Ace Science Academy

Subject : Chemistry Paper Set : 1

Structure of Atom Test
Standard : 11 Date : 27-09-2023
Total Mark : 100 Time : 0H:0M

. . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . Chemistry - Section A (MCQ) . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . .

(4) The electronic configuration of a dipositive metal M 2+ is 2, 8, 14 and its atomic weight is 56 a.m.u. The number of neutrons in its nuclei would be
(A) 30 (B) 32 (C) 34 (D) 42
o o
(5) The ratio of the energy of a photon of 2000 A wavelength radiation to that of 4000 A radiation is
(A) 0.25 (B) 4 (C) 0.5 (D) 2
(6) In a Bohr’s model of atom when an electron jumps from n = 1 to n = 3, how much energy will be emitted or absorbed
(A) 2.15 × 10−11 erg (B) 0.1911 × 10−10 erg (C) 2.389 × 10−12 erg (D) 0.239 × 10−10 erg
(7) The energy of an electron in the first Bohr orbit of Hatom is −13.6 eV . The possible energy value (s) of the excited state (s) for electrons in Bohr orbits to
hydrogen is(are) ............. eV
(A) −3.4 (B) −4.2 (C) −6.8 (D) +6.8
(8) The energy of the electron in the first orbit of He+ is −871.6 × 10−20 J. The energy of the electron in the first orbit of hydrogen would be
(A) −871.6 × 10−20 J (B) −435.8 × 10−20 J (C) −217.9 × 10−20 J (D) −108.9 × 10−20 J
(9) The number of nodal planes in a px is
(A) 1 (B) 2 (C) 3 (D) 0
(10) The frequency of one of the lines in Paschen series of hydrogen atom is 2.340 × 1011 Hz. The quantum number n2 which produces this transition is

y
(A) 6 (B) 5 (C) 4 (D) 3

m
(11) In balmer series of lines of hydrogen spectrum, the third line from the red end corresponds to which one of the following inter-orbit jumps of the electron for Bohr
orbits in an atom of hydrogen e
ad
(A) 3 → 2 (B) 5 → 2 (C) 4 → 1 (D) 2 → 5
(12) The value of Planck’s constant is 6.63 × 10−34 Js. The velocity of light is 3.0 × 108 ms−1 . Which value is closest to the wavelength in nanometres of a quantum
Ac

of light with frequency of 8 × 1015 s−1

(A) 3 × 107 (B) 2 × 10−25 (C) 5 × 10−18 (D) 4 × 101
ce

(13) The correct set of quantum numbers for the unpaired electron of chlorine atom is
nlm
n

(A) 2 1 0 (B) 2 1 1 (C) 3 1 1 (D) 3 0 0

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(14) The orbital diagram in which the Aufbau’s principle is violated is

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2s 2px 2py 2pz

(A) ↑↓ ↑↓ ↑ (B) ↑ ↑↓ ↑ ↑ (C) ↑↓ ↑ ↑ ↑ (D) ↑↓ ↑↓ ↑↓ ↑
e

(15) Which of the following is not correct for electron distribution in the ground state
Ac

4s 3d
(A) Co(Ar) ↑↓ ↑↓ ↑↓ ↑ ↑ ↑ (B) N i(Ar) ↑↓ ↑↓ ↑↓ ↑↓ ↑ ↑
(C) Cu(Ar) ↑↓ ↑↓ ↑↓ ↑↓ ↑↓ ↑ (D) Zn(Ar) ↑↓ ↑↓ ↑↓ ↑↓ ↑↓ ↑↓
(16) From the given sets of quantum numbers the one that is inconsistent with the theory is
(A) n = 3; l = 2; m = −3; s = +1/2 (B) n = 4; l = 3; m = 3; s = +1/2
(C) n = 2; l = 1; m = 0l s = −1/2 (D) n = 4; l = 3; m = 2; s = +1/2
(17) The uncertainty in the position of an electron ( mass = 9.1 × 10−28 g) moving with a velocity of 3.0 × 104 cm s−1 accurate upto 0.001% will be ................. cm
(Use 4π
h
in the uncertainty expression, where h = 6.626 × 10−27 erg − s)
(A) 1.92 (B) 7.68 (C) 5.76 (D) 3.84
(18) Values of the four quantum numbers for the last electron in the atom are n = 4, l = 1, m = +1 and s = −1/2. Atomic number of the atom will be
(A) 22 (B) 32 (C) 31 (D) 36
(19) The electrons identified by quantum numbers n and l (i) n = 4, l = 1 (ii) n = 4, l = 0 (iii) n = 3, l = 2 (iv) n = 3, l = 1 can be placed in order of increasing
energy from the lowest to highest, as
(A) (iv) < (ii) < (iii) < (i) (B) (ii) < (iv) < (i) < (iii) (C) (i) < (iii) < (ii) < (iv) (D) (iii) < (i) < (iv) < (ii)
(20) The orbital angular momentum of a p− electron is given as √
√ h √
(A) √h (B) 3 2π (C) 3 h
2 π
(D) 6 h
2π
2π
(21) The energies E1 and E2 of two radiations are 25 eV and 50 eV respectively. The relation between their wavelengths i.e., λ1 and λ2 will be
(A) λ1 = λ2 (B) λ1 = 2λ2 (C) λ1 = 4λ2 (D) λ1 = 1
2
λ2
(22) A 0.66 kg ball is moving with a speed of 100 m/s. The associated wavelength will be
(h = 6.6 × 10−34 J s)
(A) 6.6 × 10−32 m (B) 6.6 × 10−34 m (C) 1.0 × 10−35 m (D) 1.0 × 10−32 m
(23) Maximum number of electrons in a subshell of an atom is determined by the following
(A) 2l + 1 (B) 4l − 2 (C) 2n2 (D) 4l + 2

1
(24) Consider the following sets of quantum numbers :
(n)-(l)-(m)-(s)
(i) (3)-(2)-(1)- (+1/2)
(ii) (2)-(2)-(1)- (+1/2)
(iii) (4)-(3)-(−2)- (−1/2)
(iv) (1)-(0)-(−1)- (−1/2)
(v) (3)-(2-(3)- (+1/2)
Which of the following sets of quantum number is not possible ?
(A) (i), (ii), (iii) and (iv) (B) (ii), (iv) and (v) (C) (i) and (iii) (D) (ii), (iii) and (iv).
(25) According to Bohr’s theory, the angular momentum of an electron in 5th orbit is
(A) 10 h/π (B) 2.5 h/π (C) 25 h/π (D) 1.0 h/π
(26) A stream of electrons from a heated filaments was passed two charged plates kept at a potential difference V esu. If e and m are charge and mass of an electron,
respectively, then the value of h/λ, (where λ is wavelength associated with electron wave) is given by :
√ √
(A) meV (B) 2meV (C) meV (D) 2meV
(27) A 124 W bulb converts only 15 % of the energy supplied to it into visible light of wavelength 640 nm . How many photons are emitted by the light bulb in one
second
(A) 4 × 1019 (B) 6 × 1019 (C) 8 × 1018 (D) 3 × 1019 photon
(28) Which of the following plots of radial probability function 4πr 2 Ψ2r is incorrectly labelled
(A) (B)

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(D)
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(C)
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 Ace Science Academy

Subject : Chemistry Structure of Atom Test Paper Set : 1

Standard : 11 Date : 27-09-2023
Total Mark : 100 (Answer Key) Time : 0H:0M

Chemistry - Section A (MCQ)

4-A 5-D 6-B 7-A 8-C 9-A 10 - B 11 - A 12 - D 13 - C

14 - B 15 - C 16 - A 17 - A 18 - D 19 - A 20 - A 21 - B 22 - C 23 - D
24 - B 25 - B 26 - B 27 - B 28 - A

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 Ace Science Academy

Subject : Chemistry Structure of Atom Test Paper Set : 1

Standard : 11 Date : 27-09-2023
Total Mark : 100 (Solutions) Time : 0H:0M

. . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . Chemistry - Section A (MCQ) . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . .

(4) The electronic configuration of a dipositive metal M 2+ is 2, 8, 14 and its atomic weight is 56 a.m.u. The number of neutrons in its nuclei would be
(A) 30 (B) 32 (C) 34 (D) 42
Solution:(Correct Answer:A)
(a) Metal is 56 M 2+ (2, 8, 14)
than n = A − Z = 56 − 26 = 30.
o o
(5) The ratio of the energy of a photon of 2000 A wavelength radiation to that of 4000 A radiation is
(A) 0.25 (B) 4 (C) 0.5 (D) 2
Solution:(Correct Answer:D)
(d) E = hv = h λc i.e. E ∝ λ
1
E1 λ2 4000
E
= λ
= 2000
= 2.
2 1

(6) In a Bohr’s model of atom when an electron jumps from n = 1 to n = 3, how much energy will be emitted or absorbed
(A) 2.15 × 10−11 erg (B) 0.1911 × 10−10 erg (C) 2.389 × 10−12 erg (D) 0.239 × 10−10 erg
Solution:(Correct Answer:B)
(b) According to Bohr’s model ∆E = E1 − E3

y
11
= 2.179 × 10−11 − 2.179×10 9

m
= 9 × 2.179 × 10
8 −11 = 1.91 × 10−11 = 0.191 × 10−10 erg
Since electron is going from n = 1 to n = 3 hence energy is absorbed.
e
ad
(7) The energy of an electron in the first Bohr orbit of Hatom is −13.6 eV . The possible energy value (s) of the excited state (s) for electrons in Bohr orbits to
hydrogen is(are) ............. eV
Ac

(A) −3.4 (B) −4.2 (C) −6.8 (D) +6.8

Solution:(Correct Answer:A)
−13.6
(a) Values of energy in the excited state = − 13.6 eV = = −3.4 eV
ce

n2 4
in which n = 2, 3, 4 etc.
n

(8) The energy of the electron in the first orbit of He+ is −871.6 × 10−20 J. The energy of the electron in the first orbit of hydrogen would be
ie

(A) −871.6 × 10−20 J (B) −435.8 × 10−20 J (C) −217.9 × 10−20 J (D) −108.9 × 10−20 J
Solution:(Correct Answer:C)
Sc

(c) E1 He+ = E1 H × z 2
−871.6 × 10−20 = E1H × 4
e

E1 H = −217.9 × 10−20 J
Ac

(9) The number of nodal planes in a px is

(A) 1 (B) 2 (C) 3 (D) 0
Solution:(Correct Answer:A)

(a) The number of nodal plane are present in a px is one or no. of nodal place = l
for px orbital l = 1

(10) The frequency of one of the lines in Paschen series of hydrogen atom is 2.340 × 1011 Hz. The quantum number n2 which produces this transition is
(A) 6 (B) 5 (C) 4 (D) 3
Solution:(Correct Answer:B)
[ ]
(b) ν = λ
1
= RH n12 − n12
[ 1
] 2
= λ 1
= RH 312 − n12 = n2 = 3 for Paschen series.
2

(11) In balmer series of lines of hydrogen spectrum, the third line from the red end corresponds to which one of the following inter-orbit jumps of the electron for Bohr
orbits in an atom of hydrogen
(A) 3 → 2 (B) 5 → 2 (C) 4 → 1 (D) 2 → 5
Solution:(Correct Answer:A)
It’s Obvious

(12) The value of Planck’s constant is 6.63 × 10−34 Js. The velocity of light is 3.0 × 108 ms−1 . Which value is closest to the wavelength in nanometres of a quantum
of light with frequency of 8 × 1015 s−1
(A) 3 × 107 (B) 2 × 10−25 (C) 5 × 10−18 (D) 4 × 101

4
 Solution:(Correct Answer:D)
3×108
(d) λ = c
v
= 8×1015
= 3.75 × 10−8
= 3.75 × −8
10 × 10 nm= 4 × 101 nm.
9

(13) The correct set of quantum numbers for the unpaired electron of chlorine atom is
nlm
(A) 2 1 0 (B) 2 1 1 (C) 3 1 1 (D) 3 0 0
Solution:(Correct Answer:C)

(c) Electronic configuration of Cl is

[N e] 3s2 3p5 or [N e]
So for the unpaired electron (3p1z ) :
n = 3, l = 1, m = 1, S = + 21

(14) The orbital diagram in which the Aufbau’s principle is violated is

2s 2px 2py 2pz
(A) ↑↓ ↑↓ ↑ (B) ↑ ↑↓ ↑ ↑ (C) ↑↓ ↑ ↑ ↑ (D) ↑↓ ↑↓ ↑↓ ↑
Solution:(Correct Answer:B)
(b) According to Aufbau principle the orbitals of lower energy (2s) should be fully filled before the filling of orbital of higher energy starts.

(15) Which of the following is not correct for electron distribution in the ground state
4s 3d
(A) Co(Ar) ↑↓ ↑↓ ↑↓ ↑ ↑ ↑ (B) N i(Ar) ↑↓ ↑↓ ↑↓ ↑↓ ↑ ↑
(C) Cu(Ar) ↑↓ ↑↓ ↑↓ ↑↓ ↑↓ ↑ (D) Zn(Ar) ↑↓ ↑↓ ↑↓ ↑↓ ↑↓ ↑↓

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Solution:(Correct Answer:C)

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ad
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(c) The correct electronic configuration

Cu29 = [Ar], 4s1 3d10
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(16) From the given sets of quantum numbers the one that is inconsistent with the theory is
(A) n = 3; l = 2; m = −3; s = +1/2 (B) n = 4; l = 3; m = 3; s = +1/2
n

(C) n = 2; l = 1; m = 0l s = −1/2 (D) n = 4; l = 3; m = 2; s = +1/2

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Solution:(Correct Answer:A)
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(a) When l = 2, m ̸= −3.

(17) The uncertainty in the position of an electron ( mass = 9.1 × 10−28 g) moving with a velocity of 3.0 × 104 cm s−1 accurate upto 0.001% will be ................. cm
e

(Use 4π
h
in the uncertainty expression, where h = 6.626 × 10−27 erg − s)
Ac

(A) 1.92 (B) 7.68 (C) 5.76 (D) 3.84

Solution:(Correct Answer:A)
(a) ∆p = m × ∆v
∆p = 9.1 × 10−28 × 3.0 × 104 × 0.001
100
∆P = 2.73 × 10−24
6.626×10−27
Hence ∆x = ∆p×4π = 2.73×10−28 ×4×3.14
h

∆x = 1.92 cm.

(18) Values of the four quantum numbers for the last electron in the atom are n = 4, l = 1, m = +1 and s = −1/2. Atomic number of the atom will be
(A) 22 (B) 32 (C) 31 (D) 36
Solution:(Correct Answer:D)
(d) Atomic number is 36 and element is Kr.

(19) The electrons identified by quantum numbers n and l (i) n = 4, l = 1 (ii) n = 4, l = 0 (iii) n = 3, l = 2 (iv) n = 3, l = 1 can be placed in order of increasing
energy from the lowest to highest, as
(A) (iv) < (ii) < (iii) < (i) (B) (ii) < (iv) < (i) < (iii) (C) (i) < (iii) < (ii) < (iv) (D) (iii) < (i) < (iv) < (ii)
Solution:(Correct Answer:A)
(a) (i) 4p (ii) 4s (iii) 3d (iv) 3p order of increasing energy is 3p < 4s < 3d < 4p.

(20) The orbital angular momentum of a p− electron is given as √

√ h √
(A) √h (B) 3 2π (C) 3 h
2 π
(D) 6 h
2π
2π
Solution:(Correct Answer:A)
√
Orbital angular momentum = l(l + 1) × h
2π
∴ For p-electron, l = 1
∴ Orbital
√ angular momentum,
= 1(1 + 1) × 2π h
√
= 2 × 2π h

= √h
2π

5
(21) The energies E1 and E2 of two radiations are 25 eV and 50 eV respectively. The relation between their wavelengths i.e., λ1 and λ2 will be
(A) λ1 = λ2 (B) λ1 = 2λ2 (C) λ1 = 4λ2 (D) λ1 = 1
2
λ2
Solution:(Correct Answer:B)
E1 = 25eV, E2 = 50eV
E1 = λ hc
and E2 = λhc
1 2
E1
E2
= λλ1
2

25 λ2
50
= λ
1
λ1 = 2λ2

(22) A 0.66 kg ball is moving with a speed of 100 m/s. The associated wavelength will be
(h = 6.6 × 10−34 J s)
(A) 6.6 × 10−32 m (B) 6.6 × 10−34 m (C) 1.0 × 10−35 m (D) 1.0 × 10−32 m
Solution:(Correct Answer:C)
From de-Broglie equation,
−34
λ = mvh
= 6.6×10
0.66×100
= 10−35 m

(23) Maximum number of electrons in a subshell of an atom is determined by the following

(A) 2l + 1 (B) 4l − 2 (C) 2n2 (D) 4l + 2
Solution:(Correct Answer:D)
Total number of subshells = (2l + 1)
∴ Maximum number of electrons in the subshell = 2(2l + 1) = 4l + 2

(24) Consider the following sets of quantum numbers :

(n)-(l)-(m)-(s)
(i) (3)-(2)-(1)- (+1/2)
(ii) (2)-(2)-(1)- (+1/2)
(iii) (4)-(3)-(−2)- (−1/2)

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(iv) (1)-(0)-(−1)- (−1/2)

m
(v) (3)-(2-(3)- (+1/2)
Which of the following sets of quantum number is not possible ? e
ad
(A) (i), (ii), (iii) and (iv) (B) (ii), (iv) and (v) (C) (i) and (iii) (D) (ii), (iii) and (iv).
Solution:(Correct Answer:B)
Ac

The value of l varies from 0 to n − l and the value of m varies from −l to +l through zero. 1 the value of s ∓ 1
2
Which signifies the spin of the electron. The
correct sets of quantum number are following:
n l m s
ce

(ii) 2 1 1 +1/2
(iv) 1 0 0 −1/2
n

(v) 3 2 2 +1/2
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(25) According to Bohr’s theory, the angular momentum of an electron in 5th orbit is
Sc

(A) 10 h/π (B) 2.5 h/π (C) 25 h/π (D) 1.0 h/π
Solution:(Correct Answer:B)
e

Formula of angular momentum of an electron,

Ac

mvr = nh
2π
here n = 5
∴ mvr = 2π5h h
= 2.5 π

(26) A stream of electrons from a heated filaments was passed two charged plates kept at a potential difference V esu. If e and m are charge and mass of an electron,
respectively, then the value of h/λ, (where λ is wavelength associated with electron wave) is given by :
√ √
(A) meV (B) 2meV (C) meV (D) 2meV
Solution:(Correct Answer:B)
Kinetic energy = eV = 12 mu2
√
2eV
u= m
Here, u is the velocity of the electron.
The de broglie wavelength is λ = mu h
h
λ
= mu
Substitute
√ equation (1) in equation (2)
h 2eV
√
λ
= m m
= 2meV

(27) A 124 W bulb converts only 15 % of the energy supplied to it into visible light of wavelength 640 nm . How many photons are emitted by the light bulb in one
second
(A) 4 × 1019 (B) 6 × 1019 (C) 8 × 1018 (D) 3 × 1019 photon
Solution:(Correct Answer:B)
124×0.15
1240 ×1.6×10−19
640
= 124×640
124×16
× 1019 × 0.15
= 6 × 10 19

6
(28) Which of the following plots of radial probability function 4πr 2 Ψ2r is incorrectly labelled
(A) (B)

(C) (D)

Solution:(Correct Answer:A)

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e m
ad
Ac
n ce
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