Akepox 5010 Komponente A SDB GB
Akepox 5010 Komponente A SDB GB
GHS09 environment
Aquatic Chronic 2 H411 Toxic to aquatic life with long lasting effects.
GHS07
GHS07 GHS09
(Contd. on page 2)
GB
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· Signal word Warning
· Hazard-determining components
of labelling: reaction product: bisphenol-A-(epichlorhydrin) epoxy resin (number average
molecular weight = 700)
Cyclohexanedimethanol diglycidyl ether
· Hazard statements H315 Causes skin irritation.
H319 Causes serious eye irritation.
H317 May cause an allergic skin reaction.
H411 Toxic to aquatic life with long lasting effects.
· Precautionary statements P101 If medical advice is needed, have product container or label
at hand.
P102 Keep out of reach of children.
P103 Read label before use.
P261 Avoid breathing vapours.
P273 Avoid release to the environment.
P280 Wear protective gloves/protective clothing/eye protection/face
protection.
P302+P352 IF ON SKIN: Wash with plenty of water.
P305+P351+P338 IF IN EYES: Rinse cautiously with water for several minutes.
Remove contact lenses, if present and easy to do. Continue
rinsing.
P333+P313 If skin irritation or rash occurs: Get medical advice/attention.
P337+P313 If eye irritation persists: Get medical advice/attention.
P501 Dispose of contents/container in accordance with local/
regional/national/international regulations.
· Additional information: Contains epoxy constituents. May produce an allergic reaction.
· 2.3 Other hazards
· Results of PBT and vPvB assessment
· PBT: Not applicable.
· vPvB: Not applicable.
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· After skin contact: If skin irritation continues, consult a doctor.
Immediately wash with water and soap and rinse thoroughly.
· After eye contact: Rinse opened eye for several minutes under running water. If symptoms persist,
consult a doctor.
· After swallowing: Rinse out mouth and then drink plenty of water.
· 4.2 Most important symptoms
and effects, both acute and
delayed Breathing difficulty
Coughing
Allergic reactions
· Information for doctor: Bisphenol-A based resins: Inhalation, swallowing or dermal incorporation may
cause health damage. Irritates respiratory tract, digestion system, eyes and skin:
e.g., cough, dyspnea, lacrimation, burning. May cause health interferences such
as dermal changes, renal, hepatic damage, and blood count changes. May
provoke skin allergies. Sensitized users can react towards very low
concentrations of Bisphenol-A-Epichlorhydrine and should avoid any further
contact with this chemical.
The sensitizing effect of epoxide based resins is mainly caused by the
concentration of epoxy resin polymers with a specific molecular weight 300.
The observed allergic dermal and respiratory appearances should be treated
symptomatically in dependence of the severity. An epoxy resin based allergic
disease belongs to a cell mediated (interaction of lymphocytes) type IV allergy.
· Hazards Danger of impaired breathing.
Skin contact with polyester and epoxy resin solutions as ingredient of the
product should be avoided due to risks of skin irritations or allergic skin
appearances. If occasional hand contact can not be avoided, protection gloves,
proper protection ointments and protective agents generating a protective layer
on the skin were applied.
· 4.3 Indication of any immediate
medical attention and special
treatment needed If swallowed, gastric irrigation with added, activated carbon.
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· 6.2 Environmental precautions: Do not allow to penetrate the ground/soil.
Do not allow product to reach sewage system or any water course.
Inform respective authorities in case of seepage into water course or sewage
system.
Do not allow to enter sewers/ surface or ground water.
· 6.3 Methods and material for
containment and cleaning up: Dispose of the material collected according to regulations.
Absorb with liquid-binding material (sand, diatomite, acid binders, universal
binders, sawdust).
Ensure adequate ventilation.
· 6.4 Reference to other sections See Section 7 for information on safe handling.
See Section 8 for information on personal protection equipment.
See Section 13 for disposal information.
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Inhalative DNEL (Kurzzeit-akut) 12.25 mg/m³ Air (ARB)
DNEL (Langzeit-wiederholt) 12.25 mg/m³ Air (ARB)
· PNECs
25068-38-6 reaction product: bisphenol-A-(epichlorhydrin) epoxy resin (number average molecular weight
= 700)
PNEC (wässrig) 10 mg/l (KA)
0.0006 mg/l (MW)
0.006 mg/l (SW)
0.018 mg/l (WAS)
PNEC (fest) 0.196 mg/kg Trockengew (BO)
0.0996 mg/kg Trockengew (MWS)
0.996 mg/kg Trockengew (SWS)
· Additional information: The lists valid during the making were used as basis.
· 8.2 Exposure controls
· Personal protective equipment:
· General protective and hygienic
measures: Do not eat, drink, smoke or sniff while working.
Use skin protection cream for skin protection.
Clean skin thoroughly immediately after handling the product.
Keep away from foodstuffs, beverages and feed.
Immediately remove all soiled and contaminated clothing
Wash hands before breaks and at the end of work.
Do not inhale gases / fumes / aerosols.
Avoid contact with the eyes and skin.
· Respiratory protection: Not necessary if room is well-ventilated.
Short term filter device:
Filter A/P2
In case of brief exposure or low pollution use respiratory filter device. In case of
intensive or longer exposure use self-contained respiratory protective device.
· Protection of hands: Preventive skin protection by use of skin-protecting agents is recommended.
After use of gloves apply skin-cleaning agents and skin cosmetics.
Protective gloves
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This recommendation refers exclusively to the material safety data
sheet referenced product delivered by Akemi and the indicated field of
application. In case of product dilution or in case of mixture with
different substances or chemicals, and in condition of EN374 deviation
the producer of CE-approved protection gloves must be contacted for
detailed information (e.g., KCL GmbH, Germany, 36124 Eichenzell,
internet: http://www.kcl.de).
· Material of gloves Butyl rubber, BR
Fluorocarbon rubber (Viton)
The selection of the suitable gloves does not only depend on the material, but
also on further marks of quality and varies from manufacturer to manufacturer.
As the product is a preparation of several substances, the resistance of the
glove material can not be calculated in advance and has therefore to be checked
prior to the application.
· Penetration time of glove material Value for the permeation: Level 6, 480 min
The exact break trough time has to be found out by the manufacturer of the
protective gloves and has to be observed.
· For the permanent contact gloves
made of the following materials are
suitable: Butyl rubber, BR
Butoject (KCL, Art_No. 897, 898)
Fluorocarbon rubber (Viton)
Vitoject (KCL, Art_No. 890)
· As protection from splashes gloves
made of the following materials are
suitable: Nitrile rubber, NBR
Dermatril (KCL, Art_No. 740, 741, 742)
Chloroprene rubber, CR
Camapren (KCL, Art_No. 720, 722, 726)
· Not suitable are gloves made of
the following materials: Leather gloves
Strong material gloves
· Eye protection:
Tightly sealed goggles
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· CMR effects (carcinogenity, mutagenicity and toxicity for reproduction)
· Germ cell mutagenicity Based on available data, the classification criteria are not met.
· Carcinogenicity Based on available data, the classification criteria are not met.
· Reproductive toxicity Based on available data, the classification criteria are not met.
· STOT-single exposure Based on available data, the classification criteria are not met.
· STOT-repeated exposure Based on available data, the classification criteria are not met.
· Aspiration hazard Based on available data, the classification criteria are not met.
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· European waste catalogue
20 00 00 MUNICIPAL WASTES (HOUSEHOLD WASTE AND SIMILAR COMMERCIAL, INDUSTRIAL AND
INSTITUTIONAL WASTES) INCLUDING SEPARATELY COLLECTED FRACTIONS
20 01 00 separately collected fractions (except 15 01)
20 01 27* paint, inks, adhesives and resins containing hazardous substances
· Uncleaned packaging:
· Recommendation: Empty contaminated packagings thoroughly. They may be recycled after
thorough and proper cleaning.
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· Stowage Category A
· 14.7 Transport in bulk according to Annex II of
Marpol and the IBC Code Not applicable.
· Transport/Additional information:
· ADR
· Limited quantities (LQ) 5L
· Excepted quantities (EQ) Code: E1
Maximum net quantity per inner packaging: 30 ml
Maximum net quantity per outer packaging: 1000 ml
· Transport category 3
· IMDG
· Limited quantities (LQ) 5L
· Excepted quantities (EQ) Code: E1
Maximum net quantity per inner packaging: 30 ml
Maximum net quantity per outer packaging: 1000 ml
· UN "Model Regulation": UN 3082 ENVIRONMENTALLY HAZARDOUS SUBSTANCE,
LIQUID, N.O.S. (REACTION PRODUCT: BISPHENOL-A-
(EPICHLORHYDRIN) EPOXY RESIN (NUMBER AVERAGE
MOLECULAR WEIGHT = 700)), 9, III
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