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2425 Exercises

The document is an exercise sheet for a chemistry course at the University of Nueva Caceres, focusing on thermochemical calculations. It includes problems related to calculating enthalpy changes (ΔH) for specific reactions and determining the spontaneity of reactions at a given temperature. The document provides necessary equations and data for students to complete their solutions.

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13 views1 page

2425 Exercises

The document is an exercise sheet for a chemistry course at the University of Nueva Caceres, focusing on thermochemical calculations. It includes problems related to calculating enthalpy changes (ΔH) for specific reactions and determining the spontaneity of reactions at a given temperature. The document provides necessary equations and data for students to complete their solutions.

Uploaded by

Plmc10 Gaming
Copyright
© © All Rights Reserved
We take content rights seriously. If you suspect this is your content, claim it here.
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University of Nueva Caceres EXERCISE 2

CHEM113: Chemistry for Engineers


Name: Date:
Section: Student No.:
_________________________________________________________________________
Prepared by: Engr. Gina E. Diocos

Instructions: Submit complete solution to the given problems. Use short size
bond paper

1. Calculate the value of Ho for the following reaction using the given
thermochemical equations:
P 4O10(g) + 6 PCl5(g) 10POCl3(g)

(1) 1/4 P4(s) + 3/2 Cl2(g) PCl3(g) H = -306.4 kJ


(2) P 4(s) + 5 O2(g) P4O10(g) H = -
2967.3 kJ
(3) PCl 3(g) + Cl2(g) PCl5(g) H= -84.2 kJ
(4) PCl 3(g) + 1/2 O2(g) POCl3(g) H = -285.7
kJ

2. For each of the following reactions, calculate ΔH, ΔS and ΔG at 250C,


and tell if the reactions will go spontaneously:
(1) N2(g) + 3H2(g) → 2NH3(g)
(2) 2C2H2(g) + 5O2(g) → 4CO2(g) + 2H2O(g)
(3) 2CH3OH(g) + 3O2(g) → 2CO2(g) + 4H2O(g)

ΔHf values: kJ/mol ΔS values: kJ/mol-K


NH3(g) -46.1 NH3(g) 0.192 H2(g)
0.130
C2H2(g) 226.7 C2H2(g) 0.200 N2(g)
0.189
CO2(g) -393.5 CO2(g) 0.213 O2(g) 0.204
H2O(g) -241.8 H2O(g) 0.189
CH3OH(g) - 238.7 CH3OH(g) 0.234

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