SEDE LEGALE, AMMINISTRATIVA: Via Vittorio Veneto 6, 24060 Sarnico (BG)

Cap. Soc. € 10000 Cod. Fisc. 07732210963 P. IVA . 07732210963

Iscr. Reg. Imprese MI R.E.A. MI 1978346

Date: 23/09/2020

Attn: QUALITY DEP.

Dear Customer,

Here attached you can find the MSDS documents please read with attention this document before use the products.
Please send us via email a copy of this document with stamp and sign.
Thank you.

Safety & Environment

Compilato da: ALGISI GIORGIO

Data: 23/09/2020

Timbro e firma: ALGISI GIORGIO

Safety & Environment

e-mail: info@poliplasticsrl.com

COMPANY IDENTICATION

- Company name: POLIPLASTIC S.R.L

- Address : Via Padania, 24060 Villongo (BG)
- Telephone: +39 3280507271

EMERGENCY CALL

- Telephone: +39 3280507271

1) MATERIAL IDENTIFICATION

- Trade name: TRAMIDE

- Grades: ALL GRADES
- Structural formula (polymer): not applicable
- CAS Name:
- CAS Number: 25038-74-8
- EINECS Number: Not Assigned
- ELINCS Number: Not Assigned
- INDEX Number: Not assigned

2) COMPOSITION OF POLYMER
 Substances with established exposure limits or classifiable as dangerous according to EC directive 67/548 and
following amendments, in concentration equal or higher than that reported in EC directive 88/379 (item.3,
sect.6)

NAME
Polyamide
Stabilizer,others

CONCENTRATION
80-100%
0-20%

CAS Number
24937-16-4

STRUCTURAL FORMULA

RISK PHRASES
…

3) HAZARD IDENTIFICATIONS

- 3.1 ADVERSE HUMAN HEALTH EFFECTS

The product is an inert polymer, which is not dangerous for the human health
- 3.2 MAIN SYMPTOMS
See section 4
- 3.3 ENVIRONMENTAL EFFECTS
Environmental pollution only in case of emission of toxic and corrosive gases following thermal
decomposition
- 3.4 PHYSICAL AND CHEMICAL HAZARDS
Toxic and corrosive gases are released in thermal decomposition

4) FIRST-AID MEASURES

- 4.1 SYMPTOMATOLOGY FOLLOWING EXPOSURE TO PRODUCTS OF THERMAL DECOMPOSITION

-Inhalation: Headache, short breathing, cough, tachycardia
-Eye contact: Redness, irritation, burns
-Skin contact: Redness, irritation, burns

- 4.2 FIRST-AID MEASURES IN CASE OF EXPOSURE TO GASES FROM THERMAL DECOMPOSITION

-Inhalation: Move immediately affected person to fresh air.
Seek medical attention immediately.
If not breathing, supply artificial respiration, preferably mouth to mouth.
In case of difficult Breathing, give oxygen.
The symptoms by inhalation of thermal decomposition products do not occur until several Hours
after exposure
Keep the affected person under medical observation for at least 48 hours.
A timely medical attention is absolutely required.
-Eye Contact: Flush immediately and copiously with water for at least 15 minutes.
Seek medical attention in case burns continues.

-Skin Contact: Wash immediately with water and soap.

Seek medical attention in case burns continues.

5) FIRE FIGHTING MEASURES

- 5.1 SPECIFIC HAZARDS
The product is neither flammable nor explosive
 In The event of fire, corrosive and toxic gases from thermal decomposition may be formed
- 5.2 SPECIFIC METHODS
In case of surrounding fire, if possible, remove the containers in a safety place.
To do only if in safe condition (safety distance from the flames and staying upwind)
In case of impending fire, Keep containers cool by spraying with water.
- 5.3 EXTINGUISHING MEDIA
Water (spray, fog, stream), CO2, chemicals in powder or foam.
- 5.4 PROTECTION OF FIRE-FIGHTERS
Self contained breathing apparatus
Full anti-acid clothing

6) ACCIDENTAL RELEASE MEASURES

- 6.1 PERSONAL PRECAUTIONS

Keep away from hot surfaces and flames
Stop the release as soon as possible, in safe conditions.
- 6.2 ENVIRONMENTAL PRECAUTIONS
Avoid uncontrolled discharge of the product in the soil and underground waters.
- 6.3 METHODS FOR CLEANING UP
Sweep and scoop out the released material, collecting it in suitable container for re-use or disposal according
To applicable regulations.

7) HANDLING AND STORAGE

- 7.1 HANLING
7.1.1 Precautions
Wear suitable protective clothing (see par 8)
Avoid processing above decomposition temperature without adequate ventilation.
Keep attention that particles of product coming from hands or from garments will not become in
Contact with materials or substances that could be burnt. (ex cigarettes, tobacco)
Clean facilities (pipe, vessels) before any discontInuous operations
7.1.2 SECURITY MEASURES
In working areas where the materials are handled at temperatures higher than 350°C appropriate
Exhaust ventilation and smoke down bringing are required.
- 7.2 STORAGE
7.2.1 Storage conditions
Keep away from sparks and flames, hot surfaces and inflammable materials.
Do not store near incompatible materials (see par 10)
7.2.2 Packing
Paper-alluminium-polyethilene bags or plastics drums.

8) EXPOSURE CONTROLS / PERSONAL PROTECTION

- 8.1 EXPOSURE LIMITS ACGIH 2003

Total dust TLV/TWA 10 mg/mc
HF TLV/CEILING 2.6 mg/mc 3ppm
COF2 TLV/STEL 13.5 mg/mc 5ppm
- 8.2 TECHNICAL MEASURES
Adequate local exhaust ventilation is required in case of high temperature processing
- 8.3 PERSONAL PROTECTIVE EQUIPMENT
8.3.1 Respiratory protection
Dust safety masks, self-contained breathing apparatus in case of fire
8.3.2 Hand protection
Latex gloves or similar
8.3.3 Eye and body protection
 In case of high dust concentration wear safety goggles and appropriate worksuite/overalls.
8.3.4 Measures
Do not eat, drink or smoke while handling the product.

9) PHYSICAL AND CHEMICALS PROPERTIES

Physical state solid pellet

Odour oudourless
Colour Natural
Bulk density 1-1.05 g/cm3 (30°C)
Melting point 215-225°C
Decomposition Temperature >350°C
Autoignition temperature 370-450°C
Ph not applicable
Boiling point not applicable
Flash point not flammable
Explosion properties not explosive
Oxidising properties not oxidiser
Vapour pressure not applicable
Vapour density not applicable
Solubility in water 20° insoluble
Solubility in organic solvent soluble in phenols, metacresol, benzyl alchol, formic acid, sulphuric

10) STABILITY AND REACTIVITY

- 10.1 STABILITY
The product is stable in normal condition of use and storage
- 10.2 CONDITION TO AVOID
Avoid heating the product above a temperature of 350°C in absence of adequate protective measures
Avoid contact with sparks and flames, hot surfaces and inflammable materials
- 10.3 MATERIALS TO AVOID
None known.
- 10.4 HAZARDOUS DECOMPOSITION PRODUCTS
Toxic and corrosive vapour-steam (ammonia, amino derivatives, hazardous organic compound, carbon
oxides, hydrogen cyanine)
The temperature level influences directly the thermal combustion products
11) TOXICOLOGICAL INFORMATION

- 11.1 PENETRATION ROUTES

Inhalation of toxic vapours or dust ingestion
- 11.2 ADVERSE EFFECTS FOR THE HUMAN HEALTH
Delayed and/or immediate effects after short and/or prolonged exposure.
Acute Toxicity: Health injuries are not known or expected under normal use.
The thermal decomposition vapours may cause polymer fume fever with influenza like symptoms (headache,
tremors, sweating, high temperature), especially when smoking contaminated tobacco; danger to health by
prolonged exposure.
Chronic toxicity: No data available in normal industrial documentation.
Local effects: May cause irritation to the eyes or skin due to mechanical effects.
Decomposition products may cause severe burns on skin, eyes and mucousae.
Sensitisation: No data available.
Carcinogenicity: IARC Evaluation: Group 3 (The agent is not classifiable as to its carcinogenicity to humans)
Mutagenicity and Reproduction toxicity: The product is not listed as potential mutagenic agent by national
and international Agencies or Competent Authorities.
- 11.3 EXPERIMENTAL TOXICOLOGICAL DATA (ON ANIMALS)

12) ECOLOGICAL INFORMATION

- 12.1 ENVIRONMENTAL EFFECTS
Mobility and bioaccumulation: No data available
Persistence: No data available
Degradability: No data available
Ecotoxicity: no data available
- 12.2
Avoid polluting the environmental

13) DISPOSAL CONSIDERATION

- 13.1 WASTE TREATMENT

Where possible recycling is preferred to disposal or inceneration. If recycling is an option, incinerate or
dispose of in accordance with federal, state, and local regulations. Pigmented, filled and/or solvent laden
product may require special disposal practices in accordance with federal, state and local regulations. Consult
a regulatory specialist to determine appropriate state or local reporting requirements, for assistance in waste
characterization and/or hazardous waste disposal and other requirements listed in pertinent environmental
permits
- 13.2 Dispose of in authorized landfills according to local laws and regulations.

14) TRANSPORT INFORMATION

- 14.1 SPECIFIC HAZARDS

The product is not classified as dangerous in transportation
- 14.2 PACKAGING INFORMATION
Product usually shipped in paper-aluminium-plastic (PE) bags or plastic drum.
- 14.3 INTERNATIONAL TRASPORT CLASSIFICATION
Packaging group : Not assigned
U.N. Number: Not assigned

15) REGULATORY INFORMATION

- 15.1 EC REGULATION
Directive 67/548 and following amendments
- 15.2 CLASSIFICATION
Hazard class: none
Classification type: not required
- 15.3 LABELLING
Trade name: TRAMIDE
Types: ALL GRADES
Risk phrases (R): none
Safety phrases (S): none
Hazard symbol: none

CHEMICAL INVENTORY STATUS

EU.EINECS Conforms to
United States TSCA inventory Conforms to
 Canadian Domestic Substances List (DSL) Conforms to
China. Inventory of Existing Chemical Substances in China (IECSC) Conforms to
Japan. ENCS- Existing and new chemical Substance Inventory Conforms to
Japan. ISHL – Inventory of chemical substance Conforms to
Korea. Korean Existing Chemicals Inventory (KECI) Conforms to
Philippines Inventory of Chemicals and Chemical Substances (PICCS) Conforms to
Australia Inventory of Chemical Substances (AICS) Conforms to

16) OTHER INFORMATION

Data Bases: IUCLID (1996) OHMTADS (2003) IRIS (2003) RTECS (2003) HSDB (2003)
Safety data sheet according to Directive 2001/58/CE

The information given in this data sheet is based on the present available knowledge.
Their aim is to describe the security appearance related to our products and not really to grant their
properties.
The company is not responsible for damages to person or thing caused by misuse of the information
indicated in this document.

ISSUED: 29/09/2020 REV: 1.0.0