F6 Mock Exam 20-21 (Paper 1) : Marking Scheme

1 D 11 D 21 C 31 A

2 D 12 C 22 C 32 A

3 A 13 B 23 B 33 C

4 B 14 D 24 A 34 B

5 B 15 C 25 D 35 A

6 C 16 D 26 D 36 D

7 D 17 B 27 D

8 C 18 A 28 A

9 B 19 C 29 B

10 C 20 B 30 D
1. (a) 2 M HCl(aq) 1 3. (a) CaC2 : strong ionic bonds between ions 1
Nitric acid can react with silver and C2H2: weak van der Waals’ forces between molecules 1
CH3CO2H is a weak acid and it gives a slow rate of reaction 1 / weak intermolecular forces
(b) (i) It increases electrical conductivity of the solution/acts as 1 (b) 1
electrolyte/mobile ions to complete circuit
(ii) Ag+ occupies at a lower position than that of Na+ in
electrochemical series. 1 (c)
.
xx x
H x C x xx C H
x .
-
(iii) 4 OH → O2 + 2 H2O + 4 e- 1
(iv) Sacrificial protection of more reactive chromium/nickel 1 1
/impermeable oxide layer of chromium/nickel
(c) Sulphur dioxide
Brown iodine is reduced by SO2 to form colourless iodide ions 1
Oxidation number of iodine change from 0 to -1 1
(d)
2. (a) Drying agent/absorb water vapour in air 1 (i)
(b) Ca(NO3)2(aq); Na2SO4(aq):
1 5
Mix two solutions and stir; filter out CaSO4(s); stay overnigh/oven C2H2 (g) + O2 (g)
1 2
Dry by filter paper.
enthalpy 1
(c) Anhydrous CuSO4(s): from white to blue
1
or anhydrous CoCl2(s): from blue to pink 2 CO2(g) + H2O (l)
(d) Soft paste can be used to cover the broken limb and then it gives a
1
hard cast to fit the shape of broken bone. The cast can prevent the
movement of bones. (ii)
Hf
(e) (i) Reasonable average = (8.30 + 8.25 + 8.35)/3 = 8.30 cm3 2 C(s) + H2(g) C2H2(g)
1 1
No. of mole of H+ in 100 cm3 = 0.0105 x 0.0083 x 10
= 8.715 x 10-4 1 Hc(H2(g)) +
Hc(C2H2(g))
No of mole Ca = (½) (no. of mole of H+)
2+
2x Hc(C(s))
[Ca2+] = (½) (8.715 x 10-4)/0.025 = 0.01743 M 1 CO2 (g) + H2O(l) 1
(ii) concentrated HCl 1 Hf = 2 (-397) + (-286) – (- 1299) = + 219 kJmol -1
1
[conc HNO3 is an oxidizing agent; H2SO4 can precipitates out some (iii) Metal atoms are held together by strong metallic bonds and
metal ions] high temperature provides sufficient heat to melt the metal. 1
4. (a) Cu S H O (c) It increases the rate of reaction and shorten the time to reach the 1
state of equilibrium
Mass/g 56.2 7.1 1.3 35.4
No change in equilibrium constant because no temperature change
Mole 0.88 0.22 1.3 2.21 1 The catalyst increases both the rate of forward reaction and the rate 1
Mole of backward reaction to the same extent. 1
4 1 6 10
ratio 1 6. (a) At 2000 C: Mg is in vapour state; Al is in molten liquid state
o

Empirical formula : Cu4SH6O10 Delocalized electrons are found in liquid Al 1

(b) 3 Cu(OH)2 + Y = : Cu4SH6O10 Y: CuSO4 1 (b) In liquid state, metallic bonds are still present in liquid metals and
(c) high temperature provides more heat to overcome strong metallic 1
2- - 2 bonds to give vapour state. The molecules are held together by weak
[Cu(EDTA) (aq)] [ OH (aq)] 4 2 -6 1 van der Waal’s forces. Only a small amount of energy is needed for 1
K= 4- = 8.3 x 10 mol dm
[EDTA (aq)] liquid state to vapour state.
(c) Molecular size: S8 > P4 > Cl2 > Ar 1
2 4
( 10000 ) ( x ) = 8.3 x 10 As the molecular size/mass increases, the strength of van der Waal’s
1 1
x = 2.88 forces between molecules increases.
(d) (i)
[H+(aq)] [2.88)] = 10-14 ; [H+(aq)] = 3.47 x 10-15
pH = - log [H+(aq)] = 14.5 1
(d) conc. HNO3 gives out brown fumes; conc. H2SO4 gives colourless 1 1
gas bubbles
brown fumes: nitrogen dioxide, NO2; colourless gas: SO2 1 (ii) strong covalent bonds between silicon and carbon atoms in giant 1
(e) Electroplating; production of lead-acid rechargeable cell 1 covalent structure
5. (a) t1: As the volume decreases, the concentrations of NO(g) and Br2(g) 1 (iii) Silicon carbide is more corrosion-resistant than metals which 1
increases. The frequency of collision increases, the rate of reaction can be oxidized by oxygen in air
increases. 1 7 (a) The same structural formula with different arrangement of atoms in 1
t1 to t2 :As the total number of gaseous reactants is more than that of space
gaseous products, the equilibrium position shifts to right. (b) Substitution 1
t3: At equilibrium, the rate of reaction becomes a constant. 1 (c) (i) 4-bromopent-2-ene 1
(b) (ii) B No reaction with Na2Cr2O7/H+ Q is 3o alcohol 1+1
(iii)
OH
1 1
(b) Q R 1
8. (a) (i) Hydrogen; nickel or platinum 1 10. (a) More hydrogen bonds between molecule HOCH2CH2OH 1
(ii) O O (b) Na2O reacts with water to give an alkali while MgO reacts
1 slowly with water to form water-insoluble Mg(OH)2(s) 1
OH Trans (c) LPG: smaller molecular size of LPG burns more completely to
H
(b) (i) O give less toxic CO and particulates 1
CH3 C- O - C
(d) Electronegativity of F is higher than O and so H-F is more
CH2
polar than O-H 1
C C
1 (e) Number of delocalized electrons: Mg > Na;
H H
Strength of metallic bond Mg > Na 1
(ii) No, it contains ester group which undergoes alkaline hydrolysis 1
O O
(f) Aluminium: impermeable layer of Al2O3 prevents the contact
O 1
(c) conc. H2SO4
between Al metal and water/air 1
O 1. NaBH4, dry ether
OH OH OH
O 1 (g) The strength of intermolecular forces between iodine
2. H2O/H + heat 1 molecules is similar to that between hexane molecules 1
(d) J: strong hydrogen bonds between molecules of J
K: weak van der Waaals’ forces between molecules of K 1
11. -
e flow external circuit
(e) J: carboxyl group -CO2H reacts with NaHCO3 to form ionic organic > V
- + 1 Salt bridge
product, -CO2 Na which has strong interactions with water filter paper soaked with KNO3(aq)
9. Dissolve all solids in water to give aqueous solutions. Only CaCO3(s) is 1
KI(aq) KMnO4/H +
water-insoluble. 1
1 carbon - carbon
Heat all with NaOH: only NH4NO3 gives out pungent smell NH3 turns wet Electrode A + Electrode B 1
(anode) (-) (cathode) (+)
red litmus paper blue.
1
Adding 1 M HCl(aq): only NaHCO3 and CaCO3 give colourless gas Measure the voltage of two cells.
bubbles. Only CaCO3(s) is water-insoluble Higher voltage obtained indicates higher oxidizing power 1
1
Flame test: NaHCO3: golden yellow flame; CaCl2 /CaCO3: brick red flame Fair test: the same concentration of KMnO4(aq) and
1
Adding acidified Ba(NO3)2: only MgSO4 gives white precipitate (BaSO4) K2Cr2O7(aq) 1
Adding acidified AgNO3: only CaCl2 gives give white precipitate (AgCl) 1
Heating: only hydrated CaCl2 (s) and hydrated MgSO4 give a gas that 1
turns dry cobalt(II) chloride paper from blue to pink