SRI CHAITANYA EDUCATIONAL INSTITUTIONS, INDIA.

A.P,TELANGANA,KARNATAKA,TAMILNADU,MAHARASHTRA,DELHI,RANCHI,CHANDIGARH
CHEMISTRY SOLUTIONS
I. Types of Solutions :
1. Homogeneous system among the following is
(1) Milk (2) Sand in water (3) Urea in water (4) Benzene in water
2. List-1 List-2
A) Gaseous solution 1) German silver
B) Liquid solution 2) Milk
C) Solid solution 3) Sand in water
D) Colloidal solution 4) Aqueous alcoholic solution
5) Air
The correct match is
A B C D A B C D
1) 5 4 1 2 2) 1 3 2 5
3) 4 2 5 1 4) 2 3 1 4
3. Which one of the following is liquid in solid solution
(1) Camphor in N2 (2) Glucose in H2O (3) Hydrogen in palladium (4) Sodium
amalgam
II) Concentrations of Solutions :
A) Mass % :
 w
i.e., Wt %   =
Mass of solute w w
 % = × 100 × 100
 w Mass of solution  w  w +W
10% Glucose solution means 10 gm. of glucose dissolved in 100 gm. of solution (i.e.,
90 gm. of water)
4. The mass of sodium hypochlorite present in commercial bleaching solution ie.e 3.62
mass % is
(1) 3.62 (2) 1.81 (3) 7.24 (4) 0.905
5. The mass % of benzene ( C6 H 6 ) and carbon tetrachloride ( CCl4 ) if 22g of benzene is
dissolved in 122g of CCl4
(1) 15.3 & 15.3 (2) 84.7 & 84.7 (3) 15.3 & 84.7 (4) 84.7 & 15.3
B) Vol % :
v Vol. of solute v v
 % = × 100 , i.e., Vol %   = × 100
v Vol. of solution  v  v +V
10% alcohol solution means 10 ml. of alcohol dissolved in 100 ml. of solution. (i.e., 90 ml.
of water)
C) Mass by vol.
 w wt. of solute  w w
Percentage   % = × 100 , i.e.,   % = × 100
V  Vol. of solution V  V

1
 10% (w/v) Na2 CO3 solution means 10 gm. of Na2 CO3 dissolved in 100 ml. of solution.

Strength (or) Concentration :

wt. of solute (in gms ) wt. of solute (in gm.)
Conc. of solution = = × 1000 , Unit : gL−1
Vol. of solution (in lit.) Vol. of solution (in mL.)
6. KI in acidic medium is treated with 50 ml H2O2 . The liberated I2 require 20 ml of 0.1
N hypo. What is the strength of H2O2?
(1) 6.8 gm/lit (2) 0.68 gm/lit (3) 680 gm/lit (4) 68.0 gm/lit
N
7. 20ml of H2O2 is completely oxidized by 30ml acidified KMnO4 solution. The %
12
W 
  strength of H 2O2 solution is _____
V 
(1) 2.5 (2) 0.25 (3) 0.2125 (4) 0.225
8. 50ml of H 2O2 on decomposition gave 224 ml of O2 at STP. The strength of the solution
in g/lit.
(1) 13.6 gr/lit (2) 6.8 gr/lit (3) 1.7 gr/lit (4) 4.2 gr/lit
mass of solute
D) Parts per million parts (ppm) : ppm = × 106
mass of solution

1030g. of sea water i.e. 1 litre contains about 6 × 10 g of dissolved oxygen ( O2 ) . The
−3
9.
concentration in ppm is
(1) 5.8 (2) 6.8 (3) 4.8 (4) 8.5
10. Ten kg of water sample contain 81 mg of calcium bicarbonate. Degree of hardness of
water is
(1) 10 ppm (2) 5 ppm (3) 20 ppm (4) 15 ppm
11. 50ml of water sample requires 6 ml of soap solution to produce a good lather. 1 ml of
soap solution is equal to 0.001 g of CaCO3 . Then the degree of hardness of water is
(1) 120 ppm (2) 1.2 ppm (3) 12 ppm (4) 2. ppm
No.of moles of one component
E) Mole fraction : Mole fraction of a component =
Total no. of moles in the solution
No.of moles ofsolvent n1
Mole fraction of solvent = i.e., X1 =
Total no. of moles in the solution n1 + n2
No.of moles ofsolute n2
Mole fraction of solute = i.e., X2 =
Total no. of moles in the solution n1 + n2
Mole fraction of solution (or) a mixture = 1, i.e., X 1 + X 2 = 1
When molality is given, mole fraction of solute,
m X 2 × 1000
X2 = i.e., m =
1000 (1 − X 2 ) × M .W . of solvent
m+( )
M .W of solvent
X 2 = no. of moles of solute , X 1 = no. of moles of solvent

2
 m 55.5 × X 2
For an aqueous solution, X 2 = , m= i.e., X 1 = (1 − X 2 )
m + 55.5 X1
X 2 × 1000
m=
(1 − X 2 ) × M .W . of solvent
12. The mole fraction of ethylene glycol ( C2 H 6O2 ) in a solution containing 20% of
C2 H 6O2 by mass is
(1) 6.8 (2) 0.68 (3) 0.068 (4) 0.0068
13. What is the mole fraction of the solute in a 1.00 m aqueous solution ?
(1) 0.0354 (2) 0.0177 (3) 0.171 (4) 1.770
F) Molarity :
G 1000
M= ×
GMW V (ml )
G G × 1000
M × V (lit ) = = No. of moles ( or) M × V (ml ) = = No. of milli moles
GMW GMW
V (M − M 2 )
For dilute solutions, M 1V1 = M 2V2 Vol. of water to be added, V = ( V2 - V1 )= 1 1
M2
M 1V1 M 2V2 10 × d × wt %
For Neutralisation and Redox reactions, = ,M =
n1 n2 GMW
M 1V1 + M 2V2
When two similar solutions are mixed, then M =
V1 + V2
M aVa − M bVb
When acid is mixed with base,then M = ( if basicity of acid = acidity of base)
Va + Vb
14. The molarity of a solution containing 5g NaOH in 450 ml of solution is
(1) 0.278 (2) 2.78 (3) 27.8 (4) 0.722
15. 6.02 × 10 20 molecules of urea are present in 100 mL of its solution. The concentration
of solution is
(1) 0.1 M (2) 0.001M (3) 0.01M (4) 0.02M
16. The molarity of a solution containing 50g of NaCl in 500g of a solution and having a
density of 0.936 g/cm3 is
(1) 1.5 M (2) 1.6 M (3) 1.8M (4) 1.2 M
17. H 2 SO4 is labelled as 9.8% by weight. Specific gravity of H 2 SO4 is 1.8. The volume of
the acid to be taken to prepare 1000ml of 0.18M solution is
(1) 10 ml (2) 100 ml (3) 740 ml (4) 360 ml
G 1000
G) Molality : m = ×
GMW W ( g )
10 × S G × 100 G × 100
When Solubility is given m= , S= wt% =
GMW W (G + W )
1000 × Wt %
When Wt% is given , m =
(100 − Wt %) × GMW

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 1000 × M
When M and density are given m=
(1000 × d ) − ( M × GMW )
18. The molality of 2.5g of ethanoic acid ( CH 3COOH ) in 75g of benzene is
(1) 55.6 (2) 5.56 (3) 0.556 (4) 0.0556
19. 8g of NaOH is dissolved in 18g of H 2O . Mole fraction of NaOH in solution and
molality ()in mol kg-1) of the solutions respectively are :
(1) 0.167, 1.11 (2) 0.2, 22.20 (3) 0.2, 11.11 (4) 0.167, 22.20
20. The mass of urea ( NH 2CONH 2 ) present in 2.5kg of 0.25 molal aqueous solution
(1) 18.75 (2) 94 (3) 37.5 (4) 28.15
+
21. A solution of sodium sulphate contains 92g of Na ions per kilogram of water. The
molality of Na + ions in that solution in mol kg-1 is
(1) 16 (2) 8 (3) 4 (4) 12
III) Solubility :
I) Solibility of solid in liquid :
wt.of solute w
Solubility = × 100 i.e. S = × 100
wt of solvent W
II) Solubility of gas in liquids :
1 S1 P1 T2
S ∝ P, S ∝ i.e = ×
T S 2 P2 T1
Henry’s law :
p
p = K H .x ⇒ K H =
x
1 1
KH α , solubility α ∴ K H α T
x T
22. The no.of milli moles of N 2 gas dissolved in 1 lit. of water at 293k. partial pressure of
N2 is 0.987 bar Henris law constant (KH) for N2 at 293K is 76.48 K bar
(1) 0.716 (2) 3.58 (3) 7.16 (4) 0.358
23. Given that
Gas Henry’s law constant (Kb)
Ar 40.39
CO2 1.67

HCHO 1.83 × 10 −5
CH4 0.413
Which of the following is the correct order of increasing solubility?
(1) HCHO < CH 4 < CO2 < Ar (2) HCHO < CO2 < CH 4 < Ar
(3) Ar < CO2 < CH 4 < HCHO (4) Ar < CH 4 < CO2 < HCHO
24. On dissolving sugar in water at room temperature solution feels cool to touch. In
which of the following cases, dissolution of sugar will be most rapid?

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 (1) Sugar crystal in cold water (2) Sugar crystals in hot water
(3) Powdered sugar in cold water (4) Powdered sugar in hot water
IV. Vapor Pressure:
A) Vapor pressure of Liquid solutions :
 1 
Vapor pressure increases with increase in temperature i.e. V .P ∝ T ,  V .P ∝ 
 b. p 
−∆HVap / RT ∆H 1
Clausis & Clayperon eq.is P = A.e , log P = log A −
× ; y = c − mx
2.303R T
−∆Vap H P ∆HVap  1 1 
Slope m = , intercept , c = log A , log 2 =  − 
2.303R P1 2.303R  T1 T2 
1) Vapour pressure of Liquid – Liquid solutions:
For component 1, p1 ∝ x1 and p1 = p1 x1 , where p1 = Vapour pressure of pure component1
0 0

For component 2, p2 ∝ x2 and p2 = p2 x2 , where p1 = vapor pressure of pure component 2

0 0

pTotal = p1 + p2 , pTotal = p10 + x1 + p20 x2

( )
pTotal = p10 (1 − x2 ) + p20 x2 = p10 + p20 − p10 x2 ,
2) Vapour pressure of solid – Liquid solutions:
Raoult’s law :
Lowering of Vapor pressure = P0 − P (or) P1 − P1
0

P o1 − P1 W2 / M 2 P1o − P n2 W2 / M 2
RLVP, = X2 = for solute solutions, = =
P1 W1 / M1 + W2 / M 2 Po n1 W1 / M1
25. The vapor pressures of chloroform ( CHCl3 ) and dichromethane ( CH 2Cl2 ) at 298K
are 200 mm Hg and 415 mm Hg. The vapor pressure of solution containing 25.5g of
CHCl3 and 40g of vat 298K (Molar mass of CHCl3 = 119.5 and CH 2Cl2 = 85.4 )
(1) 173.9 (2) 615.0 (3) 347.95 (4) 247.95
26. The correct option for the value of vapor pressure of a solution at 45oC with benzene
to octane in molar ratio 3 : 2 is
[Ag 45oC vapor pressure of benzene is 280 mm Hg and that of octane is 420 mm Hg.
Assume Ideal gas]
(1) 168mm of Hg (2) 336 mm of Hg (3) 350 mm of Hg (4) 160 mm of Hg
B) Ideal and Non-ideal solutions
1) Ideal solutions : ∆H mix = 0 , ∆Vmix = 0 , ∆Gmix = Negtive −Ve , ∆S mix = +Ve
PA = PAo X A , PB = PBo X B , A − A, A − B, B − B interactions should be same.
Eg : Benzene + Toluene, 2) C2 H 5 Br + C2 H 5Cl 3) n-hexane + n – heptanes
27. Which one of the following is incorrect for ideal solution?
(1) ∆H mix = 0 (2) ∆Vmix = 0

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 (3) ∆P = Pobs − Pcalculated Raoult ' slaw = 0 ∆Gmix = 0 (4) ∆Gmix = 0
28. Which of the following will from in ideal solution?
(1) C2 H 5OH & water (2) HNO3 & water
(3) CHCl3 & CH 3COCH 3 (4) C6 H 6 & C6 H 5CH 3
29. The azeotropic mixture of water (b.pt.1200oC) and HCl (b.pt.85oC) boils at 108.5oC.
When this mixture is distilled, it is possible to obtain:
(1) Pure HCl (2) pure water
(3) pure water as well as water (4) neither HCl nor H 2O in their states
30. Liquids A and B form an ideal solution in the entire composition range. At 350 K, the
vapor pressures of pure A and pure B are 7 × 103 Pa and 12 × 103 Pa. respectively. The
composition of the vapor in equilibrium with a solution containing 40 mole percent of
A at this temperature is :
(1) x A = 0.37; xB = 0.63 (2) x A = 0.28; xB = 0.72
(3) x A = 0.76; xB = 0.24 (4) x A = 0.4; xB = 0.6
31. Two liquids X and Y form an ideal solution. The mixture has a vapor pressure of 400
mm at 300 K when mixed in the molar ratio f 1 : 1 and a vapor pressure of 350 mm
when mixed in the molar ratio o 1 : 2 at the same temperature. The vapor pressure of
the two pure liquids X and Y respectively are
(1) 250 mm, 550 mm (2) 350 mm, 450 mm (3) 350 mm, 700 mm (4) 550 mm, 250 mm
32. For an ideal solution, the correct option is
(1) ∆ mix H = 0 at constant T and P (2) ∆ mixG = 0 at constant T and P
(3) ∆ mix S = 0 at constant T and P (4) ∆ mixV ≠ 0 at constant T and P
2) +Ve deviation from Raoult’s law :
∆H mix > 0 or +ve, ∆Vmix > 0 or +ve , ∆Gmix = Negtive −Ve , ∆S mix = +Ve
PA > PAo X A , PB > PBo X B , A − B interactions are weaker than A-A, B-B
Eg: H 2O + C2 H 5 H , H 2O + CH 3OH , CH 3COCH 3 + C2 H 5OH , CH 3COCH 3 + CS 2
3) -Ve deviation from Raoult’s law :
∆H mix < 0 or -ve, ∆Vmix < 0 or -ve , ∆Gmix = Negtive −Ve , ∆S mix = +Ve
PA < PAo X A , PB < PBo X B , A − B interactions are songer than A-A, B-B
Eg: CHCl3 + CH 3COCH 2 , Phenol + Aniline, H 2O + HCl , H 2O + HNO3
V. Colligative properties:
M.W of solute can be calculated by using
P 0 − P W2 M 1 W2 × M 1 P0
A) RLVP: = × M2 = × 0
P0 M 2 W1 W1 P −P
P 0 (or) P0 = Vapour pressure of pure solvent, P (or) Ps = V.P. of solution,
W1 , M 1 are wt. and Mol.wt of solvent, W2 , M 2 are the wt. and Mol.wt of solute.

6
33. The vapor pressure of pure benzene is 0.850 bar 0.5g of non-volatile solute is added to
39.0g of benzene (molar mass 78 g mol-1) vapor pressure of solution is 0.845 bar, the
molar mass of solute is
(1) 170 g mol-1 (2) 340 g mol-1 (3) 85 g mol-1 (4) 255 g mol-1
34. Two liquids A and B form an ideal solution. At 300K, the V.P of solution containing
one mole of A and 4 mole ‘B’ is 560 mm Hg. At the same temp. It one mole of ‘B’ is
taken out from the solution the V.P of the solution has decreased by 10mm Hg the V.P
of pure A & B are (in mm)
(1) 400, 600 (2) 500, 500 (3) 300, 700 (4) 200, 800
35. At certain temperature, the solution of benzene in toluene exhibits the vapor pressure
(in m bar) represents as P = 150x+65, where ‘x’ is mole fraction of benzene, the vapor
pressure of pure benzene is
(1) 150 m bar (2) 65 m bar (3) 90 m bar (4) 215 m bar
36. A solution has 2:3 molar ratio of toluene to benzene. The vapor pressure of benzene
and toluene at 25oC are 28 and 95 bar respectively. The mole fraction of toluene vapor
is
(1) 0.658 (2) 0.326 (3) 0.548 (4) 0.855
B) Elevation in B.P :
W2 1000 W2 1000
∆Tb = K b × × M 2 = Kb × ×
M 2 W1 ∆Tb W1
∆Tb = Elevation of b.p, K b = molal elevation constant (or) Ebullioscopic constant of
solvent.
RTb o M 1 RTb o
Kb = = , ∆H vap W2 , M 2 , M are the wt. and Mol.wt of solute, W1 = wt.
1000 lv ∆H vap × 1000
of the solvent. R = gas constant, Tb = b.p. of pure solvent, Lv = Latent heat of
vapourisation of solvent in cals. / gm. Units of K b = K − kg mole −1 = Enthalpy of
vapourisation, M 1 = , M.W of solvent
37. If 18g of glucose ( C6 H12O6 ) dissolved in 1 kg of water, then the boiling point of
solution at 1.013 bar ( Kb of H 2O = 0.52 k k g mol − ) is (b.p of water is 373.15k)
(1) 373.0 (2) 373.15 (3) 373.1 (4) 373.202
38. The boiling point of benzene ( C6 H 6 ) is 353.23K when 1.8g of non-volatile solute was
dissolved in 90g of benzene, then boiling point raised to 354.1K, K b of benzene is
2.53 K kg mol-1 .
The molar mass of solute is
(1) 56.22 (2) 62 (3) 68 (4) 72
o
39. At 100 C the vapor pressure of a solution of 6.5gm of a solute in 100 gm of water is
732mm. If Kb = 0.52, the boiling point of this solution will be
(1) 102oC (2) 103oC (3) 101oC (4) 100oC
40. Which of the following solutions will exhibit highest boiling point?
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 (1) 0.01M Na2 SO4 (2) 0.01M KNO3 (3) 0.015 Murea (4) 0.015Mglucose
o
41. The normal boiling point of toluene is 110.7 C and its boiling point elevation constant
is 3.32K kg mol-1. The enthalpy of vaporization of toluene is nearly
(1) 17Kj mol-1 (2) 34 Kj mol-1 (3) 51 Kj mol-1 (4) 68 Kj mol-1
∆T f = K f × m , ∆ T f = T f − T f
o
C) Depression in F.P : ∆T f ∝ m
W2 1000 W2 1000
∆T f = K f × × M2 = K f × ×
M 2 W1 ∆T f W1
∆T f = Depression of f.p, K f = molal depression constant (or) Cryoscopic constant of
solvent. W2 , M 2 M are the wt. and mol. wt. of solute. is the wt. of solvent.
M 1 R ( To )
2
R(T f o )2
Kf = Kf = R = gas constant, Tf o = freezing point of solvent.
1000 L f ∆H fus ×1000
L f = Latent heat of fusion of solvent in cals / gm.. Units of K f = K − kg mole −1
∆H fus = Enthalpy of fusion, M 1 = M.W of solvent.

42. The freezing point depression constant ( K f ) of benzene is 5.12K kg mol −1 . The
freezing point depression for the solution of molality 0.078 m containing a non-
electrolyte solute in benzene is (rounded off upto two decimal places)
(1) 0.20 K (2) 0.80 K (3) 0.40 K (4) 0.60 K
43. Amount of ice that will separate out on cooling a solution containing 50g ethylene
glycol in 200g water to -9.3oC will be: (Kf for water = 1.86 K kgmol-1)
(1) 38.7g (2) 3.87 g (3) 83.7 g (4) 8.37 g
44. Calculate the molal depression constant of a solvent which has freezing point 16.6oC
and latent heat of fusion 180.75J/g.
(1) 2.68 (2) 3.86 (3) 4.68 (4) 2.86
D) Osmotic pressure : π = CST , ( π = CRT ) , C = molar conc. S = Solution constant
1
Boyle - van’t Hoff law : π ∝ C , at cons tan t temperature C∝ ,
V
1
π∝ ∴ π V = K ( PV = K ) Boyle’s law
V
Charle’s - van’t Hoff law : π ∝ T at constant concentration, π = KT , (V = KT)
Charle’s law.
1 T T
van’t Hoff equation for solutions : π ∝ , π ∝ T , π ∝ , π = S . , π V = ST
V V V
n
π ∝ CT , i.e., π = CRT (or) π = CST (or) π = MRT (or) π = RT
V
Plants take up water from soil through root hairs by the phenomenon Osmosis.
Haemolysis : When RBC placed in distilled water, it will enlarge and burst known as
haemolysis.

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 Plasmolysis : When RBC placed in Conc. solution of NaCl then it will shrink known as
plasmolysis.
P − P π ×M
0
P0 − P M
Relation between O.P and RLVP : 0
= ∴ 0
∝ π( = constant)
P dRT P dRT
 P 0 A − P A  dRT
Relation between O.P and C.P : i) π =  0 × ( R LV P)
 P A  MB
dRT dRT
ii) π = ∆Tb × ( E B P) , iii) π = ∆T f × ( D F P)
1000 K b 1000 K f
45. The following solutions were prepared by dissolving 10g of glucose ( C6 H12O6 ) in 250
ml of water ( P1 ) . 10g of urea ( CH 4 N 2O ) in 250 ml of water ( P2 ) and 10g of sucrose
( C12 H 22O11 ) in 250 ml of water ( P3 ) . The right option for the decreasing order of
osmotic pressure of these solutions is
(1) P2 > P1 > P3 (2) P1 > P2 > P3 (3) P2 > P3 > P1 (4) P3 > P1 > P2
46. The following solutions have equal concentrations. Which one will show minimum
osmotic pressure ?
(1) BaCl2 (2) AgNO3 (3) Na2 SO4 (4) ( NH 4 )3 PO4
47. 0.002 molar solutiuon of NaCl having degree of dissociation of 90% at 27oC has
osmotic pressure equal to
(1) 0.94 bar (2) 9.4 bar (3) 0.094 bar (4) 9.0 × 10 −4 bar
Determination of Molar mass of Solute :
a) Ostwald’s dynamic method : It is based on measuring RLVP of non-volatile solute.
y a W
For dilute solutions, = × , where x = Loss in wt. of solution bulbs,
x+ y M b
Loss in wt. of solvent bulbs, a = wt. of solute, b = wt.of solvent, M = M.W of solute
W = M.W of solvent.
b) Cottrell’s method : It is based on measuring elevation in B.P or depression in F.P.
Beckmann’s thermometer is used to measure elevation or depression in temperature (∆T )
a 1000 a 1000
, (−60 to 3000 C ) , ∆Tb = K b × × , M = Kb × ×
M b ∆Tb b
K b = molal elevation constant (or) ebullioscopic constant of solvent.
c) Rast’s method : It is used for solid solution i.e., solid solute in a solid solvent by
determining melting point by conventional method.
Camphor is used as a solvent.
a 1000 a 1000
∆T f = K f × × , M = Kf × × ,
M b ∆T f b
K f = molal depression constant (or) cryoscopic constant of solvent.
a = wt. of solute, b = wt. of Camphor, M = Mol. wt of solute.
d) Berkeley - Hartley method : It is used to measure Osmotic pressure of a solution.
9
 n
π = MRT (or) π =
RT
V
VI. Abnormal Molar mass :
π exp
π V = iRT (experiment), π V = RT ( calculated ) ∴
=i
π
experimental value of C.P calculated molar mass 1
i= , i= , Q C.P ∝
calculated value of C.P experimental molar mass Molar mass
1
Abnormal molecular masses and C.P : C .P ∝
molecular mass of solute
Normal M .m Observed value of C.P
van’t Hoff factor ‘i’ : i= ,i=
Observed M .m Normal value of C.P
For dissociation ( i>1), (1 − α ) ƒ nα ,
Total no. of particles after dissociation = (1 − α ) + nα = [1 + ( n − 1)α ]
(1 − α ) + nα i −1
i= , α=
1 n −1
where α =degree of ionisation, i = van’t Hoff factor n = no. of ions produced
α
For association (i<1), nA ƒ ( A) n , Total no. of particles after association = 1 − α +
n
α
(1 − α ) +
i = n (or) α = 1 − i
1 1
1−
n
48. The mixture that forms maximum boiling point azeotrope is
(1) Acetone + Carbon disulphide (2) Heptane + Octane
(3) Water + Nitric acid (4) Ethanol + Water
49. The van’t Hoff factor (i) for a dilute aqueous solution of the strong electrolyte barium
hydroxide is
(1) 0 (2) 1 (3) 2 (4) 3
50. Which one of the following electrolytes has the same value of van’t Hoff factor (i) is
that of Al2 ( SO4 )3 (if all are 100% ionized)?

(1) Al ( NO3 )3 (2) K 4  Fe ( CN 6 )  (3) K 2 SO4 (4) K 3  Fe ( CN 6 ) 

KEY
1) 3 2) 1 3) 4 4) 1 5) 3 6) 2 7) 3 8) 1 9) 1 10) 2

11) 1 12) 3 13) 2 14) 1 15) 3 16) 2 17) 2 18) 3 19) 1 20) 3

21) 3 22) 1 23) 1 24) 4 25) 3 26) 2 27) 4 28) 4 29) 4 30) 2

31) 4 32) 1 33) 1 34) 1 35) 4 36) 1 37) 4 38) 1 39) 3 40) 1

41) 2 42) 3 43) 1 44) 2 45) 1 46) 2 47) 3 48) 3 49) 4 50) 2

10