1 The distance of the point (7, −3, −4) C;

from the plane passing through the Equation of Plane is =

points (2, −3,1), (−1,1, −2) and 𝑥−2 𝑦+3 𝑧−1
(3, −4,2) is: | −3 4 −3 | = 0
4 −5 4
𝑥−𝑧−1= 0
Distance of 𝑃(7, −3, −4) from Plane is
7+4−1
d=| | = 5√2
√2

4
5
5√2
4√2
2 1 1
B;
lim𝑡→0 (1sin2⁡ 𝑡 + 2sin2 ⁡ 𝑡 + 2 2
lim (1cosec ⁡ 𝑡 + 2cosec ⁡ 𝑡
1 sin2 ⁡ 𝑡 𝑡→0
⋯ . +𝑛 sin2 ⁡ 𝑡 ) is equal to 2⁡ 𝑡 sin2⁡ 𝑡
+ ⋯ … . +𝑛cosec )
2⁡ 𝑡 2⁡ 𝑡
1 cosec 2 cosec
= lim⁡ 𝑛 (( ) +( )
𝑡→0 n n
sin2 ⁡ 𝑡

+ ⋯ … . . +1)

=n
𝑛2 + 𝑛
𝑛
n(n + 1)
2
𝑛2
3 Let u
⃗ = î − ĵ − 2k̂, v
⃗ = 2î + ĵ − k̂, v
⃗ ⋅ A;
⃗⃗ = 2⁡ and v
w ⃗ ×w ⃗⃗ = 𝑢 ⃗ + 𝜆v⃗ . Then 𝑢 ⃗ ⋅𝑤
⃗⃗ ⃗ = (1, −1, −2), v
u ⃗ = (2,1, −1), v⃗ ⋅w
⃗⃗ = 2
is equal to ⃗ ×w
v ⃗⃗ = u ⃗ + 𝜆v ⃗ . . . (1)
Taking dot with 𝑤 ⃗⃗ in (1)
𝑤
⃗⃗ ⋅ (𝑣 × 𝑤 ⃗⃗ ) = 𝑢 ⃗ ⋅𝑤 ⃗⃗ + 𝜆𝑣 ⋅ 𝑤
⃗⃗
⇒0=𝑢 ⃗ ⋅𝑤 ⃗⃗ + 2𝜆
Taking dot with v ⃗ in (1)
⃗ ⋅ (v
v ⃗ ×w ⃗⃗ ) = u ⃗ ⋅v ⃗ + 𝜆v ⃗ ⋅v
⃗
⇒ 0 = (2 − 1 + 2) + 𝜆(6)
1
𝜆=−
2
⇒𝑢 ⃗ ⋅𝑤⃗⃗ = −2𝜆 = 1
1
3
2
2
2
−
3
4 The value ∑22
r=0 ⁡ Cr ⁡ Cr is
22 23 A;
22 22

∑ ⁡22 C 23
r ⋅ ⁡ Cr = ∑ ⁡22 Cr ⋅ ⁡23 C23−r
r=0 r=0
= ⁡45 C23
 ⁡45 C23
⁡44 C23
⁡45 C24
⁡44 C22
5 Let a tangent to the curve y 2 = 24x A;
meet the curve xy = 2 at the points A y 2 = 24x
and B. Then the mid points of such line a=6
segments 𝐴𝐵 lie on a parabola with the xy = 2
AB ≡ ty = x + 6t 2 . . . (1)
AB ≡ T = S1
kx + hy = 2hk . . . (2)
From (1) and (2)
k h 2hk
= =
1 −t −6t 2
⇒ then locus is y 2 = −3x
Therefore, directrix is 4𝑥 = 3
directrix 4𝑥 = 3
directrix 4𝑥 = −3
3
Length of latus rectum 2
Length of latus rectum 2
6 Let N denote the number that turns up C;
when a fair die is rolled. If the x+y+z = 1
probability that the system of 2x + Ny + 2z = 2
equations 3x + 3y + Nz = 3
𝑥+𝑦+𝑧 = 1 1 1 1
2𝑥 + 𝑁𝑦 + 2𝑧 = 2 Δ = |2 N 2 |
3𝑥 + 3𝑦 + 𝑁𝑧 = 3 3 3 N
𝑘 = (N − 2)(N − 3)
has unique solution is 6 , then the sum
For unique solution Δ ≠ 0
of value of k and all possible values of So N ≠ 2,3
N is 4
⇒ P (system has unique solution) = 6
So k = 4
Therefore sum = 4 + 1 + 4 + 5 + 6 =
20
18
19
20
21
7 1+√3 8+4√3 C;
tan−1 ⁡ ( ) + sec −1 ⁡ (√ ) is
3+√3 6+3√3
1 + √3 8 + 4√3
equal to tan−1 ⁡ ( ) + sec −1 ⁡ (√ )
3 + √3 6 + 3√3
1 2 𝜋
= tan−1 ⁡ ( ) + sec −1 ⁡ ( ) =
√3 √3 3
𝜋
4
𝜋
2
𝜋
3
𝜋
6
8 Let PQR be a triangle. The points A, B B;
and C are on the sides QR, RP and PQ Let 𝑃 is ⃗0, 𝑄 is q
⃗ and R is r
QA RB PC
respectively such that AR = BP = CQ = A is
⃗ +r⃗
2q
, B is
2r⃗
and C is 3
⃗
q
3 3
1 Area⁡(△PQR) 1
. Then is equal to Area of △ PQR is = 2 |q ⃗ × r|
2 Area (△ABC)
1
⃗⃗⃗⃗⃗ × ⃗⃗⃗⃗⃗
Area of △ ABC is |AB AC| 2
r − 2q
⃗ −r − q⃗
⃗⃗⃗⃗⃗
AB = , ⃗⃗⃗⃗⃗
AC =
3 3
1
Area of △ ABC = |q ⃗ × r|
6
Area (ΔPQR)
=3
Area (ΔABC)
4
3
2
5
2
9 If A and B are two non-zero n × n D;
matrics such that A2 + B = A2 B, then A2 + B = A2 B
(𝐴2 − 𝐼)(𝐵 − 𝐼) = 𝐼
𝐴2 + 𝐵 = 𝐴2 𝐵
𝐴2 (𝐵 − 𝐼) = 𝐵
𝐴2 = 𝐵(𝐵 − 𝐼)−1
𝐴2 = 𝐵(𝐴2 − 𝐼)
𝐴2 = 𝐵𝐴2 − 𝐵
𝐴2 + 𝐵 = 𝐵𝐴2
𝐴2 𝐵 = 𝐵𝐴2
AB = I
A2 B = I
A2 = I or B = I
A2 B = BA2
10 Let 𝑦 = 𝑦(𝑥) be the solution of the A;
differential equation 𝑥 3 𝑑𝑦 + (𝑥𝑦 − 𝑑𝑦 1 − 𝑥𝑦 1 𝑦
1 = 3 = 3− 2
1)𝑑𝑥 = 0, 𝑥 > 0, 𝑦 (2) = 3 − 𝑒. Then 𝑑𝑥 𝑥 𝑥 𝑥
𝑑𝑦 𝑦 1
𝑦(1) is equal to + =
𝑑𝑥 𝑥 2 𝑥 3
1 1
⁡ 𝑑𝑥
If = 𝑒 ∫ 𝑥2 = 𝑒 −𝑥
1 1 1 1
𝑦 ⋅ 𝑒 −𝑥 = ∫ ⁡ 𝑒 𝑥 ⋅ 3 𝑑𝑥 ( put − = 𝑡)
𝑥 𝑥
1
𝑦 ⋅ 𝑒 −𝑥 = − ∫ ⁡ 𝑒 𝑡 ⋅ 𝑡𝑑𝑡
1
1
𝑦 = + 1 + 𝐶𝑒 𝑥 where C is
𝑥
constant
1
Put 𝑥 =
2
3 − e = 2 + 1 + Ce2
1
C=−
e
𝑦(1) = 1
1
𝑒
 2−e
3
11 The area enclosed by the curves y 2 + C;
4x = 4 and y − 2x = 2 is:

𝑦 2 + 4𝑥 = 4
𝑦 2 = −4(𝑥 − 1)
2 4 − 𝑦2 𝑦 − 2
𝐴 = ∫−4 ( − ) 𝑑𝑦 = 9
4 2
25
3
22
3
9
23
3
12 Let 𝛼 be a root of the equation (a − B;
c)x 2 + (b − a)x + (c − b) = 0 where 𝛼2 𝛼 1
a, b, c are distinct real numbers such Δ = 0 = | 1 1 1|
that the matrix a b c
𝛼2 𝛼 1 ⇒ 𝛼 2 (c − b) − 𝛼(c − a) + (b − a) = 0
[ 1 1 1] It is singular when 𝛼 = 1
a b c (𝑎 − 𝑐)2 (𝑏 − 𝑎)2
+
(𝑏 − 𝑎)(𝑐 − 𝑏) (𝑎 − 𝑐)(𝑐 − 𝑏)
is singular. Then the value of (𝑐 − 𝑏)2
(𝑎−𝑐)2 (𝑏−𝑎)2 (𝑐−𝑏)2 +
+ (𝑎−𝑐)(𝑐−𝑏) + (𝑎−𝑐)(𝑏−𝑎) is (𝑎 − 𝑐)(𝑏 − 𝑎)
(𝑏−𝑎)(𝑐−𝑏)
(𝑎 − 𝑏) + (𝑏 − 𝑐)3 + (𝑐 − 𝑎)3
3

(𝑎 − 𝑏)(𝑏 − 𝑐)(𝑐 − 𝑎)
(𝑎 − 𝑏)(𝑏 − 𝑐)(𝑐 − 𝑎)
=3 =3
(𝑎 − 𝑏)(𝑏 − 𝑐)(𝑐 − 𝑎)
6
3
9
12
13 The distance of the point (−1,9, −16) C;
from the plane 2x + 3y − z = 5 𝑥+1 𝑦−9
Equation of line 3 = −4 = 12
𝑧+16
𝑥+4
measured parallel to the line 3 = G.P on line (3𝜆 − 1, −4𝜆 + 9,12𝜆 − 16)
2−𝑦
=
𝑧−3
is point of intersection of line & plane
4 12
6𝜆 − 2 − 12𝜆 + 27 − 12𝜆 + 16 = 5
𝜆=2
Point (5,1,8)
Distance = √36 + 64 + 576 = 26
13√2
31
26
 20√2
14 For three positive integers A;
2 2
𝑝, 𝑞, 𝑟, 𝑥 𝑝𝑞 = 𝑦 𝑞𝑟 = 𝑧 𝑝 𝑟 and 𝑟 = 𝑝𝑞 + pq2 = log x ⁡ 𝜆
1 such that 3,3log 𝑦 ⁡ 𝑥, 3log 𝑧 ⁡ 𝑦, 7log 𝑥 ⁡ 𝑧 qr = log y ⁡ 𝜆
are in A.P. with common difference 2.
1 p2 r = log z ⁡ 𝜆
qr r
Then r − p − q is equal to log y ⁡ x = 2 = … … . (1)
pq pq
pq2 q2
log x ⁡ z = 2 = … … … (2)
p r pr
p2 r p2
log z ⁡ y = = … … … (3)
qr q
3r 3p2 7q2
3, , , in A.P
pq q pr
3r 1
−3=
pq 2
7
𝑟 = 𝑝𝑞
6
𝑟 = 𝑝𝑞 + 1
𝑝𝑞 = 6 … (5)
𝑟 = 7 … (6)
3𝑝 2
=4
𝑞
After solving 𝑝 = 2 and 𝑞 = 3
2
6
12
−6
15 Let p, q ∈ ℝ and (1 − √3i)200 = B;
2199 (p + iq), i = √−1 Then p + q + q2 (1 − √3i)200 = 2199 (p + iq)
and p − q + q2 are roots of the 𝜋 𝜋 200
2200 (cos⁡ − 𝑖sin⁡ ) = 2199 (𝑝 + 𝑖𝑞)
equation. 3 3
1 √3
2 (− − 𝑖 ) = 𝑝 + 𝑖𝑞
2 2
𝑝 = −1, 𝑞 = −√3
𝛼 = p + q + q2 = 2 − √3
𝛽 = p − q + q2 = 2 + √3
𝛼+𝛽 =4
𝛼⋅𝛽=1
equation 𝑥 2 − 4𝑥 + 1 = 0
x 2 + 4x − 1 = 0
x 2 − 4x + 1 = 0
𝑥 2 + 4𝑥 + 1 = 0
𝑥 2 − 4𝑥 − 1 = 0
16 The relation R = {(a, b): gcd⁡(a, b) = D;
1,2a ≠ b, a, b ∈ ℤ} is: Reflexive: (𝑎, 𝑎) ⇒ gcd of (𝑎, 𝑎) = 1
Which is not true for every a ∈ Z.
Symmetric:
Take a = 2, b = 1 ⇒ gcd⁡(2,1) = 1
Also 2a = 4 ≠ b
Now when a = 1, b = 2 ⇒ gcd⁡(1,2) = 1
Also, now 2a = 2 = b
 Hence a = 2 b
⇒ R is not Symmetric
Transitive:
Let a = 14, b = 19, c = 21
gcd⁡(a, b) = 1
gcd⁡(b, c) = 1
gcd⁡(a, c) = 7
Hence not transitive
⇒ R is neither symmetric nor transitive.
transitive but not reflexive
symmetric but not transitive
reflexive but not symmetric
neither symmetric nor transitive
17 The compound statement (∼ (P ∧ Q)) ∨ A;
((∼ P) ∧ Q) ⇒ ((∼ P) ∧ (∼ Q)) is Let 𝐫 = (∼ (P ∧ Q)) ∨ ((∼ P) ∧ Q); ⁡s =
equivalent to ((∼ P) ∧ (∼ Q))
∼ (P (−P) r
P Q r s
∧ Q) ∧Q →S

T T F F F F T

T F T F T F F

F T T T T F F

F F T F T T T

Option (A): ((∼ P) ∨ Q) ∧ ((∼ Q) ∨ P)

is equivalent to (not of only 𝑃) ∧ ( not of
only 𝑄)
= ( Both 𝑃, 𝑄) and (neither 𝑃 nor 𝑄 )
((∼ P) ∨ Q) ∧ ((∼ Q) ∨ P)
(∼ Q) ∨ P
((∼ P) ∨ Q) ∧ (∼ Q)
(∼ P) ∨ Q
18 1
𝑥 2 sin⁡ (𝑥) , 𝑥 ≠ 0 B;
Let 𝑓(𝑥) = { ; Then 1
0 ,𝑥 = 0 Continuity of 𝑓(𝑥): 𝑓(0+ ) = ℎ2 ⋅ sin⁡ ℎ =
at 𝑥 = 0 0
−1
𝑓(0− ) = (−ℎ)2 ⋅ sin⁡ ( ) = 0
ℎ
𝑓(0) = 0
𝑓(𝑥) is continuous
𝑓(0 + ℎ) − 𝑓(0)
𝑓 ′ (0+ ) = lim
ℎ→0 ℎ
1
ℎ2 ⋅ sin⁡ (ℎ) − 0
= =0
ℎ
𝑓(0 − ℎ) − 𝑓(0)
𝑓 ′ (0− ) = lim
ℎ→0 −ℎ
1
ℎ2 ⋅ sin⁡ (−ℎ) − 0
= =0
−ℎ
 f(x) is differentiable
1 1 −1
𝑓 ′ (𝑥) = 2𝑥 ⋅ sin⁡ ( ) + 𝑥 2 ⋅ cos⁡ ( ) ⋅ 2
𝑥 𝑥 𝑥
𝑓 ′ (𝑥)
1 1
= {2𝑥 ⋅ sin⁡ (𝑥 ) − cos⁡ (𝑥 ) , 𝑥 ≠ 0
0, 𝑥=0
1
⇒ 𝑓 (𝑥) is not continuous (as cos⁡ (𝑥) is
′

highly oscillating at 𝑥 = 0 )
f is continuous but not differentiable
f is continuous but f ′ is not continuous
𝑓 and 𝑓 ′ both are continuous
f ′ is continuous but not differentiable
19 The equation 𝑥 2 − 4𝑥 + [𝑥] + 3 = 𝑥[𝑥], D;
where [𝑥] denotes the greatest integer x 2 − 4x + [x] + 3 = x[x]
function, has: ⇒ x 2 − 4x + 3 = x[x] − [x]
⇒ (x − 1)(x − 3) = [x]. (x − 1)
⇒ x = 1 or x − 3 = [x]
⇒ x − [x] = 3
⇒ {x} = 3 (Not Possible)
Only one solution 𝑥 = 1 in (−∞, ∞)
exactly two solutions in (−∞, ∞)
no solution
a unique solution in (−∞, 1)
a unique solution in (−∞, ∞)
20 Let Ω be the sample space and A ⊆ Ω C;
be an event. Given below are two Ω = sample space
statements: A = be an event
(S1): If 𝑃(𝐴) = 0, then 𝐴 = 𝜙 If P(A) = 0 ⇒ A = 𝜙
(S2): If P(A) =, then A = Ω If P(A) = 1 ⇒ A = Ω
Then Then both statements are true.
only (S1) is true
only (S2) is true
both (S1) and (S2) are true
both (S1) and (S2) are false
#1,2,3,4, SINGLE ANSWER CORRECT TYPE
5,
6,7,8,9,1
0,
11,12,13
,
14,15,16
,
17,18,19
,
20
21 Let C be the largest circle centred at 118;
(2,0) and inscribed in the ellipse =
𝑥2 𝑦2
+ = 1.
36 16
If (1, 𝛼) lies on C, then 10𝛼 2 is equal to
______.
 𝑥2 𝑦2
Equation of normal of ellipse 36 + 16 = 1
at any point P(6cos⁡ 𝜃, 4sin⁡ 𝜃) is
3sec⁡ 𝜃𝑥 − 2cosec⁡ 𝜃𝑦 = 10 this normal
is also the normal of the circle passing
through the point (2,0) So,
6sec⁡ 𝜃 = 10 or sin⁡ 𝜃 = 0 (Not possible)
3 4
cos⁡ 𝜃 = 5 and sin⁡ 𝜃 = 5 so point P =
18 16
(5 , 5)
So, the largest radius of circle
√320
𝑟=
5
So the equation of circle (𝑥 − 2)2 +
64
𝑦2 = 5
Passing it through (1, 𝛼)
59
Then 𝛼 2 = 5
10𝛼 2 = 118
22 2023 1012;
Suppose r
r =0
2 2023
Cr = 2023    22022 . using result
n
Then the value of α is _______ ∑ r 2 ⁡n Cr = n(n + 1) ⋅ 2n−2
r=0
2023
Then r
r =0
2 2023
Cr = 2023  2024  22021

= 2023 × 𝛼 × 22022 So,

⇒ 𝛼 = 1012
23 3
22;
The value of 12 x 2 − 3x + 2 dx is______ 3
0 12 x 2 − 3x + 2 dx
0
3 2
 3 1
= 12  x −  −
0 
2 4
3
If x − = t
2
dx = dt
3/2
1
= 24  t 2 − dt
0
4
 1/2  1
3/2
 1 
= 24  −   t 2 −  dt +   t 2 −  dt  = 22
 0  4 1/2 
4  
24 The number of 9 digit numbers, that 60;
can be formed using all the digits of the Even digits occupy at even places
 number 123412341 so that the even 4! 5! 24 × 120
× = = 60
digits occupy only even places, is ______ 2! 2! 2! 3! 4 × 12
25 Let 𝜆 ∈ ℝ and let the equation 𝐸 be 5;
|x|2 − 2|x| + |𝜆 − 3| = 0. Then the |x|2 − 2|x| + |𝜆 − 3| = 0
largest element in the set |x|2 − 2|x| + |𝜆 − 3| − 1 = 0
S = {x + 𝜆: x is an integer solution of (|x| − 1)2 + |𝜆 − 3| = 1
E} is ______ At 𝜆 = 3, x = 0 and 2,
at 𝜆 = 4 or 2, then
x = 1 or − 1
So maximum value of x + 𝜆 = 5
26 A boy needs to select five courses from 546;
12 available courses, out of which 5 For at most two language courses
courses are language courses. If he can = ⁡5 C2 × ⁡7 C3 + ⁡5 C1 × ⁡7 C4 + ⁡7 C5 = 546
choose at most two language courses,
then the number of ways he can choose
five courses is _______
27 Let a tangent to the Curve 9𝑥 2 + 7;
16𝑦 2 = 144 intersect the coordinate Equation of tangent at point
axes at the points A and B. Then, the xcos⁡ 𝜃 ysin⁡ 𝜃
P(4cos⁡ 𝜃, 3sin⁡ 𝜃) is 4 + 3 = 1
minimum length of the line segment
So 𝐴 is (4sec⁡ 𝜃, 0) and point B is
𝐴𝐵 is _______.
(0,3cosec⁡ 𝜃)
Length AB = √16sec 2 ⁡ 𝜃 + 9cosec 2 ⁡ 𝜃 =
√25 + 16tan2 ⁡ 𝜃 + 9cot 2 ⁡ 𝜃 ≥ 7
28 The value of 2;
 

( cos x ) ( cos x )
2023 2023
2 2
8 8

 0 ( sin x )2023 + ( cos x )2023
dx is _______ 
 0 ( sin x )2023 + ( cos x )2023
dx ..

. (1)
a a

Using  f ( x ) dx =  f (a − x ) dx
0 0


( sin x )
2023
2
8
I= 
 0 ( sin x )2023 + ( cos x )2023
dx ..

. (2)
Adding (1) and (2)


82
2I =  1 dx
0
I =2
29 The shortest distance between the 14;
𝑥−2 𝑦+1 𝑧−6 𝑥−6
lines 3 = 2 = 2 and 3 = 2 =
1−𝑦 Shortest distance between the lines
𝑧+8 4 2 −14
is equal to ______ |3 2 2 |
0
= 3 −2 0
𝑖ˆ 𝑗ˆ 𝑘ˆ
|3 2 2 |
3 −2 0
16 + 12 + 168 196
= = = 14
ˆ
| − 4𝑖ˆ + 6𝑗ˆ − 12𝑘 | 14
30 The 4th term of GP is 500 and its 12;
1
common ratio is 𝑚 , m ∈ N. Let Sn T4 = 500 where a = first term
1
denote the sum of the first n terms of r = common ratio = ,m∈N
1 m
this GP. If 𝑆6 > 𝑆5 + 1 and 𝑆7 < 𝑆6 + 2, 𝑎𝑟 3 = 500
then the number of possible values of 𝑎
= 500
𝑚 is ______ m3
𝑆𝑛 − 𝑆𝑛−1 = 𝑎𝑟 𝑛−1
1
S6 > S5 + 1⁡ and S7 − S6 <
2
𝑎 1
S6 − S5 > 1 <
𝑚6 2
𝑎𝑟 5 > 1 m3 > 103
500
>1 m > 10 . . . (2)
m2
2
m < 500 . . . (1)
From (1) and (2)
m = 11,12,13 … … … … ,22
So, number of possible values of m is 12.
#21,22,2 NUMERICAL TYPE
3,24,25,
26,27,28
,29,30
31 Two long straight wires 𝑃 and 𝑄 A;
carrying equal current 10 A each were Force per unit length between two
kept parallel to each other at 5 cm 𝜇0 i1 i2
parallel straight wires = 2𝜋d
distance. Magnitude of magnetic force 𝜇0(10)2
experienced by 10 cm length of wire 𝑃 𝐹1 2𝜋(5 cm) 1
is 𝐹1 . If distance between wires is = 𝜇0 (20)2
=
𝐹2 8
halved and currents on them are 5 cm
2𝜋( 2 )
doubled, force 𝐹2 on 10 cm length of ⇒ 𝐹2 = 8 F1
wire 𝑃 will be:
8𝐹1
10 F1
𝐹1 /8
𝐹1 /10
32 Given below are two statements: B;
Statement-I: An elevator can go up or Statement-1
down with uniform speed when its When elevator is moving with uniform
weight is balanced with the tension of speed T = Fg
its cable.
Statement-II: Force exerted by the
floor of an elevator on the foot of a
person standing on it is more than
his/her weight when the elevator goes
down with increasing speed.
In the light of the above statements,
choose the correct answer from the Statement-2
options given below: When elevator is going down with
increasing speed, its acceleration is
downward.
Hence,
𝑊
𝑊−𝑁= 𝑔 ×𝑎
 𝑎
𝑁 = 𝑊 (1 − ) i.e. less than weight.
𝑔
Both statement I and statement II are
false
Statement I is true but Statement II is
false
Both Statement I and Statement II are
true
Statement I is false but Statement II is
true
33 From the photoelectric effect C;
experiment, following observations are (A) Stopping potential depends on both
made. Identify which of these are frequency of light and work
correct. function.
A. The stopping potential depends only (B) Saturation current ∝ intensity of
on the work function of the metal. light
B. The saturation current increases as (C) Maximum KE depends on
the intensity of incident light increases. frequency
C. The maximum kinetic energy of a (D) Photoelectric effect is explained
photo electron depends on the using particle theory
intensity of the incident light.
D. Photoelectric effect can be explained
using wave theory of light.
Choose the correct answer from the
options given below:
B, C only
A, C, D only
B only
A, B, D only
34 The weight of a body at the surface of D;
earth is 18 N. The weight of the body at Acceleration due to gravity at height h
g
an altitude of 3200 km above the 𝑔′ = h 2
earth's surface is (given, radius of [1+R]
earth 𝑅𝑒 = 6400 km ) So, weight at given height
mg 18
mg ′ = = =8N
h 2 1 2
[1 + R] [1 + 2]

9.8 N
4.9 N
19.6 N
8N
35 A 100 m long wire having cross- D;
sectional area 6.25 × 10−4 m2 and Fℓ
Elongation in wire 𝛿 = AY
Young's modulus is 1010 Nm−2 is 250 × 100
subjected to a load of 250 N, then the 𝛿=
6.25 × 10−4 × 1010
elongation in the wire will be: 𝛿 = 4 × 10−3 m
6.25 × 10−3 m
4 × 10−4 m
6.25 × 10−6 m
4 × 10−3 m
36 1 g of a liquid is converted to vapour at A;
3 × 105 Pa pressure. If 10% of the heat Work done = PΔV
supplied is used for increasing the = 3 × 105 × 1600 × 10−6
volume by 1600 cm3 during this phase = 480 J
change, then the increase in internal Only 10% of heat is used in work done.
energy in the process will be: Hence ΔQ = 4800 J
The rest goes in internal energy, which
is 90% of heat.
Change in internal energy = 0.9 ×
4800 = 4320 J
4320 J
432000 J
4800 J
4.32 × 108 J
37 A modulating signal is a square wave, D;
as shown in the figure. Modulation index ⁡=
Amplitude of mod ulating signal
Amplitude of carrier wave
1
𝜇=
2

If the carrier wave is given as 𝑐(𝑡) =

2sin⁡(8𝜋𝑡) volts, the modulation index
is:
1/4
1
1/3
1/2
38 As per given figure, a weightless pulley B;
𝑃 is attached on a double inclined
frictionless surface. The tension in the
string (massless) will be (if 𝑔 = 10 m/
s2 )

T − gsin⁡ 30∘ = a . . . (2)

Solving (1) and (2) we get
20√3 − T = 4 T − 20
T = 4(√3 + 1)N
(4√3 + 1)N
4(√3 + 1)N
4(√3 − 1)N
(4√3 − 1)N
39 Given below are two statements: One is B;
labelled as Assertion 𝐀 and the other is Photodiodes are operated in reverse
labelled as Reason 𝐑 Assertion A : bias as fractional change in current due
Photodiodes are preferably operated in to light is more easy to detect in reverse
reverse bias condition for light bias.
intensity measurement.
Reason 𝐑 : The current in the forward
 bias is more than the current in the
reverse bias for a 𝑝 − 𝑛 junction diode.
In the light of the above statement,
choose the correct answer from the
options given below :
A is false but 𝑅 is true
Both 𝐀 and 𝐑 are true but 𝐑 is NOT the
correct explanation of 𝐀
𝐀 is true but 𝑅 is false
Both 𝐀 and 𝐑 are true and 𝐑 is the
correct explanation of 𝐀
40 If ⃗E and K
⃗ represent electric field and A;
propagation vectors of the EM waves in Magnetic field vector will be in the
vacuum, then magnetic field vector is direction of K̂ × Ê magnitude of
𝐸 𝐾 1
given by : (𝜔) angular frequency): 𝐵 = 𝐶 = 𝜔 𝐸 Or ⃗B = 𝜔 (K⃗ × ⃗E)
1
(K⃗ × ⃗E)
𝜔
𝜔(E⃗ ×K ⃗)
𝜔(K⃗ × ⃗E)
⃗ × ⃗E
K
41 A circular loop of radius r is carrying C;
current AA. The ratio of magnetic field Magnetic field due to current carrying
at the centre of circular loop and at a circular loop on its axis is given as
distance 𝑟 from the center of the loop 𝜇0 ir 2
on its axis is: 2(r 2 + x 2 )3/2
𝜇 i
At centre, 𝑥 = 0, 𝐵1 = 2r0
𝜇0 i
At 𝑥 = 𝑟, 𝐵2 =
2 × 2√2r
B1
= 2√2
B2
1: 3√2
3√2: 2
2√2: 1
1: √2
42 A travelling wave is described by the C;
equation 𝑦(𝑥, 𝑡) = [0.05sin⁡(8x − 4t]m From the given equation k = 8 m−1 and
The velocity of the wave is: [all the 𝜔 = 4rad/s
quantities are in SI unit] 𝜔
Velocity of wave =
k
4
v = = 0.5 m/s
8
4 ms−1
2 ms−1
0.5 ms−1
8 ms−1
43 As shown in the figure, a network of D;
resistors is connected to a battery of Equivalent resistance of circuit
24 V with an internal resistance of 3Ω. 𝑅eq ⁡= 3 + 1 + 2 + 4 + 2
The currents through the resistors 𝑅4 ⁡= 12Ω
and 𝑅5 are 𝐼4 and 𝐼5 respectively. The
values of 𝐼4 and 𝐼5 are:
 24
Current through battery 𝑖 = 12 = 2 A

𝑅5 5 2
𝐼4 = ×2 = ×2= A
𝑅4 + 𝑅5 20 + 5 5

2 8
𝐼5 = 2 − = A
5 5

8 2
I4 = 5 A and I5 = 5 A
24 6
𝐼4 = A and 𝐼5 = 5 A
5
6 24
𝐼4 = A and 𝐼5 = 5 A
5
2 8
𝐼4 = A and 𝐼5 = 5 A
5
44 Given below are two statements: B;
Statement I: If the Brewster's angle for
the light propagating from air to glass
is 𝜃B , then Brewster's angle for the
light propagating from glass to air is
𝜋
− 𝜃𝐵 .
2
Statement II: The Brewster's angle for
the light propagating from glass to air
is tan−1 ⁡(𝜇g ) where 𝜇g is the refractive 𝜇a sin⁡ 𝑖1 = 𝜇g sin⁡(90 − 𝑖1 )
𝜇g
index of glass. tan⁡ 𝑖1 =
In the light of the above statements, 𝜇a
choose the correct answer from the When going from glass to air
𝜇a
options given below: tan⁡ 𝑖2 = = cot⁡ 𝑖1
𝜇g
Hence,
𝜋
𝑖2 = − 𝑖1
2
Both Statements I and Statement II are
true.
Statement I is true but Statement II is
false.
Both Statement I and Statement II are
false.
Statement I is false but Statement II is
true.
45 If two charges q1 and q2 are separated A;
with distance ' d ' and placed in a 1 q1 q2
F= (in medium)
medium of dielectric constant K. What (4𝜋𝜀0 ) kd2
will be the equivalent distance 1 q1 q2
between charges in air for the same FAir =
4𝜋𝜀0 d′2
electrostatic force? q1 q2 q1 q2
2 =
4𝜋𝜀0 kd 4𝜋𝜀0 d′2
d′ = d√k
d√k
k√d
1.5 d√k
2𝑑√𝑘
46 Consider the following radioactive C;
decay process A ⎯⎯ 
→ 214
−
 
82 A1 ⎯⎯ → 214
83 A2 ⎯⎯→ 214
218
84 83 A3
 −   + 
218
A ⎯⎯ → A1 ⎯⎯ → A2 ⎯⎯ → A3 ⎯⎯ → A4 ⎯⎯
→214A5 ⎯⎯ →
 A210 + 
83 A3 ⎯⎯ → 81 A4 ⎯⎯ → 80 A5 ⎯⎯ → 210
84 6 210
80 A6
The mass number and the atomic
number A6 are given by:
210 and 82
210 and 84
210 and 80
211 and 80
47 Given below are two statements: B;
Statements I: The temperature of a gas Statement-I
is −73∘ C. When the gas is heated to T1 = −73∘ C = 200 K
527 C, the root mean square speed of
∘ T2 = 527∘ C = 800 K
the molecules is doubled. 3RT
Statement II: The product of pressure V1 √ 1
M
and volume of an ideal gas will be =
V2 3RTT2
equal to translational kinetic energy of √
M
the molecules.
In the light of the above statements, T1
=√
choose the correct answer from the T2
options given below:
200 1
=√ =
800 2
V2 = 2 V1 (True)
PV = nRT
3
Translational KE = 2 nRT (False)
Both statement I and Statement II are
true
Statement I is true but Statement II is
false
Both Statement I and Statement 𝐼 are
false
Statement I is false but Statement II is
true
48 The maximum vertical height to which C;
a man can throw a ball is 136 m. The v2
maximum horizontal distance upto H max = = 136 m
2g
which he can throw the same ball is: v2
R max = = 2Hmax
g
= 2(136)
= 272 m
192 m
136 m
272 m
68 m
49 10
A conducting loop of radius cm is B;
√𝜋 d𝜙 BA − 0
placed perpendicular to a uniform EMF = =
magnetic field of 0.5 T. The magnetic dt t
0.12
field is decreased to zero in 0.5 s at a A = 𝜋r 2 = 𝜋 ( ) = 0.01
steady rate. The induced emf in the 𝜋
circular loop at 0.25 s is: B = 0.5
 (0.5)(0.01)
EMF = = 0.01 V = 10mV
0.5
emf = 1mV
emf = 10mV
emf = 100mV
emf = 5mV
50 Match the List-I with List-II B;
List – I List – II (A) Planck's constant
(A Planck's (I) [M1 L2 T −2 ] h𝑣 = E
) constant E M1 L2 T−2
h = 𝑣 = T−1 = M1 L2 T−1 (III)
(h)
(B) 𝐸 = 𝑞𝑉
(B Stopping (II) [M1 L1 T −1 ]
𝐸 𝑀1 𝐿2 𝑇 −2
) potential 𝑉= = = 𝑀1 𝐿2 𝑇 −3 𝐴−1 (IV)
(Vs) 𝑞 A1 𝑇1
(C Work (III [M1 L2 T −1 ] (C) 𝜙 (work function) = energy
) function ) 𝑀1 𝐿2 𝑇 −2 (I)
(Ø) (D) Momentum (p) = F.t
(D Momentu (IV [M1 L2 T −3 A−1 ] = M1 L1 T−2 T1
) m (p) ) = M1 L1 T−1 (II)
A-III, B-I, C-II, D-IV
A-III, B-IV, C-I, D-II
A-II, B-IV, C-III, D-I
A-I, B-III, C-IV, D-II
#31,32,3
3,34,35,
36,37,38
,39,40,
41,42,43
,44,45,
46,47,48
,49,50
51 A spherical body of mass 2 kg starting 40;
from rest acquires a kinetic energy of 1
× 2 × v 2 = 10000
10000 J at the end of 5th second. The 2
force acted on the body is ______ N. ⇒ v 2 = 10000
⇒ v = 100 m/s
⇒ v = at = a × 5 = 100
⇒ a = 20 m/s2
F = ma = 2 × 20 = 40 N
52 A block of mass 2 kg is attached with 5;
two identical springs of spring 2kx
F = −2kx, a = − ,
constant 20 N/m each. The block is m
placed on a frictionless surface and the 2k 2×20
𝜔=√ =√ = √20rad/s
ends of the springs are attached to m 2
rigid supports (see figure). When the 2𝜋 2𝜋 𝜋
T= = =
mass is displaced from its equilibrium 𝜔 √20 √5
position, it executes a simple harmonic
motion. The time period of oscillation 𝑥=5
𝜋
is in SI unit. The value of 𝑥 is
√𝑥
53 A hole is drilled in a metal sheet. At 12;
27∘ C, the diameter of hole is 5 cm. d0 at 27∘ C& d1 at 177 ∘ C
When the sheet is heated to 177∘ C, the d1 = d0 (1 + 𝛼ΔT)
change in the diameter of hole is d × d1 − d0 = 5 × 1.6 × 10−5 × 150 cm
10−3 cm. The value of d will be ______ if = 12 × 10−3 cm
coefficient of linear expansion of the
metal is 1.6 × 10−5 /⁡∘ C.
54 In the circuit shown in the figure, the 10;
ratio of the quality factor and the band R
Δ𝜔 =
width is ______ s. L
𝜔0 L
Q= = 𝜔0
Δ𝜔 R
1 1
𝜔0 = = −3
√3 × 27 × 10−6 9 × 10
L
Q 𝜔0 L2 1 L2
R
= R = 𝜔0 2 = √
Δ𝜔 R LC R2
L
1 9
= × = 10 s
9 × 10−3 100
55 A hollow cylindrical conductor has 2;
length of 3.14 m, while its inner and ℓ
R = 𝜌 A, the cross-sectional area is
outer diameters are 4 mm and 8 mm
𝜋(b2 − a2 )
respectively. The resistance of the ℓ
conductor is n × 10−3 Ω. If the R=𝜌
resistivity of the material is 2.4 × 𝜋(b − a2 )
2

2.4 × 10−8 × 3.14

10−8 Ωm. The value of 𝑛 is ________. =
3.14 × (42 − 22 ) × 10−6
= 2 × 10−3 Ω
→n=2
56 As shown in the figure, a combination 120;
of a thin plano concave lens and a thin 1 1
= (1.75 − 1) (− )
plano convex lens is used to image an 𝑓1 30
object placed at infinity. The radius of ⇒ 𝑓1 = −40 cm
curvature of both the lenses is 30 cm 1 1
and refraction index of the material for = (1.75 − 1) ( ) ⇒ 𝑓2 = 40 cm
𝑓2 30
both the lenses is 1.75. Both the lenses Image from 𝐿1 will be virtual and on the
are placed at distance of 40 cm from left of 𝐿1 at focal length 40 cm. So, the
each other. Due to the combination, the object for 𝐿2 will be 80 cm from 𝐿2
image of the object is formed at which is 2f. Final image is formed at
distance x = ______cm, from concave 80 cm from L2 on the right.
lens. So x = 120

57 Solid sphere 𝐴 is rotating about an axis 110;

𝑃𝑄. If the radius of the sphere is 5 cm 2
Icm = MR2
then its radius of gyration about PQ 5
will be √𝑥 cm. The value of x is _________. IPQ = Icm + md2
 2
IPQ = mR2 + m(10 cm)2
5
For radius of gyration
I𝑃𝑄 = mk 2
2
k 2 = R2 + (10 cm)2
5
2
= (5)2 + 100
5
= 10 + 100 = 110
k = √110 cm
x = 110
58 Vectors a î + 𝑏ĵ + k̂ and 2î − 3ĵ + 4k̂ 1;
are perpendicular to each other when For two perpendicular vectors
𝑥
3a + 2 b = 7, the ratio of a to 𝑏 is 2 . The (𝑎𝑖ˆ + 𝑏𝑗ˆ + 𝑘ˆ) ⋅ (2𝑖ˆ − 3ĵ + 4k̂) = 0
value of 𝑥 is _________. 2a − 3 b + 4 = 0
On solving, 2a − 3 b = −4
Also given,
3a + 2 b = 7
We get a = 1, b = 2
a x 2a 2 × 1
= ⇒x= =
b 2 b 2
⇒x=1
59 Assume that protons and neutrons 11;
have equal masses. Mass of a nucleon is mass of nuclei
density of nuclei = volume of nuclei
1.6 × 10−27 kg and radius of nucleus is
1.6 × 10−27 A
1.5 × 10−15 A1/3 m. The approximate 𝜌=4
ratio of the nuclear density and water 𝜋(1.5 × 10−15 )3 A
3
density is 𝑛 × 1013 . The value of 𝑛 is 1.6 × 10−27
_______. = = 0.113 × 1018
14.14 × 10−45
𝜌w = ⁡ 103

Hence, = 11.31  1013
w
60 A stream of a positively charged 2;
q C
particles having m = 2 × 1011 kg and
velocity v⃗ 0 = 3 × 107 îm/s is deflected
by an electric field 1.8ĵkV/m. The
electric field exists in a region of 10 cm
along x direction. Due to the electric
field, the deflection of the charge F qE
a= = = (2 × 1011 )(1.8 × 103 )
particles in the 𝑦 direction is ______ m m
mm. = 3.6 × 1014 m/s2
d
Time to cross plates =
v
0.10
t=
3 × 107
1 1 0.01
y = at⁡2 = (3.6 × 1014 ) ( )
2 2 9 × 1014
= 0.2 × 0.01
= 0.002 m
2 mm
#51,52,5 NUMERICAL TYPE
3,54,55,
56,57,58
,59,60

61 Compound X undergoes following A;

sequence of reactions to give the
Lactone (Y)

62 Assertion A: Hydrolysis of an alkyl C;

chloride is a slow reaction but in the The rate of hydrolysis of alkyl chloride
presence of NaI, the rate of the improves because of better
hydrolysis increases. Nucleophilicity of Γ −.
Reason 𝐑: Γ is a good nucleophile as
well as a good leaving group.
In the light of the above statements,
choose the correct answer from the
options given below.
A is false but R is true
A is true but R is false
Both A and R are true and R is the
correct explanation of 𝐴
Both A and R are true but R is NOT the
correct explanation of 𝐴
63 Order of Covalent bond; C;
A. KF > KI; LiF > KF According to Fajan's Rule,
B. KF < KI; LiF > KF A. KF > KI − False; LiF > KF − True
C. SnCl4 > SnCl2 ; CuCl > NaCl B. KF < KI − True; LiF > KF − True
D. LiF > KF; CuCl < NaCl C. SnCl4 > SnCl2 − True; CuCl > NaCl −
E. KF < KI; CuCl > NaCl True
D. LiF > KF - True; CuCl < NaCl − False
E. KF < KI − True; CuCl > NaCl − True
C, E only
 B, C only
B, C, E only
A, B only
64 Increasing order of stability of the D;
resonance structure is: Order should be C < A < B < D

C, D, B, A
C, D, A, B
D, C, A, B
C, A, B, D
65 The magnetic moment of a transition C;
metal compound has been calculated Cr +2 : [Ar],3 d4 , 4 s0 n = 4, 𝜇 = √4(4 + 2) = √24
to be 3.87 B.M. The metal ion is ____ ⁡= 4.89BM
Mn+2 : [Ar],3 d5 , 4 s0 n = 5, 𝜇 = √5(5 + 2) = √35
⁡= 5.91BM
V +2 : [Ar],3 d3 , 4 s0 n = 3, 𝜇 = √3(3 + 2) = √15
⁡= 3.87BM
Ti+2 : [Ar],3 d2 , 4 s0 n = 2, 𝜇 = √2(2 + 2) = √8
⁡= 2.82BM

Cr 2+
Mn2+
V 2+
Ti2+
66 Match List I with List II. A;
List – I List – II Reverberatory furnace: Used for
(A Reverberato (I) Pig iron roasting of Copper.
) ry furnace Electrolytic cell: For reactive metal: Al
(B Electrolytic (II) Aluminiu Blast furnace: Hematite to Pig Iron
) cell m Zone Refining furnace: For
(C Blast furnace (III Silicon semiconductors: Si
) )
(D Zone (IV Copper
) Refining )
furnace
A - IV, B - II, C - I, D – III
 A - I, B - IV, C-II, D – III
A - I, B - III, C - II, D – IV
A - III, B - IV, C-I, D - II
67 It is observed that characteristic X-ray C;
spectra of elements show regularity. According to Henry Moseley √𝑣𝛼𝑧 − 𝑏
When frequency to the power ' 𝑛 ' i.e., 1
So n = 2
𝑣 n of X-rays emitted is plotted against
atomic number ' Z ', following graph is
obtained.
The value of ' 𝑛 ' is:

1
2
1
2
3
68 Which of the Phosphorus oxoacid can B;
create silver mirror from AgNO3
solution?

Oxyacid having P-H bond can reduce

AgNO3 to Ag.
(HPO3 )n
H4 P2 O5
H4 P2 O6
H4 P2 O7
69 The primary and secondary valencies D;
of cobalt respectively in [Co(NH3 )5 Cl]Cl2
[Co(NH3 )5 Cl]Cl2 are: Oxidation number of Co is +3.
So primary valency is 3.
It is an octahedral complex so secondary
valency 6 or Co-ordination number 6 .
3 and 5
2 and 6
2 and 8
3 and 6
70 An ammoniacal metal salt solution D;
gives a brilliant red precipitate on NH3 (aq)
Ni+2 + 2DMG ⟶ [Ni(DMG)2 ]
addition of dimethylglyoxime. The
Rosy Red complex
metal ion is:
Cu2+
Co2+
Fe2+
Ni2+
71 ‘R’ formed in the following sequence of B;
reaction is:

72 Match List I with List II. A;

List – I List – II Chlorophyll: Mg +2 complex
(A) Chlorophyll (I) Na2 CO3 Soda ash: Na2 CO3
(B) Soda ash (II) CaSO4 Dentistry, Ornamental work: CaSO4
(C) Dentistry, (III) Mg 2+ Used in white washing: Ca(OH)2
Ornamental
work
(D) Used in (IV) Ca(OH)2
white
washing
Choose the correct answer from the
options given below.
A – III, B – I, C – II, D – IV
A − III, B – I, C – III, D – IV
A − III, B − IV, C − I, D − II
A – II, B – III, C – IV, D – I
73 Statement I : For colloidal particles, the C;
values of colligative properties are of Statement I : For colloidal particles, the
small order as compared to values values of colligative properties are of
shown by true solutions at same small order as compared to values
concentration. shown by true solutions at same
Statement II : For colloidal particles, concentration. : True
the potential difference between the Statement II : For colloidal particles, the
fixed layer and the diffused layer of potential difference between the fixed
same charges is called the layer and the diffused layer of same
electrokinetic potential or zeta charges is called the electrokinetic
potential. potential or zeta potential. : True
In the light of the above statements,
choose the correct answer from the
options given below.
Statement 𝐼 is true but Statement II is
false
Statement I is false but Statement II is
true
Both Statement I and Statement II are
true
Both Statement I and Statement II are
false
74 Reaction of BeO with ammonia and A;
hydrogen fluoride gives ' A ' which on BeO + 2NH3 + 4HF → (NH4 )2 BeF4 +
thermal decomposition gives BeF2 and Δ
H2 O (NH4 )2 BeF4 ⟶ BeF2 + NH4 F
NH4 F. What is ' A ' ?
(NH4 )2 BeF4
H3 NBeF3
(NH4 )BeF3
(NH4 )Be2 F5
75 ‘A’ and ‘B’ formed in the following set D;
of reactions are:
76 In the following given reaction ‘A’ is D;

77 Decreasing order of the hydrogen B;

bonding in following forms of water is Ice > Liquid water > Impure water
correctly represented by Due to impurity extent of H-Bonding
A. Liquid water decreases.
B. Ice
C. Impure water
A=B>C
B>A>C
C>B>A
A>B>C
78 Given below are two statements: A;
Statement I : Noradrenaline is a Fact
neurotransmitter.
Statement II : Low level of
noradrenaline is not the cause of
depression in human.
In the light of the above statements,
choose the correct answer from the
options given below
Statement I is correct but Statement II
is incorrect
Statement I is incorrect but Statement
II is correct
Both Statement I and Statement II are
correct
Both Statement I and Statement II are
incorrect
79 In the depression of freezing point A;
experiment
A. Vapour pressure of the solution is
less than that of pure solvent
B. Vapour pressure of the solution is
more than that of pure solvent
C. Only solute molecules solidify at the
freezing point
D. Only solvent molecules solidify at
the freezing point Vapour pressure (V.P.) of solvent is
greater than vapour pressure (V.P.) of
solution. Only solvent freezes
A and D only
B and C only
A and C only
A only
80 Which of the following is true about A;
freons? Fact
These are chlorofluorocarbon
compounds
These are chemicals causing skin
cancer
These are radicals of chlorine and
chlorine monoxide
All radicals are called freons
#61,62,6 SINGLE ANSWER CORRECT TYPE
3,64,65,
66,67,68
,69,70,
71,72,73
,74,75,
76,77,78
,79,80
81 The dissociation constant of acetic is 10;
x × 10−5 . When 25 mL of Buffer of HOAc and NaOAc
0.2MCH3 COONa solution is mixed with
 25 mL of 0.02MCH3 COOH solution, the 0.1
pH = pKa + log⁡
pH of the resultant solution is found to 0.01
be equal to 5. The value of 𝑥 is ______. 5 = pKa + 1
pKa = 4
Ka = 10−4
x = 10
82 5 g of NaOH was dissolved in deionized 180;
water to prepare a 450 mL stock 5 1000
M= ×
solution. What volume (in mL ) of this 40 450
solution would be required to prepare M1 V1 = M2 V2
500 mL of 0.1M solution? 5 1000
( × ) × V1 = 0.1 × 500
Given: Molar Mass of Na, O and H is 40 450
23,16 and 1gmol−1 respectively V1 = 180
83 If wavelength of the first line of the 492;
Paschen series of hydrogen atom is 1 1 1
= RH Z2 ( − )
720 nm, then the wavelength of the (𝜆1 )p 9 16
second line of this series is _____ nm. 1 1 1
(Nearest integer) = R H Z2 ( − )
(𝜆2 )p 9 25
7
(𝜆2 )p 16×9 25 × 7
= 16 =
(𝜆1 )p 16 × 16
25×9
25 × 7
(𝜆2 )P = × 720
16 × 16
(𝜆2 )P = 492 nm
84 The number of correct statement/s C;
from the following is _______ Ea
A: k = 𝐴eRT
A. Larger the activation energy, smaller As Ea increases k decreases
is the value of the rate constant. k
B: Temperature coefficient = T+10
k T
B. The higher is the activation energy, Option (C) is wrong. Δk may be greater
higher is the value of the temperature or lesser depending on temperature.
coefficient.
𝐸𝑎
C. At lower temperatures, increase in 𝐷: ln⁡ 𝑘 = ln⁡ 𝐴 −
𝑅𝑇
temperature causes more change in the
value of k than at higher temperature.
1
D. A plot of ln⁡ k vs is a straight line
T
𝐸𝑎
with slope equal to − 𝑅
85 At 298 K, a 1 litre solution containing 917;
10mmol of Cr2 O7 ⁡2− and 100mmol of Cr2 O2− +
7 + 14H + 6e → 2Cr
− 3+ + 7H O
2
Cr 3+ shows a pH of 3.0. 0.059 (0.1)2
Given: Cr2 O7 ⁡2− → Cr 3+ ; E0 = 1.330 V 𝐸 = 1.33 − log⁡
6 (10−2 )(10−3 )14
2.303RT
and F = 0.059 V 0.059
𝐸 = 1.33 − × 42 = 0.917
The potential for the half cell reaction 6
is x × 10−3 V. The value of 𝑥 is ______ 𝐸 = 917 × 10−3
𝑥 = 917
86 When Fe0.93 O is heated in presence of 4;
oxygen, it converts to Fe2 O3 . The Fe0.93 O → Fe2 O3
number of correct statement/s from 200
nf = (3 − ) × 0.93
the following is _____ 93
nf = 0.79
 A. The equivalent weight of Fe0.93 O is B: 2x + (0.93 − x) × 3 = 2
molecular weight x = 0.79
0.79 Fe2+ = 0.79, Fe3+ = 0.21
C: Fact
B. The number of moles of Fe2+ and 0.79
D: %Fe2+ = × 100 = 85%; Fe3+
Fe3+ in 1 mole of Fe0.93 O is 0.79 and 0.93
0.14 respectively. = 15%

C. Fe0.93 O is metal deficient with lattice

comprising of cubic closed packed
arrangement of O2− ions.
D. The % composition of Fe2+ and Fe3+
in Fe0.93 O is 85% and 15%
respectively.
87 The d-electronic configuration of 7;
[CoCl4 ]2− in tetrahedral crystal field is Co2+ : 3 d7 4 s0 , Cl− : WFL
𝑒 m 𝑡2 ⁡𝑛 . Sum of ' 𝑚 ' and 'number of
unpaired electrons is ______

Configuration e4 t 2 ⁡3 : m = 4
Number of unpaired electrons = 3
So, answer = 7
88 For independent process at 300 K. 2;
A: ΔG(Jmol−1 ) = −25 × 103 + 80 × 300: −ve
Process Δ𝐇/kJmol−1 Δ𝐒/𝐉 −1
B: ΔG(Jmol−1 ) = −22 × 103 − 40 × 300: −ve
C: ΔG(Jmol−1 ) = 25 × 103 + 300 × 50: +ve
A −25 −80
D: ΔG(Jmol−1 ) = 22 × 103 − 20 × 300: +ve
Processes C and D are non-spontaneous.
B −22 40

C 25 −50

D 22 20

The number of non-spontaneous

process from the following is ______
89 Uracil is base present in RNA with the 25;
following structure. % of N in uracil is Mol. Wt. of C4 N2 H4 O2 = 112
______ 28
%N= × 100 = 25%
112

Given:
Molar mass N = 14 g mol−1 ; O =
16 g mol−1 ; C = 12 g mol−1 ; H =
1 g mol−1
90 Number of moles of AgCl formed in the 2;
following reaction is ______ Benzylic and tertiary carbocations are
stable.

#81,82,8 NUMERICAL TYPE

3,84,85,
86,87,88
,89,90