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Assignment - 1 Chemical Kinetics (Physical Chemistry)

The document contains practice questions and answers related to chemical kinetics, covering topics such as reaction rates, order of reactions, and rate constants. It includes multiple-choice questions with specified reactions and calculations. An answer key is provided at the end for self-assessment.

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nishkersh.physics
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13 views2 pages

Assignment - 1 Chemical Kinetics (Physical Chemistry)

The document contains practice questions and answers related to chemical kinetics, covering topics such as reaction rates, order of reactions, and rate constants. It includes multiple-choice questions with specified reactions and calculations. An answer key is provided at the end for self-assessment.

Uploaded by

nishkersh.physics
Copyright
© © All Rights Reserved
We take content rights seriously. If you suspect this is your content, claim it here.
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Download as PDF, TXT or read online on Scribd
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BANSAL ACADEMY CHANDIGARH

SCF-19, Sector 16-D, Chandigarh

Chemical Kinetics
Practice: 1

Q1. For an elementary reaction 2A + B → 3C the Q6. If the value of rate constant of a reaction
rate of appearance of C at time‘t’ is
−4 −1 −1
2 10−3 sec-1, then reaction will be
1.3 10 mol L S . Calculate at this time rate of 1. 1st order 3. 2nd order
reaction and rate of disappearance of A. 2. zero order 4. 3rd order

Q7. If the rate of reaction becomes four times when


concentration of reactant is doubled, then what will
Q2. In the reaction 2A 2 + B2 → 2A 2 B the reactant
be the order of the reaction
A will disappear at 1. 1 2. 2 3. 3 4. 4
1. Half the rate that B will decrease
2. Same the rate that B will decrease Q8. For a reaction having rate law expression
3. Double the rate that A2B will form
Rate = k  A   B
3/2 -1/2
4. Twice the rate that B will decrease . If concentration of both A
and B becomes four times, the rate of reaction
1. becomes 4 times 3. Decreases four times
Q3. In a reaction of acidified H2O2 with Kl, the 2. becomes 16 times 4. Remains same
concentration of l2 formed rises from 0 to 10-5 mol
dm-3 in 10 sec. The rate of reaction is
−6 -3 -1 −4 -3 -1 Q9. A first order reaction is 50% completed after 32
1. 10 mol dm s 3. 10 mol dm s
−5 -3 -1 −3 -3 -1
min, then 75% of the reaction will be completed in
2. 10 mol dm s 4. 10 mol dm s 1. 24 min 3. 8min
2. 32 min 4. 64min
Q4. For the reaction which of the following does not
express the reaction rate? Q10. The half life of a 1st order reaction having rate
d C  d  D −5 −1
constant k = 1.7  10 sec is
1. − 3.
3dt dt 1. 12.1 hrs 3. 11.3 hrs
d  B d  A 2. 9.7 hrs 4. 1.8 hrs
2. − 4. −
dt 2dt

Q5. The decomposition of dimethyl ether leads to the


formation of CH4, H2 CO and the reaction rate is
3/2
given by Rate = k  PCH3OCH3  . If the pressure is
measured in bar and time in minutes then what are
the units of the rate of reaction and rate constants?
BANSAL ACADEMY CHANDIGARH
SCF-19, Sector 16-D, Chandigarh

ANSWER KEY :

1. 4.33 10−5 mol L-1S-1;8.66 10−5 mol L-1S-1


2. Option 4
3. Option 1
4. Option 1
5. bar-1/2 min-1
6. Option 1
7. Option 2
8. Option 1
9. Option 4
10.Option 3

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