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Caesium, ₅₅Cs
Caesium
Pronunciation	/ˈsiːziəm/ (SEE-zee-əm)
Alternative name	cesium (US)
Appearance	pale gold
Standard atomic weight Ar°(Cs)
	132.90545196±0.00000006; 132.91±0.01 (abridged);
Caesium in the periodic table
	xenon ← caesium → barium
Atomic number (Z)	55
Group	group 1: hydrogen and alkali metals
Period	period 6
Block	s-block
Electron configuration	[Xe] 6s1
Electrons per shell	2, 8, 18, 18, 8, 1
Physical properties
Phase at STP	solid
Melting point	301.7 K (28.5 °C, 83.3 °F)
Boiling point	944 K (671 °C, 1240 °F)
Density (at 20° C)	1.886 g/cm3
when liquid (at m.p.)	1.843 g/cm3
Critical point	1938 K, 9.4 MPa
Heat of fusion	2.09 kJ/mol
Heat of vaporization	63.9 kJ/mol
Molar heat capacity	32.210 J/(mol·K)
Atomic properties
Oxidation states	common: +1; −1
Electronegativity	Pauling scale: 0.79
Ionization energies	1st: 375.7 kJ/mol ; 2nd: 2234.3 kJ/mol ; 3rd: 3400 kJ/mol ; ;
Atomic radius	empirical: 265 pm
Covalent radius	244±11 pm
Van der Waals radius	343 pm
	Spectral lines of caesium
Other properties
Natural occurrence	primordial
Crystal structure	body-centered cubic (bcc) (cI2)
Lattice constant	a = 616.2 pm (at 20 °C)
Thermal expansion	92.6×10−6/K (at 20 °C)
Thermal conductivity	35.9 W/(m⋅K)
Electrical resistivity	205 nΩ⋅m (at 20 °C)
Magnetic ordering	paramagnetic
Young's modulus	1.7 GPa
Bulk modulus	1.6 GPa
Mohs hardness	0.2
Brinell hardness	0.14 MPa
CAS Number	7440-46-2
History
Naming	from Latin caesius 'bluish grey', for its spectral colours
Discovery	Robert Bunsen and Gustav Kirchhoff (1860)
First isolation	Carl Setterberg (1882)
Isotopes of caesium v; e;
β−	134Ba
	Category: Caesium; view; talk; edit; \| references

^ "Standard Atomic Weights: Caesium". CIAAW. 2013.
^ Prohaska, Thomas; Irrgeher, Johanna; Benefield, Jacqueline; Böhlke, John K.; Chesson, Lesley A.; Coplen, Tyler B.; Ding, Tiping; Dunn, Philip J. H.; Gröning, Manfred; Holden, Norman E.; Meijer, Harro A. J. (2022-05-04). "Standard atomic weights of the elements 2021 (IUPAC Technical Report)". Pure and Applied Chemistry. doi:10.1515/pac-2019-0603. ISSN 1365-3075.
^ ^a ^b ^c Arblaster, John W. (2018). Selected Values of the Crystallographic Properties of Elements. Materials Park, Ohio: ASM International. ISBN 978-1-62708-155-9.
^ Haynes, William M., ed. (2011). CRC Handbook of Chemistry and Physics (92nd ed.). Boca Raton, Florida: CRC Press. p. 4.121. ISBN 1-4398-5511-0.
^ Dye, J. L. (1979). "Compounds of Alkali Metal Anions". Angewandte Chemie International Edition. 18 (8): 587–598. doi:10.1002/anie.197905871.
^ "Magnetic susceptibility of the elements and inorganic compounds". Handbook of Chemistry and Physics (PDF) (87th ed.). CRC press. ISBN 0-8493-0487-3. Retrieved 2010-09-26.
^ Kondev, F. G.; Wang, M.; Huang, W. J.; Naimi, S.; Audi, G. (2021). "The NUBASE2020 evaluation of nuclear properties" (PDF). Chinese Physics C. 45 (3): 030001. doi:10.1088/1674-1137/abddae.
^ "NIST Radionuclide Half-Life Measurements". NIST. Retrieved 2011-03-13.

[1] "Standard Atomic Weights: Caesium". CIAAW. 2013.

[CIAAW2021-2] Prohaska, Thomas; Irrgeher, Johanna; Benefield, Jacqueline; Böhlke, John K.; Chesson, Lesley A.; Coplen, Tyler B.; Ding, Tiping; Dunn, Philip J. H.; Gröning, Manfred; Holden, Norman E.; Meijer, Harro A. J. (2022-05-04). "Standard atomic weights of the elements 2021 (IUPAC Technical Report)". Pure and Applied Chemistry. doi:10.1515/pac-2019-0603. ISSN 1365-3075.

[Arblaster_2018-3] Arblaster, John W. (2018). Selected Values of the Crystallographic Properties of Elements. Materials Park, Ohio: ASM International. ISBN 978-1-62708-155-9.

[b92-4] Haynes, William M., ed. (2011). CRC Handbook of Chemistry and Physics (92nd ed.). Boca Raton, Florida: CRC Press. p. 4.121. ISBN 1-4398-5511-0.

[caeside2-5] Dye, J. L. (1979). "Compounds of Alkali Metal Anions". Angewandte Chemie International Edition. 18 (8): 587–598. doi:10.1002/anie.197905871.

[magnet-6] "Magnetic susceptibility of the elements and inorganic compounds". Handbook of Chemistry and Physics (PDF) (87th ed.). CRC press. ISBN 0-8493-0487-3. Retrieved 2010-09-26.

[NUBASE2020-7] Kondev, F. G.; Wang, M.; Huang, W. J.; Naimi, S.; Audi, G. (2021). "The NUBASE2020 evaluation of nuclear properties" (PDF). Chinese Physics C. 45 (3): 030001. doi:10.1088/1674-1137/abddae.

[isotope-8] "NIST Radionuclide Half-Life Measurements". NIST. Retrieved 2011-03-13.

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