MASTER CLASS ACADEMY

Bull temple road,Basavanagudi

Bangalore-04
I PUC-QUESTION BANK Sub: Chemistry
I. ONE MARKS questions:
1.. Name any one gas responsible for green house effect.
2. What is the change in entropy when ice melts to give water.
3. State modern periodic law/Mendeleevs periodic law.
4. Arrange the repulsive interaction between electron pairs(lp-lp,bp-bp,lp-bp)
5. What happens to the oxidation number of element during oxidation.
6.. What is Green Chemistry?
7. Give the chemical formula of washing soda/plaster of paris/gypsum
8. Write the general electronic configuration of S-block elements/p-block elements/d-block elements
9. What is catenation?
10. Diamond is a bad conductor of electricity but Graphite is good conductor.Justify.
11. Write the IUPAC name of CH3-CH2-CH2-CH-COOH
CH3
12. Name the element estimated by Kjeldahals’ method/carius method/liebigs method.
13. Name the reagent used in the decarboxylation/what is lindlars catalyst?
14. What is Smog?metion its types.
15. What is Global warming?
16. What is acid rain?
17. What is the S.I unit of Temperature/amount of substance/density/luminous intensity.
18. Which allotropic form of Carbon is more stable. Ans:Graphite
19. Write the IUPAC name of the element of atomic number 108.
20. Define Dipole moment. Mention its SI unit.
21. What is the oxidation number of oxygen in peroxides &super oxides.
22. What is Water gas shift reaction/Coal gasification.
23. Give the chemical formula of plaster of paris.
24. Sodium metal is preserved under Kerosine.Give reason.
25. Give the composition of Borax.How it is prepared.
26. Write the molecular formula of inorganic benzene.
27. Name the first organic compound prepared in laboratory from inorganic compound by F.Wholer.
28. Suggest a suitaible method to separate Sugar & Salt from an Aqueous solution containing them.
29. Name the product formed When ethyne gas is passed through red hot iron tube.

II. TWO Marks questions

32. State Aufbau principle/Paulis exclision principle/Avagadro law.
33. What is the value ΔG, ΔS for Spantaneous reactions.
34. How does ionization enthalpy/Electron affinity/ionization energy varies along a period & a group in a
periodic table.
35. Show that BeF2 molecule has zero dipole moment.
36. Write any two limitations of Octet rule.
37. Define oxidation & reduction.by using Lewis concept/Lowry-bronsted theory/Arhenius theory.
38. Explain the anomalous behaviour of Carbon/Boron. Give reason.
39. What are heterolytic fission/Homolytic fission?Give an example.
40. Explain Aromatisation with an example.
41. How ozone is formed in the atmosphere?
42. State Heisenbergs uncertainity principle.Give its mathematical form.
43. What is an extensive property/intensive property ? Give an example.
44. What is isolated system/open system/closed system/isothermal process/adiabatic process.
45. Define electronegativity.Which is the most electronegative element in the periodic table.
46. Write any two differences between sigma & pi bond.
47. Write any two differences between BMO & ABMO.
48. What is Hydrogen bonding?Give an example for a molecule having intramolecular hydrogen
bonding.
49. Calculate the oxidation number Underlined elements in the given compounds a)H2SO4 b)K2Cr2O7
50. Give any two anamolous behaviour of Boron.
51. How nitrogen is detected by lassaigne’s test.
52. How ethane is prepared from Wurtz reaction.
53. What is BOD? Give its significance.

III. THREE MARKS & FIVE MARKS questions:

54. What is electron affinity?How it varies along a period & Group.
55. Write any three postulates of Molecular orbital theory
56. What is electro negativity? Ionisation enthalpy of oxygen is less than that of nitrogen. Why?
57. Write any three postulates of VSEPR theory.
58. For O2 molecule a) Write electronic configuration
b)Calculate its bond order c)state its magnetic property.
59. Explain SP hybridisation by taking Suitaible example.
60. Balance the Redox reaction using half reaction method.
Cr2O7-2 ( aq) + Fe+2 (aq) ↔ Cr3+ + Fe+3 (in acidic medium)
61. Explain the process of softening of temporary hardness by clarks method.
62. Mention the similarities between Lithium & Magnesium .
63. How is sodium carbonate manufactured by solvays process.
64. a)How is ortho boric acid prepared from borax.
b)What are silicones?
65. a) Write any two differences between Diamond & Graphite.
b) Mention the number of six membered rings present in fullerene. (2+1)
66. a) 25kg of N2(g) &5kg of H2(g) are mixed to produce ammonia.Which is the limiting reagent.How
much ammonia is formed?
b)Define molarity.
67. a) Calculate the molar mass of Glucose(C6H12O6)
b)Calculate the percentage of C & H in ethyl alcohol(C2H5OH)
c)What is amu?
68. a) Write any three postulates of Bohrs atomic theory?
b) Write Debroglie matter wave equation & Explain the terms.
69. a) Write any two differences between orbit & orbital.
b) State Hunds rule.
c)Among 2p & 3s which orbital having more energy ?
d)in which region Paschen series appears in Hydrogen Spectrum.
70. a) Write vanderwalls equation for n moles of a gas.
b)Two gas A & B have critical temperature of 250K &125K respectively .Which one of these can be
liquefied easily.
71. a)State Daltons law of partial pressure ,How partial pressure related to mole fraction.
b)Define Suface tension?Write the SI unit of surface tension.
72. a) State Hess’s law of constatnt heat summation.
b) Describe the measurement of ΔU by bomb calorimeter.
73. a) What is reversible process? Give an example.
b) Calculate the standard enthalpy of formation of liquid benzene (C 6H6). Given the enthalpies of
combustion of carbon(s),hydrogen(g)and benzene(l) are -393.5kJ, -285.83kJand-3267.0kJ resp.
74. a)Write any three characterstics of equilibrium constant.
b) Using Le-Chatelier’s principle explain the effect of temperature,pressure on equilibrium for the
following reaction
N2 (g) +3H2(g) ⇌ 2NH3 (g) ΔH=−ve
75. a)Write the conjugate base of HSO4-
b)For a reversible reaction PCl3 (g)+ Cl2 (g)------→ PCl5 (g) Kc is 3.0 at 270oCfind the value of Kp.
c)What is Buffer solution?
76. a) Define acid & base by Arrhenius concept.
b)Write the expression for equilibrium constant Kc for the reaction aA+Bb--→cC+dD.if the
equilibrium constant for the reaction is 50.What is the equilibrium constant for the reverse
reaction
c)Write the value of ionic product of water at 298K. (2+2+1)
77. a) Draw a neat labeled diagram & Give principle involved in the estimation of halogen by Carius
method.
78. a) For the Compound CH2=CH-CH2-CH2-CH3
i)bond line formula of the compound.
ii)Identify the number of sigma &pi bonds
b) What is Homologus series.Mention any two characterstics of it. (3+2)
79. a)Explain the free radical mechanism of chlorination of methane.
b)What is carcinogen.
c)How do you convert Benzene to benzene hexachloride.
80. a) What is the action of propene with HBr.Write its equation.
b)What is Ozonolysis?Explain with equation.
81. c)What is Bayers reagent?
82. For C2 molecule
a) Write electronic configuration
b)Calculate its bond order
c)state its magnetic property.
83. Explain SP3 hybridisation by taking Methane as an example.
84. Balance the Redox reaction using oxidation number method
MnO4- ( aq) + Fe+2 (aq) ↔ Mn2+ + Fe+2 (in acidic medium)
85. a)Which isotope of hydrogen is radioactive?
b)Write the composition of Water gas?
c)What is meant by 100 volume of H2O2?
86. How is sodium hydroxide prepared by Kastner kellner cell.
87. Explain the diagonal relationship between Berylium & Alluminium.
88. a)Write the structure of diborane & explain the nature of bonding in it.
89. a) What are zeolites?Give an example.
b) what is Dry ice?
90. a) An Unknown compound was found to contain 43,4% sodium,11.3%carbon &45.3% oxygen.the
molar massof the compound is 110g/mol.find out its empirical formula &molecular formula(at.mass of
Na=23,C=12,O=16)
b)How many significant figures are present in 20.0
91. a) Write the postulates of Daltons atomic theory.
b)Convert 37oC to oF (3+2)
92. a) Explain the significance of Four Quantum numbers 4
b) Sketch the shape of Px-orbital
93. a) What are the observations made by Rutherford in alpha ray Scattering experiment.
b) Write the electronic configuration of Cr.
c)in which region Paschen series appears in Hydrogen Spectrum.
94. a) what is compressibility factor (Z) ? what is its value for ideal gas? 2
b) On a ship sailing in pacific ocean where temperature is 300K, a balloon is filled with 3L of air, what will
be the volume of the balloon when the ship reaches Indian ocean , where the temperature is 310K. 3
95. a)Write any three postulates of Kinetic theory of gases.
b)Derive the ideal gas equation using gas laws.
96. a) State first law of Thermodynamics and write its mathematical form
b) 5 mol of the ideal gas undergoes a reversible and isothermal expansion from
volume of 5L to 20L at 300K. Calculate the work done by the gas in this
expansion. (Given : R= 8.214 J/K/mol )
97. a) Define Entropy. what is its value for perfect crystalline solid?
b) Calculate the Entahlpy of formation of Methane from the following data.
C(s) +O2 (g) CO2 (g), ΔH=−393.5KJ
H2 (g) + ½ O2 (g) H2 O (l) , ΔH=−285.83 KJ
CH4 (g) +2O2 (g) CO2 (g) +2H2O (l), ΔH=−890KJ
98. a) Write the relationship between Kp and Kc
b) Using Le-Chatelier’s principle explain the effect of temperature on equilibrium for the following
reaction
2NO2 (g) ⇌ N2O4 (g) ΔH=−ve (3+2)
99. a)Write the conjugate acid of OH-
b)Explain Lowry-Bronsted concept of acid & Base.
c)Write the relationship between solubility & solubility product of AB type of salt.
d)What is Homogeneous equlibria?
100. a) Prove that pH +pOH =14
b)Explain the common ion effect with example.
101. a) Write any two differences between inductive effect & Mesomeric effect.
b) Name a method used in Quantitative estimation of carbon, Nitrogen , and halogens.
102. a) What are heterocyclic compounds?Give an example What are Electrophiles /nucleophiles /
carbocation/carbanion?
b) Write a note on position isomerism/chain isomerism functional isomerism with an example
 c) What is the IUPAC name of CH3 –CH-CH2-CH3
CH2-CH2-Cl
103. a)How is Benzene prepared from phenol.
b)State & Explain the Huckels rule of aromaticity with an example.
104. a) Explain the mechanism of nitration of Benzene.
b)Complete the following equation:C6H5COONa + NaOH---------→ + Na2CO3
c)Draw the Newman projection for Staggered conformation of ethane.