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Class Xii CH 3 Worksheet

This document is a revision worksheet for Grade XII students at Krishnaswamy Vidyanikethan Senior Secondary School, focusing on Chapter 3: Chemical Kinetics. It includes various questions related to reaction rates, order of reactions, rate constants, and the effects of temperature and catalysts on reaction rates. The worksheet aims to help students understand key concepts and calculations in chemical kinetics.

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Anto Bhavin
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5 views3 pages

Class Xii CH 3 Worksheet

This document is a revision worksheet for Grade XII students at Krishnaswamy Vidyanikethan Senior Secondary School, focusing on Chapter 3: Chemical Kinetics. It includes various questions related to reaction rates, order of reactions, rate constants, and the effects of temperature and catalysts on reaction rates. The worksheet aims to help students understand key concepts and calculations in chemical kinetics.

Uploaded by

Anto Bhavin
Copyright
© © All Rights Reserved
We take content rights seriously. If you suspect this is your content, claim it here.
Available Formats
Download as DOCX, PDF, TXT or read online on Scribd
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KRISHNASWAMY VIDYANIKETHAN SENIOR SECONDARY SCHOOL

GRADE XII
REVISION WORKSHEET
CHAPTER 3 CHEMICAL KINECTICS

elements 𝑋 and 𝑌 is 1gm each. What will be the ratio of 𝑋 and 𝑌 after two days if their half-
1. (A) Radioactive decay follows first-order kinetics. The initial amount of two radioactive

lives are 12 hours and 16 hours respectively?


(B) The hypothetical reaction 𝑃 + 𝑄 → 𝑅 is half order w.r.t ' 𝑃 ' and zero order w.r.t ' 𝑄 '.
What is the unit of rate constant for this reaction? [CBSE SQP 2023]
2. How will the rate of reaction be affected when:
(A) surface area of the reactant is reduced,
(B) temperature of the reaction is increased, and
(C) catalyst is added in a reversible reaction? [CBSE 2020]
3. Write units of rate constant for zero order and for the second order reactions if the
concentration is expressed in molL−1 and time in second. [CBSE 2015]
4. Define rate of reaction. Write two factors that affect the rate of reaction. [CBSE 2015]
5. A first order reaction takes 20 minutes for 50% completion. Calculate the time required for
90% completion of this reaction. log 2 = 0.30) [Delhi Gov. SQP Term-2 2022]
6. In the given reaction 𝐴 + 3𝐵 → 2𝐶, the rate of formation of 𝐶 is 2.5 × 10−4 mol L−1 s−1.
Calculate the: (A) rate of reaction, and (B) rate of disappearance of 𝐵. [CBSE 2020]
8. For the reaction, 2 N2O5( g) → 4NO2( g) + O2( g), the rate of formation of NO2( g) is 2.8 ×
10−3 Ms−1. Calculate the rate of disappearance of N2O5( g). [CBSE 2018]
RATE LAW, ORDER & MOLECULARITY
Very Short & Short Qs [1 − 3 marks]
9. (A) The conversion of molecule 𝐴 to 𝐵 followed second order kinetics. If concentration of A
increased to three times, how will it affect the rate of formation of 𝐵?
(B) Define Pseudo first order reaction with an example. [CBSE 2023]
10. For a reaction: 2H2O2 I alkaline medium 2H2O + O2 the proposed mechanism is as given
below: (1) H2O2 + I− → H2O + IO−(slow) (2) H2O2 + IO− → H2O + I− + O2 (fast)
(A) Write rate law for the reaction.
(B) Write the overall order of reaction.
(C) Out of steps (1) and (2), which one is rate determining step? [CBSE 2019]
11. For a reaction: H2 + Cl2 ⟶ hv 2HCl; Rate = 𝐤 (A) Write the order and molecularity of this
reaction. (B) Write the unit of k. [CBSE 2016]
12. For a reaction: 2NH3(𝑔) ⟶ Pt N2(𝑔) + 3H2(𝑔); Rate = 𝑘. (A) Write the order and
molecularity of this reaction.
(B) Write the unit of 𝑘. [CBSE 2016]
13 "Chemical reactions proceed at vastly different speeds depending on the nature of the reacting
substances, the type of chemical transformation, the temperature, and other factors." Give an
insight on the "specific rate" of a reaction. [Mod. CBSE 2014]
14. (A) For a reaction 2NH3 → N2 + 3H2 (in the presence of Pt catalyst at 1130 K ), Rate = k.
Write the order of the reaction and unit of the rate constant of the reaction.
(B) Write three differences between order of reaction and molecularity of the reaction. [Delhi
Gov. SQP Term-2 2022]
INTEGRATED RATE EQUATION
15. Answer the following questions (Do any two)
(A) Identify the order of reaction from the following unit for its rate constant: Lmol −1 s−1.
(B) The conversion of molecules A to B follow second order kinetics. If concentration of 𝐴 is
increased to three times, how will it affect the rate of formation of 𝐵?
(C) Write the expression of integrated rate equation for zero order reaction. [CBSE Term-2
2022)
16. A first-order reaction takes 69.3 min for 50% completion. What is the time needed for 80%
of the reaction to get completed? (Given: log 5 = 0.6990, log 8 = 0.9030, log 2 = 0.3010 ).
[CBSE SQP 2022]
17. A first order reaction is 40% completed in 80 minutes. Calculate the value of rate constant
(𝑘). In what time will the reaction be 90% completed? [Given: log 2 = 0.3010, log 3 = 0.4771,
log 4 = 0.6021, log 5 = 0.6771, log 6 = 0.7782] [CBSE 2020]
18. Write the slope value obtained in the plot of In [𝑅] vs time for a first order reaction. [CBSE
2020]
19. The decomposition of NH3 on platinum surface is zero order reaction. If rate constant (k) is 4
× 10−3Ms−1, how long will it take to reduce the initial concentration of NH3 from 0.1M to
0.064M[CBSE 2019]
20. Define half-life of a reaction. Write the expression of half-life for: (A) zero order reaction
and (B) first order reaction. [CBSE 2014]
21. Define the type of a reaction in which a bimolecular reaction becomes first order reaction, by
stating the condition. [Mod. CBSE 2014]
22. "The half-life of a radionuclide is important 𝑛 determining the safety of food that has been
radioactively contaminated." Define "half-life" period of a reaction. [Mod. CBSE 2014]
EFFECT OF TEMPERATURE & CATALYST ON RATE OF THE REACTION

Calculate the value of 𝐸𝑎 (Given 2.303R = 19.15JK−1 mol−1) [CBSE SQP 2023]
23. The rate constants of a reaction at 200 K and 500 K are 0.02 s−1 and 0.20 s−1 respectively.

24. A first order reaction is 50% complete in 30 minutes at 300 K and in 100 minutes at 320K.
Calculate activation energy (𝐸𝑎) for the reaction. [𝑅 = 8.314JK−1 mol−1] [Given: log 2 = 0.3010,
log 3 = 0.4771, log 4 = 0.6021] [CBSE 2023]
25. Explain how and why will the rate of reaction for a given reaction be affected when: (A) a
catalyst is added (B) the temperature at which the reaction was taking place is decreased. [CBSE
SQP 2022]
26. Draw the plot of In 𝑘 vs 1/𝑇 for a chemical reaction. What does the intercept represent?
What is the relation between slope and E ? [CBSE 2019]
27.. A first order reaction is 50% complete in 50 minutes at 300 K and the same reaction is again
50% complete in 25 minutes at 350 K. Calculate activation energy of the reaction. [CBSE SQP
2019]

(△ 𝐺) of a reaction? [CBSE 2017]


28.What is the effect of adding a catalyst on: (A) Activation energy (𝐸𝑎), and (B) Gibbs energy

29. The rate of a first order reaction increases from 2 × 10−2 to 4 × 10−2 when the temperature
changes from 300 K to 310 K. Calculate the activation energy (𝐸𝑎). (log 2 = 0.301, log 3 =
0.4771, log 4 = 0.6021) [CBSE 2015]
30. The rate constants of a reaction at 500 K and 700 K are 0.02 and 0.07 s−1 respectively.
Calculate the value of E ? [CBSE 2015]
31. How does a change in temperature affect the rate of a reaction? How can this effect on the
rate constant of reaction be represented quantitatively? [CBSE 2014]
Numerical Qs [1 - 5 marks]

: 𝑘 = (2.5 × 1014 s−1)𝑒(−25000)/T


32. The rate constant for the first order decomposition of N2O3 is given by the following equation

Calculate E𝑎 for this reaction and rate constant if its half-life period be 300 minutes. [CBSE
2020]
33. The rate of a reaction becomes four times when the temperature changes from 293 K to 313
K. Calculate the energy of activation (𝐸𝛼) of the reaction assuming that it does not change with
temperature. [𝑅 = 8.134 J K−1 mol−1, log 4 = 0.6021] [CBSE 2019]
34. A first order reaction is 50% completed in 80 minutes at 300 K and in 10 minutes at 320 K.
Calculate the activation energy(Ea) for the reaction. (Given: log 2 = 0.3010, log 4 = 0.6021, log 3
= 0.4771 R = 8.314 J K−1 mol−1) [CBSE 2018]

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