Time : 45 Mins. CHEMISTRY Max.

Marks : 45

Name of Student : ____________________________________________________________

1) A crystalline solid
a) changes abruptly from solid to liquid b) has no definite melting point
c) undergoes deformation of its geometry easily d) has an irregular 3-dimensional arrangement

2) A pseudo solid is
a) glass b) NaCl c) KCl d) both (b) and (c)

3) Quartz glass is obtained from

a) SiO2 b) Al2O3 c) FeO d) none of these

4) Which of the following is a molecular crystal?

a) Gold b) NaCl c) Graphite d) Ice

5) London forces are present between

a) HCl molecules b) NH3 molecules c) H2O molecules d) H2 molecules

6) The volume of a single water molecule is

a) 15 × 10-24 cm3 b) 1.5 × 10-24 cm3 c) 0.15 × 10-24 cm3 d) none of these

7) A particular solid is very hard and has a very high melting point. In solid state it is a non-conductor and
its melt is a conductor of electricity. Classify the solid.
a) Metallic b) Molecular c) Network d) Ionic

8) Which type of solid crystals will conduct heat and electricity ?

a) Ionic b) Covalent c) Molecular d) Metallic

9) Which of the following is a network solid?

a) SO2 (solid) b) I2 c) Diamond d) H2O (ice)

10) Among solids the highest melting point is established by

a) covalent solids b) ionic solids c) pseudo solids d) molecular solid

11) To which of the crystal systems does TiO2 (titanium dioxide) belong?
a) Tetragonal b) Cubic c) Hexagonal d) Monoclinic

12) The number of atoms in a simple primitive cubic unit cells is

a) 1 b) 2 c) 4 d) 8

13) Calcite belongs to

a) tetragonal system b) trigonal system c) diagonal system d) hexagonal system

14) Body centred cubic lattice has a coordination number of

a) 4 b) 8 c) 12 d) 6

15) If body centred cubic structure, the space occupied is about

a) 68% b) 53% c) 38% d) 32%

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16) The number of octahedral voids in a unit cell of a cubic close packed structures is
a) 1 b) 2 c) 4 d) 8

17) Percentage of free space in cubic close packed structure and in body centred packed structure are
respectively
a) 32% and 48% c) 48% and 26% c) 30% and 26% d) 26% and 32%

18) Niobium is found to crystallise with bcc structure and found to have density of 8.55 gcm -3. Determine the
atomic radius of niobium if its atomic mass is 93 u.
a) 143.1 pm b) 152.3 pm c) 167.5 pm d) 132.7 pm

19) The radii of Na+ and Cl ions are 95 pm and 181 pm respectively. Edge length of NaCl unit cell is
a) 276 pm b) 135 pm c) 552 pm d) 415 pm

20) A solid has a bcc structure. If the distance of closest approach between the two atoms is 1.73 , the edge
length of the cell is
a) 200 pm b) c) 142.2 pm d)

21) The number of atoms in 100 g of a fcc crystal with density. r = 10 g cm-3 and cell edge as 200 pm is equal
to
a) 3 × 1025 b) 0.5 × 1025 c) 1 × 1025 d) 2 × 1025

22) A metal has bcc structure and the edge length of its unit cell is 3.04 . The volume of the unit cell in cm 3
will be
a) 1.6 × 1021 b) 2.81× 10-23 c) 6.02× 10-23 d) 6.6 × 10-24

23) Potassium has a bcc structure with nearest neighbour distance 4.52 . Its atomic mass is 39. Its density
will be
a) 454 kg m-3 b) 804 kg m-3 c) 852 kg m-3 d) 910 kg m-3

24) An ionic crystal lattice has radius ratio of 0.410, its coordination number will be
a) 2 b) 3 c) 4 d) 6

25) In which of the following crystals alternate tetrahedral voids are occupied?
a) NaCl b) CsCl c) Na2O d) ZnS

26) In a solid ‘AB’ having the NaCl structure, A atoms form the ccp. If all the face centred atoms along one
of the axes are removed, then the resultant Stoichiometry of the solid is
a) A2B b) AB2 c) A3B4 d) A4B3

27) The coordination number of a cation occupying a tetrahedral hole and an octahedral hole respectively are
a) 4, 6 b) 6, 4 c) 8, 4 c) 4, 8

28) An ionic crystal lattice has r+/r radius ratio of 0.524, its coordination number is
a) 2 b) 4 c) 6 d) 8

29) The limiting radius ratio for tetrahedral shape is

a) 0 – 0.155 b) 0.115 – 0.225 c) 0.225 – 0.414 d) 0.414 – 0.732

30) Frenkel defect, in ionic solids, is mainly due to the migration of the
a) anion b) cation c) anion or cation d) anion and cation

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31) Schottky defect defines imperfection in the lattice structure of a
a) solid b) liquid c) gas d) plasma
32) Which one of the following has Frenkel defect?
a) NaCl b) AgBr c) Graphite d) Diamond

33) When NaCl crystal is doped with MgCl2, the nature of defect produced is
a) interstitial defect b) Schottky defect c) Frenkel defect d) impurity defect

34) Germanium is an example of

a) a n-type semiconductor b) a p-type semiconductor
c) an insulator d) none of these

35) Metals are ______ conductors of heat and electricity.

a) poor b) good c) semi d) any of these

36) n-type semiconductor is formed when trace amount of impurity is added to silicon. The number of
electrons in the impurity atom must be
a) 3 b) 5 c) 1 d) 2

37) Packing efficiency in cubic close packed structure and in body centred packed structure are respectively
a) 48 % and 26% b) 30% and 26% c) 74% and 68% d) 32% and 48%

38) CsBr has bcc structure with edge length 4.3. The shortest interionic distance in between CS + and Br is
a) 3.72 b) 1.86 c) 7.44 d) 4.3

39) In a compound, atoms of element Y form ccp lattice and those of element X occupy 2/3 rd of tetrahedral
voids. The formula of the compound will be
a) X3Y4 b) X4Y3 c) X2Y3 d) X2Y

40) Copper crystallises in fcc type unit cell. The edge length of unit cell is 360.8 pm. The density of metallic
copper is 8.92 g cm-3. Atomic mass of copper is
a) 63.07 b) 65.37 c) 61.50 d) 76.80

41) Select a ferromagnetic material from the following.

a) Dioxygen b) Chromium (IV) oxide
c) Benzene d) Dihydrogen monoxide

42) The number of carbon atoms per unit cell of diamond unit cell
a) 6 b) 1 c) 4 d) 8

43) Experimentally it was found that a metal oxide has formula M 0.98O. Metal M, is present as M 2+ and M3+ in
its oxide. Fraction of the metal which exists as M3+ would be
a) 5.08% b) 7.01% c) 4.08% d) 6.05%

44) The number of octahedral void(s) per atom present in a cubic close-packed structure is
a) 1 b) 3 c) 2 d) 4

45) A solid compound XY has NaCl structure. If the radius of the cation is 100 pm, the radius of the anion
(Y) will be
a) 275.1 pm b) 322.5 pm c) 241.5 pm d) 165.7 pm

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