CHEM TEST 04 (Gaseous State) SF
CHEM TEST 04 (Gaseous State) SF
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1. If the pressure of a certain amount of gas is reduced to th (b) Volume of the gas is equal to the volume of the
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of its initial pressure at a fixed Temperature, then what container
would be its final volume? (c) Confined gas exerts uniform pressure on the wall of
(a) 2 times b) 3 times the container in all directions
(c) 4 times d) 6 times (d) Real gases obey all gas laws at all T and P
2. At which temperature the real gas behaves as an ideal 13. What happens to the volume of a given mass of a gas
gas? when both its temperature (K) and pressure are doubled?
(a) At high pressure and low temperature; (a) Reduced by 1/4 (b) Increase 4 times
(b) At low-pressure and high temperature; (c) Is unchanged (d) None of these
(c) At low pressure and low temperature; 14. The volume of a given mass of a gas is 2 liter at 10oC
(d) AT high pressure and high temperature; keeping the pressure constant; at what temperature the
3. The molecules of a gas 𝐴 travel four times faster than the volume would be 4 liters?
molecules of gas 𝐵 at same temperature. The ratio of (a) 5 𝑜𝐶 (b) 20 𝑜𝐶
𝑜
molecular weights 𝐴 and 𝐵 is (c) 283 𝐶 (d) 293 𝑜𝐶
(a) 5: 2 (b) 4:1 15. Which one of the following has the highest pressure?
(c) 3: 2 (d) 16:3 (a) 1 mole of 𝑂2 at 0oC in 11.2 liters container
4. Which of the following pair will diffuse at the same rate? (b) 1 mole of 𝑂2 at 2oC 22.4 liters container
(a) 𝐶𝑂2 and 𝑁2 𝑂 (b) 𝐶𝑂2 and 𝑁𝑂 (c) 1 mole of 𝐶𝑂2 at 10oC in 22.4 liters container
(c) 𝐶𝑂2 and 𝐶𝑂 (d) 𝑁2𝑂 and 𝑁𝑂 (d) 1 mole of 𝐶𝑂2 at 20oC is 11.2 liters container
5. When pressure is constant, at which temp: the volume of 16. Hydrogen gas diffuses six times faster than gas A. The
a gas will become twice what it is at 0℃: molar mass of gas is:
(a) 546℃ (b) 200℃ (a) 72 (b) 6
(c) 546𝐾 (d) 273𝐾 (c) 24 (d 36
6. If the absolute Temp: of gas is doubled and pressure is 17. A gas contract at constant temperature is due to:
reduced to one-half the volume of the gas will: (a) pressure is increases
(a) Remains unchanged (b) pressure is decreases
(b) Increases four times (c) Both a & b
(c) Reduces to one-fourth (d) None
(d) Be doubled 18. Which of the following relationship is true?
V
7. The total pressure of a mixture of two gases is: (a) nR
(a) The sum of the partial pressures of gases T
(b) The difference between the partial pressures 1
(b) V T
(c) The product of the partial pressures of gases P
(d) The ratio of the partial pressures (c) o
C o F 273
8. If helium and methane are allowed to diffuse out of the rA mA
(d)
container at same temperature and pressure, then the rB mB
ratio of rate of diffusion of helium to methane is: 19. A mixture contains equal masses of O2 & H2 at constant
(a) 2: 1 (b) 1: 2 temperature. The ratio of their partial pressures will be:
(c) 3: 5 (d) 4: 1 (a) 8: 1 (b) 8: 2
9. The volume occupied by 16𝑔 of Sulphur dioxide at 273 (c) 16: 1 (d) 1: 4
degrees and 1520 torr pressure is 20. 3 moles of He and 4 moles of Ar are enclosed in a vessel
(a) 5.6𝑑𝑚3 (b) 11.2𝑑𝑚3 under same conditions of temperature & pressure. The
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(c) 22.4𝑑𝑚 (d) 1.6𝑑𝑚3 partial pressure of “He” is :
10. 55 grams of 𝐶𝑂2 at 𝑆𝑇𝑃 occupies
(a) 3 4 of the total pressure
(a) 44.8 𝑑𝑚3 (b) 55 𝑑𝑚3
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(c) 28 𝑑𝑚 (d) 22.4 𝑑𝑚3 (b) 4 3 of the total pressure
11. Which of the following will have the same number of
molecules at 𝑆𝑇𝑃: (c) 4 7 of the total pressure
(a) 280 𝑐𝑚3 of 𝐶𝑂2 and 280 𝑐𝑚3 of 𝑁2 𝑂
(b) 44𝑔 of 𝐶𝑂2 and 11.2 𝑑𝑚3 𝐶𝑂 (d) 3 7 of the total pressure
(c)11.2 𝑑𝑚3 𝑜𝑓 𝑂2 and 32𝑔 𝑜𝑓 𝑂2 21. Which of the following is Vander Waal’s equation?
(d) 28𝑔 𝑜𝑓 𝑁2 and 5.6 𝑑𝑚3 of oxygen (a) PV nRT
12. Which statement is incorrect for gases? an 2
(a) Gases do not have definite shape and volume (b) ( P )(v nb) nRT
v2
ENTRY -24 JAI PRAKASH (JP)
THE SCIENCE FOUNDATION QASIMABAD CLASS TEST_04 (GAS)
47. Which of the following gas will exert more pressure: (d) Volume
(a) 64g O2 (b) 66g CO2 62. Which of the following pairs have same rate of diffusion:
(c) 6g H2 (d) 160g SO3 (a) H2 and He (b) O2 and CH4
48. The ratio of volume to its absolute temperature is always (c) CO2 and CO (d) N2 and CO2
constant. This is according to: 63. Which of the following pairs gas at STP contains more
(a) Boyle’s law (b) Charles law molecules:
(c) Avogadro’s law (d) Dalton’s law (a) 8g H2 (b) 96g oxygen
49. Which is correct order of rate diffusion of following gases: (c) 16g SO3 (d) 213g CI2
(a) H2 > He> SO2> CH4 (b) He> H2> CH4> CO2 64. Proposed a volume - pressure relation of gases:
(c) SO2 > CH4> He> H2 (d) H2 > He> CH4> SO2 (a) Avogadro’s constant (b) Boyle’s law
50. Which is not variable of Ideal gas equation: (c) Charle’s law (d) Dalton’s law
(a) P (b) V 65. Two containers having 1mole of Helium gas and 1mole of
(c) n (d) R methane gas respectively are opened. What will be ratio
51. The volume of R in atm dm3 mole-1 K-1: of the rate of the Helium to that of Methane?
(a) 8.314 (b) 0.0821 (a) 4:1 (b) 16:4
(c) 0.821 (d) 0.00821 (c) 2:1 (d) 1:2
52. If gas is heated from 60˚C, at what temperature in 66. At 1atm pressure and 273K how many moles of a gas are
celciusits volume will be doubled: present in 33.6 liter?
(a) 120˚C (b) 666˚C (a) 1 (b) 1.5
(c) 393˚C (d) 546˚C (c) 1.75 (d) 2
53. Which of the following contains more molecules: 67. Graham’s Law refer’s to:
(a) 6g H2 (b) 1m3 of oxygen (a) Boiling point of gas
(c) 32g O2 (d) 22g CO2 (b) Gases compression
54. Dolton’s law of partial pressure is not valid when: (c) Volume changes of gases when the pressure changes
(a) Oxygen gas is collected over water (d) Gaseous diffusion
(b) Nitrogen gas is collected over water 68. According to kinetic molecular theory kinetic energy of
(c) CO2 gas is collected over water molecules increases when they:
(d) Hydrogen gas is collected over water (a) Are frozen into solid
55. Which is expression of Charle’s law: (b) Are condensed into a liquid
(a) PV = K (b) V∝n (c) Are melted from solid to a liquid state
(c) V ∝1/T (d) V/T = K (d) Colloide with each other in a container at low temp
56. 16g of oxygen at S.T.P occupy: 69. If are density of a diatomic gas is 1.43 gram/liter what is
(a) 22.4 dm3 (b) 11.2 dm3 its gram molecular mass.
(c) 33.6 dm 3
(d) 5.6 dm3 (a) 16g (b) 32g
57. Which has more mass: (c) 48g (d) 64g
(a) 1 dm3of CO2 (b) 1 dm3 ofO2 70. Four grams of hydrogen at STP contains:
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(c)1 dm of SO2 (d) 1dm3 of H2 (a) 12.04 × 1023 𝑎𝑡𝑜𝑚𝑠
58. Gases can easily be easily compressed because: (b)12.04 × 1023 𝑎𝑡𝑜𝑚
(a) The particles are very small (c) 12.04 × 1023 𝑚𝑜𝑙𝑒𝑐𝑢𝑙𝑒𝑠
(b) There is plenty of space b/w the particles (d) 12.04 × 1023 𝑎𝑡𝑜𝑚𝑠
(c) The particles can move about very quickly 71. What volume of gas, in liters would 1.5 moles of hydrogen
(d) The particles are in random arrangement occupy at STP?
59. Which is correct order of rate of diffusion of gases: (a) 11.2 (b) 22.4
(a) CH4> O2> CI2> N2 (c) 33.6 (d) 44.8
(b) CH4> N2> O2> CI2 72. 5.6 liters of gas at STP have a mass of 16g rams. What is
(c) N2> CH4> O2> CI2 the molecular mass of the gas?
(d) CH4> CI2>O2 N2 (a) 16𝑔 (b)32𝑔
60. At STP which gas has low density: (c) 48𝑔 (d) 64𝑔
(a) N2 (b) O2 73. If the molecular mass of NH3 is 17, what is the density of
(c) CH4 (d) CI2 this compound at STP?
61. One mole of CO2 and one ole of O2 at STP have same: (a) 0.25𝑔/𝐿 (b) 0.75𝑔/𝐿
(a) Relative molar mass (c) 1.52𝑔/𝐿 (d) 3.04𝑔/𝐿
(b) No. of atoms 74. 𝑃𝑉 = 𝑛𝑅𝑇 is not valid for:
(c) Ratio of rate of diffusion (a) Ideal gases (b) Real gases
(c) Perfect gases (d) All of these
ENTRY -24 JAI PRAKASH (JP)
THE SCIENCE FOUNDATION QASIMABAD CLASS TEST_04 (GAS)
75. Which of the following gas exerts more pressure. (a) 2atm (b) 0.8 atm
(a) 48g oxygen (b) 3g H2 (c) 8 atm (d) 0.4 atm
(c) 64g SO2 (d) 8g He 84. The rate of diffusion of a gas having molecular weight just
76. Real gases deviate from ideal behavior at: double of 𝑁2 gas is 56 𝑚𝐿𝑠 −1. The rate of diffusion of 𝑁2
(a) Low pressure high temperature will be:
(b) Low pressure low temperature (a) 79.19 𝑚𝐿𝑠 −1 (b) 56 𝑚𝐿𝑠 −1
−1
(c) High pressure high temperature (c) 112.0 𝑚𝐿𝑠 (d) 90.0 𝑚𝐿𝑠 −1
−1
(d) High pressure low temperature (e) 210 𝑚𝑠
77. An open flask contains air at 25oC. To what temp., the 85. Relative rates of diffusions of two gases 𝑋 and 𝑌 are
flask should be heated to expel one fifth of the air found to be 3: 2. If the density of 𝑌 is 27 the density of 𝑋
measured at 25oC? is.
(a) 49.25 oC (b) 99.5 oC (a) 27 (b) 54
o
(c) 125 C (d) 200 oC (c) 4 (d) 12
78. A gas mixture contains O2 and H2 in the ratio of 16: 1 by 86. Which pair of gases have same rate of diffusion at 𝑆𝑇𝑃?
weight. The ratio of their number of molecules in the (a) 𝐻2 and 𝑁𝑂2 and 𝐶𝑂 (b) 𝐶𝑂2 and 𝐶3 𝐻8
mixture is : (c) 𝐶𝑂2 and 𝑆𝑂2 (d) None of these
(a) 1 ∶ 1 (b) 1 ∶ 8 87. According to the Ideal Gas Law, what is the approximate
(c) 3 ∶ 16 (d) 7 ∶ 32 volume that will be occupied by 0.5 moles of an ideal gas
79. Consider the following relationship : at 30℃ and 3𝑎𝑡𝑚 Pressure
(Gas constant 𝑅 = 0.0821 𝐿. 𝑎𝑡𝑚/𝑚𝑜𝑙. 𝐾)?
(a) Less than 1𝐿 (b) 5𝐿
(c) 10𝐿 (d) 15𝐿
(e) More than 20𝐿
88. The rate of diffusion of a gas is
(a) Directly proportional to its density
(b) Directly proportional to its molecular weight
(c) Inversely proportional to square root of the molecular
density
Which of the following is correct statement? (d) Inversely proportional to square root of the formula
(a) Pressure on the gas is inversely proportional to its
(e) Inversely proportional to its molecular weight.
density at given temperature
89. Comparative rates of diffusion of 𝐻𝑒 and 𝑆𝑂2 will be
(b) T1>T2>T3
(a) 8 (b) 2
(c) T1<T2<T3
(c) 4 (d)16
(d) Both a & b
(e) 64
80. Two cylinders A & B of equal volumes are filled as under
90. Ideal Gas Equation is obtained by combining.
A. 2.2g of hydrogen gas at STP
(a) Boyle's Law, Dalton's Law and Charles's Law
B. 4.4g of helium at 0oC & 2atm
(b) Boyle's Law, Charles's Law and Avogadro's Law
If gases are allowed to escape from cylinders, then which
(c) Dalton's Law, Charles's Law and Avogadro's Law
gas highest rate of diffusion in the beginning?
(d) Boyle's Law, Dalton's Law and Avogadro's Law
(a) Hydrogen
(e) All of the above
(b) Helium
91. In the Boyle's Law, if the volume of a gas is plotted v/s
(c) Both gases have same rate of diffusion
reciprocal of the pressure, the curve obtained is:
(d) None
(a) Parabolic curve (b) Hyperbole curve
81. Sudden expansion of a gas causes :
(c) Straight line (d) Symbolic
(a) Cooling (b) Heating
(e) All of the above
(c) Pressure (d) None of these
92. Which phenomenon of physical chemistry occurs when
82. The time taken for the effusion of 10 L He from a hole of
you tissue paper on a wet surface?
diameter 2mm is 15sec. What will be time taken by 5L of
(a) Evaporation (b) Capillary action
CH4 to effuse from the same hole?
(c) Boiling (d) Condensation
(a) 30sec (b) 45sec
93. 𝑃𝑉 = 𝐾 represents:
(c) 60sec (d) 15sec
(a) Boyle's law (b) Avogadro's law
83. A vessel of 120 mL capacity contains a certain amount of
(c) Charles's law (d) Graham's law
gas at 35 °C and 1.2 atm pressure. The gas is transferred
(e) Dalton's law
to another vessel of volume 180 mL at 35 °C. What would
94. What volume does 400 cm³ sample of a gas at 700 torr
be its pressure?
occupy when the pressure is changed to 2𝑎𝑡𝑚?
ENTRY -24 JAI PRAKASH (JP)
THE SCIENCE FOUNDATION QASIMABAD CLASS TEST_04 (GAS)
(a) 1.40000 𝑐𝑚³ (b) 184 𝑐𝑚³ (a) I only (b) II only
(c) 0.0184 𝑐𝑚³ (d) 140 𝑐𝑚³ (c) III only (d) IV only
(e) 0.00184 𝑐𝑚³ (e) I and II
95. If volume of a gas is plotted against the total pressure, the 104. If absolute temperature of a gas is doubled and the
curve obtained would be: pressure is reduced to one half, the volume of the gas will
(a) Straight line (c) Parabolic curve (a) Remain unchanged (b) Increases four times
(c) Hyperbolic curve (d) Exponential curve (c) Reduce to 1/4 (d) Be doubled
(e) None of the above (e) Decrease four times
96. 300𝑚𝐿 of a gas at 27℃ is cooled to 3℃ at constant 105. The formula for general gas equation is:
pressure. Its final volume is: (a) 𝑃1 𝑉1 = 𝑃2 𝑉2 (b) 𝑉1 /𝑇1 = 𝑉2 /𝑇2
(a) 135 𝑚𝐿 (b) 540 𝑚𝐿 (c) 𝐸 = 𝑚𝑐 2 (d) 𝑃1 𝑉1 /𝑇1 = 𝑃2 𝑉2 /𝑇2
(c) 300 𝑚𝐿 (d) 350 𝑚𝐿 106. The molecular mass of 𝑆𝑂2 , is 64 and molecular
(e) 276 𝑚𝐿 mass of He is 4 than He diffuses how many times
97. 1 liter of a gas weighs 2𝑔 at 300 𝐾 and 1𝑎𝑡𝑚 . If the greater than 𝑆𝑂2 .
pressure is made 75 𝑎𝑡𝑚, at which of the following (a) 2 times (b) 4 times
temperatures will 1𝐿 of the same gas weigh 1𝑔? (c) 16 times (d) 12 times
(a) 450 K (b) 800 K 107. At constant temperature the volume of gas 95 𝑐𝑚3 at a
(c) 600 K (d) 900 K pressure of 9.961 × 104 𝑁/𝑚2. What would be its
98. Which of the following pairs of gases has same rate of volume at 10.13 × 104 𝑁/𝑚2?
diffusion? (a) 1𝑐𝑚3 (b) 94.8𝑐𝑚3
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(a) 𝐶𝑂2 and 𝑁2 𝑂 (b) 𝐶𝑂2 and 𝐶𝑂 (c) 93.4𝑐𝑚 (d) 10𝑐𝑚3
(c) 𝑁𝑂2 and 𝐶𝑂2 (d) 𝐶𝑂2 and 𝑁2𝑂4 108. The ratio of the rate of diffusion of two gases is
99. Hydrogen diffuses six times faster than gas A. The 1: 3, and then ratio of their molecular wt. is:
molar mass of gas A is: (a) 13 (b) 31
(a) 16 (b) 36 (c) 1.9 (d) 91
(c) 6 (d) 24 109. Total pressure is equal to the sum of partial
(e) 72 pressure of all the individual gases due to following
100. "The total pressure of mixture of gases is the sum of reason:
partial pressures of the gases in the mixture" is the (a) Collisions with the walls of the container
statement of: (b) Effective collision of all individual gases
(a) Boyle's law (c) Collision with the bottom of the container
(b) Graham's law of diffusion (d) None of the above
(c) Avogadro's law 110. "Equal volume of gases at the same temperature and
(d) Charles's law pressure contains same number of molecules" This law
(e) Dalton's law of partial pressure can be represented as________
101. A sample of argon occupies 50𝐿 at standard temp. (a) 𝑉 ∝ 𝑇 (b) 𝑉 ∝ 1/𝑃
Assuming constant pressure, what volume will the gas (c) 𝑉 ∝ 𝑛 (d) 𝑉 ∝ 𝑚
occupy if the temperature is doubled? 111. The temperature 273 k corresponds to:
(a) 25𝐿 (b) 50𝐿 (a) 0℃ (b) 273℃
(c) 100𝐿 (d) 200𝐿 (c) 100℃ (d) None of the above
(e) 2500𝐿 112. What volume does 400 𝑐𝑚3 of sample of at 700 𝑡𝑜𝑟𝑟
102. All of the following statements undefined the kinetic occupy when the pressure in changed to 2 𝑎𝑡𝑚. (Assume
molecular theory of gasses EXCEPT: temperature is constant)
(a) Gas molecules have no intermolecular forces (a) 368 𝑐𝑚3 (b) 184 𝑐𝑚3
(b) Gas particles are in random motion (c) 170 𝑐𝑚3 (d) 870 𝑐𝑚3
(c) The collision between gas particles are elastic 113. The average speed and average kinetic energy of gas
(d) Gas particles have no volume molecules are directly proportional to the_______
(e) The average kinetic energy is proportional to the (a) ℃ (Centigrade temp)
temp of the gas (b) ℉ (Fahrenheit)
103. Four containers of equal volume are filled as follows: (c) 𝐾 (Kelvin temp)
I. 2.0𝑔 𝐻2 at 0℃ (d) None of the above.
II. 1.0𝑔 𝐻2 at 273℃ 114. Volumes of given mass of a gas varies __________
III. 24𝑔 𝑂2 at 0℃ (a) Inversely (b) Directly
IV. 16𝑔 𝐶𝐻4 at 273℃ (c) Three times (d) None of the above
Which container is at the greatest pressure? 115. The particles of gas can be described as:
ENTRY -24 JAI PRAKASH (JP)
THE SCIENCE FOUNDATION QASIMABAD CLASS TEST_04 (GAS)