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Ammonia Storage O2 Calculation

The document summarizes calculations to determine the amount of oxygen in liquid ammonia in a storage tank. It provides the total pressure, temperature, and molecular fractions of ammonia and oxygen in the vapor and liquid. It then calculates the vapor pressure of oxygen using the Antoine equation. Finally, it uses Raoult's law and the vapor pressure to determine the molecular fraction and ppm of oxygen in the liquid ammonia is 0.03806 ppm.

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lokeshmishra123
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104 views2 pages

Ammonia Storage O2 Calculation

The document summarizes calculations to determine the amount of oxygen in liquid ammonia in a storage tank. It provides the total pressure, temperature, and molecular fractions of ammonia and oxygen in the vapor and liquid. It then calculates the vapor pressure of oxygen using the Antoine equation. Finally, it uses Raoult's law and the vapor pressure to determine the molecular fraction and ppm of oxygen in the liquid ammonia is 0.03806 ppm.

Uploaded by

lokeshmishra123
Copyright
© Attribution Non-Commercial (BY-NC)
We take content rights seriously. If you suspect this is your content, claim it here.
Available Formats
Download as XLS, PDF, TXT or read online on Scribd
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Conditions taken

Total pressure in vessel Temperature of storage tank Mol. Fraction of ammonia in vapour Mol. Fraction of oxygen in vapour Mol. Fraction of ammonia in liquid
Variables to calculate

PT =
T= yNH3 =

600 -33 0.999 0.001 0.998

yO2 =

xNH3 = xO2
P*O2

Mol. Fraction of oxygen in liquid Vapour pressure of O2 By Antoine equation


Log P = A - B/(T+C) A= B= C= 6.69 319.01 266.69

= =

A,B,C values taken from " Lange's Handbook of chemistry " From above equation vapor pressure of oxygen at this temperature P*02 = P*02 =
By Roults law

PT= P*NH3 (xNH3) + P*02 (x02) PT= PT (yNH3) + P*02 (x02) X02 = PT (1- yNH3) / P*02 X02 = 3.80557E-06 X02 = 0.038055727

ppm

Amount of oxygen in liquid is

= 0.03806 ppm

mmWC = C (10ppm)

15.55338 psia

211300.7 mm Hg

4087 psia

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