2+ Q7.According to VSEPR theory, the shape of a molecule with the formula AB₃E (where E represents a lone pair of electrons) is:- (a)Trigonal planar (b)Tetrahedral (c)Trigonal pyramidal (d)Bent Q8. Find out whether the following reaction is spontaneous or not at 127 degrees centigrade? N2(g) + 3H2(g) ⇌ 2NH3(g); ΔH = 92.22 kJ/mol and ΔS = -198.75 J/K-mol. (a) it is spontaneous (b) it is not spontaneous (c) it may be spontaneous (d) cannot predict Q9.The concentration of hydrogen ion in a sample of soft drink is 3.8 × 10-3M. what is its pH? a) 1.37 b) 2.42 c) 3.34 d)4.56
Q10. Calculate the degree of hydrolysis of a mixture of containing 0.1N
NH4OH and 0.1N HCN. If Ka=10-5 and Kb=10-5 . a) 105 b) 102 c) 10-5 d) 10-2 Q11 TO Q19 CARRY TWO(2) MARKS EACH:- Q11. Solubility of PbSO4 in water at 296K is 0.038 g/lit. Calculate its solubility product constant, (PbSO4 = 303) Q12. Calculate the degree of ionization for an acetic acid solution where the concentration of acetic acid is 0.1 M and the concentration of H+ ions is 0.001 M. Q13.Derive the work done in an isothermally reversible process. Q14. Derive the relationship between ΔH and ΔU for an ideal gas. Explain each term Involved in the equation. Q15.Calculate the number of kj of heat necessary to raise the temperature of 60 g of aluminium from 35°C to 55°C.Molar heat capacity of Al is 24 J mol-1 K-1. Q16.Using the VSEPR theory identifies the type of hybridisation and draw the structure of OF2. Q17. Describe the hybridisation in case of PCl5. Why are the axial bonds longer as compared to equatorial bonds? Q18. Using the molecular orbital theory, compare the bond energy and magnetic character of O2+ and O2- species. Q19.State Hund’s rule of maximum multiplicity.
Q20 TO Q23 CARRY THREE(3) MARKS EACH:-
Q20. A welding fuel gas contains carbon and hydrogen only. Burning a small sample of it in oxygen gives 3.38 g carbon dioxide, 0.690 g of water and no other products. A volume of 10.0 L (measured at STP) of this welding gas is found to weigh 11.6 g. Calculate (i) empirical formula, (ii) molar mass of the gas, and (iii) molecular formula.
Q21. For the reaction PCl5↔PCl3+Cl2 at 473K the value of equilibrium
constant Kc is 8.3 x10-3 . (i) Write an expression for Kc (ii)What is the value of Kc for reverse reaction at same temperature. (iii) What would be effect on Kc if pressure is increased.
Q22. Give reasons:-
(a)Size of cation is always smaller than the parent atom. (b)Ionization enthalpy of nitrogen is greater than that of oxygen. (c)Electron gain enthalpies of beryllium and magnesium are positive Q23.The enthalpy of combustion of methane, graphite and dihydrogen at 298 K are -890.3 KJ mol-1,– 393.5 KJ mol-1 and – 285.8 KJmol-1 respectively. Enthalpy of formation of CH4 (g) will be ?