THICK BLEACH

Safety Data Sheet

according to Regulation (EC) No. 1907/2006 (REACH) with its amendment Regulation (EU) 2020/878
Date first issue: 01/08/2008 Review date: 19/10/2020 Supersedes version of: 24/04/2019 Version: 6.0

SECTION 1: Identification of the substance/mixture and of the company/undertaking

1.1. Product identifier
Product form : Mixture
Product name : THICK BLEACH
Product code : 215
Type of product : Detergent
Product group : Mixture
1.2. Relevant identified uses of the substance or mixture and uses advised against
1.2.1. Relevant identified uses
Industrial/Professional use spec : Industrial
For professional use only
Use of the substance/mixture : Cleaning/washing agents and additives

1.2.2. Uses advised against

No additional information available
1.3. Details of the supplier of the safety data sheet
Clover Chemicals Ltd
Clover House
Macclesfield Road
SK23 7DQ Whaley Bridge - United Kingdom
T 01663 733114 - F 01663 733115
info@cloverchemicals.com - www.cloverchemicals.com
1.4. Emergency telephone number
Country Official advisory body Address Emergency number Comment
Ireland National Poisons Information Centre PO Box 1297 +353 1 809 2566
Beaumont Hospital Beaumont Road (Healthcare professionals-
9 Dublin 24/7)
+353 1 809 2166 (public,
8am - 10pm, 7/7)
United Kingdom National Poisons Information Service Dudley Road 0344 892 0111
(Birmingham Centre) B18 7QH Birmingham
City Hospital

SECTION 2: Hazards identification

2.1. Classification of the substance or mixture
Classification according to Regulation (EC) No. 1272/2008 [CLP]
Met. Corr. 1 H290
Skin Corr. 1B H314
Eye Dam. 1 H318
Aquatic Acute 1 H400
Aquatic Chronic 2 H411
Full text of hazard classes and H-statements : see section 16

Adverse physicochemical, human health and environmental effects

No additional information available
2.2. Label elements
Labelling according to Regulation (EC) No. 1272/2008 [CLP]
Hazard pictograms (CLP) :

GHS05 GHS09
CLP Signal word : Danger
Contains : Sodium hypochlorite; Alcohols, ethoxylated, sulfates, sodium salts; Amines, C12-14 (Even
numbered) Alkyldimethylamine,-N-Oxides
Hazard statements (CLP) : H290 - May be corrosive to metals.
H314 - Causes severe skin burns and eye damage.
H318 - Causes serious eye damage.
H410 - Very toxic to aquatic life with long lasting effects.

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THICK BLEACH
Safety Data Sheet
according to Regulation (EC) No. 1907/2006 (REACH) with its amendment Regulation (EU) 2020/878

Precautionary statements (CLP) : P102 - Keep out of reach of children.

P264 - Wash hands thoroughly after handling.
P280 - Wear protective gloves, eye protection.
P301+P330+P331 - IF SWALLOWED: Rinse mouth. Do NOT induce vomiting.
P314 - Get medical advice/attention if you feel unwell.
P303+P361+P353 - IF ON SKIN (or hair): Take off immediately all contaminated clothing.
Rinse skin with water or shower.
P332+P313 - If skin irritation occurs: Get medical advice/attention.
P304+P340 - IF INHALED: Remove person to fresh air and keep comfortable for breathing.
P305+P351+P338 - IF IN EYES: Rinse cautiously with water for several minutes. Remove
contact lenses, if present and easy to do. Continue rinsing.
P337+P313 - If eye irritation persists: Get medical advice/attention.
P362 - Take off contaminated clothing.
EUH-statements : EUH206 - Warning! Do not use together with other products. May release dangerous
gases (chlorine).
2.3. Other hazards
This substance/mixture does not meet the PBT criteria of REACH regulation, annex XIII
This substance/mixture does not meet the vPvB criteria of REACH regulation, annex XIII

Component
Alcohols, ethoxylated, sulfates, sodium salts (68891- This substance/mixture does not meet the PBT criteria of REACH regulation, annex XIII
38-3) This substance/mixture does not meet the vPvB criteria of REACH regulation, annex XIII

SECTION 3: Composition/information on ingredients

3.1. Substances
Not applicable
3.2. Mixtures
Name Product identifier % Classification according to
Regulation (EC) No.
1272/2008 [CLP]
Sodium hypochlorite (CAS-no) 7681-52-9 3–5 Met. Corr. 1, H290
(Einecs nr) 231-668-3 Skin Corr. 1B, H314
(EG annex nr) 017-011-00-1 Aquatic Acute 1, H400 (M=10)
(REACH-no) 01-2119488154-34
Amines, C12-14 (Even numbered) (CAS-no) 308062-28-4 1–3 Acute Tox. 4 (Oral), H302
Alkyldimethylamine,-N-Oxides (EG annex nr) 931-292-6 (ATE=1064 mg/kg bodyweight)
(REACH-no) 01-2119490061-47-0000 Skin Irrit. 2, H315
Eye Dam. 1, H318
Aquatic Acute 1, H400
Aquatic Chronic 2, H411
Alcohols, ethoxylated, sulfates, sodium salts (CAS-no) 68891-38-3 1–3 Skin Irrit. 2, H315
(Einecs nr) 500-234-8 Eye Dam. 1, H318
(REACH-no) 01-2119488639-16 Aquatic Chronic 3, H412

Specific concentration limits:

Name Product identifier Specific concentration limits
Sodium hypochlorite (CAS-no) 7681-52-9 ( 5 ≤C ≤ 100) EUH031
(Einecs nr) 231-668-3
(EG annex nr) 017-011-00-1
(REACH-no) 01-2119488154-34
Alcohols, ethoxylated, sulfates, sodium salts (CAS-no) 68891-38-3 ( 5 ≤C < 10) Eye Irrit. 2, H319
(Einecs nr) 500-234-8 ( 10 ≤C < 100) Eye Dam. 1, H318
(REACH-no) 01-2119488639-16
Full text of H-statements: see section 16

SECTION 4: First aid measures

4.1. Description of first aid measures
General advice : Never give anything by mouth to an unconscious person. If you feel unwell, seek medical
advice (show the label where possible).
Inhalation : Remove person to fresh air and keep comfortable for breathing. Immediately call a
POISON CENTER/doctor.

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THICK BLEACH
Safety Data Sheet
according to Regulation (EC) No. 1907/2006 (REACH) with its amendment Regulation (EU) 2020/878

Skin contact : Take off immediately all contaminated clothing. Rinse skin with water/shower. Immediately
call a POISON CENTER/doctor.
Eye contact : Rinse cautiously with water for several minutes. Remove contact lenses, if present and
easy to do. Continue rinsing. Immediately call a POISON CENTER/doctor.
Ingestion : Rinse mouth. Do NOT induce vomiting. Immediately call a POISON CENTER/doctor.
4.2. Most important symptoms and effects, both acute and delayed
Symptoms/effects : Causes severe skin burns and eye damage.
Acute effects inhalation : May cause irritation to the respiratory tract, sneezing, coughing, burning sensation of throat
with constricting sensation of the larynx and difficulty in breathing.
Acute effects skin : Causes severe burns.
Acute effects eyes : Causes serious eye damage.
Acute effects oral route : Burns or irritation of the linings of the mouth, throat, and gastrointestinal tract. Blood in
vomit.
4.3. Indication of any immediate medical attention and special treatment needed
No additional information available

SECTION 5: Firefighting measures

5.1. Extinguishing media
Suitable extinguishing media : Water.
5.2. Special hazards arising from the substance or mixture
Hazardous decomposition products in case of fire : Corrosive vapours. Toxic fumes may be released.
5.3. Advice for firefighters
Firefighting instructions : Use water spray or fog for cooling exposed containers. Exercise caution when fighting any
chemical fire. Prevent fire fighting water from entering the environment.
Protection during firefighting : Do not enter fire area without proper protective equipment, including respiratory protection.

SECTION 6: Accidental release measures

6.1. Personal precautions, protective equipment and emergency procedures
6.1.1. For non-emergency personnel
Emergency procedures : Evacuate unnecessary personnel.

6.1.2. For emergency responders

Protective equipment : Equip cleanup crew with proper protection.
Emergency procedures : Ventilate area.
6.2. Environmental precautions
Prevent entry to sewers and public waters. Notify authorities if liquid enters sewers or public waters. Avoid release to the environment.
6.3. Methods and material for containment and cleaning up
Methods for cleaning up : Soak up spills with inert solids, such as clay or diatomaceous earth as soon as possible.
Collect spillage. Store away from other materials. Absorb spillage to prevent material
damage.
6.4. Reference to other sections
See Heading 8. Exposure controls and personal protection.

SECTION 7: Handling and storage

7.1. Precautions for safe handling
Additional hazards when processed : May be corrosive to metals.
Precautions for safe handling : Wash hands and other exposed areas with mild soap and water before eating, drinking or
smoking and when leaving work. Provide good ventilation in process area to prevent
formation of vapour. Do not breathe dust/fume/gas/mist/vapours/spray.
Hygiene measures : Wash hands, forearms and face thoroughly after handling. Wash contaminated clothing
before reuse.
7.2. Conditions for safe storage, including any incompatibilities
Technical measures : Comply with applicable regulations.
Storage conditions : Store in a cool, well-ventilated place. Keep container tightly closed.
Incompatible products : Strong acids.
Incompatible materials : Sources of ignition. Direct sunlight.
Packaging materials : Store in corrosive resistant container with a resistant inner liner. polyethylene.
7.3. Specific end use(s)
No additional information available

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THICK BLEACH
Safety Data Sheet
according to Regulation (EC) No. 1907/2006 (REACH) with its amendment Regulation (EU) 2020/878

SECTION 8: Exposure controls/personal protection

8.1. Control parameters
8.1.1 National occupational exposure and biological limit values
No additional information available

8.1.2. Recommended monitoring procedures

No additional information available

8.1.3. Air contaminants formed

No additional information available

8.1.4. DNEL and PNEC

No additional information available

8.1.5. Control banding

No additional information available
8.2. Exposure controls
8.2.1. Appropriate engineering controls
Appropriate engineering controls:
Ensure that there is a suitable ventilation system.

8.2.2. Personal protection equipment

Personal protective equipment:
Avoid all unnecessary exposure.
Personal protective equipment symbol(s):

8.2.2.1. Eye and face protection

Eye protection:
Chemical goggles or face shield

8.2.2.2. Skin protection

Protective equipment:
Wear suitable protective clothing

Hand protection:
Wear protective gloves.

8.2.2.3. Respiratory protection

No additional information available

8.2.2.4. Thermal hazards

No additional information available

8.2.3. Environmental exposure controls

Other information:
Do not eat, drink or smoke during use.

SECTION 9: Physical and chemical properties

9.1. Information on basic physical and chemical properties
Physical state : Liquid
Colour : Pale yellow.
Physical state/form : Liquid.
Odour : Characteristic.
Odour threshold : Not available

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THICK BLEACH
Safety Data Sheet
according to Regulation (EC) No. 1907/2006 (REACH) with its amendment Regulation (EU) 2020/878

Melting point/range : 0 °C
Freezing point : Not available
Boiling point/Boiling range : 100 °C
Flammability : Non flammable.
Explosive limits : Not available
Lower explosive limit (LEL) : Not available
Upper explosive limit (UEL) : Not available
Flash point : Not available
Autoignition temperature : Not available
Decomposition temperature : Not available
pH : 12 – 14
Viscosity, kinematic : Not available
Viscosity, dynamic : 150 – 400 cP at 20 °C
Solubility : Soluble in water.
Partition coefficient n-octanol/water (Log Kow) : Not available
Vapour pressure : Not available
Vapour pressure at 50 °C : Not available
Density : Not available
Relative density : 1.08
Relative vapour density at 20 °C : Not available
Particle size : Not applicable
Particle size distribution : Not applicable
Particle shape : Not applicable
Particle aspect ratio : Not applicable
Particle aggregation state : Not applicable
Particle agglomeration state : Not applicable
Particle specific surface area : Not applicable
Particle dustiness : Not applicable
9.2. Other information
9.2.1. Information with regard to physical hazard classes
No additional information available

9.2.2. Other safety characteristics

No additional information available

SECTION 10: Stability and reactivity

10.1. Reactivity
Thermal decomposition generates : Corrosive vapours.
10.2. Chemical stability
Stable under normal conditions.
10.3. Possibility of hazardous reactions
No dangerous reactions known under normal conditions of use.
10.4. Conditions to avoid
Direct sunlight. Extremely high or low temperatures.
10.5. Incompatible materials
Strong acids. metals. May be corrosive to metals.
10.6. Hazardous decomposition products
fume. Carbon monoxide. Carbon dioxide. Thermal decomposition generates : Corrosive vapours.

SECTION 11: Toxicological information

11.1. Information on hazard classes as defined in Regulation (EC) No 1272/2008
Acute toxicity (oral) : Not classified
Acute toxicity (dermal) : Not classified
Acute toxicity (inhalation) : Not classified

Sodium hypochlorite (7681-52-9)

LD50 oral rat > 2000 mg/kg
LD50 dermal rabbit > 2000 mg/kg

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THICK BLEACH
Safety Data Sheet
according to Regulation (EC) No. 1907/2006 (REACH) with its amendment Regulation (EU) 2020/878

Alcohols, ethoxylated, sulfates, sodium salts (68891-38-3)

LD50 oral rat > 4100 mg/kg OCDE 401
LD50 dermal rat > 2000 mg/kg OCDE 402

Amines, C12-14 (Even numbered) Alkyldimethylamine,-N-Oxides (308062-28-4)

LD50 oral rat 1064 mg/kg
LD50 dermal rat > 2000 mg/kg

Skin corrosion/irritation : Causes severe skin burns.

pH: 12 – 14
Serious eye damage/irritation : Causes serious eye damage.
pH: 12 – 14
Respiratory or skin sensitisation : Not classified
Additional information : Based on available data, the classification criteria are not met
Germ cell mutagenicity : Not classified
Additional information : Based on available data, the classification criteria are not met
Carcinogenicity : Not classified
Additional information : Based on available data, the classification criteria are not met

Reproductive toxicity : Not classified

Additional information : Based on available data, the classification criteria are not met

STOT-single exposure : Not classified

Additional information : Based on available data, the classification criteria are not met

STOT-repeated exposure : Not classified

Additional information : Based on available data, the classification criteria are not met

Aspiration hazard : Not classified

Additional information : Based on available data, the classification criteria are not met
11.2. Information on other hazards
11.2.1. Endocrine disrupting properties

11.2.2 Other information

Potential adverse human health effects and : Based on available data, the classification criteria are not met
symptoms

SECTION 12: Ecological information

12.1. Toxicity
Ecology - water : Very toxic to aquatic life. Toxic to aquatic life with long lasting effects.
Hazardous to the aquatic environment, short-term : Very toxic to aquatic life.
(acute)
Hazardous to the aquatic environment, long-term : Toxic to aquatic life with long lasting effects.
(chronic)

Sodium hypochlorite (7681-52-9)

LC50 - Fish [1] 0.06 mg/l (fresh water)
LC50 - Fish [2] 0.032 mg/l (marine water)
EC50 - Crustacea [1] 0.141 mg/l (Daphnia magna - fresh water)
EC50 - Other aquatic organisms [1] 0.026 mg/l (Crassostrea virginica - marine water)

Alcohols, ethoxylated, sulfates, sodium salts (68891-38-3)

LC50 - Fish [1] 7.1 mg/l OECD 203
EC50 - Crustacea [1] 7.4 mg/l OECD 202 Daphnia sp.Acute Immobilization Test and Reproduction Test

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THICK BLEACH
Safety Data Sheet
according to Regulation (EC) No. 1907/2006 (REACH) with its amendment Regulation (EU) 2020/878

EC50 72h - Algae [1] 27.7 mg/l

ErC50 algae 27.7 mg/l OECD 201 Alga, Growth Inhibition Test
NOEC chronic algae 0.95 mg/l OECD 201 Alga, Growth Inhibition Test

Amines, C12-14 (Even numbered) Alkyldimethylamine,-N-Oxides (308062-28-4)

LC50 - Fish [1] 2.67 – 3.46 mg/l
EC50 - Crustacea [1] 3.1 mg/l
ErC50 algae 0.14 mg/l 72H
12.2. Persistence and degradability
THICK BLEACH
Persistence and degradability May cause long-term adverse effects in the environment.

Sodium hypochlorite (7681-52-9)

Persistence and degradability Strong oxidizing agent. It will react with organic substances present in soil and sediments
and degrades rapidly to chloride. Sodium hypochlorite is substantially removed in
biological treatment processes.

Alcohols, ethoxylated, sulfates, sodium salts (68891-38-3)

Persistence and degradability Biodegradable.
12.3. Bioaccumulative potential
THICK BLEACH
Bioaccumulative potential No bioaccumulation.

Sodium hypochlorite (7681-52-9)

Bioaccumulative potential Bioaccumulation unlikely.
12.4. Mobility in soil
No additional information available
12.5. Results of PBT and vPvB assessment
THICK BLEACH
This substance/mixture does not meet the PBT criteria of REACH regulation, annex XIII
This substance/mixture does not meet the vPvB criteria of REACH regulation, annex XIII

Component
Alcohols, ethoxylated, sulfates, sodium salts (68891- This substance/mixture does not meet the PBT criteria of REACH regulation, annex XIII
38-3) This substance/mixture does not meet the vPvB criteria of REACH regulation, annex XIII
12.6. Endocrine disrupting properties
No additional information available
12.7. Other adverse effects
Additional information : Avoid release to the environment.

SECTION 13: Disposal considerations

13.1. Waste treatment methods
Product/Packaging disposal recommendations : Dispose in a safe manner in accordance with local/national regulations. Dispose of
contents/container to hazardous or special waste collection point, in accordance with local,
regional, national and/or international regulation.
Waste / unused products : Avoid release to the environment.

SECTION 14: Transport information

In accordance with ADR / IMDG / IATA
ADR IMDG IATA

14.1. UN number or ID number

UN 1760 UN 1760 UN 1760

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THICK BLEACH
Safety Data Sheet
according to Regulation (EC) No. 1907/2006 (REACH) with its amendment Regulation (EU) 2020/878

14.2. UN proper shipping name

CORROSIVE LIQUID, N.O.S. CORROSIVE LIQUID, N.O.S. Corrosive liquid, n.o.s.
Transport document description
UN 1760 CORROSIVE LIQUID, N.O.S. UN 1760 CORROSIVE LIQUID, N.O.S. UN 1760 Corrosive liquid, n.o.s. (Sodium
(Sodium hypochlorite), 8, III, (E), (Sodium hypochlorite), 8, III, MARINE hypochlorite), 8, III, ENVIRONMENTALLY
ENVIRONMENTALLY HAZARDOUS POLLUTANT/ENVIRONMENTALLY HAZARDOUS
HAZARDOUS

14.3. Transport hazard class(es)

8 8 8

14.4. Packing group

III III III

14.5. Environmental hazards

Dangerous for the environment : Yes Dangerous for the environment : Yes Dangerous for the environment : Yes
Marine pollutant : Yes
No supplementary information available
14.6. Special precautions for user
Overland transport
Classification code (ADR) : C9
Special provisions (ADR) : 274
Limited quantities (ADR) : 5l
Packing instructions (ADR) : P001, IBC03, LP01, R001
Mixed packing provisions (ADR) : MP19
Portable tank and bulk container instructions : T7
(ADR)
Portable tank and bulk container special provisions : TP1, TP28
(ADR)
Tank code (ADR) : L4BN
Vehicle for tank carriage : AT
Transport category (ADR) :3
Special provisions for carriage - Packages (ADR) : V12
Hazard identification number (Kemler No.) : 80
Orange plates :

Tunnel code :E
EAC code : 2X
APP code :B
Transport by sea
Special provisions (IMDG) : 223, 274
Limited quantities (IMDG) :5L
Packing instructions (IMDG) : P001, LP01
IBC packing instructions (IMDG) : IBC03
Air transport
PCA Limited quantities (IATA) : Y841
PCA limited quantity max net quantity (IATA) : 1L
PCA packing instructions (IATA) : 852
PCA max net quantity (IATA) : 5L
CAO packing instructions (IATA) : 856

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THICK BLEACH
Safety Data Sheet
according to Regulation (EC) No. 1907/2006 (REACH) with its amendment Regulation (EU) 2020/878

CAO max net quantity (IATA) : 60L

Special provisions (IATA) : A3, A803
14.7. Maritime transport in bulk according to IMO instruments
Not applicable

SECTION 15: Regulatory information

15.1. Safety, health and environmental regulations/legislation specific for the substance or mixture
15.1.1. EU-Regulations
Contains no REACH substances with Annex XVII restrictions
Contains no substance on the REACH candidate list
Contains no REACH Annex XIV substances
Contains no substance subject to Regulation (EU) No 649/2012 of the European Parliament and of the Council of 4 July 2012 concerning the export
and import of hazardous chemicals.
Contains no substance subject to Regulation (EU) No 2019/1021 of the European Parliament and of the Council of 20 June 2019 on persistent
organic pollutants
Detergent Regulation (648/2004/EC): Labelling of contents:

Component %
chlorine-based bleaching agents, anionic surfactants <5%

15.1.2. National regulations

No additional information available
15.2. Chemical safety assessment
No chemical safety assessment has been carried out

SECTION 16: Other information

Data sources : REGULATION (EC) No 1272/2008 OF THE EUROPEAN PARLIAMENT AND OF THE COUNCIL of 16
December 2008 on classification, labelling and packaging of substances and mixtures, amending and
repealing Directives 67/548/EEC and 1999/45/EC, and amending Regulation (EC) No 1907/2006.
Other information : None.

Full text of H- and EUH-statements:

Acute Tox. 4 (Oral) Acute toxicity (oral), Category 4
Aquatic Acute 1 Hazardous to the aquatic environment — Acute Hazard, Category 1
Aquatic Chronic 2 Hazardous to the aquatic environment — Chronic Hazard, Category 2
Aquatic Chronic 3 Hazardous to the aquatic environment — Chronic Hazard, Category 3
EUH031
Eye Dam. 1 Serious eye damage/eye irritation, Category 1
Eye Irrit. 2 Serious eye damage/eye irritation, Category 2
Met. Corr. 1 Corrosive to metals, Category 1
Skin Corr. 1B Skin corrosion/irritation, Category 1, Sub-Category 1B
Skin Irrit. 2 Skin corrosion/irritation, Category 2
H290 May be corrosive to metals.
H302 Harmful if swallowed.
H314 Causes severe skin burns and eye damage.
H315 Causes skin irritation.
H318 Causes serious eye damage.
H319 Causes serious eye irritation.
H400 Very toxic to aquatic life.
H411 Toxic to aquatic life with long lasting effects.
H412 Harmful to aquatic life with long lasting effects.
EUH206 Warning! Do not use together with other products. May release dangerous gases (chlorine).

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THICK BLEACH
Safety Data Sheet
according to Regulation (EC) No. 1907/2006 (REACH) with its amendment Regulation (EU) 2020/878

Classification and procedure used to derive the classification for mixtures according to Regulation (EC) 1272/2008 [CLP]:
Met. Corr. 1 H290 Calculation method
Skin Corr. 1B H314 Expert judgment
Eye Dam. 1 H318 Expert judgment
Aquatic Acute 1 H400 Calculation method
Aquatic Chronic 2 H411 Expert judgment
Safety Data Sheet (SDS), EU
This information is based on our current knowledge and is intended to describe the product for the purposes of health, safety and environmental
requirements only. It should not therefore be construed as guaranteeing any specific property of the product.

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