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MTP 2

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Ananta Sarkar
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55 views19 pages

MTP 2

Uploaded by

Ananta Sarkar
Copyright
© © All Rights Reserved
We take content rights seriously. If you suspect this is your content, claim it here.
Available Formats
Download as PPTX, PDF, TXT or read online on Scribd
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DEVELOPMENT OF DOPED SODIUM VANADIUM FLURO-

PHOSPHATE CATHODE MATERIALS FOR SODIUM ION


BATTERIES

Presented by:

Sameer Tirkey

Roll No - 22CH60R14

Under the supervision of

Prof. Ananta Kumar Sarkar

DEPARTMENT OF CHEMICAL ENGINEERING

INDIAN INSTITUTE OF TECHNOLOGY KHARAGPUR


Outline
 Introduction
 Objective
 Components of battery
 Why commercialize battery
 Different cathode materials
 Why NVPF
 Sodium Vanadium Fluorophosphate
 Synthesis of NVPF by sol-gel method
 Synthesis of NVPF by hydrothermal method
 Structural analysis
 Morphological analysis
 Functional group analysis
 Conclusion
 Future plan
 Acknowledgment
2
Introduction

 Energy crisis

 Energy storage devices

 Battery

 Sodium-ion battery

3
Objective

To investigate the impact of Sodium


vanadium fluorophosphate as cathode
material for sodium-ion batteries and
techniques to enhance its performance
and durability.

4
Introduction
Battery

Electrochemical devices that convert chemical
energy into electrical energy.

Consists of two electrodes (cathode and anode)
and an electrolyte.

Chemical reaction in a battery involves the
flow of electrons from one electrode to
another. in a battery involve the flow of
electrons from one electrode to another Fig1: Electrochemical cell
[1]

5
Components of Battery

 Electrodes
 Electrolyte
 Separators
 Terminal
 Current collectors

Fig 2: Battery
Components[2] 6
Sodium Vanadium Fluorophosphates

 Class of cathode materials known as sodium


vanadium fluorophosphate (NVPF)
 Three-dimensional vanadium-oxygen
polyhedral linked by phosphate and fluoride
groups
 Result in a higher energy density
 Abundance of the elements in NVPF
materials
Fig 4: NVPF crystal
 Strong thermal stability and inexpensive structure[4]
7
Why NVPF.?

MERITS DRAWBACKS

High thermal stability Limited research

Low cost Low conductivity

High operating voltage Safety concerns

Environmentally friendly Limited temperature range

Good electrochemical
performance

Table 1: Merits and Drawbacks

8
Synthesis of Doped NVPF by Sol-Gel Method
TiO2

Fig 5: Ti doped NVPF sample made by sol-gel method [5]


9
Structural Analysis

Fig 6: XRD patterns of a) NVPF b) NVPF doped TiO2-0.02 c) NVPF doped


TiO2-0.05 10
Morphological Analysis

Fig 7: FESEM Images of the Ti-doped NVPF samples


12
Morphological Analysis

Fig 8: FESEM Images of the NVPF samples


12
Electrochemical Analysis

Galvanostatic Charge Discharge

Fig 9: GCD curve of NVPF-Ti-0.02 and NVPF-Ti- 0.05 samples at different cycles
13
Cyclic Voltammetry

Fig 10. CV curve of NVPF-Ti-0.02 sample at different cycles


14
Conclusion
 We successfully synthesized NVPF and Ti-doped NVPF by the
cost-effective Sol-gel method.
 The structural and morphological analysis done by XRD and
FESEM of the prepared materials respectively.
 The NVPF-Ti-0.02 doped sample has the best performance of all
the samples tested in electrochemical tests, with a specific capacity
of 130 mAh/g after 60 cycles of charging and discharging. This
means that it has a lot of potential as a cathode material for SIBs.

15
Acknowledgment

 I would like to thank my supervisor Prof. Ananta Sarkar for always


guiding and encouraging me.
I would also like to thank my HOD B.C. Meikap and all the faculty
members.

 I would like to thank our institute for all the financial support and the
Department of Chemical Technology for providing all the lab facilities.

 I would also like to thank my all lab members.

16
Future Plan

 Scaling up production, and integrating into full cells for practical application

17
References
1. K. Ohishi et al., “Sodium Diffusion in Hard Carbon Studied by Small- and Wide-Angle Neutron Scattering and Muon Spin Relaxation,”
in Journal of Physics: Conference Series, Institute of Physics, 2023

2. A. Lennon et al., “High-rate lithium-ion energy storage to facilitate increased penetration of photovoltaic systems in electricity grids,”
MRS Energy and Sustainability, vol. 6, no. 1. Springer Nature, Dec. 01, 2019

3. T. Wang, W. Zhang, H. Li, J. Hu, Y. Lai, and Z. Zhang, “N-Doped Carbon Nanotubes Decorated Na 3V2(PO4)2F3as a Durable Ultrahigh-
rate Cathode for Sodium-Ion Batteries,” ACS Appl Energy Mater, vol. 3, no. 4, pp. 3845–3853, Apr. 2020

4. V. Shipitsyn, R. Jayakumar, W. Zuo, B. Sun, and L. Ma, “Understanding High-Voltage Behavior of Sodium-Ion Battery Cathode
Materials Using Synchrotron X-ray and Neutron Techniques: A Review,” Batteries, vol. 9, no. 9. Multidisciplinary Digital Publishing
Institute 2023

5. Y. Qin et al., “Effect of chelator content on the structural and electrochemical performance of Na 3V2(PO4)2F3 by sol-gel preparation,”
CrystEngComm, vol. 24, no. 25, pp. 4519–4526, May 2022

18
Thank You

19

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