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Introductory Course For Themodynamics 2

1) The document discusses key concepts in chemical engineering thermodynamics including the analysis of thermodynamic cycles like the Rankine, Carnot, Otto, and Diesel cycles. 2) Key terms discussed include heat, work, efficiency, entropy, phase changes, vapor-liquid equilibrium, bubble/dew points, refrigeration, and Raoult's law. 3) The document is from the Adamson University Chemical Engineering Society and covers topics relevant to chemical engineering thermodynamics.

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John Aguila
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47 views3 pages

Introductory Course For Themodynamics 2

1) The document discusses key concepts in chemical engineering thermodynamics including the analysis of thermodynamic cycles like the Rankine, Carnot, Otto, and Diesel cycles. 2) Key terms discussed include heat, work, efficiency, entropy, phase changes, vapor-liquid equilibrium, bubble/dew points, refrigeration, and Raoult's law. 3) The document is from the Adamson University Chemical Engineering Society and covers topics relevant to chemical engineering thermodynamics.

Uploaded by

John Aguila
Copyright
© Attribution Non-Commercial (BY-NC)
We take content rights seriously. If you suspect this is your content, claim it here.
Available Formats
Download as PDF, TXT or read online on Scribd
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Adamson University Chemical Engineering Society

CHE THERMODYNAMICS 2 Chemical engineering thermodynamics 2 is all about the application of laws of thermodynamics to open systems and its applications to industrial processes. Analysis of Cycles: 1) 2) 3) 4) 5) Heat supplied Heat rejected Net work Efficiency Mean effective pressure Step 1-2 Isobaric heat addition Step 2-3 Isentropic expansion Step 3-4 Isobaric heat rejection Step 4-1 Isentropic compression

Rankine Cycle

Heat Engine or Thermal Engine a closed system (no mass crosses its boundaries) that exchanges only heat and work with its surroundings and that operates in cycles. Carnot Cycle is a cycles which consists of two isothermal and two isentropic processes. Nicolas Leonard Sadi Carnot devised and analyzed the Carnot cycle and became the father of thermodynamics. Temperature vs Entropy diagram of a carnot cycle Water working medium Saturated liquid (black) Saturated vapor (red)

Internal Combustion Engines Air Standard Otto Cycle

State 1 saturated vapor State 2 saturated mixture State 3 saturated mixture State 4 saturated liquid Step 4 1 Isothermal Heat adsorption Step 1 2 Isentropic Expansion Step 2 3 Isothermal Heat rejection Step 3 4 Isothermal Compression

AngeloMagnaye|2012

Adamson University Chemical Engineering Society


Diesel Cycle Vapor Compression Cycle

Ton of refrigeration = rate of heat removal of 1 ton of water initially at 320F to freeze it in a hour. 1 ton of refrigeration = 12,000 BTU/hr = 12,660 KJ/hr

Solutions Thermodynamics

Brayton Cycle

Bubble Point and Dew Point 1) The bubble point is the point at which the first drop of a liquid mixture begins to vaporize. 2) The dew point is the point at which the first drop of a gaseous mixture begins to condense. Txy and Curve) Pxy diagrams (Vapor-Equilibrium

Vaporliquid equilibrium (VLE) is a condition where a liquid and its vapor (gas phase) are in equilibrium with each other, a condition or state where the rate of evaporation (liquid changing to vapor) equals the rate of condensation (vapor changing to liquid) on a molecular level such that there is no net (overall) vapor-liquid interconversion.

Refrigeration: For Carnot refrigeration:

AngeloMagnaye|2012

Adamson University Chemical Engineering Society


Raoult's Law Ptot = P1 + P2 + y1 = P1/Ptot, y2 = P2/Ptot, P1 = x1 P01, P2 = x2 P02 P1(T) = x1 P01(T), P2(T) = x2 P02(T) Flash Distillation

F=L+V 1=L+V xF = xiL + yi V

ion of

AngeloMagnaye|2012

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