JEE Adv 2018

In the following reaction sequence, the amount of D (in gram) formed from 10 moles of
acetophenone is …............................
(Atomic weights in g mol–1 : H = 1, C = 12, N = 14, O = 16, Br = 80. The yield (%)
corresponding to the product in each step is given in the parenthesis)
O

NaOBr NH3 Br2/KOH Br2(3 equivalent)

A B C D
H2O+ ∆ AcOH
(60%) (50%) (50%) (100%)

[Ans : 495]
QUESTION

The number of ethoxy groups in an organic compound can be determined by the

following reactions.
R(OCH2CH3)x + xHI → R(OH)x + xCH3CH2I
CH3CH2I + Ag+ + H2O → CH3CH2OH + AgI(s) + H+
When 37 g of organic compound (molar mass = 176 g/mol) was treated as above, 148 g
Agl was precipitated out. How many ethoxy groups are present in each molecule of the
organic compound? (Ag = 108, I = 127)
 JEE Adv. 2022

The treatment of an aqueous solution of 3.74 g of Cu(NO3)2 with excess KI results

in a brown solution along with the formation of a precipitate. Passing H2S through
this brown solution gives another precipitate X. The amount of X (in g) is__________.
[Given: Atomic mass of H = 1, N = 14, O = 16, S = 32, K = 39, Cu = 63,1 = 127]

[Ans : 0.32 g]
 JEE Adv. 2016

The mole fraction of a solute in a solution is 0.1 .At 298K,molarity of this solution is the
same its molality. Density of this solution at 298K is 2.0 g ml .The ratio of the molecular
weights of the solute and solvent, is
QUESTION

Two substance A2 and B2 react in the above manner when A2 is limited it gives A2B4,
when in excess gives A3B4, A2B4 can be converted to A2B4 when reacted with A2
Using this information calculate the composition of the final mixture when
mentioned amount of A2 and B2 are taken
(i) If 4 moles of A2 and 4 moles of B2 is taken in reaction container
1
(ii) If moles of A2 & 2 moles of B2 is taken in reaction container
2
5
(iii) If moles of A2 s 2 moles of B2 is taken
4
Comprehension - II

The vapour density of a gaseous mixture containing only Ar and N2O4 gases, is 40.
When the mixture is left for some time, the vapour density decreased and finally
becomes 37.5. It happened due to dissociation of some N2O4 into NO2. (Ar = 40)
QUESTION

What is the degree of dissociation of N2O4?

A 0.086

B 0.133

C 0.067

D 0.0625
Comprehension - II

The vapour density of a gaseous mixture containing only Ar and N2O4 gases, is 40.
When the mixture is left for some time, the vapour density decreased and finally
becomes 37.5. It happened due to dissociation of some N2O4 into NO2. (Ar = 40)
QUESTION

What is the initial mole ratio of Ar and N2O4?

A 1:1

B 3 : 10

C 1:3

D 1:5
Comprehension - II

The vapour density of a gaseous mixture containing only Ar and N2O4 gases, is 40.
When the mixture is left for some time, the vapour density decreased and finally
becomes 37.5. It happened due to dissociation of some N2O4 into NO2. (Ar = 40)
QUESTION

What is the final mole ratio of Ar, N2O4 and NO2?

A 1:1:1

B 1 : 3 : 11

C 45 : 137 : 26

D 4 : 13 : 3
QUESTION

Column I Column II

(A) 20 V H2O (P) 1.78 M

(B) 17.45% w/v H2SO4 (Q) 60.7 g/L

(C) Pure water (R) 1.5 M

(D) 5% w/w NaOH (d / 1.2 g/ml) (S) 55.5 M

QUESTION

One litre of milk weighs 1.035 kg. The butter fat is 10%(v/v) of milk has density of 875
kg/m3. The density of fat free skimmed milk is?
QUESTION

A quantity of 720 g water is added in 230 g ethanol at a certain temperature to get 11 of

solution. Which of the following is/are correct regarding the solution formed?

A The density of solution is 950 kg/m3.

B The mole fraction of ethanol is 0.11.

C The molarity of solution is 5 M.

D The molality of solution is 6.94 M.

QUESTION

PCl5 + H2O H3PO4 + HCl

nH3PO4 (HPO3)n + nH2O

The mass of PCl5 is required to prepare 320 gm of cyclic meta phosphoric acid ( HPO3)n is

A 208.5 gm

B 417 gm

C 1042.5 gm

D 834 gm
 JEE Adv 2016
The mole fraction of a solute in a solution is 0.1. At 298 K, molarity of this solution is
the same as its molality. Density of this solution at 298 K is 2 g cm–3. The ratio of the
𝑚𝑚𝑠𝑠𝑠𝑠𝑠𝑠𝑠𝑠𝑠𝑠𝑠𝑠
molecular weights of the solute and solvent, is ….
𝑚𝑚𝑠𝑠𝑠𝑠𝑠𝑠𝑠𝑠𝑠𝑠𝑠𝑠𝑠𝑠

[Ans : 9]
 JEE Adv 2018
Galena (an ore) is partially oxidized by passing air through it at high temperature.
After some time, the passage of air is stopped, but the heating is continued in a closed
furnace such that the contents undergo self-reduction. The weight (in kg) of Pb
produced per kg of O2 consumed is
(Atomic weights in g/mol : O = 16, S = 32, Pb = 207)

[Ans : 6.47 Kg]

Comprehension - I

The first concept of atomic weight was given by Dalton. He defined that the absolute
mass of an atom cannot be determined but we may compare the masses of atoms of
different elements, perfectly, by knowing the chemical formula and percentage
composition, by mass, of the compound formed by the elements concerned. The
chemical or molecular formula can be determined with the help of Avogadro's
hypothesis that is, under the similar conditions of pressure and temperature, equal
volume of all the gases have equal number of molecules. Dalton defined the atomic
weight of an element as the number of times by which one atom of the element is
heavier than one atom of hydrogen. In order to determine the atomic weight of
nitrogen, the following data are observed by experiments, for a compound containing
only nitrogen and hydrogen atoms:
Data I : The compound contains 88% nitrogen and 12% hydrogen, by mass.
Date II : 10 ml of this gaseous compound exactly gives 10 ml nitrogen and 20 ml
hydrogen, on complete decomposition. (All volumes are at the same
temperature and pressure)
QUESTION

What is the molecular formula of the compound if nitrogen and hydrogen,

both are diatomic?

A NH3

B N2H4

C N4H2

D N2H2

[Ans : B ]
QUESTION

What is the atomic weight of nitrogen on this hydrogen scale?

A 14

B 14.67

C 14.33

D 13.67

[Ans : B ]
QUESTION

What would the molecular formula of the compound if nitrogen were

triatomic and hydrogen were diatomic?

A NH3

B N3H4

C N4H3

D N3H2

[Ans : B ]
QUESTION

A graph is plotted for an element, by putting its mass on X-axis and the
corresponding number of number of atoms on Y-axis. What is the atomic mass of the
element for which the graph is plotted? (NA = 6.0 × 1023)

A 80

B 40

C 0.025

D 20

[Ans : B ]
 JEE Adv 2022
Dissolving 1.24 g of white phosphorus in boiling NaOH solution in an inert atmosphere
gives gas Q. The amount of CuSO4 (in g) required to completely consume the gas Q is
______________.
[Give : Atomic mass of H = 1, O = 16, Na = 23, P = 31, S = 32, Cu = 63]

[Ans : 2.385 g ]
Comprehension - II

Crude calcium carbide is made in an electric furnace by the reaction :

CaO + 3C → CaC2 + CO ↑
The product contains 80% CaC2 and 20% unreacted CaO.
QUESTION

How much CaO is to be added to the furnace charge for each 1280 kg of pure CaC2
produced?

A 1120 kg

B 1440 kg

C 1152 kg

D 1344 kg
Comprehension - II

Crude calcium carbide is made in an electric furnace by the reaction :

CaO + 3C → CaC2 + CO ↑
The product contains 80% CaC2 and 20% unreacted CaO.
QUESTION

How much CaO is to be added to the furnace charge for each 1280 kg of crude product?

A 1120 kg

B 1440 kg

C 1152 kg

D 1344 kg
Comprehension - II

Crude calcium carbide is made in an electric furnace by the reaction :

CaO + 3C → CaC2 + CO ↑
The product contains 80% CaC2 and 20% unreacted CaO.
QUESTION

What will be the volume of CO gas evolved, measured at 0°C and 1 atm, when 1280 kg
of crude product is formed?
A 448 m3

B 358.4 m3

C 537.6 m3

D 89.6 m3
Question
A sample of iron ore contains FeS and non-volatile inert impurity only. Roasting of this
ore converts all FeS into Fe2O3 and a 4% loss in weight was observed. If the mass
𝑥𝑥
percent of FeS in the ore is ‘x’, then the value of is (Fe = 56)
11