Neet Model - Units V + Vi - 27-06-2020
Neet Model - Units V + Vi - 27-06-2020
Brilliant
STUDY CENTRE
Puliyannoor P.O., PALA
Ph - 04822 206416, 206516, 206459
NEET MODEL EXAMINATION - UNIT V+VI
Physics + Chemistry + Biology Time: 3 hrs. A1
www.brilliantpala.org Max. Mark: 720
2
1) v1 v 2 : v 2 v 3 t1 t 2 : t 2 t 3
gt
1) 8gH g 2 t 2 2) 8gH
2 2) v1 v 2 : v 2 v 3 t1 t 2 : t 2 t 3
1 3) v1 v 2 : v 2 v 3 t1 t 2 : t1 t 3
3) 8gH g 2 t 2 4) 8gH 4g 2 t 2
2
5
(i) x = 3t+2.5t2 (ii) x t 2 t
2
(iii) x 6 3t – 2.5t 2
3) 7.2 4) 6.4
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7. A point object starts from rest at the origin
T H
and moves with a uniform acceleration 12. At time t ,
4 H max is (where T is the total
in ms of ˆi ˆj kˆ .
2
The distance of
time of flight, H max is the maximum height,
the object from the origin after 1 second
is and H is the height at time t of a projectile
launched from ground)
2 2 2
1) 2) 1 3
2 2 1) 2)
2 4
3) 4)
2
3 5
8. A car travels in a straight line with varying 3) 4)
velocity given by 8 8
v t t 0 ms 1 for 0 t 2t 0 where, t = time 13. Rain drops falling with actual velocity of
and t0 = time at which velocity is zero. 5ms 1 on a windy day appear to fall
The distance travelled by the car in this vertically down on a man moving
interval is Eastward with a speed of 3ms–1. If the
man reverses his direction with the
1) t 02 2) 2t 20 same speed, the raindrops will fall on
him with a speed of (in ms–1)
3 2
3) t0 4) 0
2 1) 35 2) 52
9. A bullet fired into a large block of wood of
uniform resistance, hits the block with a 3) 47 4) 83
velocity of 48ms–1. It penetrates a distance
of 60cm and the velocity is then reduced 14. A certain force applied to a mass m1
to 24ms–1. It then penetrates a further
distance of (in cm) gives it an acceleration of 15ms2 . The
same force produces an acceleration
1) 50 2) 16
of 10ms 2 in another mass m2. If the
3) 18 4) 20
two masses stick together, the
10. A body is projected horizontally from a acceleration produced by the same
height h above ground with an initial force is
velocity of 10ms–1. If the body hits the
ground with a velocity of 20ms–1 then the
1) 5ms 2 2) 6ms 2
value of h is (g=10ms–2)
1) 10m 2) 15m
3) 25ms 2 4) 12.5ms2
3) 30m 4) 40m
11. A parti cle has an initial velocity 15. A block of mass 0.15kg rests on an
inclined plane of coefficient of friction
of 6iˆ 5jˆ ms . The particle accelerates at
1
0.3. If the angle of the plane with the
horizontal is 30°, the minimum force
0.5iˆ 0.35jˆ ms 2
. Its speed 20s later is parallel to the plane necessary to
prevent it from slipping is (g=10ms–2)
1) 10ms 1 2) 16ms 1
1) 0.5N 2) 0.36N
3) 20ms1 4) 11ms1 3) 1.5N 4) 0.25N
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16. The period T of a soap bubble under SHM
19. A vector A points vertically upward and
i s gi v en b y T Pa D bSc , where P is
B points towards north. The vector
pressure, D is density and S is surface
tension. Then the values of a,b and c product A B is
are
1) Zero
3 1 2) Along west
1) , ,1 2) 1, 2,3
2 2
3) Along east
1 3 3 4) Vertically downward
3) , , 1 / 2 4) 1, 2,
2 2 2
20. A projectile is thrown into air so as to
17. A students performs an experiment for have the maximum possible range
equal to 200. Taking projection point
42 as origin, the coordinates of the point
determination of g and he
T2 where the velocity of the projectile is
commits an error of . For that he minimum, are
takes the time of n oscillations with
1) (200,50) 2) (100,50)
the stop watch of least count T and
he commits a human error of 0.1s. For 3) (100,75) 4) (100,100)
which of the following data, the
measurement of g will be most 21. The equation of trajectory of an oblique
accurate
gx 2
projectile y 3x . The angle of
T n 2
projection is
(1) 5mm 0.2s 10
1) 30° 2) 45°
(2) 5mm 0.2s 20
3) 60° 4) 15°
(3) 5mm 0.1s 20
22. A boat is sent across a river with a velocity
(4) 1mm 0.1s 50 of 8 km/h. If the resultant velocity of the
boat is 10 km/h, the river is flowing with
18. The density of a solid ball is to be a velocity of
determined in an experiment. The
diameter of the ball is measured with 1) 12.8km/h 2) 6km/h
a screw gauge, whose pitch is 0.5mm
3) 8 km/h 4) 10 km/h
and there are 50 divisions on the
circular scale. The reading on the main 23. A river 500m wide is flowing at a rate of
scale is 2.5mm and that on the circular 4m/s. A boat is sailing at a velocity of 10
scale is 20 divisions. If the measured m/s with respect to the water, in a
mass of the ball has a relative error of direction perpendicular to the river. The
2%, the relative percentage error in time taken by the boat to reach the
the density is opposite bank
1) 30s 2) 40s
1) 0.9% 2) 2.4%
3) 50s 4) 60s
3) 3.1% 4) 4.2%
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24. The blocks A and B of masses 2m and 27. A man of mass m stands on a frame of
respectively, are connected by a massless mass M. He pulls on a light rope, which
and inextensible string. The whole passes over a pulley. The other end of
system is suspended by a massless spring the rope is attached to the frame. For the
as shown in the figure. The magnitudes system to be in equilibrium, what force
of acceleration of A and B, immediately must be man exert on the rope?
after the string is cut, are respectively
M m g
1) g, g / 2 2) g / 2, g 1) 2) M m g
2
3) g,g 4) g / 2, g / 2 3) M m g 4) M 2m g
28. Consider the situation as shown. The
25. A balloon with mass m is descending down maximum value of force F such that the
with an acceleration a (where a<g). How block does not move
much mass should be removed from it so
that i t starts moving up with an
acceleration a?
2ma ma
1) 2)
ga ga
1) 5 N 2) 10 N
ma 2ma
3) 4) 3) 15 N 4) 20 N
ga ga
29. Consider the situation as shown in the
figure. Choose the correct option
26. A block of mass m placed on a wedge of
inclination . The whole system is
accelerated horizontally so that the block
does not slip on the wedge. The force
exerted by the wedge on the block has a
magnitude
mg
1) mg 2) 1) The friction force on the block is 1 N if
cos
m = 0.1kg
3) mg cos 4) mg tan 2) The friction force on the block is 5 N if
m = 1.0kg
3) Both 1 and 2 are correct
4) Both 1 and 2 are incorrect
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30. A convey belt is moving at a constant 33. The power of a pump, which can pump
speed of 2m/s. A box is gently dropped 200 kg of water upto a height 200m in
on it. The coefficient of friction between 10s is
them is 0.5 . The distance that the 1) 40 kw 2) 80 kw
box will move relative to belt before
3) 400 kw 4) 960 kw
coming to rest on it, taking g = 10m/s2, is
34. A particle is released from the top of the
1) zero 2) 0.4m smooth hemisphere R as shown
3) 1.2m 4) 0.6m
h1 h 2 h1 h 2 3) mg 4 cos 3 4) mg 4 3 cos
2
1) Ag 2) Ag
2 2 35. A bucket tied at the end of a 1.6m long
string is whirled in a vertical circle with
constant speed. What should be the
h1 h 2 h1 h 2
2
minimum speed so that the water from
3) Ag 4) Ag the bucket does not spill, when the
4 4 bucket is at the highest position (Take
g = 10m/s2)
32. One end of a spring of natural length h
and spring constant k is fixed at the 1) 4 m/s 2) 6.25 m/s
ground and the other is fitted with a 3) 16 m/s 4) None of the above
smooth ring of mass m which is allowed 36. Consider the situation as shown in the
to slide on a horizontal rod fixed at a diagram. The bullet penetrates
height h (see the figure). Initially, the
spring makes an angle of 37° with the
vertical when the system is released
from rest. The speed of the ring when
the spring becomes vertical
h k h k 3M M
3) 4) 3) 2gL 4) 2gL
2 2m 4 2m 2m m
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37. A sphere A impinges directly on an 40. A sphere is rolling without slipping on a
identical sphere B at rest. If coefficient fixed horizontal plane surface. In the
of restitution is e, the ratio of velocities figure, A is the point of contact, B is the
of A and B after collision is center of the sphere and C is its topmost
point. Then
1 e 1 e
1) 2)
1 e 1 e
e 2e
3) 4)
1 e 1 e
(iv) V C V A 4 V B
3) 7:5 4) 5:7
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2G
1/2 1) –14.01 kJ 2) +18.02 kJ
2) m1 m2
r
3) +4.01 kJ 4) –8.02 kJ
1/2
r
3) 48. A stationary mass of gas is compressed
2G m1m 2 without friction from an initial state of
0.3 m3 and 0.105 M Pa to a final state of
1/2
2G 0.15 m3 and 0.105 M Pa. The pressure
4) m1m 2 remaining constant. During the process
r there is a transfer of 37.6 kJ of heat from
the system. During the process the
45. The escape velocity for a planet is v e . A amount of internal energy change is
tunnel is dug along a diameter of the
planet and a small body is dropped into it
at the surface. When the body reaches 1) –28.85 kJ
the centre of the planet, its speed will be
2) –21.85 kJ
ve
1) v e 2)
2 3) –21.85 MJ
ve
3) 4) zero 4) –53.35 kJ
2
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49. The heat of formation of C 2H 5OH(l) is 52. Two moles of NH 3 when put into a
–66 kcal/mol. The heat of combustion previously evacuated vessel (one litre)
of CH 3OCH 3(g) is –348 kcal/mol. Hf partially dissociate into N2 and H2. If at
equilibrium one mole of NH3 is present,
for H 2O and CO 2 are –68 kcal/mol and the equilibrium constant K C for the
–94 kcal/mol respectively. Then, the
reaction 2NH3(g ) N2(g ) 3H2(g ) is
H for the isomerisation reaction
C2H5OH CH3OCH3 (g) , and U
1) 3 4 mol litre
2 2
for the same are at T = 25°C
1) H 18 kcal / mol,
2) 27 64 mol litre
2 2
U 17.301kcal / mol
3) 27 32 mol litre
2 2
2) H 22 kcal / mol,
3) H 26 kcal / mol,
3) 62.5% 4) 64%
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55. Lemon juice normally has a pH of 2. If all 59. In context with the industrial preparation
the acid in the lemon juice is citric acid of hydrogen from water gas, which of the
and there are no citrate salts present, following is the correct statement?
then what will be the citric acid
concentration [HCit] in the lemon juice? 1) CO is oxidised to CO2 with steam in the
(Assume that only the first hydrogen of presence of a catalyst followed by
citric acid is important) absorption of CO2 in sodium arsenite
solution
HCit H Cit , K a 8.4 10 mol L
4 1
2) CO and H2 are fractionally separated
using difference in their densities
1) 8.4 10 4 M 2) 4.2 10 4 M
3) CO is removed by absorption in aqueous
Cu2Cl2
3) 16.8 104 M 4) 11.9 10 2 M
4) H2 is removed through occlusion with
56. In a saturated solution of the sparingly Pd
soluble salt AgIO3 (molecular mass = 283) 60. Hydrogen is evolved by the action of cold
the equilibrium which sets in is dilute HNO3 on
AgIO3 (s)
Ag (aq) IO3 (aq) . If the
1) Fe 2) Mg
solubility product constant Ksp of AgIO3 3) Cu 4) Al
at a given temperature is 1.0 10 8 , what 61. X-ray analysis of ice crystals shows that
is the mass of AgIO3 contained in 100 mL each oxygen atom is surrounded
of its saturated solution? 1) Octahedrally by six hydrogen atoms at
a distance of 95.7 pm
1) 28.3 102 g 2) 28.3 103 g
2) Tetrahedrally by four other oxygen
atoms at a distance of 276 pm
3) 1.0 10 7 g 4) 1.0 10 4 g
3) By two hydrogen atoms at a distance of
57. The pH of 0.02 M NH4Cl (aq) (pKb = 4.73) 98.8 pm
is equal to 4) Cubically by eight oxygen atoms at a
1) 3.78 2) 4.73 distance of 147.5 pm
62. When a substance A reacts with water it
3) 5.48 4) 7.00
produces a combustible gas B and a
58. One of the following is an incorrect solution of substance C in water. When
statement. Point out the incorrect one another substance D reacts with this
solution of C, it also produces the same
1) H2O2 decomposes rapidly in presence gas B on warming but D can produce gas
of MnO2 B on reaction with dilute sulphuric acid
at room temperature. A imparts a deep
2) Ice at its melting point is lighter than
golden yellow colour to a smokeless flame
water because ice crystals have hollow
of Bunsen burner. A, B, C and D
hexagonal arrangement of H2O molecules
respectively are
3) D2O will have maximum density at 1) K, H2, KOH, Al
284.2 K
2) Na, H2, NaOH, Zn
4) Water gas is a mixture of CO, H2 and
3) Ca, H2, Ca(OH)2, Sn
N2
4) CaC2, C2H2, Ca(OH)2, Fe
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63. When a crystal of caustic soda is exposed 69. The dissolution of Al(OH)3 by a solution of
to air, a liquid layer is deposited because NaOH results in the formation of
1) crystal melts
1) Al H2O 2 OH 4
2) crystal loses water
2
3) crystal absorbs moisture and CO2 2) Al H2O 4 OH
4) crystal sublimes
64. LiAlH4 is obtained by reacting an excess 3) Al H2O 3 OH 3
of .............. with an ethereal solution of
AlCl3 4) Al H2O 6 OH 3
1) LiCl 2) LiH 70. The number of OH units directly linked
3) Li 4) LiOH to boron atoms in Na2B4O7.10H2O is
65. The pair of compounds which cannot exist 1) 2 2) 3
together in solution is 3) 4 4) 10
1) NaHCO3 and NaOH 71. The soldiers of Napoleon army while at
Alphs during freezing winter suffered a
2) Na2CO3 and NaHCO3 serious problem with regard to the tin
3) Na2CO3 and NaOH buttons of their uniform. White metallic
tin buttons get converted to grey powder.
4) NaHCO3 and NaCl
This transformation is related to
66. Excess of dilute sodium hydroxide solution 1) an interaction with water vapour
is gradually added with shaking to an contained in humid air
aqueous solution of zinc sulphates. What
would you observe? 2) an interaction with N2 of air at low
temperature
1) A light blue precipitate is first formed
3) a change in the partial pressure of O2
which finally dissolves to give a deep blue
in air
solution
4) a change in crystalline structure of tin
2) A white precipitate appears which
dissolves to give a colourless solution 72. When CO is heated with NaOH under
pressure, we get
3) A white precipitate is formed which does 1) Sodium benzoate 2) Sodium acetate
not dissolve 3) Sodium formate 4) Sodium carbonate
4) No change takes place and the solution 73. For decolourization of 1 mole of KMnO4,
remains clear the moles of H2O2 required is
1) 1/2 2) 3/2
67. In India, at the occasion of marriages, the 3) 5/2 4) 7/2
fire works used give green flame. Which
one of the following metals may be present 74. 1mole MnO24 in neutral aqueous medium
as it salt in the gun powder used? disproportionate to
1) Na 2) K 1) 2/3 mole of MnO4 and 1/ 3 mole of
3) Ba 4) Ca MnO2
68. Which among the following hydrated 2) 1/3 mole of MnO4 and 2/3 mole of
halides undergo hydrolysis on heating? MnO2
1) BaCl2 . 2H2O 2) SrCl2.6H2O 3) 1/3 mole of Mn2O7 and 1/3 mole of
MnO2
3) CaCl2.6H2O 4) MgCl2.6H2O 4) 2/3 mole of Mn2O7 and 1/3 mole of
MnO2
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75. In a balanced equation H2SO4 + xHI H2S
+ yI2 + zH2O, the values of x,y, z are
80. IUPAC name of the compound is
1) x = 3, y = 5, z = 2 2) x = 4, y = 8, z = 5
3) x = 8, y = 4, z = 4 4) x = 5, y = 3, z = 4
1) Nonatetraene
76. Which of the following acid possesses
oxidising, reducing and complex forming 2) Diene pentadiene
properties? 3) 3,3-Diethenyl-1,4-pentadiene
1) HNO3 2) H2SO4 4) None of these
3) HCl 4) HNO2 81. The correct structure of 2-ethyl-3-
77. What is the oxidation number of Co in methylhex-1,4-diene
1) +5 2) +3 1) 2)
3) +4 4) +2
78. The IUPAC name of the alkane
3) 4)
is
4) 2,2,6,6,7-pentamethyloctane 1) COOH
2) 3,4,4-triethyl-2,2,5-trimethylhexane OH
3) 3,4-diethyl -4-isopropyl-2,2-
dimethylhexane COOH
4)
4) 3,3,4-triethyl-2,5,5-trimethylhexane
FT20C/TP/MOD/NEET/PCB/[A1] 12 Brilliant STUDY CENTRE
83. The medium present in the environment 87. The molar conductivity of an infinitely dilute
which consumes some amount of certain solution of NH 4 Cl is 150 Scm 2
pollutant is called a mol–1 and the ionic conductance at infinite
dilution of OH– and Cl– ions are 198Scm2
1) sink 2) target mol–1 and 76 Scm2 mol–1 respectively. If
3) receptor 4) none of these the molar condutance of a 0.01 M solution
of NH4OH is 9.6Scm2 mol–1. What will be its
84. Which of the following statements is true degree of dissociation?
about photochemical smong? 1) 0.0353 2) 0.0103
1) it is reducing in nature 3) 0.96 4) 0.414
2) it is formed in cool humid climate 88. Given
105. Identify the common respiratory pathway A) Substrate and inhibitor compete to
of both aerobic and anaerobic respiration: binds with active site of enzyme
1) Glycolysis 2) Krebs cycle B) Reversible process
3) Link reaction 4) All the above
C) Km value increases
106. How many tricarboxylic acids are formed
during in a single Krebs cycle: 1) A only 2) C only
1) Two 2) Three 3) B only 4) A, B and C
3) Four 4) Six
115. How many type of spindle fibres are
107. Apoenzyme is: formed during mitosis?
1) Protein part of conjugated enzyme
1) One 2) Two
2) Non- protein part of conjugated enzyme
3) Co-factor of conjugated enzyme 3) Three 4) Four
4) Both 2 and 3 116. In which order, cytokinesis occurs in
108. Product formed by the activity of malic plants:
dehydrogenase during krebs cycle:
1) Malic acid 2) Fumaric acid 1) Centripetal
3) Succinic acid 4) Oxalo acetic acid 2) Centrifugal
109. Substrate level ATP molecules gain during
3) Both centripetal and centrifugal
complete oxidation of one molecule of
glucose: 4) From periphery towards centre
1) 2 ATP 2) 4 ATP
117. Chromosomal disjunction is:
3) 12 ATP 4) 8 ATP
110. Identify the average composition of lipids 1) Separation of homologous chromosomes
in a cell: during Anaphase I
1) 1% 2) 2% 2) Separation of chromosomes during
3) 3% 4) 5-7% Anaphase II
111. How many of the following are secondary 3) Alignment of chromosomes at
metabolites metaphase plate during Metaphase I
A) Anthocyanins B) Scent
C) Abrin D) Codeine 4) Alignment of chromosomes at
Metaphase plate during Metaphase II
1) One 2) Two
3) Three 4) Four 118. Middle lamella contains more amount of:
112. Lactose contains: 1) Ca
1) Glucose and galactose 2) Mg only
2) Glucose and glucose 3) Ca and Mg are equal amount
3) Glucose and Fructose
4) Ca, Mg and Mn
4) Glucose and Maltose
FT20C/TP/MOD/NEET/PCB/[A1] 15 Brilliant STUDY CENTRE
119. Identity the main reason for the stability 125. Porins are present in:
of plasma membrane: 1) Plant cell wall
1) Phospholipid 2) Cholesterol 2) Gram -ve bacteria
3) Carbohydrate 4) Lecithin 3) All Eubacteria
4) Archaebacteria only
120. Identify the pleiomorphic and polymorphic
organelles respectively: 126. Tonoplast is
1) Semipermeable
1) Lysosomes and Golgi bodies
2) Selectively permeable
2) Golgi bodies and Lysosomes
3) Impermeable
3) Golgi bodies and Endoplasmic reticulum
4) Both 1 and 2
4) Lysosomes and Endoplasmic reticulum 127. Primary lysosomes are formed from:
121. Phagosomes / Heterophagosomes are: 1) Plasma membrane
1) Primary lysosomes 2) Nuclear membrane
2) Secondary lysosomes 3) Mitochondrial membrane
3) Tertiary lysosomes 4) Vescicles of golgi bodies
4) Cisternae 128. Microfilaments are responsible for:
122. Identify the organelle within an organelle: 1) contraction of muscles
1) Smooth endoplasmic recticulum
2) cyclosis
2) Microbodies
3) movement of microvilli
3) Ribosomes
4) all the above
4) Nucleus
129. Fluid Mosaic Model was proposed in:
123. Identify the arrangement of microtubules
in the basal body of Cilia in eukaryotes: 1) 1971 2) 1871
1) No definite arrangement 3) 1972 4) 1872
2) 9+0 130. Consider the following statements;
3) 9+2 A) In C4 plants, photosynthesis involves
4) Both 2 and 3 both C3 and C4 cycles.
124. Consider the following statements B) C4 cycle operates in both mesophyll
regarding chromatin fibre: and bundle sheath cells
A) DNA content is more amount than RNA C) In C4 plants, C3 cycle occurs only in
B) RNA content is more amount than DNA bundle sheath cells
C) Histone proteins are more amount than D) In C4 plants, six C4 and six C3 cycles
non-histone proteins are required for the synthesis of one
D) Non- histone proteins are more amount molecule of glucose
than histone proteins Of the above statements;
1) Only A is true 1) Only A and B are true
2) Both A and C are true 2) All except D are true
3) Only B is true 3) Only B is false
4) Only D is true
4) All statements are true
FT20C/TP/MOD/NEET/PCB/[A1] 16 Brilliant STUDY CENTRE
131. LHS includes: 140. Respiration and photosynthesis both
require:
1) Antenna pigments only
1) Green cells 2) Sunlight
2) Reaction centre only
3) Cytochromes 4) Ferredoxin
3) Both antenna and reaction centre
4) Both core pigments and reaction centre 141. Aquatic amphibians and chondrichthys:
3) Humerus >Ulna Radius > Carpals > 2) A negative feed back regulation
Metacarpals 3) A hormone that is involved in a positive
157. Which of the following is an unpaired facial feed back loop
bone? 4) The key role of neurohypophysis in
1) Temporal bone 2) Ethmoid bone regulating uterine contraction
1. 3
2. 4
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3. 3
4. 2
5. 1
6. 4
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7. 1
8. 1
9. 4
10. 2
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11. 3
12. 2
13. 2
14. 2
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15. 2
16. 1
17. 4
18. 3
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19. 2
20. 2
21. 3
22. 2
23. 3
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24. 2
25. 4
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26. 2
N cos mg
N mg
cos
27. 1
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28. 4
29. 3
30. 2
31. 2
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32. 2
mgh
33. 1 P
t
200 10 200
10
= 40000 = 40 kw
34. 2
35. 1
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36. 3
37. 1
38. 1
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39. 1
40. 2
41. 1
42. 4
43. 2
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44. 2
45. 2
CHEMISTRY
N 18 106 3 18 106 3
46. 1 W = –P V 105 0.99987 m 0.915 m
m2
= 105 1.67 10 6 Jm 0.167 J 0.17 J
P1 1
47. 3 W 2.303 nRT log ; So, w 2.303 1 8.314 300 log
P2 5
q 37.6 kJ
U W q 37.6 15.75 21.85 kJ
FT20C/TP/MOD/NEET/PCB/[A1] 14 Brilliant STUDY CENTRE
1
2C 3H2 O2 C 2H5OH ; H 66 kcal / mol
2
CH3 O CH3 3O2 2CO2 3H2O ...................(1)
H 348 kcal / mol ................................................(2)
1
C 2 O2 CO2
x
50. 2 Bon d en t h alpy (BE) of A 2 = x, AB = x and B2 =
2
1 1
A 2 B2 AB –100 kJ/mol–1 .......... (i)
2 2
1 1
A 2 O2 AO – 1200 kJ/mol (given)
2 2
A 2 O2 2AO –2400 kJ/mol ............ (ii)
51. 2
2SO2 (g) O2 2SO3 (g)
KP = 4.0 atm–2
SO3
2
KP =
SO2 O2
2
SO3 4
2
Given that at equilibrium the amount of SO2 and SO3 is the same so
SO2 O2
2
1
[O2] = 0.25 atm
4
Initial eqbm. 2NH3 N 2 3H2
52. 4
2 0 0
1 3
1
2 2
Therefore, G 2.303 8.314 298 log 2.47 10
0 29
G0 16,3000 J mol 1 163 kJ mol1
54. 2
2NH3 N2 3H2
Initial mole a 0 0
Mole at eqbm. (a 2x) x 3x
Initial pressure of NH3 of a mole = 15 atm at 27°C
The pressure of ‘a’ mole of NH3 = p atm at 347°C
15 P
; P 3atm
300 620
At constant volume and at 347°C, mole pressure
a 31 (before equilibrium)
a + 2x 50 (After equilibrium)
a 2x 50 19 2x
; x a ; % of NH3 decomposed = 100
a 31 62 a
2 19a
= 100 61.33%
62 a
FT20C/TP/MOD/NEET/PCB/[A1] 16 Brilliant STUDY CENTRE
C 11.9 102 M
56. 2 AgIO3(s) Ag aq IO3(aq )
104 283
S = 10–4 mol/litre = 100 283 105 = 2.83 103 g /100 mL
1000
1 1
57. 3 pH pK w pK b log C = 14 4.73 1og 0.02
2 2
1
= 14 4.73 1.698 5.48
2
58. 4
59. 1 The water gas is mixed with excess of steam and passed 450°C over a heated catalyst
(Fe2O3 + Cr2O3). CO is mostly oxidised to CO2 and more H2 is set free. CO2 is absorbed
in aqueous sodium arsenite
Water gas
60. 2 Only Mg react with cold dil. HNO3 to give H2.
61. 2 In ice crystals each oxygen atom is surrounded tetrahedrally by four oxygen atoms
at a distance of 276 pm.
67. 3 Na K Ba Ca Sr
OH
B
O O
HO B O B OH
O O
B
OH
71. 4 White tin crumbles into powder due to formation of grey tin at low temperature.
74. 1 MnO24 in neutral aqueous medium is disproportionate to 2/3 mole of MnO4 and 1/
3 mole of MnO2
75. 3 The values of x, y, z are 8, 4, 4 respectively hence the reaction is
H2SO4 8HI H2S 4I2 4H2O
76. 4 HNO2 (Nitrous acid) acid acts as an oxidising, reducing agent and has complex formation
properties
5 3
6 2 1
7
78. 4 8
4 2,2,6,6,7-Pentamethyloctane
Set or locants = 2, 2, 6, 6, 7
79. 2 The largest chain with maximum number of locants become the parent chain.
6
5
3 4
1 2
3,4,4-trimethyl-2,2,5-triethyl hexane
2 1
80. 3
5 4
2 4
3 6
5
81. 3 1
OH
2
3
COOH
82. 1
4
5
96500
1g of Al is obtained by passing a current of 3 C
27
96500
5.12 103 g of Al is obtained by passing a current of 3 5.12 1000
27
0 9.6
87. 1 N H4OH 150 76 198 272 ; 0.0353
272
2
Cr 3 0.1
2
0.0591 0.0591
E cell E 0
log 0.42 0.72 log
0.01
cell 3 3
6 Fe2 6
0.1
2
0.0591 0.0591
= 0.30 – log 3 = 0.30 log104 ; Ecell 0.2606 V
6 0.01 6
0.75 10 60
89. 3 2O2 O2 4e ; Mole of e = ;
96500
4.66 103
M ole of O 2 = 0.0261 L
4
2 4
90. 3 Al2O3 Al O2
3 3
2
Thus, 3 O2
3
BIOLOGY
91. 2 121. 2 150. 2
93. 4 152. 4
123. 2
94. 3 153. 3
124. 2
154. 2
95. 1
125. 2
155. 3
96. 1
126. 2
156. 3
97. 1
127. 4 157. 4
98. 1
128. 4 158. 1 Only a is correct; b,c & d are wrong
99. 1
129. 3 159. 2
100. 3
130. 4 160. 4
101. 4
161. 3
131. 1
102. 1
162. 3
132. 4
103. 4 163. 3 c and d are correct
104. 3 133. 2
164. 3
105. 1 134. 4
165. 1
106. 3 135. 2 166. 3
107. 1 136. 1 167. 2
108. 4 137. 3 168. 2
110. 2 170. 1
139. 1
111. 4 171. 1
140. 3
172. 3
112. 1
141. 3
173. 2
113. 2
142. 2
174. 1
114. 4
143. 2
175. 2
115. 3
144. 1
176. 1
116. 2
145. 4
177. 4
117. 1
146. 3
178. 2
118. 1 147. 2
179. 2
119. 2 148. 3
180. 3
120. 2 149. 3