GRADE : 11

DURATION : 3 h
SUBJECT: CHEMISTRY
ANNUAL EXAM MARKS : 70

General instructions
1. There are 35 questions in this question paper with internal choice.
2. Section A consists of 18 multiple choice questions carrying 1 mark each.
3. Section B consists of 7 very short answer questions carrying 2 marks each.
4. Section C consists of 5 short answer questions carrying 3 marks each.
5. Section D consists of 2 case- based questions carrying 4 marks each.
6. Section E consists of 3 long answer questions carrying five marks each.
7. All questions are compulsory.
8. Use of log tables and calculators is not allowed.

SECTION A

1. What is the mass per cent of carbon in carbon dioxide?

(a) 0.034% (b) 27.27% (c) 3.4% (d) 28.7%
2. Two atoms are said to be isobars if
(a) they have same atomic number but different mass number.
(b) they have same number of electrons but different number of neutrons.
(c) they are same number of neutrons but different number of electrons.
(d) Sum of the number of protons and neutrons is same but the number of protons is different.
3. The number of radial nodes for 3p orbital is .
(a) 3 (b) 4 (c) 2 (d) 1
+ 2+ 2-
4. Consider the isoelectronic species, Na , Mg , F and O . The correct order of increasing length of
their radii is

5. Which of the following has the highest dipole moment?

(a) C02 (b) HI (c) H20 (d) S02
6. In an adiabatic process, no transfer-of heat takes place between system and surroundings. Choose
the correct option for free expansion of an ideal gas under adiabatic condition from the following.

7. When water freezes in a glass beaker, choose the correct statement amongst the following:
(a) ∆S(system) decreases but ∆S(surroundings) remains the same.
(b) ∆S(system) increases but ∆S(surroundings) decreases.
(C) ∆S(system) decreases but ∆S(surroundmgs) increases.
(d) ∆S(system) decreases but ∆S(surroundings) also decreases.

for the reaction NH4C1(s) ⇆ NH3(g) + HCl(g)?

8. We know that the relationship between Kc and Kp is Kp = Kc(RT)∆n What would be the value of Δn

(a) 1 (b) 0.5 (c) 1.5 (d) 2

9. Which of the following is the strongest oxidizing agent. E° values: Fe3+/Fe2+ = +0.77; I2(g)/I =
+0.54;Cu2+/Cu = +0.34; Ag+/Ag = +0.80 V
(a) Fe3+ (b) I2(g) (c) Cu2+ (d) Ag+
 10. Which of the following is the correct IUPAC name?
(a) 3-Ethyl-4,4-dimethylheptane (b) 4,4-Dimethyl-3-ethylheptane
(c) 5-Ethyl-4,4-dimethylheptane (d) 4,4-Bis(methyl)-3-ethylheptane
11. In which of the following compounds, the carbon marked with asterisk is most electronegative?

12. In which of the following, functional group isomerism is not possible?

(a) Alcohols (b) Aldehydes (c) Alkyl halides (d) Cyanides
13. Which of the following will not show geometrical isomerism?

14. Which of the following reactions of methane is incomplete combustion?

Direction : (Q. nos, 15-18) Each of these questions contain two statements, Assertion and Reason. Each of
these questions also has four alternative choices, only one of which is the correct answer. You have to select
one of the codes (a), (b), (c) and (d) given below.
(a) Assertion is correct, reason is correct; reason is a correct explanation for assertion.
(b) Assertion is correct, reason is correct; reason is not a correct explanation for assertion
(c) Assertion is correct, reason is incorrect
(d) Assertion is incorrect, reason is correct.

15. Assertion: Combustion of 16 g of methane gives 18 g of water.

Reason: In the combustion of methane, water is one of the products.

16. Assertion: Boron has a smaller first ionization enthalpy than beryllium.
Reason : The penetration of a 2s electron to the nucleus is more than the 2p electron, hence, 2p
electron is more shielded by the inner core of electrons that the 2s electrons.

17. Assertion: Electron gain enthalpy becomes less negative as we go down a group.
Reason : Size of the atom increases on going down the group and the added electron would be
farther from the nucleus.

18. Assertion : For any chemical reaction at a particular temperature the equilibrium constant is fixed and is a
characteristic property.
Reason : Equilibrium constant is independent of temperature.

SECTION B

19. Give differences between Molarity and Molality.

20. State (a) Heisenber’s uncertainty principle. (b) Hund’s rule
21. Give differences between bonding and antibonding molecular orbitals.
22. What will be the enthalpy change for the following reaction?
H2(g) + Br2(g)→2HBr(g) Given that bond energy of H2, Br2 and HBr is 4.35 kJ mol-1, 192
kJ mol-1 and 368 kJ mol-1 respectively.
23. Calculate the volume of water required to dissolve 0.1 g lead (II) chloride to get a saturated
solution. (Ksp of PbCl2 = 3.2 x 10-8, atomic mass of Pb = 207 u).
24. Explain Friedel – Craft’s acylation of benzene.
25. Draw Newman projection formula for eclipsed and staggered form of ethane.

SECTION C

26. Define : (i) Mole (iii) Molality (iii) Mole fraction

27. Give postulates of Valence bond theory.
OR
Explain electronic configuration, bond order and magnetic property of Oxygen molecule.

28. (i) Define Le Chatelier’s principle.

(ii) Following reactions occur in a Blast furnace.
Fe2O3(s) + 3CO(g) ———–>2Fe(s) + 3CO2(g)
use Le chatelier’s principle to predict the direction of reaction when equilibrium mixture is disturbed
by (a) adding Fe2O3 (b) removing CO.
29. Balance the redox reaction using ion electron method in acidic medium.
Mn0–4 reacts with sulphur dioxide gas in acidic medium to produce Mn2+ and hydrogensulphate ion.
30. Explain partition chromatography.
OR
Explain fractional distillation with diagram.

SECTION D

31. In addition to displaying the classification of elements into s-, p-, d-, and f-blocks, another
broad classification of elements based on their properties is available. The elements can be divided
into Metals and Non-Metals. Metals comprise more than 78% of all known elements and appear on
the left side of the Periodic Table. Metals are usually solids at room temperature Metals usually
have high melting and boiling points. They are good conductors of heat and electricity. They are
malleable (can be flattened into thin sheets by hammering) and ductile (can be drawn into wires).
In contrast, non-metals are located at the top right hand side of the Periodic Table.

1. The elements in which electrons are progressively filled in 4f-orbital are called
2. Al3+ < Mg2+ < Na+ < F– (increasing ionic size) . True / false
3. How does metallic nature vary down the group?
4. Arrange the elements N, P, O and S in the order of increasing non-metallic character.

32. Aromatic hydrocarbon are also known as ‘arenes’. Since most of them possess pleasant odour
(Greek; aroma meaning pleasant smelling), the class of compounds was named as ‘aromatic
compounds’. Most of such compounds were found to contain benzene ring. Benzene ring is highly
unsaturated but in a majority of reactions of aromatic compounds, the unsaturation of benzene ring
is retained. However, there are examples of aromatic hydrocarbons which do not contain a benzene
ring but instead contain other highly unsaturated ring. Aromatic compounds containing benzene
 ring are known as benzenoids and those not containing a benzene ring are known as non-
benzenoids.
1. Write equation for sulphonation of benzene.
2. Write equation for the conversion of phenol to benzene.
3. How is benzene obtained from alkane?
4. How is benzene converted to BHC.
SECTION E

33. a) Complete the following table:

b) Calculate energy of one mole of photons of radiation whose frequency is 5 ×1014 Hz.

34. a) State i) Hess’s law ii) third law of thermodynamics iii) Extensive property.
b)

35. a) Give differences between inductive and resonance effect.

b) Explain test for detection of phosphorus.