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Fugacity

The document discusses the concept of fugacity in thermodynamics and chemistry and how it relates to the concentration and transport of chemicals between different environmental compartments such as air, water, soil, and biota. It provides equations to calculate fugacity in various phases and compartments and considers factors like properties, conditions, and transport mechanisms.

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Truong Nguyen
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35 views18 pages

Fugacity

The document discusses the concept of fugacity in thermodynamics and chemistry and how it relates to the concentration and transport of chemicals between different environmental compartments such as air, water, soil, and biota. It provides equations to calculate fugacity in various phases and compartments and considers factors like properties, conditions, and transport mechanisms.

Uploaded by

Truong Nguyen
Copyright
© © All Rights Reserved
We take content rights seriously. If you suspect this is your content, claim it here.
Available Formats
Download as PPTX, PDF, TXT or read online on Scribd
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Art & Nature

Connection Between Art and the Great Outdoors


2.1
Fugacity và
Fugacity Capacity
Fugacity là gì?
Fugacity is a concept in thermodynamics and physical chemistry that describes the
“escaping tendency” of a substance from a system. It's a measure of the tendency
of a substance to escape or vaporize from a mixture, relative to an ideal gas

Ký hiệu: f
Fugacity level III domain model

Transport
Compartment Affect the
Chemicals of the concentration
environment
Chemicals
Air, water, soil,
biotas, sediment

→ Models for calculating these concentration in each of compartments


Fugacity level III domain model
Các công thức của fugacity
(1) Air phase (Ideal gas eq)

(2) Water phase

Trong đó, Φ là hệ số fugacity C1 là nồng độ cấu tử trong air phase


y là phần mol trong air phase C2 là nồng độ cấu tử trong water phase
x là phần mol trong water phase Ps là áp suất hơi bão hòa
PT là áp suất tổng Z1, Z2 lần lượt là fugacity trong air, water phase
𝛾 là hệ số hoạt độ
Các công thức của fugacity
(3) Solid phase

Trong đó,
Kd là hệ số phân bố cân bằng (L solution/kg solids) hay hệ số góc của sorption isotherm
C2 là nồng độ trong pha lỏng (mol/L)
Cs là nồng độ bị hấp phụ/thụ (mol/L)
Koc là hệ số phân bố organic carbon-based (L/kg)
H là hằng số Henry
ρ là mật độ pha (kg solid/m3 solid)
Các công thức của fugacity
Table. Fugacity Capacity (Z) Values
❖The "Fugacity model" is a modeling framework used to predict the
distribution and movement of chemicals in different environmental
compartments such as air, water, soil, and biota.
❖It considers various factors such as chemical properties, environmental
conditions, and transport mechanisms to estimate the concentrations of
chemicals in each compartment over time
2.2
Intermedia Transport
Transport between environmental compartments
What is intermedia transport?
Chemicals move between environmental compartments by
Volatilization from water
❖Diffusive processes to air or soil to air
❖Non-diffusive processes

Characteristics of diffusive processes


❖Can proceed in more than one direction
❖Depending on the fugacity difference between compartments

The diffusive rate of transfer


What is intermedia transport?
Non-diffusive transport is one-way diffusive transport, such as
❖rain washout
❖dry/wet deposition atmospheric particles to soil and water
❖sediment deposition and resuspension
Can be described by:

Where G is volumetric flow rate (m3/h)


C is phase concentration (mole/m3)
All of the intermediate diffusive and non-diffusive transport mechanisms within the model domain

Air/Water Transport (D12 - D21)


Air-Soil Transport (D13 - D31)
Water-Sediment Transport (D24 - D42)
Soil to Water Transport (D32)
Advective Transport
Case study
Biogas to syngas through the combined Steam/Dry
Reforming Process: An Environmental Impact Assessment
Case study
Method for Environmental Impact Assessment

ReCiPe2016 Method

Life cycle assessment (LCA)


Cumulative energy
demand (CED
Collecting Materials
• Old magazines and newspapers

• Scissors

• Glue

• Recycled cardboard or poster board

• Markers or colored pencils


Eco-Collage Project
• Arrange and glue down the materials you've collected to

express your environmental message.

• Remember to focus on color and composition to make

your message clear.

• Add your own drawings, symbols, or messages to make

it uniquely yours.

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