Sec: XII_PASS_IR_IIT Date:04-09-2023

Time: 3 Hrs. FTM –04 Max.Marks:300

JEE MAIN 2022 Model
KEY SHEET
PHYSICS
1 2 3 4 5 6 7 8 9 10
A D C D B C D C A C
11 12 13 14 15 16 17 18 19 20

B A D D B A A D C D

21 22 23 24 25 26 27 28 29 30

10 40 16 15 28 3 46 3750 20 8

CHEMISTRY
31 32 33 34 35 36 37 38 39 40
B A C A D A D C C C

41 42 43 44 45 46 47 48 49 50

D C B B B C C A D B

51 52 53 54 55 56 57 58 59 60
8 120 4 4 6 16 70 51 265 4

MATHEMATICS
61 62 63 64 65 66 67 68 69 70

C B D B B D C B B A
71 72 73 74 75 76 77 78 79 80

B B D A C C B B B B

81 82 83 84 85 86 87 88 89 90

4 4 7 2 2 3 0 2 3 2

For More Join: @PREMINUM_SERIES

 XII_PASS_IR_IIT_FTM–04 EX. DT: 04-09-2023
Solutions
1. Net force is towards centre

2F1
Fnet  F2   F2 + 2F1
2

Gm2 Gm2
F2 = =
 2r 
2
4r 2
Gm 2 2Gm 2 mv 2
 Fnet  + =
Gm2 Gm2 4r 2 2r 2 r
F1 = =
 2r 
2
2r 2

v=
Gm
4r
1 2 2  

2. Kinetic energy decreases with increase in radius

while the potential and total energy increases

with increase in radius.

3. Initial total energy = Initial kinetic energy + initial potential energy

1  GMm  GMm
 m  0    
2

2  R0  R0

1  GMm 
Total energy, When it reaches the surface of earth =  mv 2    
2  R 

Applying energy conservation,

1 GMm GMm
mv 2  
2 R R0
1 1 
v = 2GM   
R R0 

2
For More Join: @PREMINUM_SERIES
 XII_PASS_IR_IIT_FTM–04 EX. DT: 04-09-2023
4. For point ‘A’ :

For any point outside, the shells acts as point situated

at centre.

G  M1 +M 2 
So, FA  m
p2

For point ‘B’ :

There will be no force by shell B.

M1m
So, FB = G
q2

For point ‘C’ :

There will be no gravitational field.

So, FC= 0
5.

Keq  K1  K 2

Y2A Y1A Y2 A
 

Y1 + Y2
Y=
2

2 2
6. v= r .  ρ0  ρ w  g
9

7.

2
For More Join: @PREMINUM_SERIES
 XII_PASS_IR_IIT_FTM–04 EX. DT: 04-09-2023

PA has to be equal to PB.

PA ,PB

PA = P0 + ρgh .....(i)
4
Now PC – P0 =  soap bubble has 2 films
r

and PC = PBsame air is filled

4
 P0 + = P0 + ρgh ....(ii)
r
ρghr
Get  =
4
8. WA> WB as mass of water in A is more than in B

PA = PB
Area of A = Area of B

orPA AreaA = PB AreaB

or FA = FB .

9. From continuity equation, velocity at cross-section

(1) is more than that at cross-section (2)

Hence; P1< P2

10. 103 × + 13.5 × 103 × =×1

or  = 3.5 × 103 kg/m3

11.

3
For More Join: @PREMINUM_SERIES
 XII_PASS_IR_IIT_FTM–04 EX. DT: 04-09-2023

When A point travels  distance then B point 2 so,

2 length of string passes through the hand of the boy.

12. a = (g tan ) so net force along the indined plane is zero

so it will continue in pure rolling with constant angular velocity.

1 2 k2   3v 2 
13. From energy conservation mv 1  2   mgh = mg  
2  r   4g 

R
K=
2
 Body is a disc
14. As the inclined plane is smooth, the sphere can never roll rather it will just slip down.

Hence, the angular momentum remains conserved about any point on a line parallel to the inclined
plane and passing through the centre of the ball.
15. Conservation of angular momentum about C.O.M. of m and loop of mass m gives

mVR    R   R 
2 2

  m R  m     m    
2

2    2    2  

V
 V = 3 R   =
3R
16.

For toppling about edge xx’

3a a 2mg
F min.  mg  F min. 
4 2 3
17.

4
For More Join: @PREMINUM_SERIES
 XII_PASS_IR_IIT_FTM–04 EX. DT: 04-09-2023

The block will not topple if mg acts from within the

block. So ,
a b b
cosθ   cosθ 
2 2 a

18. FBD for sphere & block

fr μmg fr μmg
a1 = = a2 = =
m m m m
a1 = μgiˆ a 2 =  μgiˆ

a rel  a1  a 2 = 2μgiˆ

a rel  2μg.
19. Using Energy conservation,

(AT MAXIMUM DISTNCE V = 0 V0 = 0)

1 2
Kx =  mg × sin θ 
2
 2mg sin θ 
x = 
 2 
20. There is no relative motion between sphere and plank so

friction force is zero then no any change in motion of sphere and plank.

5
For More Join: @PREMINUM_SERIES
 XII_PASS_IR_IIT_FTM–04 EX. DT: 04-09-2023
21. Speed of particle at A, VA= escape velocity on

2GM
the surface of moon =
R

At highest point B, VB= 0

From energy conservation.

1 U U 
mVA2 = m  VB -VA  = m  B - A 
2  m m 

VA2  U B U A 
   ,also 3R  r 
2 2
or
2  m m 

GM GM  GM  R  
2 2
 1 -1 3 1  99  1
   1.5R  0.5  R 
2
  or     
R R+h  R 3   100    R R+h 2R 2  100  R

100    99 
2 2

h= R
100    99 
2 2

19801
h= R
199

or h = 99.5R  99R

3/2
T1  r1 
22.  
T2  r2 

T
  4
3/2
or or T = 40 hr.
5

AY 4AY
23. K , K' =  8K
/2

1
 8K   2
U 2
  U = 16 J
2 1
K 2

ΔV 5
24. F= ηA where F = mgsinθ = 130 
ΔZ 13

5 0.5
130   η 11
13 0.15  102

50  0.15 102
η  0.15
0.5

6
For More Join: @PREMINUM_SERIES
 XII_PASS_IR_IIT_FTM–04 EX. DT: 04-09-2023
2 2
25.  ρhg =  h=
r ρrg

N
2  70  103 
 m  0.28 m.
kg  0.1  3
1000 3    10 10
m  2 

26. mg = 60 ………………(i)

mg  ρi Vg = 40 ……………….(ii)

mg  ρ Vg 2 ρ0
 or 3
mg 3 ρ

ρ0 ρ
Where = density of the block and = density of

the liquid.

27.

πR 2dh/dt = πr 2 v ………(i)

v = 2gh
……….(ii)

from equation (ii) put the value of v in equation (i)

πR 2dh/dt = πr 2 2gh

R 2dh
  r 2 2gh   dt
0 T
R2 dh
r 2 2g 
h h 0
 dt

R2 2h
T=
r2 g

On solving t = 46.26 second.

7
For More Join: @PREMINUM_SERIES
 XII_PASS_IR_IIT_FTM–04 EX. DT: 04-09-2023
m1g m 2g
28. 
A1 A2

Solving m2 = 3.75 kg.

29. 20 = Vcm + wR

  ω
20  10  ω  10   ω = 20 / se 
2 2
30. Let velocity of c.m. of sphere be v. The velocity of

the plank = 2v.

1
 m   2v   2mv2
2
Kinetic energy of plank =
2

Kinetic energy of cylinder

1 1 1 
= mv 2    mR 2 ω2 
2 2 2 

1  1 3 1
 mv 2  1    . mv
2

2  2 2 2

K.E of plank 2mv 2 8

  
K.E of sphere 3 mv 2 3
4

31. B
N 2O4 2NO 2
1  2
If  is degree of dissociation of N2O4 and P is the total equilibrium pressure then total moles =

2
1    2  1   then partial pressure of PNO2  P
1   

8
For More Join: @PREMINUM_SERIES
 XII_PASS_IR_IIT_FTM–04 EX. DT: 04-09-2023

32. A

d = 4.24 g/L.
33. C
Le Chatelier's principle
34. A
According to Le Chatelier's Principle, if a system in equilibrium is subjected to a change of
concentration, pressure or temperature, the equilibrium shifts in the direction that tends to undo the
effect of the change.
When the pressure is applied to the equilibrium system between ice and water, the phase transition
temperature of ice reduces. Thus the equilibrium shifts more to right side. Also, when pressure is
increased the equilibrium shifts in the direction of less volume.
Therefore, more ice will melt into water.
35. D
Ag   NH3 [Ag  NH3 ] ; K1  1.6 103
[Ag  NH3 ]  NH3 [Ag  NH3 2 ] ; K 2 6.8 103

The formation constant of [Ag(NH3)2]+ will be obtained by adding the above 2 reactions.
So, the resultant K will be equal to K1  K 2

9
For More Join: @PREMINUM_SERIES
 XII_PASS_IR_IIT_FTM–04 EX. DT: 04-09-2023
K  K1  K 2
K  1.6 103    6.8 103 
K  1.08 107
36. A
nf for both CH3COOH and NaOH = 1
∴ Normality = Molarilty

initial 0.1 0.1 0 0

equilibrium 0.075 0.075 0.025 0.025

37. D
For the salt A 2 X 3 , the relationship between solubility and solubility product is,

10
For More Join: @PREMINUM_SERIES
 XII_PASS_IR_IIT_FTM–04 EX. DT: 04-09-2023
-3
Substitute s = y mold m in the above expression.
KSP  108y5
38. C
1 1
KSP = Ag    Cl 

Its an rectangular hyperbola

39. C
E 0Mg2 / Mg  2.37V

E 0Fe3 / Fe  0.04V
As reduction potential of Fe3+ is higher that that of Mg2+
in term of oxidation potential
E 0Mg2 / Mg  2.37V

E 0Fe3 / Fe  0.04V
⟹ strong reducing agent reduce other species ⟹ oxidise itself ⟹ should have high oxidation
potential. As Mg has high oidation potential than Fe.
∴ Mg will act as strong reducing agent.
40. C

41. D
Applying △G = − nFE

42. C

11
For More Join: @PREMINUM_SERIES
 XII_PASS_IR_IIT_FTM–04 EX. DT: 04-09-2023

43. B

44. B
A → C; ΔS = 50; C → D; ΔS = 30;
D → B; ΔS = − 20
For A → B; ΔS = 50 + 30 – 20 = 60
45. B
ΔG0 = ΔH0 – T ΔS0 = −54.07 × 1000 – 298 × 10
= − 54070 – 2980 = −57050
ΔG0 = −2.303RT log10K
− 57050 = −2.303 × 298 × 8.314 log10 K = −5705 log10K
log10 K = 10
46. C
Work done against constant external pressure = Pext(V2 − V1)
In adiabatic condition Δq = 0
therefore w = Δu

12
For More Join: @PREMINUM_SERIES
 XII_PASS_IR_IIT_FTM–04 EX. DT: 04-09-2023
[Expansion work is negative]

47. C
Given: (2 atm, 3.0 L ,95 K)→(4 atm, 5.0 L ,245 K)
Therefore, P1 = 2atm, P2 = 4atm
V1 = 3L, V2 = 5L
T1 = 95K T2 = 245K
ΔU = 30L.atm
As we know that,
ΔH = ΔU + (P2V2 − P1V1)
∴ ΔH = 30 + (4 × 5 – 2 × 3)
⇒ ΔH = 30 + 14 = 44 L.atm
48. A
Due to equilibrium between liquid and gaseous state of H2O on 373K, ΔG=0
As the state changes from liquid to gas, the entropy also increases, ∴ ΔS = positive
49. D
H = E + PV
ΔH = ΔE + Δ(PV)
Since, PV = nRT
So, ΔH = ΔE + nRΔT
ΔT = 0 and ΔE = 0
∴ ΔH = 0
Enthalpy change for an ideal gas in an isothermal and reversible process is Zero.
50. B
The standard enthalpy of formation  H 0f  is the enthalpy change during formation of 1 mole of
substance when its constituent elements are in their standard states.
Only (B) follows the definition of H0f .
51. 8

52. 120
0.05 N solution means 0.05 g eq are present in 1000 mL.
1000
Hence, 1g eq will be present in V =  20000mL.
0.05
13
For More Join: @PREMINUM_SERIES
 XII_PASS_IR_IIT_FTM–04 EX. DT: 04-09-2023
1 1.5
The specific conductivity k    6 103 mhocm1
a  R 5  50
The equivalent conductivity is   k  V  6 103 mhocm1  20000cm3 / eq

 120mhocm2 / eq
53. 4
54. 4
Mixture of 2N acetic acid and 1N sodium acetate will act as buffer.

55.
BaSO4  s  Ba 2  aq   SO 24  aq 
At t = 0 1 0 0
At equilibrium in water 1-s s s
At equilibrium in the 1-s s s+0.01
presence of sulphuric acid

The expression for Ksp in the presence of sulphuric acid will be as follows.
Ksp = (S) (S+0.01)_(2)
Since the value of Ksp will not change in the presence of sulphuric acid, therefore from (i) and (ii)

14
For More Join: @PREMINUM_SERIES
 XII_PASS_IR_IIT_FTM–04 EX. DT: 04-09-2023

 6 104 mol dm3

56. 1

n g
n   P  1
2 2 1
 12 
KP  CO     
n CO2  n g  0.5  1.5 
12
Kp   16 atm
1.5  0.5
57. 97
CH3OH(l)+ (3/2)O2(g) → CO2(g) + 2H2O(l)

ΔGf0 CH3OH (l) = -166.2 kJ mol-1

ΔGf0 H2O (l) = -394.4 kJ mol-1

ΔG = ΣΔGf0 products – ΣΔGf0 reactants

= -394.4 -2(237.2) + 166.2

= -702.6 kJ mol-1

15
For More Join: @PREMINUM_SERIES
 XII_PASS_IR_IIT_FTM–04 EX. DT: 04-09-2023
The efficiency of fuel cell = (ΔG / ΔH)×100

= (702.6/726)×100 = 97%

58. 51
The balanced chemical equation for the atomization of phosphine is PH3 ⟶ P + 3H; ΔH = 228
228
ep  H 
3
The balanced chemical equation for the atomization of P2H4(g) is H2P–

The energy of the P − P bond is 51 kcal.

59. 265
60. 4
Extensive  Mole, Volume, Gibbs free energy.
Intensive  Molar mass, Molar heat capacity, Molarity, E  cell.

61. (C)

C1C2  r1  r2 , Hence equation of common tangents x = 2

62. (B)

The given parabola is y 2  4  x  1 ………….(1)

Shifting the origin to (1, 0) by putting x  1  X

And y=Y, we get Y 2  4 X

Its focus is (1, 0) i.,e (2, 0)

Any line through (2, 0) is y  m( x  2) ……….(2)

Putting the value of “y” from (2) in (1)

We get m 2  x  2   4  x  1
2

 m 2 x 2  4  m 2  1 x  4  m 2  1  0

     
2
If m  0 then D  16 m2  1  16 m2  1 m2  16 m2  1  0 (for all m R ) but if m = 0 then ‘x’ does

not have real and distinct value

63. (D)

16
For More Join: @PREMINUM_SERIES
 XII_PASS_IR_IIT_FTM–04 EX. DT: 04-09-2023
Let P(h, k) be the mid-point of the line segement joining the focus (a, 0) and a general point Q(x, y) on the
xa y
parabola. Then h  , k  put the value of x, y in y 2  4ax then k 2  2ah  a 2
2 2

Locus of P(h, k) is y 2  2ax  a 2

a a
directrix  x    x0
2 2
64. (B)

Parametric equation of the parabola y 2  4ax are x  t 2 and y  2t

t2 2t 1
4 1  5  t 2  t  6 
1
Area PXQ  4
2
9 6 1

 1 2 25 
 5  t    
 2  4 

1
For maximum area, t 
2

 25  125
Maximum area = 5  
 4  4

65. (B)

Common chord of the given two circles s = 0 & s '  0 is s  s '  0

 3x  y  2  0 ; vertex (0, 0) given

“Z” is foot of perpendicular of A(0, 0) on the directrix

 3 1   3 1 
Z   ,  . Since A is midpoint of SZ; focus S   , 
5 5   5 5

66. (D)

17
For More Join: @PREMINUM_SERIES
 XII_PASS_IR_IIT_FTM–04 EX. DT: 04-09-2023
 2
1   2
1 
Let P at , 2at1 Q at , 2at1 and R(h, k )

By using section formula, we have

2at1
h  at12 ; k  ,
3

3k  2at1  9k 2  4a 2t12  4a  h 

9k 2  4ah  9k 2  4h

 9 y 2  4 x

67. (C)

S  y2  x  0

S11  0   1  k  0  k  1
2

68. (B)

Since pair of tangents from the directrix to the parabola are always perpendicular to each other

Locus is directrix of parabola x  3  4  0  x  1  0

69. (B)

Centre  h, k    4, 3

a 2  b2 3
e 2

a 2

 Equation of latusrectum x  h  ae  4  6
70. (A)

Given equation of line x  y  2  y  x  2

Slope m  1

x 2 y2
Eq of Hyperbola is  1
5 4

a 2  5, b2  4

Eq of tangent to the hyperbola is y  mx  a 2 m2  b2

 1 x  5  4

y  x 1

 x  y 1  0

18
For More Join: @PREMINUM_SERIES
 XII_PASS_IR_IIT_FTM–04 EX. DT: 04-09-2023
71. (B)
Distance from focus to directrix of a parabola =2a
72. (B)
3
4a 1  t 2  2 
 

Length of normal chord at ‘t’ is , here t = 2

t2
73. (D)
Product of slopes of line joining points to vertex = -1
2 2
.  1
t1 t2

74. (A)

a
Tangent equation is y  mx   m2 x  my  a  0
m

y a
m1  m2  , m1m2 
x x

y ky
tan 1  tan 2   sin 1  2  
x x

ak
Now cos 1  2   k 
x
2 2
 ky   ak 
     k    1  k 2  x  a   y 2   x 2
2

 x  x   

75. (C)
Let (h, k) be the locus of mid point
xh yk h 2 k 2
 T  S1     …..(i)
a 2 b2 a 2 b2
(i) passes through ,  so putting ,  in it
h k h2 k2
   
a 2 b2 a 2 b2
 h 2 h   k 2 k 
  2  2    2  2   0
a a  b b 
2 2
   
h   k   2 2
  2 

2
  0
a2 b2 4a 2 4b 2
2 2
   
 x    y  
 2  2 2 2
required locus is    0
a2 b2 4a 2 4b 2
 
which is a hyperbola with centre  , 
 2 2

76. (C)

19
For More Join: @PREMINUM_SERIES
 XII_PASS_IR_IIT_FTM–04 EX. DT: 04-09-2023

h k 1
 
4 3 7

Gives h  4 / 7 and k  3 / 7

77. (B)
Let eccentric angle be , then equation of tangent is
x y
cos   sin   1 ….(i)
a b
Given equation is
x y
  2 ….(ii)
a b
Comparing (i) and (ii)
1
cos   sin      45o
2
78. (B)
 5x  12 y  1
2 2 2
 1  2
 x     y    a   PS2  e 2 PM2
 13   13   13
Here a  e 2  0  e 1
So 0 < a < 1
79. (B)
1 Standard result
80. (B)
2b 2  q 2  4pr 
Length of LR = and maximum value of px 2  qx  r, p  0 is
a 4p
81. (4)
C1C2  r1  r2 , Hence No. of common tangents = 4
82. (4)

Since both curves are symmetrical about the line y=x

Distance between any pair of points

 
=2( distance of t , t 2  1 on the parabola y  x 2  1 from y  x  0 )

 t2 1 t 
  2  t  t  1
2
2
 2 

3
The minimum value of t 2  t  1 
4

20
For More Join: @PREMINUM_SERIES
 XII_PASS_IR_IIT_FTM–04 EX. DT: 04-09-2023
3 2
Minimum distance is  k 4
4
83. (7)
Let P(4, 0) & Q(0, 3) are two points on given ellipse E1

P1 and Q1 are images of P,Q w.r.to x – y – 2 = 0

 P1(2, 2) Q1 (5, 2) lies on E2

 a  160, b  292
84. (2)
The given point (-a, 2a) lies on the directrix x= –a of the parabola y 2  4ax . Thus, the tangents are at right
angle.
85. (2)
Given parabolas are symmetrical about the line y-x. So slope of tangents must be 1
1 5
 x 2  y  1  m  2 x  1  point of contact   , 
2 4
1 5 1
y2  x 1  m   1  point of contact =  , 
2y 4 2
3 2
So radius =half of diameter =
8
86. (3)
S11  y12  4a 2 
Length of chord of contact  3 5
a
87. (0)
a  a  a 
Equation of tangent is y  mx   B   0,  , A    2 , 0 
m  m  m 
 a a 
Midpoint  x, y    ,   2 y  ax  0
2

 2m 2m 
2

  4a   a / 2
 = 1/8
88. (2)

89. (3)
2y = x + 4

21
For More Join: @PREMINUM_SERIES
 XII_PASS_IR_IIT_FTM–04 EX. DT: 04-09-2023
x 1
y 2  m
2 2
y  mx  a m  b
2 2 2

2   4m 2  b 2  b2  3
90. (2)

22
For More Join: @PREMINUM_SERIES