ox Loaicat 1. At300K, Ky forthe reaction. g) Axe) + Bg) is 100 mol L-1. Whats its KC (in ara) at the same temperature? Law of Mass Action, Equilibrium Constant (K. and K,) and its Application (R= 0,082 Latm mol K"!) [AP /May 23, 2024 (D] (2) 100 (b) 2460 (©) 4.05 (a) 246 2. At equilibrium for the reaction [AP/May 22, 2024 (D] Az(g)+B2(¢) == 2AB(g) the concentrations of A,, B, and AB respectively are 1,3 ¥ 1073 M, 2.1 10 Mand 1.4 * 10° M ina sealed vessel at $00 K. What will be K,, for the decomposition of AB at same temperature? @) 062 16 044 227 3. 1Smoles of H, and 5.2 moles of, are mixed and allowed toattsin equilibrium at 773 K. Atequilibrium, the number ‘of moles of Hl is found to be 10. The equilibrium constant for the disse ion of HI is [AP/May 21, 2024 (ID] (@ 2x10? @ 50 () 2*107 @ 5.0 4. K forthe reaction (= Bile) is 39.0. Ina closed one litre flask, one mole of A,(g) was heated to T(K). What are the concentrations of A,(g) and B,(g) (in mol L~+) respectively at equilibrium? [APMMay 21, 2024 ()] (2) 0.025, 0.975 (&) 0.975, 0.025 (6) 0.05,0.95 (@),0.02, 098 5. AtT(K), the equilibrium constant for the reaction H,(g) + Br, of HBr is introduced into a sealed vessel at T(K), the equilibrium pressure of HBr (in bar) is approximately [AP/May 20, 2024 (1)} © 995 (@) 1195 Ww), 6. — K, for the reaction, A2(g)=——=* B() is 99.0. Ina L closed flask two moles of B, (g)isheated to T(K). What is the concentration of B, (g) (in mol L! at equilibrium? [AP/May 20, 2024 (1)] (a) 1020 (b) 10.95 (2) 002 (b) 198 (@) 0.198) 15 7. K, for the following reaction is 99.0 06), An(8); By(e) In aone litre flask, 2 moles of A, was heated to T(K) and the above equilibrium is reached. The concentrations at equilibrium of A, and B, are C,(A,) and C,(B,) respectively. Now, one mole of A, was added to flask and heated to T(K) to establish the equilibrium again. ‘The concentrations of A, and B, are C,(A,) and C(B,) respectively. What i the value of C(A,) in mal L-!? [APMay 19, 2024 (1D] (©) 003 (@ 297 (@) 198) 0.01 ) = 2HBr (g) is 1.6 x 10°. If 10 bar % nL oe 13. vm a7 AUT (K), K, for the reaction. A,(g) —=* B,(g) is 99.0. Two moles of A, (g) was heated to T (K) in a IL, closed Mask to reach the above equilibrium, What are the concentrations (in mol L~') of A, (g) and B,(g) respectively at equilibrium? — [AP/May 18, 2024 (1)) (=) 1.86,0.0187 (b) 1.98,0.02 (©) 0.0187,1.86 (@) 0.02,1.98 ACT(K) the equilibrium constants forthe following two reactions are given below {TS/May 11, 2024 ()] 2A(g)=—= Big) +C(g); Ky =16 2B(e)+C(g) = 2D(B); Ky =25 What is the value of equilibrium constant (K) for the reaction given below at T(K)? Ag+ 5) —= Dw) (100 @) 50 © 20 (75 AtT(K), K, for the dissociation of PCI, is 2 x 10-2 mot 1-1. The number of moles of PCI, that must be taken in 1.0 L flask at the same temperature to get 0.2 mol of chlorine at equilibrium is ITS/Miay 9, 2024 (1N)] @22 Miu ©1s @ 44 AtT(K), K, for the reaction AO) (g)+ BO2(g) —=* AOs (g)+BO(g) is 16. One role each of reactants and products are taken in IL flask and heated to T(K), and equilibrium is established. What is the equilibrium concentration of BO (in mol L~!)? [TSMMay 9, 2024 (D] @ 16 () 04 © 12 @) 08 At T(K), the K,, for the reaction ABy(g) -> A,B,(e) + B,(g) is 0.04 atm. The equilibrium pressure (in atm) of A;B,)g) when it is placed in a flask at 4 atm pressure and allowed to come to above equilibrium is [AP/May 19, 2023 ()] (@) 0362 (&) 0380 (©) 362 (A) 2.62 At 1000 K, the value of K, for the below reaction is 10 mol L"!, Value of K, (in atm) is [AP/May 18, 2023 (D] A(g)=B(s)+C(s) (given R = 0.082 atm L mot"! K~!) () 8 (6) 082) B2_— (a) 820 One mole of A(g) is heated to T(K) tll the following equilibrium is obtained Ag) ne) The equilibrium constant of this reaction is 10-!, After reaching the equilibrium, 0.5 moles of A(g) is added and heated. The equilibrium is again established. The value A] of i is (@) 107 [AP/May 17, 2023 ()] @) 10) 107) 10048. 1S, One mole H,O(g) and one mole CO(g) are taken in IL flask and heated to 725K. Atequilibrium, 40% (by mass) of water reacted with CO(g) as follows. 130 (g) +CO(a) = Hs (g)+ CO (2). ts K, value is IAP/May 17, 2023 (1); Similar to AP/May 15,2023 (D] (a) 2220 (b) 0444 (@) 4.440 (a) 0.222 16. One mole of PCI,(g) was heated in a IL closed flask at 500 K. At equilibrium, 0.1 mole of Cl, (g) was formed What is its K,, (in ata)? (Given R= 0,082 Lam mot! K“!) [AP/May 16, 2023 (D] (@) 2.7*104 (b) 0.455 (©) 0.0111 (@ 900 17. AtT(K), the equilibrium constant for the reaction a A(g) 2B (g)isK,. Ifthe reaction takes place in the following form 2aA(g) —> 2b B(g) its equilibrium constant is K’ ‘The correct relationship between K, and K, is TAP/May 15, 2023 (11)} (@®) K= (K) © Kw)! @K, 18, AtT(K), Ke value for the reaction 1 Z £N2(0)H2(}—=FNH() ig 50. THe Ke ve for the reaction 2NH,(g) ==N,(2) + 3H,(e) atthe same temperature is ITS/May 13, 2023 (1D) (a) 4x 10% (by 8 x 10-6 (©) 6x 10% @ 8% 107 19. AtT(K) when one mol of X and one mol of ¥ are heated ina I L flask, 0.5 moles of Zs formed at the equilibrium. ‘The K, value for the reaction is X(g) + ¥(g) = Z(g) + A(g) (0S G10) 0.75 K JK for the reaction at T(K) is [AP/Suly 8, 2022 (1); Similar to TS/July 18, 2022 (1) [TS/May 13, 2023 ()] (@ 082 20. () JRF (b) 2RT For ammonia formation from constituent elements, the oR @ Var mL expression “ is [AP/July 6, 2022 (1) ta) Ke [wap 0) K o- tl “hs 7 (H} <"TNallel oe (@) Ko INH 22, Calculate the value of the equilibrium constant (K) for the reaction of oxygen gas oxidising ammonia gas to nitric oxide and water vapour. The pressure of each gas at equilibrium is 0.5 atm, ITSiJuly 20, 2022 (11); Similar to TS/duly 19, 2022 (D)} (2) 1Satm (b) 05.atm (6) Latm (A) 25 atm 2B. 25. 26. 2 28, Si For the formation of ammonia from its constituent elements (I mole of N, and 3 moles of H,) in a closed vessel of volume V(L), the value of Ke is {units of Ke =molL?} (TStduly 20, 2022 (1) aev2 ) anv? ® Sana 9(1-x) ay2 ev ( @ ° 0s) 2-1) For a reaction A(s) ~ B(s) + C(g) the set of all correct statements are [rs/duly 18, 2022 (D] (A) K is independent of [A] (B) K is dependent on partial pressure of C at a given temperature. (C) AH will be independent of temperature. (D) AH is independent of the catalyst addition. (@A,B,.C,D (by A,Bonly © A,B,Donly —(@) A,B, Conly Wdentify the correct expression for the equilibrium constant ofthe following reaction. {AP/Aug. 23, 2021 (D)] 2X(g)+Y (g)==32(g) @e-PTE yy be zp GPP 3{Z] © ith (@) k= ZP OP Which among the following denotes the correct relationship between X, and X, for the reaction, 24(g)—=B(g)+C(8) {AP/Aug, 19, 2021 (LI); Similar to TS/Aug, 6, 2021 (1)] (0) K,>K, ) K>K, © K=(K,P @) KK, ‘The equilibrium constant (K,) for the formation of ummonia fiom its constituent elements et 27°C is 1.2 « 104 and at 127°C is 0.60 = 10°. Calculate the mean heat of formation of ammonia per mole in this temperature range. [TS/Aug. 5, 2021 (1)} (a) ~ 82.64 cal (b) - 826.4 cal (©) ~ 1652.8 cal (d) 165.2 cal For a reaction, 2A > B + C, Kis 2 x 10. Ata given time, the reaction mixture has [A] = [B] = [C] = 3 = 104 M. Which of the following options is correct? ITS/Aug. 8, 2021 ()] (a) The system is at equilibrium (b) The reaction proceeds to the left (6) The reaction proceeds to the right (a) The reaction is completeelnoy a 32. 3B. 34, For a reversible reaction, if the concentration of the reactants is reduced to half the equilibrium constant will be IAP/Sept. 18, 2020 (1) (a) doubled (6) halved (©) reduced to one-fourth (d) remains same What is the equilibrinm constant (K.) for the given reaction? Nz +0; ==22N0 Where the equilibrium concentration of Ny, O, and NO are found to be 4 * 10,3» 10° and 3 x 103M respectively. [TS/Sept. 10, 2020 ( (a) 0.750 (b) 0.622 (©) 9% 103 (@) 12.8 «10-6 For the given equilibrium reaction, 2A (g) = 2B(e) + Ce) the equilibrium constant (Kg) at 1000 K is 4 x 104. Calculate K, for the reaction at 800 K temperature [TS/Sept. 9, 2020 (1)] a) 0.044 (6) 0.026 (~) 033 (a) 1 In which of the following plots, an endothermic reaction similar to AP/Apr. 21,2019 (1)] is correctly represented? [TS/May 6, 2019 (1) * + @ "| BX 7 nw : * © &%| @ * L_ a For the reaction, 0.5C(s) + 0.5CO,(g) == COle) the equilibrium pressure is 12 atin. If CO, conversion is 50% the value of &,, in atm is [TS/May 3, 2019 (1)] @4 1 0s @2 ‘At 1000 K, the equilibrium constant. Ke for the reaction 2NOCI(g)=—=*2NO(g)+Ch(g) is 40% 0mol L". The K; (in bar) at the same temperature is {AP/2018) (R= 0.083 L bar K"!mot-) a) 3.32% 10% (b) 3.32% 104 (c) 3.32* 104 (d) 3.32 « 107 . Consider the following reaction in a1 L closed vessel N, 43H, == 2NH, If all the species; N,, H, and NH, are in 1 mol in the beginning of the reaction and equilibrium is attained equilibrium constant? [TS/May 5, 2018 (D] (a) 3600.00 (by 3657.14 (©) 2657.14 (a) 1828.57 36. 3 40. after unreacted Ny is 0.7 mol, What is the value of 41. At300K, a9 The equilibrium constant (K,) for the following equilibrium [apr0r7} 2803 (s) +02 (g) === 280s (2) at 563 K is 100. At equilibrium, the number of moles of 0, in the 10 litre flask is twice the number of moles of S0,, then the number of moles of oxygen is, @04 (03 (02 dor (i) HyPO, (aq) =H" (cq) +H2PO§ (aa) (ii) HPO; (ag)—H"* (aq) + HPOF (a9) (ii) HPO} (ag) =H" (ag)+ POY (aq) ‘The equilibrium constants for the above reactions ata certain temperature are K,, K, and K, respectively. ‘The equilibrium constant for the reaction HPO, (aq)—==3H" (aq) + PO} (aq) in terms of Ky, K,and Kis {AP/2017] _ Ky ® Rakes © aw GS ORK @ KKK AL 400 K, in a 1.0 L vessel, N,O, is allowed to attain equilibrium, N,O4(g)===2NO3(g) At equilibrium, the total pressure is 600 mm Hg, when 20% of N;O, is dissociated. The value of K, for the reaction is |AP/2016] (50 (b) 100) 150 (@) 200 Which one of the following is correct? (TS/2016] (a) The equilibrium constant (K,) is independent of temperature. (b) The value of Kis independent of initial concentrations of reactants and products. (©) At equilibrium, the rate of the forward reaction is twice the rate of the backward reaction. (@ The equilibrium constant (K,) forthe reaction ” {NW(CO).) Nils) + 4CO(g)=== Ni(CO),(e) is, ——- _ Nil) +4CO(g) == NUCO) (8) is “TE When one mole of 4 and one mole of B were heated in one litre flask at 7(K), 0.5 mole of C was formed in the equilibrium, A+B == CHD the equilibrium constant, Kis (7/2015) () 025 OS 1 2 Relation between K, Q and G and Factors Effecting Equilibrium forthe reaction A,(g) = B,(g) is-11.5 kd mot"! The equilibrium constant at 300 K is approximately (R* 83145 mol! KH) JAP/May 22, 2024 (ID) (a) 10 (b) 100) 1000 (4) 2550 2 4B. 44, 45, 46. a7. 48. Observe the following equilibrium Fe (aq) + SCN (aq) = [Fe(SCN)]?* (aq) yellow colourless deep red ‘Addition of aqueous oxalic acid solution to the above equilibrium [AP/May 18, 2023 (1D (@) Shifts the equilibrium towards the formation of [Fe(SCNye (b) Deep red color increases (©) Intensity of deep red color decreases (@) No change in equilibrium Observe the following equilibrium at T (K) H,(e) + 1; (@) = 2HI(e) Which one of the following does not disturb the above equilibrium? IAP/May 16, 2023 (1)] (a) Addition of H, (g) — (b) Removal of HI(g) (©) Addition of (2) (4) Addition of He(g) At 780 K and 10 atmosphere pressure the equilibrium constant for the reaction 2A(g) = B(g) + C(g) is 3.52. At the same temperature and 7.04 atmosphere pressure, the equilibrium constant for the same reaction is (TS/May 12, 2023 (1)] (a) 7.04 (0) 352 () 10.56 (@) 5.23 Fora reaction A(e)+5B(e) Cle) + het favorable conditions for the reaction to occur in the forward direction are [AP/Suly 5, 2022 (1D) (@) LowT and LowP —(b) LowT and high P (c) HighTand Low P —(@) High Tand high P ‘Which of the following expression is correct [AP /duly 4, 2022 (11)] (b) 4G= (a) AG=-RT In K RP INK nk ‘The formation of ammonia from its constituent elements is sn exothermic reaction. The effet of inerese temperature on the reaction equilibrium is IAP/July 4, 2022 (D] (a) The rate of the forward reaction becomes zero (b) No effect of temperature. (@) Forward reaction is favored (8) Backward reaction is favored In which of the following reactions at equilibria, the position of the equilibrium shifts towards the products, if the total pressure is increased? {TS/duly 19, 2022 (1)] ()_Xz(g)+3¥; (8) 2XY5 (eg) (i) Xz(g)+ ¥> (g)===2XY() (6) Xs (@)+ 23 (0) —2NZEE) 49. 50. st. 52, 33. Es (We) Xz(B)+ Ya (@)-=2X¥2 (8) (a) (ii) () iii) © @ (a) (iv) When reaction is caried out at standard states then, at {AP/Ang. 23, 2021 (1D) (©) equilibrium constant (K} (4) equilibrium constant (&) = 1 Le-Chateliers’ principle is not applicable to IAP/Aug. 20, 2021 (D] (2) Hp(g)+12(s)—=2HI() (b) Fe(s)+8(s)—=FeS(s) (©) N2()+3H2 (s)-—==2NHs () (@) No(g)+02(¢)===2NO(s) Standard entropies of X,, ¥, and X¥, are 60, 40 and 50 JK-! mol~! respectively. At what temperature, the following reaction will be at equilibrium’? [given : AAP = -30 KJ] JAP/Aug. 19, 2021 ID] 1e3y pity (a) SOOK (b) 750K (ec) 1000K (4) 1250K For the reaction $03(¢)+403 (g}—==803 (g). the percentage yield of product at different pressure is shown in the figure. Then, which among the following is true? [AP/Aug, 19, 2021 (1D [S04] Py yield 7. Py T (a) Pressure has no effect (b) p, PL? Ps (@) p= P.=Ps#0 For the formation of NH(g) from its constituent clements, the favourable conditions for its formation ITS/Aug, 6, 2021 ( (@) high pressure and low temperature (b) high pressure and high temperature (€) low pressure and high temperature (@) low pressure and low temperature Find the value of the equilibrium constant (K) of areaction at 300 K, when standard Gibbs free energy change is -25 KJ mol"!? (Consider R = 8.33 mot~!K7}) [TS/Sept. 11, 2020 (1)} @& Me (el @ ell56. 57. 58. 59. 61. 2. Ei pics Kp for the conversion of oxygen to ozone at 400 K is 1.0 * 10%, its standard Gibbs energy change in Ai mot"! is approximately {AP/Apr. 22, 2019 (1) (2) 2298 (6) 1149 (©) -2298 (d) -1149 On increasing temperature, the equilibrium constant of ‘exothermic and endothermic reactions, respectively 1AP/2015} (a) increases and decreases (b) decreases and increases (©) increases and increases (@) decreases and decreases Theories of Acids and Bases, lonic Product of Water and pH Scale 100 mL of 0.1 MHA (weak acid) and 100 mL of 0.2MNaA are mixed, Whats the pl! ofresultant solution? (K, of HA is 10°5; log2=03) [AP/May 22, 2024 (1D @47 50 @53 (40 Which of the following when added to 20 mL of a 0.01 M solution of HCI would decrease its pH? IAP/May 22, 2024 (D] (@) 20 mL of 0.02 M HCI (b) 20 mL of 0.008 M HCI (6) 20 mL of 0.01 MHCI (4) 40 mL of 0.005 MHCI AC27°C, 100 mL of 0.4 MHC! is mixed with 100 mL of 0.5MNaOH solution. To the resultant solution. 800 mL of distilled water is added. What is the pH of final solution? IAP/May 20, 2024 (0 @I2 @2 @13 @10 Observe the following stoichiometric equation Pit 3 OH” +3H,0 —> PH, + 3-[AP/May 19, 2024 (11)} ‘What isthe conjugate acid of? (a) Phosphorous acid (©) Hypophosphorous acid (©) Phosphoric acid (d) Pyrophosphoric acid ‘What is the conjugate base of chlor acid? [AP/May 19, 2024 (1D] (@) C107 () CIO” (©) ClO (d) ClO At27°C, 100 mL of 0.5 M HCl is mixed with 100 mL of (0.4 MNaOH solution To this resultant solution, 00 mL of distilled water is added, What is the pH of final solution? ITS/May 10, 2024 (1D) (a) 120 (b) 20 © 13 @ 10 Observe the following species [TS/May 10, 2024 (1)] () NR, (i) AICI, (iit) Sn, (ivy CO, (W) Agt (vi) HSO,- How many of the above species act as Lewis acids? @s 3 @4 @2 Observe the following species AICI, NH,, H*, Co", “OH, Mg?*, BF,, Cl- How many Lewis acids are preseat in the above list? IAP/May 18, 2023 (UD; Similar to AP/May 17, 2023 (1D fa) 5 (b) 4 (2 (a) 3 65, 7. 9. 70. n. n 2B. mM. 78. ASL Given below are two statements ‘Statement I: The changes in pH with temperature are so small that we ofien ignore it Statement I; When the hydrogen ion concentration ‘changes by a factor of 100, the pH changes by one unit In the light of above statements, identify the correct ‘answer from the options given below [AP/May 17, 2023 (| (a) Both statements I and Il are correct. (b) Both statements | and Il are not correct. (©) Statement | is correct but statement II is not correct. (@) Statement [is not correct but statement Il is correct. Observe the following solutions 1. Black coffee I. 0.2M NaOH IIL. Lemon juice IV, Lime water V. Human Saliva VI. Tomato juice ‘The number of solutions with pH less than 7 is [AP/May 16, 2023 (LD; Similar to AP/May 15, 2023 (I)] @2 ws @4 @3 Conjugate acid and conjugate base of HCOy are respectively JAP/May 16, 2023 (1) @) X, C0 Hy CO," (b) Hy £05, coe" © coe", HCO, (d) co} CO, ‘A solution is prepared by mixing 10 ml. of 1.0 M acetic acid and 20 mL of 0.5M sodium acetate and diluted to 100 mL. If the pK, of acetic acid is 4.76, then the pH of the solution is. [TSMay 12, 2023 (D] (476 () 3.76 (©) 5.76 (a) 9.24 The conjugate base of HO" is JAP/July 6, 2022 (1)] (@) HO (b) OH (e) HT (@) H ‘The pH of 0.01 N time water is [AP/July 4, 2022 (U)} @ 1309 @ 1 | I2 @98 ‘Ammonia is a Lewis base because itis {TS/July 20, 2022 (11) (a) Electron pair donor (b) Electron pair acceptor (©) Proton donor (d) Proton acceptor How many of the following are diprotic acids? Citric acid, Chromic acid, Oxalie acid, Pyrosulfuric acid, Sulfurous acid ITSiJuly 20, 2022 (1)] @2 5 4 @3 Calculate the number of moles of NaOH required to completely neutralise 100 g of 118% oleum [TSiduly 18, 2022 (1D (a) 24 (b) 12 (ce) 48 (a) 84 The pH of pure water at 80°C is [TS/duly 18, 2022 (1)} (97.0) 2) >70 <7 Which of the following gas fas the highest pli at 25°C? JAP/Aug. 23, 2021 (D] (b) 1 Mag NH, (@) IMHCL (2) Distitled #,0 (©) IMNaH52 76. The successive equilibrium constants for the stepwise dissociation of a tribasie acid are Kj. Ky and Ky respectively. The equilibrium constant for tie ov dissociation is [TS/Aup. 6 2021 (DI (0) 4K +R) 0) YA Ka R3) (KX Kx Ky) (@) Ky *K,*K, 77. Strongest conjugate base among the following is TAP/Sept. 18, 2020 (1)] @cr OF ©Be wt 78. At T (K), if the ionisation constant of ammonia in solution is 2.5 * 10°%, the pH of 0.01 M ammonia solution and the ionisation constant ofits conjugate acid respectively at that temperature are (log 2 = 0.30) IAP/Apr. 22, 2019 (LD (a) 10.7, 4.0 « 10-8 (b) 10.7, 4.0 x 10-9 (©) 3340x108 —— (@) 33,40 10-9 79. The number of species ofthe following that can act both as Bronsted acids and bases is [AP/Apr. 20, 2019 ()] HCI, Cl0;, “OH, H’, HzO, HS0q, SOF", HySO,, Cl” (@4 (b) 3 ©! @2 80. What is the order of relative basic strength of C103, ClO;, c10;? [TS/May 6, 2019 ( (a) C107, > C1054> ClO, (b) ClO, >ClO>,> ClO", (©) ClO™,>C105> C10, (@ Clo-,>clo-,> clo7, 81, pH of an aqueous solution of NH,Cl is {TS/2016} @7 @>7 ©<7 @I 82, What is the pH of the NaOl solution when 0.04 g of it dissolved in water and made to 100 mL solution? [AP/2015] @2 OO! OB @R lonisation of Weak Acids and Bases and Uutas) Relation between K, and K, 83. At27°C. the degree of of HA (weak acid) in 0.5 M of its solution is 1%. The concentrations of H,O", ‘A~ and HA at equilibrium (in mol L~! ) are respectively [AP/May 23,2024 (D)] (a) 0.005, 0.005, 0.495 (b) 0.05, 0.05, 0.45 (c) 0.01, 0.01, 0.49 {d) 0.005, 0.495, 0.005 84. AL27°C, the degree of dissociation of weak acid (HA) in its ‘0.5M aqueous solution is 1%. Its K, value is approximately [AP/May 18, 2024 (1)] (a) $x 104 (b) 5* 10° (© 3x 10% (a) 5* 108 85, The pH of 0.01M BOH solution is 10. What is its degree of dissociation? [AP/May 19, 2023 (1) (Given K, of BOH is 1 * 10°) (2) 10% (6) 5% =) M% == 1% 81. 88 89. 90. 91. 2. 93. 9s. «oh The K, values of A, Band C are 18 * 10-4, 5 10-4 and 3° 10° respectively. The correct order of their acide strength is [AP {duly 5, 2022 (11)} (a) B>A>C (by B>CHA (©) A>B>C (d) A>CoB Equal volumes of 0.5 N acetic acid and 0.5 N sodium acetate are mixed. What is the plY of resultant solution? (pk of acetic acid = 4.75) [APiSuly 4, 2022 (1) (a) 485 (b) 465 (6) 4.75 dl) 70 ‘The pil of 10° M FIC! solution is [AP/Sept. 21, 2020 (1 (@ 8 (b) -8 () Between 7-8 (d) Between 6-7 Which acid among the following has the highest pK, value? 1AP/Sept. 21, 2020 (1)] (a) HCL (6) HE (@) HE @) HBr ‘The ionic product of water with increase in temperature. IAP/Sept. 21, 2020 (1)) (a) remains constant —_(b) increases (©) decreases (@) may increase or decrease 30.0 mL of the given HCI solution requires 20.0 mL. of 0.1 M sodium carbonate solution for complete neutralisation. What is the volume of this HC! solution required to neutralise 30.0 mL of 0.2 M NaOH solution? IAP/Apr. 21, 2019 (1D)] (a) 25mL (b) 50m (e) 90mL (a) 45 mL. If the pK, of acetic acid and pX, of dimethylamine are 4.76 and 3.26 respectively, the pH of dimethy] ‘ammonium acetate solution is [AP/2018} (a) 7.75 (6) 6.75 (e) 720) 8S ‘Common lon Effect, Salt Hydrolysis, Buffer Solutions and Solubility Product ‘The solubility of barium phosphate of molar mass *M* g mol"! in water is x g per 100 mL at 298 K. tts solubility product is 1.08 x (2) % (10). The values of « and & respectively are IAP/May 21, 2024 (1)} M758 O57 55 W717 At T(K), the solubility product of AX is 10-"°. What is the molar solubility of AX in 0.1 M HX solution? IAP/May 21, 2024 ()] (@) 105 (b) 10") 10%) 10°F Which of the following will makea basic buffer solution IAP/May 20, 2024 (1D) (2) 100 in of 0.1 M CH,COOH + 100 mL of 0.1 M NaOH (b) 100 mL. of 0.1 M HCI +100 mL of 0.1 M NaOH (©) 50 mt of 0.1 M KOH +25 mL of 0.1 M CH,COOH (d) 100 mL of 0.1 M HCI +200 mL of 0.1 M NH,OH ‘Observe the following solutions (i) 1Lof 10 MAgNO, (ii) ILof 10-7 M AgNO,[ equitiprium J 97. 98. 9. 100. tor. 102. ii) HL of 10°? MAgNO, (iv) IL of 107 M AgNO, (v) ILof 10° M NaCl Which of the above two solutions when mixed will give a white precipitate, Ag!” [AP/May 18, 2023 ()] (Given K,, of AgCl = 1 10-19) (@) @.0) ©) Gi, © 6.0) (@) Gi, () AL 298 K the molar solubility of Cd(OH), in 0.1 M KOH solution is x*10°Y. The values of.x and y-are respectively (at 298 K, K,, of CA(OH), = 2.5 « 10-4) [TS/May 14, 2023 (1D) (a) 25,14 (b) 25,13 (©) 25,14 (@ 25,16 Which of the following does not form a bulfer solution? ITS/May 14, 2023 (D] (a) NH, + HCI (2:1 mote ratio) (®) CH,CO,H + NaOH (2:1 mole ratio) (©) NaOH +CH,COOH (1:1 mole ratio) (@) NH,CL+ NH, (1:1 mole ratio) Statement A + pH! of buffer increases with increasing ‘temperature, Statement B : The value of Ky of water decreases with ‘decreasing temperature. IAPiJuly 8, 2022 (D} (@) Ais correct, but B is wrong. (©) Both A and B are correct (©) Both A and B are wrong (@) Ais wrong but Bis correct, ‘AL 25°C, the solubility product of MCI is tx 10" What is its molar solubility in 0.1 M NaCl solution at same temperature? IAP/July 7, 2022 (11) (a) 01M (b) 005M (c) 10%M (d) 10M “The solubility products of NiS, ZnS, CdS and HyS are 4715, 16% 10,8 x 10-27 and 4 = 10°5 respectively. ‘An aqueous solution contains N?*, Zx?*, Cd, and Hg of | ‘equal concerization. HS gis was passed into this solution very slowly. The frst and the last ions that precipitate as sulphides are respectively IAP /July 7, 2022 (11) (a) Nit, Hg? (b) He*, Ca?" (©) Zn?*, Hg?* (@) He?*, NP Match the following. Metal sulfide Solubility product (A) PbS a) 40% 10-3 (B) HgS al) 8.0 « 10°78 (©) Mns (a 1.6 10° (0) 208 (y)25 * 10" The correct answer is [TSisuly 19, 2022 (IDL A BC D @ tou om ow mr wom ou m wit @m wor om 10; 104. 106. 107. 108. 109. 053 ‘The solubility of AgBr(s), having solubility product 5x 10"! in 0.2 M NaBr solution equals JAP/Aug, 20, 2021 (I); Similar to AP/Sep. 21, 2020 (D @) 5*10M (b) 25 «1071 M (©) OSM (@) 0.002 M 100 g of a mixture of NaOH and Na,SO, is neutralised by 100 mL. of 0.5 MH,S0,, What is the amount of Na,SO, present in the mixture? ITS/Aug. 6, 2021 (1)] (@) 822 0) %g (BZ NE Match the following columns: {TS/Aug. 42021 (D] caetiaal Column-t ation ag, fa A. HCN 1. 68% 104 B. 2. 89x10 c 3. 4.9% 10710 D. 4. 56% 107 5. 15x10 ‘The correct match is Codes: A BOC OD @io3 4 5 ms 23 4 ©@2 3 4°55 @3 4 2 5 Ifthe molar concentrations of base and its conjugate acid are same, then pOH of the buffer solution is ITS/Aug. 4, 2021 (D] (a) sameas pK, of base (b) same as pK, of base (© sameas pK, of acid (4) same as pK, of acid The solubility product of Ni(OH), at 298 K is 2 « 10"! mol? drv®, The pH value if, its aqueous and saturated solution is IAP/Sept. 17, 2020 (| 5 75 9 (@ 13 What is the pH of 10 L of a buffer solution containing 0.01 MNH,CI and 0.1 M NH,OH having pK, of 5? [TS/Sept. 11, 2020 (1) (8 7 (10 WS ‘At 25°C, the ionisation constant for anilinium bydroxide is $.00 x 1010. The hydrolysis constant of anilinium chloride is {TS/Sept. 9, 2020 (1)] (a) 2.00 « 10-5 (b) 4.00 « 10° (©) 150 10% (a) 2.50% 104 ‘The solubility product of a sparingly soluble salt 4,2 is, 3.2 « 10-U1 Its solubility in mol L7! is [AP/Apr. 21, 2019 (11): Similar to TS/May 3, 2019 (D}] (@) 4*104 (b) 2 104 (© 6x 104 (a) 310+AS4 111. In which of the following, the solubility of AgCI will be minimum? [TS/May 4, 2019 (1) (a) 0.1MKNO, (b) 0.1 MKC (©) 0.2 MKNO, (@) Water 112. If the solubility product of Ni(OH), is 4.0 « 107 the solubility (in mol L-!) is [TSMay 5, 2018 (1; Similar to TS/ 2015 (D) (a) 5.0 «105 (b) 4.0 « 10% (c) 2.0 10-5 @ 1.0« 10-4 113. In which of the following salts, only cationic hydrolysis is involved? [AP2016) IS (®) CH,COONH, (&) CH,COONa (©) NH,CL (@) Na,S0, 114, The buffer system which helps to maintain blood between 7.26 to 7.42, i (a) HCO, / HCO; (b) NH,OH/NH,CI (©) CH;COOH/CH;COo™ (@ CHjCOONH, the pH of rrs/2015}() Ky=K x (RT) Given, = 100mol L~! ‘ R= 0,082 L atm mot"! K-! T=300K An = (No. of gaseous product) ~(no. of gaseous reactant) 2-161 Kp = 100 mol L7! » (0,082 L atm mot“! k-# x 300K)! k= 2460 atm b) Ag) + B,(g) = 2 ABLE) At equilibrium 1.5 «10-3M_ 2.1 108M 1.4% 107M. _1Aal (a2][2] 1.4107 1.410 15x10 x2.1x10" K, K, = 0.622 K=KXRD an=0 K,=K,=0.622 For the decomposition of AB(K’) = (@) H, +l, = 2HI tea 6 820 Ateqiivim 1S-x 82-1 28 Let Vis volume in iter Given, 2x = 10 xs Concentration of H, at equilibrium = 15 ~5 Equilibrium . 1 for the dissociation of His = K, =deo2«107 = 5g 702210 =2« 107 aK) Ae) ——= Bia) ' ° Concentration of B, = 0.975 ‘Concentration of A, = 1 -0.975 = 0.025 (@) Given ‘ H,(g) + Br,(g) = 2HBr (g). K, = Reverse reaction, 24Br(g) + H,(e) + Brg), Ky = x ? «105 12 ef 1 «{1) HBr(g) = > Ha(s)+>Br(e)Kp (¢) 2 vd re Mem wx EF v a(x) (ow pee 10>>x 0 X= 005 = Pg, = 10-0.A152 6 ) 198 Ate) EE Bw.k, moles of, =2 [B.)° Ke [ral {l) ”* Tas] Initial concentration of A, = 0 Initial concentration of B, Let x be the concentration of A so the change in By would be — 2x Equilibrium concentration are [Ag] =x, (B,]=2-2x Putting the value in eq. (1) Lot's simplify the equation —[(a~ b)?= 22 2ab + 0%] 4(i-2x+7) 992 99x = 4— Bx + 4x? 4x? 107x+4=0 Solving the quadratic equation we use the Quadratic formule: ~bi Vb? -4a0 2a 07) + an4b W7,e=4 107) - 4(4)(4) 2x4 f11449 ~ 64 8 107 ft1385 8 fa EE 8 = 213.65 o7t $26.11, 030 Putting the value of x o finding the concentration of B, By72-2x 10 2moles 0 1 Equilibrium, 0.02 9. 10, aN On adding one mole ofA, Aa(s) = Br(e) t-Eqilim 002+ 001 Henee, C(A,) = 0.03 moles. (@) given K,=99.0 n=2moles ofA, vel A, =; etal 2 ° Atego, 2-2 Product} concentration of B, at equilibrium is 1.98 mol L“' concentration of A, at equilibrium is (2 - 198) =0.02 mol L-! = 0.02 mol L" (©) 2A(g) = Big) + Cig) :K, -[ellel. 16 Ky= =16 (i) TAF 2 B(g) + C(e) = 20(e); K,= 25 2 k,= LOL, nas Ai) {ells} S A+ TBM ADK, [D) - inet” a) Ky = Kp xk; - OL BI. esae (elie AF Pl 44520 (8y*[4) (a) 22 Given - K, = 2 «10? mol L! PCI, (g) > PCI, (g) + Cl, (@) moe tinal “ oO rmokesatequiibrium =x-02 0202 Equlitium constant k = ECC] [Peis]M 13. 4. 18. {0.2] <{0.2] “[x-02) 2 moles 40; ](80] [A02][202] al concentrations - 2x107 = () k [AO,] = BO] = [A,] = [B0,] = LOL ‘Cone. [a0,} | [BO,} | [A0,) | [BO] Tnitial ro [10 [10 [10 ‘Atequilibrium [1-a [i-a [ita [iva] (ta)xQi+a) 16 16, (i-@)(i-a) dee Ima . 1+a=4-40 5 1 =3/5=06 :. Equilibrium concentration of BO] is=1+0.6 (© A, Bg (g) =A, B, (2) +B, (o) il peda 00 1 vim Sta pata panda =4(1-a) ic, = BUADBA)*P (BD) oot an 18. P(A2 Bs = (a)(da) _ 40? 4g? i-e) T-a = a=0l ‘Therefore, P(A,B,) a equilibrium = 4 (1 ~ a) =4(1 - 0.1) = 3.62 (@) K,=K.QD K,= 10 mol L“, T= i000 K, mi R= 0,082 L atm mot! K = ‘An,=(1+1)-1-1 =k, Ciowoee wes (b) Ke a 10 “5 Sioce Kg remains content at given temperate, the value of [3] will still be the same, fa] oft] [aio [Bl (b) K,=K, (RTP H,O (g) + CO (g) =H, (g) + CO,(e) = n=(+1)-(+1=0 a1s3 => KK Now, 40% of mass of water reacted with CO. = a=04 ©, 0.0 04 H,0 10. co [H, 00 08 Initial moles ‘At equilibrium 4 =06 Thus, o)= 2 06M, [CO] =06M, (HJ= ay te {H2}{C02] | (04)(04) Ko=fp,0][co] "(06)(06)~ ‘Thus, 0.444. yee, PCI, (g) > PCI, (g) + Cl, (@) 1 o 0 Eqn 1-3 x) ta x= 0.1 (given) sol -x=09 “2 (oi! ix 09 ‘Thus, K, = (0.011) (0.082 « 500)2- = 0.451, 2b x, =P eax, -BE 5 fap [AP ©) Fy tet EN, Ke= $0 given, Multiply by 3 ineq? (1) N,+3H,=2NH, 7. Ke= (50) Reverse eq. (2) 3 2NH, =! N, +3H, Ke! = (4) Ke 1011 Ky a) =) 8x10, ph ely 50° 5050 Imol o (x]=4Re = aney] = “Bt IM OS mol os Me L X(g)+¥(g) = Bits [IY] z= 2g) +Alg) x Y Before | 1 i Ateguili. | t-a | 1-a a= 0,5 and (X] = [Y]= 1 - = 05M. Also, [A] =0.5M. ° eloAis4 20, 2 2 2, m4, 28. 26, 2. @ KK |= Chat [n= Change in the no. gaseous molecules from reactant to product] In tis equation, (, K, melee (b)Np+3Hy > 2NH3;K, (b) 4NH() + 50,(e)—> 4NO{g) + 64,06) (Pxo)* (Pa30)* _(05)” (Fas) (Po.)° (05) © N@ + 3H) == 2NHe lois: ml 3d ° peg (-niml — G-md kal (ys? omg [) Ke= ©" [alae eye 3) 7 Satm axty? ary? (-ayfa0-xy 270-x)" 7 ok EEL cena sd bmi K =[C] partial pressure of C= pe (b) Given reaction is 2X+Y 23Z Equilibrium constant & zl LTP] (d) 2(A)ge=== Bo) + Cle) An=2-2=0 K,=Ke (RT) = Kyp= Ke Ky. alt [1 ©) ee = T3008 TT ‘Substituting the values in above equation jog 22107 -an fi 12x10 2.303x2| 300 400. ait [_100 logos = A =~ 1663.6 hans | 7M? Mean heat of formation ME -1663.69 826.43cal 2 28, 32, 3. _[aiIc) © =H As [A]=(B]=(C] o, Hl) 21 3 0,>K. (ar ‘The reaction will proceed in the reverse direction. |. (a). The value of equilibrium constant does not depend ‘on initial concentrations of reactants and products, |. (a) Np +02 =22NO Ko forthe above reaction can be given as, tno? © T2102) 3 __ uo? oy [4x10 J3x107) 3 i e075 |.) Given, Ko 4 * 10+ T= 100K K,= KeART)"t ‘An, = moles of gaseous product (,) ~ moles of gaseous reottant (n,) =2-1=1 K,= 4% 10-4 (0.0821 * 800)" Y= 0.026129. (8) Forthe reaction, COn(e) + Cls) 2.002) Also, K, = K (RT) where, An K, = K=nk = K ORT = K,=289x107 — 74 __ 29.0289 0.0821«1000 (approx. closer to option b) @ WnK,= a + constant ‘SH > 0 for endothermic reaction, thus, slope (- *) is negative. {a) For the reaction, 0.5C(s) + 0.500,(g) = COs) 1 503% conversion of CO,(g) takes place. We have concentration of CO,(g) = [0.25] K, is calculated only for gaseous species, thus Hetil toy (Reactant), (0.25) Hence, option (a) isthe correct answer. (©) Given, Kp= 4s 10° mov (n= p= np 3-2-1)