ASCEND (2025) 11th

JEE Main
Code [B]

DURATION : 180 Minutes DATE : 06/02/2025 M.MARKS : 300

ANSWER KEY
PHYSICS CHEMISTRY MATHEMATICS
1. (3) 26. (2) 51. (3)
2. (3) 27. (2) 52. (2)
3. (3) 28. (3) 53. (1)
4. (2) 29. (3) 54. (4)
5. (2) 30. (4) 55. (3)
6. (2) 31. (3) 56. (2)
7. (3) 32. (2) 57. (4)
8. (2) 33. (2) 58. (2)
9. (3) 34. (1) 59. (3)
10. (3) 35. (2) 60. (4)
11. (3) 36. (1) 61. (2)
12. (2) 37. (4) 62. (3)
13. (2) 38. (2) 63. (2)
14. (4) 39. (2) 64. (4)
15. (3) 40. (1) 65. (1)
16. (1) 41. (4) 66. (3)
17. (3) 42. (2) 67. (3)
18. (4) 43. (3) 68. (3)
19. (3) 44. (3) 69. (3)
20. (4) 45. (2) 70. (3)
21. (4) 46. (33) 71. (25)
22. (50) 47. (72) 72. (4)
23. (10) 48. (32) 73. (576)
24. (10) 49. (18) 74. (3)
25. (6) 50. (75) 75. (9)

[1]
 SECTION-I (PHYSICS)
1. (3) 5. (2)

rmin =
( v cos  ) 2
r3
(A) Time period, T = 2
g GM
2
 v cos   4  a3
2   Since M =   R 3  ; T 
sin  
=
v' r
r= = min 3  R 3
g cos  g sin  sin 3 
GMm
(B) Force, F =
r2
2. (3)
Conserving energy between the surface and height R 3 m
Therefore, F 
R above the surface, a2
2
1 2 GMm 1  v  GMm (C), (D) Kinetic energy, K =
GMm
mv − = m  −
2 R 2 4 2R 2r
GMm
 v=
16GM Total energy, T .E. = −
15R 2r
Let the maximum height above the surface that Therefore, both K and T.E. are proportional to
the object reaches be h R 3 m
Then, conserving energy between the surface and a
the maximum height,
1 2 GMm GMm 6. (2)
mv − =−
2 R R+h
2u 2 sin  cos 
8GM GM GM R= = 38.4 m
 − =− g
15 R R R+h
2u sin 
8R T= = 2.4 s
 h= g
7
man has to travel 38.4 – 7.2 = 31.2 m in 2.4 s
3. (3) 31.2
so vman = = 13 m/s
2.4

7. (3)
 R 
vB = 2 ( a0 )   = a0 R
 2 
vB2
aC = = a0 
F cos37° – T cos53° = 5a R
 a = 1.2 m/s2
( a0 ) + ( a0 )
2 2
aB = aT2 + aC2 =
4. (2)
aB = a0 1 + 2
Conserving energy between the initial and final
instants,
K + mgH = 2K  mgH = K 8. (2)
Let the kinetic energy of the particle when it is at Velocity: v = at
a height h above the ground be denoted by K (h) Power: P = Fv = (ma) (at)
Now, conserving energy between the initial Therefore, the instantaneous power is proportional
instant and the instant when the particle is at a to t
height h above the ground, 1
Distance: s = at 2
K + mgH = K(h) + mgh  K(h) = K + mgH – mgh 2
 h   h Since the distance s is proportional to t2, the
= K +K −K  = K 2− 
H   H instantaneous power is proportional to s1/2

[2]
9. (3)
3g − 2 g
a= = 2 m/s 2
5 F – 80 = 20ª
1 F
25 = 0 +  2  t 2 F − 80 = 20  
2  50 
t = 5 sec
3F
= 80
10. (3) 5
Acceleration due to gravity varies with depth d as 400
F= N
 d 3
g ' = g 1 − 
 R 
As the particle falls into the well, d increases so g 16. (1)
decreases

11. (3)
u sin 2
= 2d ….(i)
g
AB = 2R cosθ
h u sin  u 2 sin 2 
= h= …(ii) Acceleration along AB
u sin  g g a = g cosθ
h u = 0 from A to B
= tan 
d
h 17. (3)
 = tan −1  
d 

12. (2) kx – 5 = 4  1.5

[P] = [M0L1T0]x [M1L–3T0]y [ML–2 T–2]z kx = 11
[M1L2T–3] = [My+z Lx–3y–2z T–2z]
3
−2 z = −3, z = 30 − 11 19
2 a= =
6 6
1
y + z = 1, y = − = 3.17 m/s2
2

18. (4)
13. (2)
The system is at rest (Fnet = 0)
T sinθ = mω2 sinθ
For maximum M/m; Limiting friction will be
T cosθ = mg acing on both blocks (at contact surfaces).
μ(T cosθ + Mg)  T sinθ FL + FL = Net pulling force on the whole system
1 2
m tan 
 μmg + μMg cosθ = Mg sinθ
m+M
Mg (sin θ – μ cosθ) = μmg

14. (4)
( ) ( ) (
A B  A = B A A − A B  A )
A  ( B  A) A ( B  A)
B= +
A A A A
M 
=
m ( sin  −  cos  )
15. (3)
19. (3)
F
a= , fL = (0.4) (200) = 80 N Average method:
50
d
Time to cross the river =
u
[3]
 v0 d vd 23. (10)
Drift = 2 = 0
2 2u 2u mg = N = 100 g
2
Alter: mvmax
N =
Speed of river from bank to mid stream R
2
v0 2v0 x mvmax
v= x= mg =
d /2 d R
d /2 2
dx 2v0 x vmax
 d ( drift ) = 2  u

d
5=
20
0
vmax = 10 m/s
v0 d
drift =
2u 24. (10)
srel = 5 m
20. (4) 2u y u y
T= =
I 0 g 5
L = I 00 =  2I0 = I
2 40  v1 + 40v2 = 80  8
1  1 v1 + v2 = 16 m/s  v2 = 16 – v1
 2  m0 r 2  = m0 r 2 + ( t ) r 2
2  2 5 25 25
v1 − 8 = =  v1 = 8 +
m0 T uy uy
 t=
2 50
v1 − v2 = vrel x = 2v1 − 16 = 16 + − 16
uy
21. (4) vrel y = uy
Moment of inertia of the cylinder about the
502
central axis, vrel = + u 2y
u 2y
1 1
I = mR 2 = (12.5 )( 0.2 ) = 0.25 kg-m 2
2
For vrel min,
2 2
d 502
Now,  = I  = I 2u y − 2 = 0
dt u 3y

1
10
1 u 4y = 502
 = 
I 0
dt = (Area under torque-time
I
u y = 50 = 5 2
1 1 
graph) =  ( 0.2 )(10 )  = 4 rad/s vrel = 50 + 50 = 10 m/s
0.25  2 

25. (6)
22. (50) Solve in the reference frame fixed to the wall.
1 2 3 1 Before collision, velocity of ball = 3v
y= gt , vx =  gt 2
2 8 2 towards it.
when particle strikes to ground  After elastic collision of ball = 3v away from
v y = 2 gH = 40 m/s it
2h
2H Time of flight =
Time of flight = = 4s g
g
 Distance between wall and ball
3g 2 2h
vx = t = 3v. = 6 m.
16 g
At t = 4s (Here no pseudo force is applied since the wall
vx = 3g = 30 m/s keeps on moving with constant velocity w.r.t
v = vx2 + v 2y ground, it being very heavy.)

v = 50 m/s

[4]
 SECTION-II (CHEMISTRY)
 n = 0.3  0.5 = 0.15
26. (2) NO3−
( required )
AgCl(s) + 2NH3 (aq)  Ag(NH3)2Cl
Moles of NO3− obtained from KNO3 = 0.1
K = Ksp  Kf = 10–4
Moles of NO3− required from Ba(NO3)2 – 0.15 –
27. (2) 0.1 = 0.05
KMnO4 will oxidise Fe+2 into Fe+3 (in the acidic [2 mol of NO3− is obtained from 1 mol of
medium)
Ba(NO3)2]
meq of KMnO4 = meq of Fe2+
Moles of Ba ( NO3 )2 =
0.05
M  5  0.01 = (0.01  1) 
2
1
Molarity of KMnO4 = = 0.20 M Weight of Ba ( NO3 )2 =
0.05
 261 = 6.5g
5 2

28. (3) 32. (2)

Order of i.E. C > B > Si > Al
1 KE 2 1 1
 = = or
KE KE1 2 0.991
29. (3)
KE1
Due to resonance the bond order is greater than 1  KE 2 = = 1.02KE1
in case of graphite. ( 0.99 )2
Diamond has higher thermal conductivity than KE 2 − KE1
graphite. % change in KE = 100  2%
KE1
Density of graphite = 2.26 g/cc
Density of diamond = 3.53 g/cc
33. (2)
BF3 = sp2 hybridised
30. (4)
NF3 = sp3 hybridized
% s character is more in hybrid orbital of BF3
+3 −1  +6 +7 −1
Cr I3 + Cl2 + KOH → K 2 CrO4 + KI O4 + K Cl+ H 2 O than NH3
( nf =27 ) ( nf =2)
34. (1)
2CrI3 + 27Cl2 + 64KOH → 2K 2CrO4 + 6KIO4 All given species have 14 electrons.
+54KCl + 32H3O
35. (2)
54 mole electrons are exchanged for 32 mole of
H2O NH4Cl → salt of S.A/W.B (pH < 7)
 moles of electron exchanged for each mole Na2CO3 → salt of W. A/S. B (pH > 7)
54 27 K2SO4 → salt of S.A./S.B (pH = 7)
of H 2 O = =
32 16
36. (1)
n
31. (3) As K p = K c ( RT ) for the reaction

Moles of KNO3 = moles of NO3− =

10.1
= 0.1 2NOCl ( g ) 2NO ( g ) + Cl 2 ( g )
101
n = +1, thus Kp = Kc  RT
Density of H2O = 1 g mL–1
Weight of H2O = 500 mL  1 = 500 g = 0.5 kg
Kp 3.5  10−3
 Kc = = = 1.42  10−4
n RT 0.0821  300
Moles of NO3− NO3−
m = =
NO3− Weight of solvent (H 2 O) in kg 0.5 kg
37. (4)
n
NO3− CCl4(g) → C(g) + 4Cl(g) (Reaction-1)
 0.3 =
0.5 kg r H = f HoCl( g ) − f HCCl
o
(Equation-1)
4 (g)

[5]
 f HoC( g ) = standard molar enthalpy of 42. (2)
z2
atomization of graphite = 720 kJ/mole E = −13.6 ev / atom
1 n2
 f H oCl( g ) = (Standard molar enthalpy of
2 On increasing value of n, E increases but energy
atomization of Cl2(g)) difference between successive energy levels
1
= ( 240 ) = 120 kJ / mole decreases.
2
As CCl4 ( ) → CCl4 ( g ) ,  vap HoCCl4 ( ) 43. (3)
(I) (Fluorine), (II) (Oxygen), (III) (Chlorine),
 vap HoCCl ( ) = f HCCl
o
− f HCCl
o
4 4 (g ) 4( ) (IV) (Phosphorus)
Equation-2 Chlorine has highest value of 1st electron gain
30 = f HoCCl ( g ) −  −130 enthalpy (magnitude)
4

f HoCCl ( g ) = −100 kJ / mole

4
44. (3)
 For reaction-1
(1) Energy of ground state of He+
rH = 720 + 4[120] – [–100]
= 720 + 480 + 100 = 720 + 580 = 1300 kJ = –13.6  22 = –54.4 eV (S)
(2) Potential energy of 1 orbit of H-atom
38. (2) = –27.2  12 = –27.2 eV (Q)
p → q (Isochoric heating) (3) Kinetic energy of II excited state of He+
q → r (Isobaric heating)
22
r → s (Isochoric cooling) = 13.6  = 6.04 eV (P)
s → p (isobaric cooling) 32
(4) Ionisation potential of He+
39. (2) = 13.6  22 = 54.4 V
For N2O4  N2 + 2O2
1 1000 45. (2)
Kp = −2 −1
= = 200 atm
5  10  10 5
SO24− : Central atom sp3-hybridised hence

40. (1) tetrahedral.

( NH 4 )2 CO3 ( s ) 2NH3 ( g ) + H 2 O ( g ) + CO 2 ( g ) NF3: N–sp3-hybridised with one lone pair hence
Initially 0.2atm pyramidal.
At equil. ( 0.2 + 2P ) atm P atm P atm
ICl3: I–sp3d-hybridised with two lone pair hence
T-shaped.
 Total pressure of the gases at equilibrium XeF4: Xe-sp3d2–hybridised with two lone pairs
= (0.2 + 4p) = 1 hence square planar.
 4P = 0.8 or P = 0.2 atm
As Kp = (0.2 + 2P)2 (P) (P) = (0.36) (0.04) 46. (33)
1.44  10–2

41. (4)
SnO 2 + 2H 2 → Sn + 2H 2O
2gm 
2 4
mol mol
151 151

4
 22.4lit.
151
= 0.593 lit. 47. (72)
2 mol of Ag+ ions are present in 1 mole of Ag2S

[6]
 Moles of Ag2S formed 2Cr +3 + 2Fe+3 + 4CO2 + 7H2O
g 1.24 1.24
= = = = 0.005  n1 = 1, n2 = 2, n3 = 2, n4 = 2, n5 = 4, n6 = 7
M 0 (108  2 ) + 32 248
And (n1 + n2 + n3 + n4 + n5 + n6) = 18
So mol of Ag+ ions that must have been present =
0.01 mol
50. (75)
Mass of 0.01 mol Ag+ ions = 0.01  108 = 1.08 g
At end point we will obtain an aqueous solution
Mass of Silver
% of silver in the ore = 100 of KH2PO2
Mass of Ore
By the reaction
1.08 H3PO 2 + KOH → KH 2 PO 2 + H 2O
=  100 = 72%
1.5 ( Monoprotic )
10  1 / 5 1
Here  KH 2 PO 2  = = = 0.1
48. (32) (10 + 10 ) 10
QP 300
CP = = = 40J/mole-K 1
nT 3  2.5 pH = 7 + pka + log  H 2 PO 2−  
2    salt 
As CP – CV = R (for ideal gases)
1
 CV = CP – R = 40 – 8.3 = 31.7 J/mole-K =7+  2 − 1 = 7 + 0.5 = 7.5
2

49. (18)
14H + + Cr2O7−2 + 2FeC2O4 →

SECTION-III (MATHEMATICS)
51. (3) y + 3 = 0 (Rejected)
5
C3  3!  5! = 10  6  120 = 7200 3y −1 = 0

52. (2) 55. (3)

tanA tanC = 3 and tanB tanC = 6
Distance = (1 + 1)2 + ( 2 + 4 )2 cotA·cotB + cotB·cotC + cotC·cotA = 1
= 4 + 36 = = 2 10  cotA·cotB + + = 1
1 1
6 3
 tanA·tanB = 2
Let tanA = 
tanB = 2
tan A 1
=
tan B 2
3
53. (1) tan C =

1
e = , a = 14  tanA + tanB + tanC = tanA tanB tanC
2 3
 b2 = a2(1 – e2)  + 2 + = 6

 b=7 3 3
  2 
2b 2 
Area of the rectangle = 2ae × 3 3
a  3 + = 6  = 3
= 294 sq. units  
  =1
54. (4) tan A = 1, tan B = 2, tan C = 3
x2
x2 = 8 y + y2 = 1 56. (2)
 )
3
8y
+ y2 = 1
(
X = 0,9,. 4n − 3n − 1
3 Y = {0,9,..9(n − 1)}
3y2 + 8 y − 3 = 0
[7]
 Now 4n − 3n − 1 = (3 + 1)n − 3n − 1 As b  c and d  c

= 3n + n  3n−1 +. + n C2  9 63. (2)

Is a multiple of 9. Point in second quadrant with given constraint is
Also Y consists of all multiples of ‘9’ from 0, 9,
(–, 2),  > 0
….
This satisfies both the lines.
Hence, all values of X are subset of values of Y.
Thus X  Y = Y c
 −6a + 4a + c = 0   =
2a
57. (4) d
and − 5 b + 6 b + d = 0   = −
 cos 2 x cos 2 x sin x b
[ H int : put = x, T1 = =
28 sin 3 x sin 3 x sin x c d
 = −  bc + 2ad = 0
1  sin 3 x − sin x  2a b
= 
2  sin 3x sin x 
1 64. (4)
= [cosec x − cosec3 x]
2 −2 + 5 / 2
mop = = −1
1− 3 / 2
58. (2)
−2  ,   2
−b
 f (−2)  0, f (2)  0, D  0,  [ −2, 2]
2a

59. (3)
Let number a – d , a, a + d
Given a – d + a + a + d = 18  a = 6  equation of the chord AB
9 y + 2 = 1( x − 1)
New numbers 6 − d + 6,6 + ,6 + d + 3
2 x − y −3= 0
2
 9
 6 +  = (12 − d )(9 + d )
 2 65. (1)
441
= 108 + 3d − d 2
4
 4d 2 − 12d + 9 = 0
3
 (2d − 3) 2 = 0  d =
2
9 15
Numbers : , 6, Focus is (0, 4)
2 2
2 2 2a = 2  a = 1
9  15  225
Sum of squares   + (6)2 +   = Possible coordinates of vertex are (–1, 4) & (1, 4)
2 2 2
60. (4) x12 + x22 + y12 + y22 = 34

( )
6
 10 C0 +10 C1 x 2 +10 C2 x 4 +  1 − x 2
  66. (3)
  10
C0 + C1x + C2 x +
10 2 10 4 We have,
  log 49 7 + log 25 5 − log 4 2
1 − C1x + C2 x 
6 2 6 4
  log17.5
10 C0 6 C2 −10 C1 6 C1 +10 C2  75/2  55/2 
log  
 15 − 60 + 45 = 0  25/2
=   = 5 log17.5 = 5
61. (2) log17.5 2 log17.5 2
A1 =35 C0 45 C1 −35 C1 45 C0 = 10
A2 =35 C045C2 −35 C1 45 C1 +35 C2 45 C0 67. (3)
[x – 2]2 + y2] = (x + y + 1)2
= 10 = A1
62. (3) ( x − 2) 2 + y 2
 =2=e
9 x + y +1
Required number =  (10 − c)(9 − c) = 330 2
c=0

[8]
68. (3) 1

x+ = 1,3
1 2  sin19 x
S= −
cos11 cos19 cos19 1
(1) x + = 3  x 2 − 3 x + 1 = 0

=
1 − 2sin19 cos11
=
(
1 − sin 30 + sin 8 ) 3 5
x


cos11 cos19 
cos11 cos19   x=
2
(1 / 2) − sin 8 sin 30 − sin 8 1
= = (2) x + = 1 (rejected)
cos11 cos19 cos11 cos19 x
2cos19 sin11 3+ 5 3− 5
=  
= 2 tan11 Real roots are 1, ,
cos11 cos19 2 2

69. (3) 73. (576)

x + 2 x cosec  + 1 = 0
2 2x + y < 50
if y = 1  x {1,2,.,24}
x = − cosec   cosec2  − 1
if y = 2  x {1,2,.,23}
= − cosec  + cot , − cosec  − cot 
if y = 3  x {1,2,.,23}
  
for   − , −  if y = 4  x {1,2,.,22}
 4 6
 1 = − cosec  + cot , 1 = − cosec  − cot  if y = 5  x {1,2,.,22}
if y = 6  x {1,2,.,21}
x 2 + 2 x cot  − 1 = 0
 x = − cot  + cosec , − cot  − cosec  
 2 = − cot  − cosec , 2 = − cot  + cosec  
 1 + 2 = 0
if y = 46  x {1}
70. (3) if y = 47  x {1}
a = 1, a + d = log y x, a + 2d = log z y Total integral point 2[1+2+3+…. + 23] + 24
23  24
a + 3d = −15log x z = 2 + 24 = 576
2
 (1 + d )(1 + 2d )(1 + 3d ) = −15
 6d 3 + 11d 2 + 6d + 16 = 0  d = −2 74. (3)
25
S25 = [2(1) + (24)(−2)] = 25(1 − 24) = −575 r = 16 + 4 + 5
2
r=5
71. (25)

( )
31
(1 − x)30 1 + x + x 2

= (1 − x3 ) (1 + x + x 2 )
30

Coefficient of x17 In (1 − x ) (1 + x + x ) 3 30 2
centre C(4,2)
15
= Coeff. Of x in (1 – x3)30 AC = 25 + 144 = 13
= –30C5 = –30C25
(PA) = AC – r
72. (4) ( x + 1)2 + ( y + 10)2 = 13 – 5
Sum of the coefficients = 0
 One roots is 1 ( x + 1)2 + ( y + 10)2 = 64
x5 − 5 x 4 + 9 x3 − 9 x 2 + 5 x − 1 = 0 x2 + 2 x + 1 + y 2 + 100 + 20 y = 64
(
( x –1) x4 − 4 x3 + 5 x 2 − 4 x + 1 = 0 ) x2 + y 2 + 2 x + 20 y + 40 = 3
4 1 75. (9)
x2 − 4 x + 5 − + =0
x x2 Case I: When 9, 9, 9 are used
2 9
 1  1
 x +  − 2 − 4 x +  + 5 = 0
 x   x

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 4! 4!
Total number = 9 C2  = 432 Total number = 9 C2  = 288
2! 3!
Case II: When 3 identical digit is different from So, N= 720
9
9

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